Test 7

R a n j e e t S h a h i C h e m i s t r y C l a s s e s R a n j e e t S h a h i C h e m i s t r y C l a s s e s R a n j e e t S h a h i C h e m i s t r y C l a s s e s R a n j e e t S h a h i C h e m i s t r y C l a s s e s
SCO 4 8 , I I
n d
Fl o o r , Se c t o r 2 0 C, CHANDI GARH Ph: 2 7 2 5 7 4 8 , 3 0 4 0 6 6 0
S C F 7 2 , S e c t o r 1 0 , P a n c h k u l a , P h : 3 9 1 4 8 4 4 T e s t - 7 A
1

Dated: 07/02/10
Duration: Two Hour

SCO 4 8 , I I
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PRACTI CE TEST CHEMI STRY
for IIT IIT IIT IIT- -- -JEE JEE JEE JEE 2010
Section-A
1.
If nitrogen atoms are represented as filled circles and
oxygen atoms as open circles, how much NO
2
can be
prepared from the mixture given:
(a) 4
(b) 5
(c) 6
(d) 8

D
2.
A 25.0-mL sample of a solution of an unknown compound
is titrated with a 0.115 M NaOH solution. The titration
curve above was obtained. The unknown compound is
__________.
(a) a weak acid
(b) a strong base
(c) a weak base
(d) a strong acid

A
3.
Sodium hypochlorite (NaOCl) is a good oxidizing agent in alkaline medium. What volume of a 0.15 M alkaline solution of
NaOCl would be required to oxidize completely a 20-mL 0.2 M NaCrO
2
solution according to the reaction:
NaOCl + NaCrO
2
+ NaOH NaCl + Na
2
CrO
4
+ H
2
O
(a) 80-mL (b) 40-mL (c) 20-mL (d)10-mL

B
4.
For any chemical substance, how many combinations of temperature and pressure will allow the solid and liquid states
(but not the gas state) to exist at the same time?
(a) 1 -- there is just one unique temperature and pressure where the solid and liquid states can both be stable at the
same time.
(b) 2 -- there are two extremes of temperature and pressure where solid and liquid can both be stable at the same time.
(c) 3 -- there are three unique combinations of temperature and pressure where solid and liquid can both be stable at the
same time.
(d) an infinite number -- there are infinitely many combinations of temperature and pressure where solid and liquid can
both be stable at the same time.

D
5.
Which of the following statements is not true?
(a) The pressure of a real gas is greater than, equal to or less than that calculated for an ideal gas.
(b) The volume of a real gas is greater than or equal to the volume calculated for an ideal gas.
(c) The van der Waals equation helps to calculate the pressure and volume of real gases.
(d) Real gas molecules do occupy a finite, but small, volume.

B
6.
Consider the reaction: A C; H = +35 kcal/m. and the reaction C B; H = -40 kcal/m.
List the enthalpy of formations of A, B, and C respectively in order of increasing enthalpy(H
o
).
(a) C, B, A (b) C, A, B (c) A, B, C (d) B, A, C
D
7.
A gas is allowed to expand at constant temperature from a volume of 1.0 L to 10.1 L against an external pressure of 0.50
atm. If the gas absorbs 250 J of heat from the surroundings, what are the values of q, w, and E?
q w E q w E
(a) 250 J -460 J -210 J (c) 250 J 460 J 710 J
(b) -250 J -460 J -710 J (d) -250 J 460 J 245 J

A

SCO 4 8 , I I
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8.
Which of the following represents a reaction condition that will only be spontaneous at HIGH temperatures?
(a) H
o
RXN
= negative; S
o
RXN
= positive (b) H
o
RXN
= positive; S
o
RXN
= negative
(c) H
o
RXN
= positive; S
o
RXN
= positive (d) H
o
RXN
= negative; S
o
RXN
= negative

C
9.
0.02 mol/L N
2
O(g) and 0.056 mol/L of O
2
(g) are reacted at 1000K. The equilibrium concentration of NO
2
(g) was found to
be 0.02 mol/L. The equilibrium constant K
C
for the reaction is:
2N
2
O(g) + 3O
2
(g) 4NO
2
(g)
(a) 0.043 L/mol (b) 23.2 L/mol (c) 4.3 L/mol (d) 0.43 mol/L

