JEE Advanced 2013 Paper 1 PCM All India Test Series Solutions

AITS-FT-IV-(Paper-1)-PCM(S)-JEE(Advanced)/13
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1

ANSWERS, HINTS & SOLUTIONS
FULL TEST IV
(Paper-1)

Q. No. PHYSICS CHEMISTRY MATHEMATICS
1.
D A C
2.
B B A
3.
C D A
4.
D B D
5.
C C B
6.
B A C
7.
A A A
8.
A C C
9.
C C D
10.
D D B
11.
B, D D B, C, D
12.
A, B A, B, C A, B, D
13.
A, C A, C, D A, C, D
14.
A, B, C B, C, D A, B, C, D
15.
A, B, C, D B, C, D A, B, C
1.
2 6 4
2.
9 2 9
3.
6 3 3
4.
2 3 8
5.
3 8 9

A
L
L

I
N
D
I
A

T
E
S
T

S
E
R
I
E
S

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4
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7
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2
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1
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9

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2


2
P Ph hy ys si ic cs s PART I

SECTION A

1. On heating a metal sheet, distance between any two points increases.

2. Heat taken by ice to convert to water at 100C fully :
5 (40) (0.5) + 5 80 + 5 (100) (1) = 1000 cal.
Heat given by steam to condense fully :
2 500 = 1000 cal. Hence everything will be water at 100C.

3. WAB + WBC + WCD + WDA = Q { U = 0 in cyclic process}
WAB + 0 + nRT0 ln
0
0
V
3V
| |
|
\ .
+ nR (2T0 T0) = 4nRT0 { DA is isobaric process}
get WAB = nRT0 ln3 + 3nRT0

4. As > , no collision will occur with the wall and the ball is doing SHM
with amplitude only.
T = 2
g
.

5. As the fluid is at rest; pressure at the same horizontal level in a connected fluid is same if it is at
equilibrium.

6. The magnetic field will make electrons revolve around the direction of B. It may cause some
electrons not to reach the collector plate. If it is very strong; it will not let electrons reach the
collector. As the magnitude is not given, hence photo current may decrease.
7. The work done by cell = =

V
0
Vdq CVdV =
1
2
CV
2
.

8. As the magnet-1 falls into solenoid A, the magnetic
flux associated with solenoid A increases. From
Lenz's law, induced current in solenoid A will oppose
this increase in magnetic flux. Hence direction of
induced current in solenoids is as shown.
The nature of magnetic field produced by solenoid B is
as shown. Therefore magnet 2 will be attracted by
magnetic field due to solenoid B.

9. at t = 0
R
eq.
=
(4 2) 6
6 6
+
+
+ 7 = 3 + 7 = 10


3
i
1
=
10
10
= 1 A.
at t =
7 +
4 6
6 4
+
= 9.4

i
2
=
10
9.4
so
1
2
i 1
i (10/ 9.4)
= = 0.94

10. Power delivered by mg is converted to the heat dissipated in R
1
and R
2

mgv =
1 2
R R
P P +
solving, we get
2
R
P = 6W

11. The changing magnetic field inside the plane produces electric lines of
forces in anticlockwise direction.
There is no direct connection in the shown conductors, so electrons,
experiencing electric force, try to accumulate as shown.

All electrons accumulate at Q symmetrically
V
P
= V
R

All electrons accumulate at R
V
P
> V
R

electrons accumulate
at P V
P
< V
R

electrons accumulate at R
V
P
> V
R

12. Fission of a nucleus is feasible only if the binding energy of daughter nuclei is more than the
parent nucleus.
A = 55 will have more BE than 110.
A = 70 will have same BE as 110 but A = 40 will have more B.E.
A = 100 will have same BE as 110 but A = 10 will have lesser B.E.
A = 90 will have same BE as 110 but A = 20 will have lesser B.E.

13.
1
T
T
1
> T
2
> T
3
as
1
<
2
<
3
(Wien's law)
Now as the area under the curve E
and gives the intensity; so


4

Ae
3
T
3
4
>

Ae
2
T
2
4
{Areas of the bodies are same, given}
Now as T
3
< T
2
e
3
> e
2
.
14. hv = K.E. (T) + work function (W)
hv = T + W
4.25 eV = T
A
+ W
A
(for Metal A)
4.70 eV = T
B
+ W
B
(for Metal B)
Since T
B
= (T
A
1.5) eV
Also = h/p
=

` = =
)
2
h p
T K.E.
2m
2mT

A
B
=
B
A
T
T

Since
A
=
B
1
2

T
A
= 4T
B

T
B
= T
A
1.50 gives
T
B
= 4T
B
1.5
T
B
= 0.5 eV
T
A
= 2 eV
W
A
= 2.25 eV
W
B
= 4.20 Ev

15. P = V
3
, for ideal gas
PV = nRT
(A) relation between V and T
V (3V
3
) = nRT
V
4
=
nR
T
3
| |
|
\ .
V
4
T
(B) Relation between P and T
PV = nRT P
1/ 3
P
3
| |
|
\ .
= nRT
P
4/3
T

(C) For expansion
V increases
work-done : positive
internal energy : increases
Hence, heat will have to supplied to the gas.
(D) As T V
4

with increase in temperature, volume increases
Hence work done is positive.
SECTION C

1. =
T
v
T can be calculated by using Hookes Law and on stretching also changes.

