KESAVA N K CHAITANYA G Dr. G. V .R. PRASADA RAJ U P.G Student Professor Department of Civil Engineering Dr. K. RAMU University College of Engineering Associate Professor KAKINADA-533003::INDIA.
ABSTRACT
Expansive soils, such as black cotton soils, are basically susceptible to detrimental volumetric changes, with changes in moisture. This behavior of soil is attributed to the presence of mineral montmorillonite, which has an expanding lattice. In the present work, experimentation is carried-out to investigate the influence of strong electrolyte viz. potassium chloride, calcium chloride and ferric chloride on the properties of expansive soil. A methodical process, involving experimentation in the laboratory under controlled conditions is done. It is observed form the laboratory studies that maximum improvement in the properties of Expansive soil is for Ferric Chloride treatment compared to other electrolytes tried in this investigation.
Expansive soil cover large tracts of several world nations and in India; these deposits are known by the name, black cotton soils which occupy about 20% of its surface area. In India, these soils are predominant in the states of Gujarat, Maharashtra, Madhya Pradesh, Andhra Pradesh, Karnataka and Tamilnadu. After recognizing the problems posed by these soils to civil engineering structures, Engineers from all parts of the world have been trying to find solutions. Among several techniques adopted to overcome the problems posed by expansive soils, lime stabilization gained prominence during the past few decades due to its abundance and adaptability (Snethan et al, 1979). However, it is reported (Chen, 1988) that lime stabilization suffers from the major drawback of difficulty in soil pulverization and mixing of with it. Recent studies (Ramana Murthy, 1998; Srinivas,(2008), D. Koteswararao, (2011)). indicated that CaCl 2 could be an effective alternative to conventional lime used due to its ready dissolvability in water and to supply adequate calcium ions for exchange reactions. Katti et al (1966) made an attempt to stabilize the in-situ soil using KOH solution and they revealed that it is possible to alter the properties of black cotton soils in place by treating them with aqueous solution of KOH. Frydman et al (1977) studied the use of KCl to modify heavy clay in the laboratory and revealed that from engineering point of view, the use of KCl as a stabilizer appears potentially promising in locations where it is readily and cheaply available. In the present work, the efficiency of Potassium Chloride (KCl), Calcium Chloride (CaCl 2 ) and Ferric Chloride (FeCl 3 ) , as stabilizing
agents, was extensively studied in the laboratory for improving the properties of expansive soil.
Kesava N K Chaitanya G et al. / International Journal of Engineering Science and Technology (IJEST) ISSN : 0975-5462 Vol. 3 No.12 December 2011 8298 1.2 OBJECTIV E The objective of the present work is to study the impact of the electrolytes like KCl, CaCl 2 and FeCl 3 on the properties of expansive soil with laboratory.
1.3 MATERIALS USED The details of the various materials and chemicals used in the laboratory experimentation are reported in the following sections.
1.3.1 Soil The black cotton soil collected from Kothapeta near Amalapuram, in East Godavari District, Andhra Pradesh State, India. The properties of soil are presented in the table. All the tests carried on the soil are as per IS specifications. Table.1. Properties of Expansive soil
1.3.2 Chemicals Used Commercial grade KCl, CaCl 2 and FeCl 3 was used in this study. The quantity of Chemicals was varied from 0 to 1.5% by dry weight of soil. 1.4 LABORATORY EXPERIMENTATION
1.4.1 Index Properties S.No Property Value 1. Grain size distribution Sand (%) Silt (%) Clay (%)
0.46 2 Kesava N K Chaitanya G et al. / International Journal of Engineering Science and Technology (IJEST) ISSN : 0975-5462 Vol. 3 No.12 December 2011 8299 Different percentages of chemicals (ranging from 0-1.5% by weight) were mixed with soil (for all the combinations as listed in the table) and the liquid limit, plastic limit and shrinkage limit were determined as per IS:2720 (part-5)-1985; IS:2720 (part-6)-1972.
1.4.2 Compaction Properties Optimum moisture content and maximum dry density of the black cotton soil were determined according to the IS Heavy weight compaction test (IS:2720 part-8,1983).
1.4.3 Differential Free Swell (DFS) The DFS values for all the combinations listed in table and also of the untreated soil, were determined as per IS:2720-part XL-1977.
1.4.4 Strength Tests Tri-axial test, California bearing ratio and Unconfined compressive strength were found for all the soil combinations, as presented.
1.5 LABORATORY TEST RESULTS ON CHEMICAL STABILIZATION
In the laboratory, index tests and strength tests were conducted by using different percentages of chemicals with a view to determine the optimum percentage of chemical. The effect of addition of different chemicals to the expansive soil on the Atterberg limits, differential free swell and strength properties are discussed in detail in the following sections.