B
10.
Compound A is a D-aldopentose that can be oxidized to an optically inactive aldaric acid. A on treatment with HCN
followed by treatment with SnCl
2
/Con. HCl yields B and C. B can be oxidized to an optically active aldaric acid while C is
oxidized to an optically inactive aldaric acid. Which of the following is correct labeling of A, B and C?
CH
2
OH
OH
OH
OH H
H
H
CHO
OH
OH
OH H
H
H
OH H
CH
2
OH
CHO
OH
OH
H O H
H
H
OH H
CH
2
OH
CHO
A B C
CH
2
OH
OH
OH
OH H
H
H
CHO
OH
OH
H O H
H
H
OH H
CH
2
OH
CHO
OH
OH
OH H
H
H
OH H
CH
2
OH
CHO
A B C
(a) (b)
CH
2
OH
OH
H
OH H
O H
H
CHO
OH
OH
OH H
H
H
OH H
CH
2
OH
CHO
OH
OH
H O H
H
H
OH H
CH
2
OH
CHO
A B C
CH
2
OH
OH
OH
OH H
H
H
CHO
OH
H
H O H
O H
H
OH H
CH
2
OH
CHO
OH
OH
OH H
H
H
OH H
CH
2
OH
CHO
A B C
(c) (d)

B
11.
Losing one electron to become the He
+
cation can singly ionize helium. Which of the following statements is true
concerning this helium cation?
(a) The spectral lines in the line spectrum of this helium cation will be more closely spaced than spectral lines in the line
spectrum of a hydrogen atom.
(b) The spectral lines in line spectrum of this helium cation will appear at same wavelengths as in the line spectrum of a
Li
2+
.
(c) The line spectrum of this helium cation will remain the same as for unionized helium.
(d) The line spectrum of this helium cation will have same numbers of spectral lines as in the line spectrum of a hydrogen
atom.

D
12.
Which of these molecules or ions has a trigonal pyramid molecular geometry?
(a) O
3
(b) CO
3
2
(c) PF
4
+
(d) ClO
3

D
13.
You are given a small bar of an unknown metal, whose molar mass is X. You find the density of the metal to be 19.32
g/cm
3
. An X-ray diffraction experiment measures the edge of the unit cell as 4.07 . Assuming that the metal crystallizes
in a face-centered cubic lattice, what is the most likely atomic weight of X?
(a) 197 (b) 108 (c) 63.5 (d) 206

A
14.
Which of the following substances lowers the freezing point of an aqueous solution the least?
(a) 0.10 M KBr (b) 0.10 M CaCl
2
(c) 0.05 M Mg(NO
3
)
2
(d) 0.05 M Al(NO
3
)
3

A
15.
The cell shown below generates a potential of 0.65V at 300K. K
sp
for AgBr is ?
Ag | AgBr(s), NaBr (0.10M) | | AgNO
3
(0.10M) | Ag E = 0.65V
(a) 1.15 x 10
-9
(b) 2.00 x 10
-30
(c) 1.25 x 10
-13
(d) 3.5 x 10
-11

C
16.
Ethylene is reacted with bromine water containing chloride ion and nitrate ion. Which of the following compounds is NOT
formed ?
(a) Br(CH
2
)
2
Br (b) Br(CH
2
)
2
Cl (c) Br(CH
2
)
2
OH (d) Br(CH
2
)
2
ONO
2

C

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17.
The order of stability of complex of trimethyl amine with BX
3
is BF
3
< BCl
3
< BBr
3
. The correct statement concerning this
order is:
(a) This order is as expected based on the relative electronegativities of halogens.
(b) This order is contrary to the acid strength, and is due to deviation from planarity of the molecule.
(c) This order is expected order in accordance with their acid strength.
(d) This order is unexpected based on the electronegativities of the halogens and attributed to -bonding between 2pX
and the empty B 2p orbitals.

C
18.
The first order decomposition of dinitrogen pentaoxide,
N
2
O
5
, was studied in chloroform solution at 45C and the
results are expressed on the diagram in the right margin.
From the diagram, The expected value for the specific
rate constant k for the reaction is:
2 N
2
O
5
2 N
2
O
4
+ O
2

(a) 6.2 x 10
4
s
1

(b) 9.7 x 10
5
s
1

(c) 8.7 x 10
3
s
1

(d) 5.4 x 10
6
s
1

A
19.
An Au(NO
3
)
3
solution containing a gold electrode is connected by means of a salt bridge to a PbCl
2
solution containing
lead electrode. Which of the following is the correct representation of this Galvanic cell?