2. f
1
=
| |
=
|
\ .
340 10
f f
340 34 9


5
and f
2
=
| |
=
|
\ .
340 20
f f
340 17 19

and
1
2
f
f
= =
10
19
9
20
18
19

3. For 1
st
reading of oscillator
f
A
= (514 2)Hz
f
A
= 516 Hz or 512 Hz
For 2
nd
reading of oscillator
f
A
= (510 6) Hz
f
A
= 516 Hz or 504 Hz
A has a frequency of 516 Hz

4. Velocity of approach of man towards the bicycle = (u v)
Hence velocity of approach of image towards bicycle is 2(u v).

5. For A :
Total number of waves =
(1.5) t
....(1)

| | | |
=
| |
\ . \ .
Totalnumber optical path length
of waves wavelength

For B and C :
Total number of waves =
| | | |
| |
\ . \ .
+

B
1 2t
n (1.6)
3 3
....(2)
Equating (1) and (2)
n
B
= 1.3

6
C Ch he em mi is st tr ry y PART II

SECTION A

1. Reaction of X with Br
2
+ KOH suggests that X is an amide. Evolution of N
2
and formation of
alcohol suggests that Y is a 1 aliphatic amine. Iodoform test of Z suggests that it is an alcohol
containing
C H
3
CH
OH
group.

C
2
H
5
CONH
2
2
Br KOH +
C
2
H
5
NH
2
2
HNO
2
HNO
2 3 2
N CH CH OH +
C
2
H
5
N C S
(Y)
CS
2
2
I NaOH +
3
HCOONa CHI +

2.
OH
NO
2
2
PhSO Cl
O
NO
2
SO
2
Ph
(A)
NaF/ DMSO
F
NO
2
(B)
F
is very reactive unsolvated which can displace
3
PhSO which being a good leaving group in
presence of strong withdrawing group NO
2
.

3.
3 2 3
Limiting reagent
1
PCl O POCl
2
11 1.34
137.3 32
0.0801 0.0419 0.0801
+
= =

Moles of POCl
3
formed = 0.0801
Mass of POCl
3
= 0.0801 153.3
= 12.3 g
Percentage yield =
11.2
100 91%
12.3
=

4. d = 0.714 g/L at STP
m = 0.714 g T = 273 K
P = 1 atm V = 1 L

2
PV 1 1
n 4.46 10
RT 0.0821 273

= = =

mass of this one litre sample is known from density
molar mass of the gas, M =
2
0.714
16g/ mole
4.46 10


7
5.
rms
3RT 3 8.314 300
U 432.78 433
M 0.03995

= = =
As molar mass of Ar = 39.95 g/mol
= 0.03995 kg/mol
6.
2
2 2
1 2
1 1 1
Z Rh
n n
(
=
(
(

2 7
2 2
1 1
6 1.097 10
1 3
(
=
(

7 1
8
36 1.097 10 m
9

(
=
(

= 2.85 nm
7.
N
Cl O

Central N-atom is bonded to two other atoms and has one l.p., the electron pair arrangement is
trigonal planar. The C N O bond angle is about 120 (we expect it to be slightly less than 120
because of greater lp-bp-repulsions) and the molecule is V-shaped.

8.
3 2 4
NCl 4H O NH OH 3HOCl + +

10.
2
1
2
2
Cu 2e Cu, G 2F 0.34
Cu Cu e G F 0.16
Cu e Cu
+
+ +
+
+ =
+ =
+

3 1 2
G G G 0.52 F = + =

cu / Cu
E 0.52 V
+
=

11.
A B
C

Thus it is a cyclic process.
Hence, E = 0, H = 0, S = 0
and E = q + w (1
st
law)
0 = q + w
or q = w
Total work done = W
A B
+ W
B C
+ W
C A

w = P (V
B
V
A
) + 0 + 2.303 nRT log
C
A
V
V

= (40 20) + 0 + 2.303 1 0.082 log
C
A
V
V

= 6.13 litre-atmosphere
= 620.77 J

8
12. Milli equivalent of Ba(MnO
4
)
2
= Meq of Fe
+2

= Meq of FeCrO
4

= Meq of K
2
Cr
2
O
7

13.
| |
0
2 2
120 C heated
4 2 4 2 4 2 2
3H O H O strongly
Plaster of Paris
2 CaSO .2H O 2CaSO .H O 2CaSO 2CaO 2SO O

+ +

14. In case of B, C and D, the salt are of weak base and strong acid which undergo hydrolysis to give
acidic solutions CH
3
COONa however, on hydrolysis gives basic solution.

15. On increasing temperature, the Maxwell curve of distribution of molecular velocity is flattened and
maximum is shifted to higher velocity.

