Assessment

Assessment
Name TUTORIAL 1 - FADZEELAH (Jun-Oct 2014)
Description These tutorial questions are exercise for Chapters 1 & 2.
Instruction Answer all questions.
Date & Time
Range
From 2014-06-22 12:00:00 to 2014-06-29 12:00:00
Current date & time : 2014-06-29 11:07:30
This quiz is available now.


Question
1 [Multiple Choice]
Question A catalyst is sufficiently active the concentration of the reactant at the external
surface of the catalyst is essentially zero. The reaction is limited by external mass
transfer. If the feed concentration is doubled, what happens to the rate of reaction
at steady-state?
Answer
1) no change
2) rate increases by 2
3) rate will double
4) all of answer is incorrect

Point : 3
2 [Multiple Answer]
Question Below are a few examples of how a chemical species can lose its chemical identity.
Choose the incorrect example.
Answer
1) Isomerization of Azobenzene
2) Condensation of Gas mixture; C3H8(g) + H2O(g) C3H8(g) + H2O(l)
3) Production of Ammonia; 0.5N2 + 1.5H2 NH3
4) Dehydrogenated Propane to form Propylene: C3H8 C3H6 + H2

Point : 2
3 [Multiple Choice]
Question Consider this exothermic reaction process. 1/2N2 (g) + 3/2H2 (g) NH3 (g)
Which are from the answers below is correct for reaction rate of N2 and H2 if the
rate of formation NH3 is 10 mol/dm3s.
Answer
1) rN2 = 25 mol/dm3s; rH2 = 15 mol/dm3s.
2) rN2 = 5 mol/dm3s; rH2 = 10 mol/dm3s.
3) rN2 = 10 mol/dm3s; rH2 = 15 mol/dm3s.
4) rN2 = 5 mol/dm3s; rH2 = 15 mol/dm3s.

Point : 3
4 [Multiple Choice]
Question State the order of the reaction for this process: 2NO + O2 2NO2
Answer
1) 2
2) 1.5
3) 3
4) 4

Point : 1
5 [True/False]
Question An elementary reaction is a chemical reaction in which one or more of the
chemical species react directly to form products in a single reaction step and with a
single transition state.
Answer
True
False

Point : 2
6 [Multiple Choice]
Question Consider this exothermic reaction process. 1/2N2 (g) + 3/2H2 (g) NH3 (g)
Which of the rate law for this elementary reaction and its order of reaction is
correct.
Answer
1) rN2 = k (CN2)1/2 (CH2)3
2) rN2 = k (CN2)1/2 (CH2)3/2
3) rN2 = k (CN2)2 (CH2)3/2
4) rN2 = k (CN2) (CH2)3/2

Point : 2
7 [True/False]
Question The rate law : (a) is relates reaction rate and concentration of reacting species. (b)
is a differential equation (c) is a function of temperature or concentration or
pressure
Answer
True
False

Point : 3
8 [True/False]
Question In heterogeneous systems, the rate of mass transfer and heat transfer also become
the variable affect of rate of reaction.
Answer
True
False

Point : 2
9 [Multiple Choice]
Question Consider this exothermic reaction process. 1/2N2 (g) + 3/2H2 (g) NH3 (g)
Determine the unit of specific reaction rate, k, for the above reaction.
Answer
1) dm6/mol2s
2) mol/dm3s
3) dm3/mols
4) s-1

Point : 2
10 [True/False]
Question The meaning of rA in words is the rate of formation of species A perunit volume
(mol/dm3s)
Answer
True
False

Point : 1
11 [True/False]
Question The various intermediates that can be formed in a non-elementary reaction are free
radicals, ions and polar substances, molecules and transition complexes.
Answer
True
False

Point : 2
12 [Multiple Choice]
Question The rate laws and the order of the reaction for the below process are: i. CH3COCH
CH2CO + CH4 ii. CNBr + CH3NH2 CH3Br + NCNH2 iii. 2NO + O2
2NO2 Choose the correct answer
Answer
1) rCH3COCH = k (CH3COCH), n =1; rNBR = k (CNBr)(CCH3NH2), n
= 2; rNO = k (CNO)2(CO2), n = 3
2) rCH3COCH = k (CH3COCH), n =1; rNBR = k (CNBr)(CCH3NH2), n
= 2; rNO = k (CNO)2(CO2), n = 3.5
3) rCH3COCH = k (CH3COCH), n =1; rNBR = k (CNBr)(CCH3NH2), n
= 1; rNO = k (CNO)2(CO2), n = 3
4) rCH3COCH = k (CH3COCH), n =1; rNBR = k (CNBr)(CCH3NH2), n
= 2; rNO = k (CNO)(CO2), n = 3

Point : 4
13 [True/False]
Question The rate of reaction is defined as the rate of change in number of moles of any
component i' due to chemical reaction per unit volume of the reacting fluid per
unit time. It is given by the expression, ri = (1/V) (dNi/dt) = [moles of i formed] /
[(volume of fluid) (time)]
Answer
True
False

Point : 1
14 [Multiple Answer]
Question Which affect cannot change the rate law (-rA)?
Answer
1) raise temperature
2) use catalyst
3) choose other types of reactor
4) concentration

Point : 3