. Table.2. Effect of strong electrolytes on Index Properties of expansive soil
Chemical Percentages of chemical Index properties WL (%) P.L. (%) I P
Kesava N K Chaitanya G et al. / International Journal of Engineering Science and Technology (IJEST) ISSN : 0975-5462 Vol. 3 No.12 December 2011 8300
Fig.1.Effect of chemicals on liquid limit
Fig.2.Variation of Plastic limit
Fig.3.Variation of plasticity Index 0 20 40 60 80 100 0 0.5 1 1.5 2 L i q u i d
L i m i t
( % ) (%) Chemical Potassium Chloride Calcium Chloride Ferric Chloride 36.5 37 37.5 38 38.5 39 39.5 40 40.5 0 0.5 1 1.5 2 P l a s t i c
L i m i t
( % ) (%) Chemical Potassium Chloride Calcium Chloride Ferric Chloride 0 5 10 15 20 25 30 35 40 45 0 0.5 1 1.5 2 P l a s t i c i t y
I n d e x
( % ) (%) Chemical Potassium Chloride Calcium Chloride Ferric Chloride Kesava N K Chaitanya G et al. / International Journal of Engineering Science and Technology (IJEST) ISSN : 0975-5462 Vol. 3 No.12 December 2011 8301
Fig.4.Variation of Shrinkage Limit
1.5.1 Effect of Additives on Atterberg Limits
The decrease in the liquid limit values for different percentages of chemicals added to the expansive soil is presented in the Table.2. The decrease in the values of liquid limit upto 1% of chemical is significant for all the chemicals, as shown in Fig.1. Beyond 1% there is a nominal decrease in the liquid limit values, for all the chemicals, tried in this investigation. For FeCl 3 treatment there is maximum decrease in the values of the liquid limit when compared with other two chemicals viz. KCl and CaCl 2 . There is a nominal increase in the values of the plastic limit with the increase in the percentage of the chemical. The increase in the plastic limit values and the reduction in the liquid limit values cause a net reduction in the values of plasticity index. For 1% chemical, it is observed that, the reduction in plasticity index values are of the order of 35%, 45% and 68% for KCl, CaCl 2 and FeCl 3 treatment respectively with respect to the untreated soil. The effect of KCl, CaCl 2 and FeCl 3 treatments on plasticity index of expansive clay as observed in the laboratory testing are shown in Tables.2. and Fig 3. It can be seen from the figure that, the FeCl 3
treatment has effectively controlled the plasticity index compared to other additives. The shrinkage limit values are increased by 13%, 18% & 22% respectively for 1% KCl, CaCl 2 and FeCl 3 treatments. The reduction in plasticity index, with FeCl 3 treatment could be attributed to the depressed double layer thickness due to cation exchange by trivalent Ferric ions and increased electrolyte concentration, as the chemical is completely soluble in water
Table 3: Effect of Chemical on DFS
0 5 10 15 20 0 0.5 1 1.5 2 S h r i n k a g e
L i m i t
( % ) (%) Chemical Potassium Chloride Calcium Chloride Ferric Chloride chemical
% chemical
D F S (%)
KCl 0 110 0.5 90 1 75 1.5 70 0 110 CaCl 0.5 80 1 70 1.5 65 0 110 FeCl 0.5 70 1 55 1.5 50 Kesava N K Chaitanya G et al. / International Journal of Engineering Science and Technology (IJEST) ISSN : 0975-5462 Vol. 3 No.12 December 2011 8302
Fig 5. Variation of DFS
1.5.2 Effect of Additives on DFS
The variation of D.F.S. for different percentages of the chemicals is shown in the Table.3& Fig 5. There is a significant decrease in D.F.S. values upto 1% of the chemical, after that the change is marginal. The reduction in the values of D.F.S. at 1% chemical are at the order of 32%, 37% and 50% for KCl, CaCl 2 and FeCl 3 treatments respectively in comparison with untreated soil. The reduction in DFS values could be supported by the fact that the double layer thickness is suppressed by cation exchange with trivalent ferric ions and increased electrolyte concentration. .