T
1

T
2

T
2
> T
1

dN
N

Fraction
V
Velocity

SECTION C

1.
C
10
H
20
3
O
reductive
C H
3
CH
2
CH
CH
3
CHO (C
5
H
10
O)
Structure of A C H
3
CH
2
CH
CH
3
CH CH CH
CH
3
CH
2
CH
3
No. of stereoisomers of A = 6

3. x 1 + y 1 = 4 1 Eq. (1)
x 1 + 2y = 5 + 1 Eq. (2)
From Eq. (1) and Eq. (2) we get
y = 1
x = 3
x / y = 3

4. t
1/2

1 n
1
a

t
1/2
= K a
1n

K
1
rate constant
Log t
1/2
= log K + (1 n) log a
Y = C + mx
Slope = (1 n) = 2
n = 3
5. K
h
=
14
8 w
6
b
K 10
10
K
10
= =

9
M Ma at th he em ma at ti ic cs s PART III

SECTION A

1. 3x
3
+ bx
2
+ bx + 3 = 0 3 (x
3
+ 1) + bx (x + 1) = 0 has roots 1, 2,
1
2
.
So,
( ) f x 2 2
1 1
x x
2 2
e 1 3x bx bx 3
lim lim
2x 1 2x 1

+ + +
=

( )( )
1
x
2
1
3 x 1 x 2 x
2
lim
1
2 x
2
| |
+
|
\ .
=
| |
|
\ .
=
3 3 3 27
2 2 2 8

=

7. f(x) =
1 x
1 f(x)
+
+
. Also f(x) > 0 f(x) is increasing f(x) > f(0) = 0 x > 0

8. When P < 3, F(x+p) will have 4 positive roots

9. We have
a b c
15 8 17
= = a = 15, b = 8, c = 17 ( being a positive constant)
Note that a
2
+ b
2
= c
2

Triangle ABC is right angled
( )
1
R 17 ,
2
= = area of ABC = 60
2

s = 20, s a = 5, s b = 12, s c = 3
r
1
+ r
2
+ r
3
r
s a s b s c s

= + +

= 12 + 5 + 20 3 = 34

1 2 3
r r r r
34
2 4
R 17
+ +

= =

10. Any line perpendicular to x y +10 = 0 is of the form x + y = k
If this line is a tangent to the hyperbola x
2
2y
2
= 16, k
2
= 16 (1)
2
8 = 8 (using c
2
= a
2
m
2
b
2
)
k = 22
T
1
and T
2
are x + y + 22 = 0 and x + y 22 = 0
Distance between them =
4 2
4
2
=

11.
x 3
y 0
x 1
+
= >
+
x 3 or x 1 < >
or
x 3 x
y 0 y 1

( ) ( ) 0,1 1,

12. ( ) P x is an even function.
( )
4 2
P x ax bx 1 = + + and ( )
( )
3 2
P x 4ax 2bx 2x 2ax b = + = +
It has two minima. Hence, a > and b < 0.
So, at ( )
b
x , P x
2a
= has minima.

10

b
2 2 b 2a
2a
= =
Maximum at (0, 1).
Also,
( ) ( )
b
a
4 2
0
8 2
2 1 ax bx 1 dx
15
= + +

1
b 1 a
2
= =
Now,
( ) ( ) ( ) ( )
2
x 0
P x g x g x
lim
x
+
is finite.

1
C ,B 1
2
= =
Also, y = 1 is tangent to ( )
2
1
Ax x f x
2
+ =

2
1
Ax x 1
2
+ = has equal roots

1
A
2
=

13. z
1
and z
2
are end points of diameter.

14. S is radical circle of S
1
, S
2
and S. S is circle of centre = radical centre and radius = 8 and r
1
= 4,
r = 8

15. 2ae = 5, 2a = (22 + 1) 5, e
5
2 2 1 +

Foci are S
1
(1, 1) and S
2
(4, 5)
1 1
2 2
S N PS 40
2 2
S N PS
5
= = =

SECTION C

1. Perimeter of DEF = a cos A + b cos B + c cos C
= R [sin 2A + sin 2B + sin 2C]
= R [4 sin A + sin B + sin C]
= 4R
3 2
abc abc 2
4cm.
R
8R 2R

= = =

2. A =
{ } ( )
4 3 4 3 2 2
1 2
3
A 1, 2, 3,2 , B , , m 3 c 2 c 36 2 3
4 2 4

= = = = =
`
)
hence number of
divisors of m is 9

4.
( ) ( )
20 20
20 20 2 20 4 20 20
0 2 4 20
1 x 1 x
c c x c x c x
2
+ +
= + + +

20 20 20 18 20 16 20
0 2 4 20
c x c x c x c = + + +
So,
9
20 20
2r 2r 2
r 0
c c
+
=
=
coeff of x
22
in
( ) ( )
2n 2n
1 x 1 x
4
(
+ +
(

a = 10 xy = 40 has total order pair (x, y) solution = 4 2 = 8

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AITS-FT-IV-(Paper-1)-PCM(S)-JEE(Advanced)/13

and gives the intensity; so

is very reactive unsolvated which can displace

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