D
20.
The order of reactivity of the following alkenes towards electrophilic attack is :
Propene(i) Propenoic acid(ii) Ethylene(iii) 2-methylpropene(iv)
(a) (i) > (iii) > (iv) > (ii) (b) (i) > (iii) > (ii) > (iv) (c) (iv) > (i) > (iii) > (ii) (d) (i) > (iv) > (iii) > (ii)

C
21.
What would be the product from the photochemical monochlorination of propane at room temperature?
(a) 1-chloropropane (b) 2-chloropropane
(c) an approximately equal mixture of 1-chloropropane and 2-chloropropane
(d) a mixture of 75% 1-chloropropane and 25% 2-chloropropane

C
22.
Which of the following structures is least likely to be a resonance form of the others in the group?
(a)
(b)
(c) (d)
CH
3
CH=CH C
O
NH
2
CH
3
CH=CH C
O
N
_
CH
3
CH=CH C
O
NH
2
_
CH
3
CH=CH C
O
N
_
+
H
2
+
+
H
2

B
23.
Which of the following represents best possible starting route for the synthesis of cyclohexanecarboxylic acid.
NaOEt
CH
2
(COOEt)
2
Br(CH
2
)
4
Br
(a) (b)
C H
3
O
COOEt
NaOEt
I-(CH
2
)
5
-I
(c)
C H
3
COOEt
COOEt
NaOEt
I
2
(d)
C H
3
O
COOEt
NaOEt
Br-(CH
2
)
5
-Br

B

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24.
What is the order of reactivity of these organic halides towards unimolecular solvolysis?
Br
(I)
(II) CH
2
=CH.CH
2
Br (III) Ph.CH
2
.CH
2
Br (IV) CH
2
=CH.CH
2
.CH
2
.Br
(a) I > II > III > IV (b) I > II > IV > III (c) II > III > IV > I (d) II > III > I > IV

C
25.
A carboxylic acid X is treated with bromine (1 mole) in the presence of a little phosphorus. The isolated product is heated
with a strong base and in turn oxidized. One of the two oxidation products is a neutral compound which reacts with
hydroxylamine to give oximes; X is
(a) CH
3
CH
2
CH(CH
3
)CO
2
H (b) C
6
H
5
CH
2
CH
2
CO
2
H (c) (CH
3
)
2
CHCH
2
CO
2
H (d) CH
3
CH
2
CH(CH
3
)CH
2
CO
2
H

D
26.
Which is a possible set of quantum numbers for a valence
electron in ground state atom of phosphorus?
n l m
l
m
s
n l m
l
m
s

(a) 2 1 0 + (c) 3 1 -1 +
(b) 3 0 0 0 (d) 3 2 1 -
C
27.
Which one of the following statements is true?
(a) Acetamide is a liquid with an ammoniacal smell, which reacts with mineral acids to form stable salts.
(b) Acetamide is a solid, acidic to litmus, which reacts with sodium hydroxide to liberate ammonia.
(c) Acetamide reacts with benzene sulphonyl chloride in alkaline soluton to give a crystalline sulphonamide.
(d) Acetamide reacts on warming with phosphorous pentaoxide to give acetonitrile.

D
28.
Which of the following is most expected product in the following reaction?
(a) (b) (c) (d)
CH
3
O H OH
H
2
SO
4
heat
C H
2
CH
2
CH
3
O C H
3
O
CH
3 CH
3

C
29.
Select the best reaction sequence to accomplish the following transformation:
NH
2
HNO
3
H
2
SO
4
Cl
O
AlCl
3
Zn(Hg), HCl
excess
(a) (b)
HNO
3
H
2
SO
4
Cl
AlCl
3
Zn(Hg), HCl
excess
(c)
HNO
3
H
2
SO
4
Cl
O
AlCl
3
Zn(Hg), HCl
excess
Zn(Hg)
ClH
HNO
3
H
2
SO
4
Cl
O
AlCl
3
Zn(Hg), HCl
excess
(d)

D
30.
Amino acids have higher melting points than either amine or acid of comparable molar masses due to?
(a) It has more sites available for H-bonding than either amine or acid.
(b) In solid state, an amino acids exist predominantly as zwitterionic form.
(c) In solid state, amino acids have more effective packing of molecules than either amine or acid.
(d) None of the above is correct explanation.