Table 4: Effect of Chemical on CBR
Fig 6. Variation of CBR
0 20 40 60 80 100 120 0 0.5 1 1.5 2 D F S
( % ) (%) Chemical Potassium Chloride Calcium Chloride Ferric Chloride 0 1 2 3 4 5 6 0 0.5 1 1.5 2 C B R
( % ) (%) Chemical Potassium Chloride Calcium Chloride Ferric Chloride chemical
% chemical
CBR(soaked)
KCl 0 2.00 0.5 2.66 1 3.96 1.5 4.22 CaCl 0.5 2.82 1 4.50 1.5 4.75 FeCl 0.5 3.06 1 5.00 1.5 5.30 Kesava N K Chaitanya G et al. / International Journal of Engineering Science and Technology (IJEST) ISSN : 0975-5462 Vol. 3 No.12 December 2011 8303 1.5.3 Effect of Additives on CBR The CBR values are increased by 98%, 125% , 150% when treated with 1% KCl, 1%CaCl 2 &1% FeCl 3 as shown in Table 4 & Fig .6. The increase in the strength with addition of chemicals may be attributed to the cation exchange of KCl, CaCl 2 & FeCl 3 between mineral layers and due to the formation of silicate gel. The reduction in strength beyond 1% each of KCl, CaCl 2 & FeCl 3 may be due to the absorbtion of more moisture at higher KCl, CaCl 2 & FeCl 3 contents.
Table 5: Effect of Chemical on shear strength parameters
1.5.4 Effect of Additives on Shear Parameters The significant improvement of shear parameters was observed, when treated with 1%KCl, 1%CaCl 2 , and 1% FeCl 3 respectively as shown in Table 5.
Table 6: Effect of Chemical on UCS
chemical (%) chemical Shear strength Parameters (c, ) in Kg/cm & degrees
KCl 1 day 7 days 14days 0 0.46,2 0 ----- ---- 0.5 0.51,6 0 1.02,5 0 1.12,3 0
FeCl 0 84 ------ ------ 0.5 134 238 251 1.0 174 260 296 1.5 127 217 243 Kesava N K Chaitanya G et al. / International Journal of Engineering Science and Technology (IJEST) ISSN : 0975-5462 Vol. 3 No.12 December 2011 8304
Fig 7. Variation of UCS in 14 days curing Period
1.5.5 Effect of Additives on UCS
The UCS values are increased by 147%, 189% and 252% when treated with KCl, CaCl 2 and FeCl 3 . The increase in the strength with addition of chemicals may be attributed to the cation exchange of KCl, CaCl 2 and FeCl 3 between mineral layers and due to the formation of silicate gel. The reduction in strength beyond 1% each of KCl, CaCl 2 and FeCl 3 , may be due to the absorbtion of more moisture at higher KCl, CaCl 2 & FeCl 3 contents.
The optimum percentage of different additives observed during the laboratory experimentation are summarized and presented in the following Table.
1.6 CONCLUSIONS The following conclusions are made based on the laboratory experiments carried out in this investigation.
1. From the laboratory studies, it is observed that the liquid limit values are decreased by 18%, 23% and 33% respectively for 1% of KCl, CaCl 2 and FeCl 3 . There is a decrease in the values of plasticity index with respective chemical treatment because of the decrease in liquid limit and increase in the plastic limit values. Plasticity index is decreased by 35%, 48% and 68% respectively for 1% of KCl, CaCl 2 , FeCl 3 . 2. The Shrinkage Limit values are increased by 13%, 18% & 22% respectively for 1% KCl, CaCl 2 and FeCl 3 treatments. 3. The Differential free swell values are decreased by 32%, 37% and 50% for 1% KCl, 1% CaCl 2 , 1% FeCl 3 respectively with respect to the untreated soil. 4. There is a significant improvement in plasticity and DFS upto 1% chemical, after that the change is marginal. 5. The CBR values are increased by 98%, 125% & 150% respectively for 1% KCl, CaCl 2 and FeCl 3
treatments. 6. The significant improvement of shear parameters was observed, when treated with 1%KCl, 1%CaCl 2 , and 1% FeCl 3 respectively 7. The UCS values, are increased by 147%, 189% and 252% respectively for 1% KCl, CaCl 2 and FeCl 3
treatments, for a curing period of 14 days. 0 50 100 150 200 250 300 350 0 0.5 1 1.5 2 U C S
K P a (%) Chemical Potassium Chloride Calcium Chloride Ferric Chloride Additives Optimum percentage KCl CaCl 2
FeCl 3 1 1 1 Kesava N K Chaitanya G et al. / International Journal of Engineering Science and Technology (IJEST) ISSN : 0975-5462 Vol. 3 No.12 December 2011 8305 8. It is observed that, the UCS values are increased for all the three chemicals up to 1% and later the strength decrease in trend is observed.
REFERENCES
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Kesava N K Chaitanya G et al. / International Journal of Engineering Science and Technology (IJEST) ISSN : 0975-5462 Vol. 3 No.12 December 2011 8306