Exam 3 Special Code 111111 Name: __________________,________________

Petrovich, Fall 2010 print last print first

Student Number: ___________________(000######)

1. To what temperature must a substance be heated to contain 10 kJ/mol of thermal energy?

A) 1203 K B) 930 K C) 122 K D) -151 K
2. What is the concentration of Ne in a container at 40 C and 3.2 atmospheres of pressure?


A) 0.974 mol/L B) 0.124 mol/L C) 0.00123 mol/L D) 0.0096 mol/L
E) cannot be answered without volume.
3. A balloon is filled with 2.00 liters of gas at 300 K. What is the volume of the balloon at
100K?


A) 0.75 L B) 1.50 L C) 6.00 L D) 0.67 L
4. Choose the correct letter(A-D) to make a true statement. At 25 C, iodine (I
2
) is a solid
and fluorine(F
2
) is a gas. This is because..
A) the thermal energy of I
2
is greater than the thermal energy of F
2
.
B) the thermal energy of I
2
is less than the thermal energy of F
2
.
C) the interaction energy of I
2
is greater than the interaction energy of F
2
.
D) the interaction energy of I
2
is less than the interaction energy of F
2
.
5. The pressure of the atmosphere is 755 mm Hg. What is the pressure in atmospheres of
the Argon gas in the bulb if the height difference is 145 mm Hg?

A) 0.803 atm
B) 900 atm
C) 1.18 atm
D) 610 atm
6. How many moles of atoms are in 51.0 grams of S
8
?


A) 1.64x10
3
mol atoms B) 7.66 x 10
24
mol atoms C) 1.59 mol atoms D) 12.7 mol atoms

7. In Phoenix, Arizona, a typical summer day is 40
o
C (104
o
F) with 10.% humidity. What is
the vapor pressure of water in the air. The vapor pressure of water at 40
o
C is 55.3 mm
Hg.

A) 5.5 mm Hg B) 4.0 mm Hg C) 55.3 mm Hg D) 22 mm Hg

Exam 3

P
r
e
s
s
u
r
e

(
a
t
m
)
1.00
0.75
0.50
0.25
10 20 30 40 50 60 70 80
Temperature (C)
90
A
B
C
D
E
F
G
H
I
J
K
L
P
r
e
s
s
u
r
e

(
a
t
m
)
1.00
0.75
0.50
0.25
10 20 30 40 50 60 70 80
Temperature (C)
90
A
B
C
D
E
F
G
H
I
J
K
L
C H N
H
..
H
H
C
H
H
C
H
H
H C H
H
N C
H
H
C
H
H
H
H
H
C H
H
C C
H
H
C
H
H
H
H
H
H
C H N
H
..
H
H
C
H
H
H
A B
..
C D
Consider the phase diagram below for kryptonite for the next two questions.
8. Under what conditions is kryptonite a solid and gas, but NOT a liquid?
A) 70
o
C, 0.75 atm
B) 20
o
C, 0.25 atm
C) 30
o
C, 1.0 atm
D) 40
o
C, 0.50 atm

9. What process is occurring along arrow C?
A) freezing B) evaporation C) melting D) sublimation

10. Which compound below would have the LOWEST boiling point?








11. Which numeric combination (A-E) belongs together in the diagrams below?






A) 1,4,5 B) 2,3,6 C) 1,4,6 D) 2,4,6 E) 2,4,5

12. Select that pair in which hydrogen bonding will NOT occur.






A) I with I B) II with II C) I with II D) I with III E) No correct answer

1
2 H-Cl
5
temperature
4 3
F-F
6
H
H
H
H
C
N
C
C
C
C
H
H
H
H
H
C
N
C
C
C
C
H H
.
.
H
. .
F
F
N F
. .
I II III
Exam 3

13. Choose the POLAR compounds from the choices below.

A) I & II B) III & IV C) I & III D) II & IV E) II & III
14. The unit cell of an ionic compound is shown below. The X atom occupies the center and
edges of the unit cell. The Y atom occupies the faces of the unit cell. Choose the correct
formula for the compound below.

A) X
13
Y
6
B) X
4
Y
3
C) X
7
Y
4
D) X
3
Y
4

15. In the band diagram shown below, which letter represents the valence band?

16. A weak, light metal would likely pack in this type of unit cell.

17. Choose the correct set of words to complete the statement below.
ZnS is a(n) ____i_____ substance. SO
3
is a(n) ____ii_____ substance.