B
Section-B The following Eitht questions may have more than one correct answer.

31.
Which of the following statements are true for the
molecule shown below?
N
H
CO
N
H
CO
Cl
CH
3
CH
3
Cl

(a) The compound is optically active.
(b) The compound has a plane of symmetry.
(c) The compound has a center of symmetry.
(d) The compound has an axis of symmetry.

A
D

SCO 4 8 , I I
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32.
Which of the following have all the resonance structures more stable than the shown one?
(a) (b)
O
(c)
OMe
(d)
+
+
+
+

B
D

33.
Which of the following compound(s) on treatment with dilute base followed by heating of resulting aldol will produce more
than one dehydration products?
(a) Ethanal (b) Acetone (c) Propanal (d) 4-methyl cyclohexanone

A
C
D

34.
What are the final product(s) of the following reactions?
O H
2
NOH
PCl
5
NH
O
NH
O
NH
O
N
H
O
(a) (b) (c) (d)
+

A
B

35.
Which of the following statements is(are) true?
(a) The ratio of the average speed to the r.m.s. speed is independent of the temperature.
(b) The square of the mean speed of the molecules is equal to the mean squared speed at a certain temperature.
(c) Mean kinetic energy of the gas molecules at any given temperature is independent of the mean speed.
(d) The difference between r.m.s. speed and average speed at any temperature for different gases diminishes as larger
and yet larger molar masses are considered.

A
C
D

36.
Which of the following is(are) correct colligative observations?
(a) As surface area of a volatile liquid is decreased at constant temperature, some vapour molecules condenses back
decreasing the number of molecule in vapour phase in equilibrium with liquid phase.
(b) When a non volatile solute is added to a volatile solvent, a stronger intermolecular Solute-solvent attraction is
established lowering the vapour pressure.
(c) When a non-volatile solute is added to a volatile solvent, vapour pressure is lowered and resulting solution require
higher temperature compared to pure solvent in order to take its vapour pressure equal to external pressure.
(d) A solution of non-volatile solute in a volatile solvent is first heated to temperature slightly above to its boiling point and
then finally cooled for freezing. The final solution will start freezing at higher temperature than the original solution.

A
C

37.
When a micelle is formed, at critical micelle concentration
(a) Conductance decreases abruptly
(b) Surface tension decreases abruptly
(c) Boiling point of solution is less then the boiling point when concentration is less then CMC.
(d) Coagulation takes place.

A
B
C

38.
What is true regarding aspartic acid?
(a) An aqueous solution of pure aspartic acid has pH < 7. (b) At pH = 6, it bears net positive charge.
(c) At pH = 8, it bears net negative charge. (d) It is a monobasic amino acid.

A
C

Section C

Following five questions contains Assertion and Reasons. Answer them according to following options: (a)
Both assertion and reason are correct and reason is the correct explanation of assertion. (b) Both assertion and reason
are correct but reason is not the correct explanation of assertion. (c) Assertion is correct but reason is wrong. (d)
Assertion is wrong but reason is true.

39.
A: The thermodynamic function, which determines the spontaneity of a process, is the free energy.
R: The change in entropy must be always positive in order to make G negative, which ensure the spontaneous process.

C

SCO 4 8 , I I
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40.
A: Rate of catalytic hydrogenation of alkene is function of temperature and nature of catalyst only.
R: Catalytic hydrogenation of alkene follows zero order kinetics.

D
41.
A: According to law of mass action, active masses of solids and pure liquids are taken to be unity.
R: Concentration of solids and pure liquids are constant in a given condition of temperature and pressure.

A
42.
A: Orthonitrophenol is more volatile than its para isomer.
R: Paranitrophenol shows intramolecular H-bonding whereas orthonitrophenol shows intermolecular H-bonding.

C
43.
A Alkynes are more reactive than alkenes towards electrophilic addition reaction
R Alkynes have greater electron density than alkene at multiple bond

D
Section-D The following Nine questions are based on Passages. Read the corresponding passage
and answer the following questions based on the information provided in the passage.

44.
Passage-1:
An electrochemical cell with inert platinum electrodes is shown on right: The half cell reactions are:
Fe
3+
+ e
-
Fe
2+
E
o
=+0.77 V at 25
o
C
VO
2+
+ 2H
+
+ e
-
V
3+
+ H
2
O E
o
=+0.34V at 25
o
C

The statement which is incorrect about this cel is:
(a) E
o
cell
is 0.43 V.
(b) Electrons flow from left to right electrode.
(c) If some Fe
3+
is added to left half-cell, E
cell
increases.
(d) If some VCl
3
is added to right half-cell, E
cell
increases.

KCl
Fe
3+
, Fe
2+
and Cl
-
V
3+
, VO
2+
and H
+

Pt Pt

B
45.
Emf of the cell when all the species are at 1.0 M except H
+
which is at 0.01 M is:
(a) 1.35 V (b) 0.55 V (c) 0.67 V (d) 0.194 V

C
46.
The maximum useful work that can be obtained from this cell under standard condition is:
(a) 32.8 kJ (b) 41.5 kJ (c) 74.3 kJ (d) 107 kJ

B
Passage-2:
In a student experiment designed to demonstrate microscale extraction techniques, the three compounds shown below
are dissolved in diethyl ether and separated:
O
(X)
NH
2
H
3
COOC COOH
(Y) (Z)

The mixture is created by dissolving 50 mg of each compound in diethyl ether. Some 2M HCl is then added creating a
two phase system. The system is mixed thoroughly and then allowed to separate. The aqueous layer is removed and the
step is repeated with reminder of the mixture.
6M NaOH is added to the extracted aqueous solution. The solution is cooled in an ice bath and precipitate is
collected and washed.
The remaining mixture is now separated by extraction with some 3M NaOH. 6 M HCl is added to the alkaline
solution, which is then cooled to form a precipitate. The remaining component is washed with distilled water. Next, some
Na
2
SO
4
is added. The Na
2
SO
4
is then filtered off using a filter paper and the remaining solution is transferred to an
Erlenmeyer flask.

47.
Which of the following comes out in aqueous layer of the first extraction with 3M HCl?
(a) X (b) Y (c) Z (d) diethyl ether

B

SCO 4 8 , I I
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48.
What is the expected molecular weight of the compound extracted by NaOH?
(a) 46 (b) 122 (c) 165 (d) 180

49.
If the last fraction present in the Erlenmeyer flask is treated with Fe/Br
2
, the major monobromination product would be?
O
Br
NH
2
H
3
COOC
Br
COOH
Br
(a)
(b)
(c) (d)
O
Br

D
Passage-3:
A white, anhydrous solid A is water soluble. An aqueous solution of A gives a white precipitate with BaCl
2
. The
precipitate thus obtained is then fused with Na
2
CO
3
on charcoal and the fusion mixture is extracted in water. This extract
on treatment with freshly prepared sodium nitroprusside solution gives a transient purple colouration. A also gives the
following reaction:
A(aq) + K
4
[Fe(CN)
6
] White precipitate, insoluble in dilute acid.
A(aq) + CuSO
4
+ H
+

( ) ( )
4
2 4
[ ] NH Hg SCN
B(violet precipitate)
A(s) + Cu(NO
3
)
2
+ Heat C(green, infusible residue)

50.
The salt A is:
(a) Al
2
(SO
4
)
3
(b) Pb(NO
3
)
2
(c) CaSO
4
(d) ZnSO
4

D
51.
Precipitate B is:
(a) Pb[Hg(SCN)
4
] (b) Cu[Hg(SCN)
4
] (c) Zn[Hg(SCN)
4
] (d) both b and c

D
52.
The residue C is:
(a) CoAl
2
O
4
(b) PbCoO
2
(c) ZnCoO
2
(d) CaCoO
2

C
Section E Matrix Matching Type Questions

53.
Match the quantity from column-I with that in column-II:
Column-I Column-II Ans
(A) Boron(B) (P) Can be prepared by thermal decomposition of their iodide. A: PQS
(B) Silicon(Si) (Q) Its oxide gives acidic solution in water. B:PRS
(C) P
4
(R) Its organohalide, on hydrolysis gives polymer. C:Q
(D) Cl
2
(S) Its hydrides are good reducing agent. D:Q