A) i=network covalent, ii=ionic B) i=network covalent, ii=molecular
C) i=metallic, ii=ionic D) i=ionic, ii=molecular
E
n
e
r
g
y
A
B
C
D
E
E
n
e
r
g
y
C
A B C
Y
X
Exam 3

18. E for a system is 12.0 kJ. If the system is an endothermic reaction with a value of 17.5
kJ, what is the work component?

A) 5.5 kJ done by the system B) 5.5 kJ done on the system
C) 29.5 kJ done by the system D) 29.5 kJ done on the system
19. The reaction for the reaction of nitrogen with chlorine is shown below. Using bond
enthalpies, determine the value of H for the reaction. Be sure to draw Lewis structures
of the products and reactants, to assist in determining the bond order.

N
2

(g)
+ 3Cl
2

(g)
2NCl
3

(g)


Table of Bond Energies (kJ/mol)

A) -17 kJ/mol B) +889 kJ/mol C) -56 kJ/mol D) +467 kJ/mol E) +1067 kJ/mol
20. The reaction below is similar to the thermite reaction, but uses black iron ore instead of
red iron ore. What is the value of H
o
when 94.0 grams of Fe is formed?
3Fe
3
O
4

(s)
+ 8 Al
(s)
4Al
2
O
3

(s)
+ 9Fe
(s)
H
o
= -3347.6 kJ/mol



A) -6.7 kJ B) -5.08x10
4
kJ C) -5.63x10
3
kJ D) -59.9 kJ E) -626 kJ
21. Liquid hydrogen peroxide decomposes according to the reaction:
2H
2
O
2

(l)


2H
2
O
(l)
+ O
2

(g)
H
o
= -196 kJ/mol

What is the value of H for the reaction shown below?

6H
2
O
(l)
+ 3O
2

(g)
6H
2
O
2

(l)


A) + 196 / 3 kJ B) +6 x 196 kJ C) +3 x 196 kJ D) -196 / 3 kJ

C-H 413 N-H 391 O-H 463 H-H 436
C-F 485 N-F 272 O-F 190 H-F 565 F-F 155
C-Cl 328 N-Cl 200 O-Cl 203 H-Cl 431 Cl-Cl 242
C-Br 276 N-Br 243 O-Br 235 H-Br 366 Br-Br 193
C-I 234 O-I 234 H-I 299 I-I 151
C-C 347 N-N 163 C-N 293 C-O 358 O-O 146
C=C 612 N=N 418 C=N 615 C=O 799 O=O 495
C C 820 N N 941 C N 891 C O 1072
C-H 413 N-H 391 O-H 463 H-H 436
C-F 485 N-F 272 O-F 190 H-F 565 F-F 155
C-Cl 328 N-Cl 200 O-Cl 203 H-Cl 431 Cl-Cl 242
C-Br 276 N-Br 243 O-Br 235 H-Br 366 Br-Br 193
C-I 234 O-I 234 H-I 299 I-I 151
C-H 413 N-H 391 O-H 463 H-H 436
C-F 485 N-F 272 O-F 190 H-F 565 F-F 155
C-Cl 328 N-Cl 200 O-Cl 203 H-Cl 431 Cl-Cl 242
C-Br 276 N-Br 243 O-Br 235 H-Br 366 Br-Br 193
C-I 234 O-I 234 H-I 299 I-I 151
C-H C-H 413 413 N-H N-H 391 391 O-H O-H 463 463 H-H H-H 436 436
C-F C-F 485 485 N-F N-F 272 272 O-F O-F 190 190 H-F H-F 565 565 F-F F-F 155 155
C-Cl C-Cl 328 328 N-Cl N-Cl 200 200 O-Cl O-Cl 203 203 H-Cl H-Cl 431 431 Cl-Cl Cl-Cl 242 242
C-Br C-Br 276 276 N-Br N-Br 243 243 O-Br O-Br 235 235 H-Br H-Br 366 366 Br-Br Br-Br 193 193
C-I C-I 234 234 O-I O-I 234 234 H-I H-I 299 299 I-I I-I 151 151
C-C 347 N-N 163 C-N 293 C-O 358 O-O 146
C=C 612 N=N 418 C=N 615 C=O 799 O=O 495
C C 820 N N 941 C N 891 C O 1072
C-C 347 N-N 163 C-N 293 C-O 358 O-O 146
C=C 612 N=N 418 C=N 615 C=O 799 O=O 495
C C 820 N N 941 C N 891 C O 1072
C-C 347 N-N 163 C-N 293 C-O 358 O-O 146
C=C 612 N=N 418 C=N 615 C=O 799 O=O 495
C C 820 N N 941 C N 891 C O 1072
C-C C-C 347 347 N-N N-N 163 163 C-N C-N 293 293 C-O C-O 358 358 O-O O-O 146 146
C=C C=C 612 612 N=N N=N 418 418 C=N C=N 615 615 C=O C=O 799 799 O=O O=O 495 495
C C C C 820 820 N N N N 941 941 C N C N 891 891 C O C O 1072 1072
Exam 3