54.
(A) K
4
[Fe(CN)
6
] (P) Diamagnetic A: PQR
(B) [Fe(CO)
5
] (Q) Show Linkage isomerism B:PR
(C) [Ti(H
2
O)
6
](NO
2
)
2
(R) Show d
bonding. C:S
(D) K
4
[Sc(SCN)
6
] (S) Paramagnetic D:QS

SCO 4 8 , I I
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55.
Match the reactions of column-I with the properties of products in column-II:
(A)
(B)
(C)
(D)
C H
3
CH
3
H
H
Br
H
Br H
Ph
Ph
O
2
N
NO
2
CH
3
C H
3
CH
3
O
Cl
H
H
C H
3
H
Cl
Cl
CH
3
H
(P)
Br
2
/CCl
4
Br
2
heat
a pure enantiomer
CH
3
ONa
CH
3
OH
NaCN(aq)
one equivalent
(Q) pair of distereomers
(R)
(S)
pair of enantiomers
only meso
Column-I
Column-II
one of the product
is a meso form

Ans:
A: PQ
B: PQ
C: S
D:R

56.
(A) Wave function ( ) (P) Depends only on n and l A: QRS
(B) Probability density ( )
2
(Q) Depends on n, l and m. B:QS
(C) Probability of finding an electron at
distance r from nucleus.
(R) Changes sign at nodes. C:Q
(D) Radial wave function. (S) Maximum at nucleus for 1s orbital. D:PRS

SCO 4 8 , I I
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Answer Sheet
Name: ______________________________________________________
Batch: ______________________________________________________

1.

A B C D

21.
A B C D

41.
A B C D

2.

A B C D

22.
A B C D

42.
A B C D

3.

A B C D

23.
A B C D

43.
A B C D

4.
A B C D

24.
A B C D

44.
A B C D

5.

A B C D

25.
A B C D

45.
A B C D

6.

A B C D

26.
A B C D

46.
A B C D

7.

A B C D

27.
A B C D

47.
A B C D

8.

A B C D

28.
A B C D

48.
A B C D

9.

A B C D

29.
A B C D

49.
A B C D

10.

A B C D

30.
A B C D

50.
A B C D

11.

A B C D

31.
A B C D

51.
A B C D

12.

A B C D

32.
A B C D

52.
A B C D

13.

A B C D

33.
A B C D

53.

14.

A B C D

34.
A B C D

15.

A B C D

35.
A B C D

54.

16.

A B C D

36.
A B C D

17.

A B C D

37.
A B C D

55.

18.

A B C D

38.
A B C D

19.

A B C D

39.
A B C D

56.

20.

A B C D

40.
A B C D

SCO 4 8 , I I
n d
11

Answers +2 Test Series Test-7 07-02-2010

Set-A

Set-B

Set-ABC
1. D 1. D 31. A D
2. A 2. D 32. BD
3. B 3. C 33. A C D
4. D 4. A 34. A B
5. B 5. D 35. A C D
6. D 6. A 36. A C
7. A 7. C 37. A B C
8. C 8. B 38. A C
9. B 9. D 39. C
10. B 10. B 40. D
11. D 11. B 41. A
12. D 12. C 42. C
13. A 13. B 43. D
14. A 14. C 44. B
15. C 15. C 45. C
16. C 16. D 46. B
17. C 17. A 47. B
18. A 18. A 48. B
19. D 19. D 49. D
20. C 20. C 50. D
21. C 21. B 51. D
22. B 22. C 52. C
23. B 23. D 53. A: PQS, B:PRS
24. C 24. C

C:Q, D:Q
25. D 25. A 54. A: PQR, B:PR
26. C 26. B

C:S, D:QS
27. D 27. D 55. A: PQ, B:PQ
28. C 28. C

C:S, D:R
29. D 29. B 56. A: QRS, B:QS
30. B 30. D

C:Q, D:PRS

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R a n j e e t S h a h i C h e m i s t r y C l a s s e s R a n j e e t S h a h i C h e m i s t r y C l a s s e s R a n j e e t S h a h i C h e m i s t r y C l a s s e s R a n j e e t S h a h i C h e m i s t r y C l a s s e s

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