22. What is the approximate value of S for the reaction below?
Ca
2+

(aq)
+ 2HCO
3
1-
(aq)
CaCO
3

(s)
+ CO
2

(g)
+ H
2
O
(l)

A) S < 0 B) S > 0 C) S ~ 0 D) cannot be predicted
23. Choose the correct statement that describes the reaction below.
MgCO
3 (s)
MgO
(s)
+ CO
2 (g)
H = +117.3 kJ/mol
A) The reaction is extensive at high temperature.
B) The reaction is extensive at low temperature.
C) The reaction is extensive at any temperature.
D) The reaction is not extensive at any temperature.
24. Mustard gas is prepared according to the reaction below. Given that K
eq
= 5.48x10
-1
,
[SCl
2
] = 0.385 M and [C
2
H
4
] = 0.831 M, what is the concentration of S(CH
2
CH
2
Cl)
2
in the
mixture?
SCl
2 (g)
+ 2 C
2
H
4

(g)
S(CH
2
CH
2
Cl)
2

(g)

A) 0.175 B) 0.485 C) 0.351 D) 0.146 E) 0.268
Use the reaction coordinate diagram below to answer the next three questions regarding the
reaction: A-B + C A + B-C .

25. Which reaction above has the largest forward rate constant?
A) I B) II C) III
26. Which reaction above has the smallest value of K
equilibrium
?
A) I B) II C) III
27. Which reaction(s) above will increase in the concentration of [B-C] when heated?
A) I only B) II only C) III only D) I & II E) II & III


5 kJ
10 kJ
15 kJ
A-B, C
A, B-C
reaction coordinate
1 kJ
2 kJ
5 kJ
A-B, C
A, B-C
reaction coordinate
3 kJ
6 kJ
9 kJ
A-B, C
A, B-C
reaction coordinate
I
II
III
Exam 3

28. Consider the following reaction at equilibrium.
2 C
2
H
6
O (aq) + 2CO
2
(g) C
6
H
12
O
6
(aq) H > 0
ethanol glucose
Which changes would shift the equilibrium to the right?
I) addition of CO
2

II) removal of CO
2

III) removal of glucose
IV) heating the reaction
V) cooling the reaction

A) I, III, & IV B) II, III, & V C) I & IV D) I & V E) II, III, & IV

I pledge that I have neither given nor received aid on this exam.
Signature:______________________
Exam 3 Special Code 111111
Petrovich, Fall 2010

Directions:
1) Please put away all papers, cell phones and clear the memory on your calculators.
2) On the scantron sheet, fill and bubble in your last name, first name, special code (111111)
and student identification number (000######).
3) On the paper exam, print your last name and first name on page 1 of the exam.
4) Completely bubble in your answers for questions 1-28 on the scantron.
5) Please sign the honor pledge at the end of the exam.
6) Return all exam materials to Dr. Petrovich/TA before leaving DAB222.
7) Failure to follow the exam labeling instructions will result in a loss of 2 points on your
exam score.

Oxidation State Rules
1) The oxidation states of the atoms in an element are all zero.
2) Fluorine is always assigned an oxidation number of -1.
3) Group 1A metals are +1, Group 2A metals are +2, and aluminum is +3.
4) H is +1 when bonded to non-metals. H is 1 when bonded to metals.
5) Oxygen is assigned an oxidation number of 2.
6) Group 7A elements are assigned an oxidation number of -1.

PV = nRT G = H - T S
R = 0.0821 L*atm/K*mol or 8.314 J/K*mol 1 atm = 760 mm Hg = 760 torr
K = C + 273.15 H = coeffxD
bonds broke
coeffxD
bonds formed



Exam 3

Key:
1) A 15) E
2) B 16) B
3) D 17) B
4) C 18) A
5) A 19) D
6) C 20) E
7) A 21) C
8) B 22) B
9) C 23) A
10) C 24) D
11) E 25) A
12) B 26) B
13) D 27) E
14) B 28) A