Di Electric Const. For Pure Liquids

NBS CIRCULAR
514
AD-A278
lltl956
11111111111111111
1111
IIIliii 11111
Table of Dielectric Constants

of Pure Liquids
DTIC
ELECTE
SAPR
281994
UNITED STATES DEPARTMENT OF COMMERCE

NATIONAL BUREAU OF STANDARDS
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*Charles
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E. U. Condon,, Dirtelo,

of Pure Liquids
Arthur A. Maryott and Edgar R. Smith
Accesion For
NTIS CRAMi
OTIC TAB
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National Bureau of Standards Circular 514

Issued August 10, 1951
94-12769
For ale by the S
n n
fDcu
..
V~~
it
a ino2,
et o
062
Contents
Page
1. Introduction ------------- -------------------------------2. Description of table ---.-------------------------------------2.1 List of svmhol

-..
.
........------------------2.2 Standard liquids -------------------------------2.3 Chemical formulas and the order of listing of substances _II
2.4 Estimated accuracy of the values of fiielectric constant_- Iv
2.5 Variation of dielectric constant with temperature ---------- Iv
2.6 Literature references in table -------------------------Iv
3. Table of dielectric constants ---------------------------A. Standard liquids- --.---------------------------------7
B. Inorganic liquids- ------------------8
C. Organic liquids -------------------------------------15
4. Bibliography --------------------------------------------40
I!
Table of Dielectric Constants of Pure Liquids

Arthur A. Maryott and Edgar R. Smith
The "static" dielectric constants of more than 800 substances in the liquid state were
critically examined and tabulated ini concise form. Tihe table consists of three sections: A,
Standard Liquids; 13, Inorganic liquids; and (', Organic Liquids. An indication of the probable accuracy of the data is given. Wherever feasible, a simple analytical fuinction is employed to express the variation of dielectric constant with temperature.
1. Introduction
This tabulation of the dielectric constants of
pure liquids is part of a program for a critical examination of the data of physics and chemistry,
sponsored by the National Bureau of Standards in
cooperation with the Committee on Tables of
Constants and Numerical Data of the National
Research Council and the Commission on Tables
of Constants of the International Union of
Chemistry.
The preparation of additional tables

of the dielectric constants of gases, solids, aqueous
and nonaqueous solutions and mixtures, and of
dipole moments is in progress.
The assemblage and evaluation of the data

at the National Bureau
have been made entirelySbsecond
of Standards with the assistance of 'I.

during the preliminary stages.
Temperature is
the only variable considered explicitly. Usually
the pressure is atmospheric or insignificantly different with respect to its effect on dielectric constant.
However, where data are listed at temperatures
above the normal boiling point, the pressure corresponds to the vapor pressure of the liquid unless
indicated otherwise in a footnote.
quency is given in a footnote.
Eden
However, helpful
2.1.
List of Symbols
I=dielectric
constant.
(' (C)
C
t1=
temperature,
Celsius
I)
T=temperature, absolute ( K)
a=-de/t
a=-dlogio e/dt
f=frequency of alternating current in cycles per
t1, t2=the limits of temperature between
a is considered applicable
mp = melting point
which a or
suggestions from M. E. Hobbs of Duke University,

C. P. Smyth of Princeton University, and the
Committees of the National Research Council
and International Union of Chemistry are gratefully acknowledged.
The compilations of P.
Debye and H. Sack (Tables de Constantes et
Donn6es Numdriques XI, Fasicule 2, 1931-34;
XII, Fasicule :32, 1935-:36 and earlier volumes of
Tables Annuelles), International Critical Tables,
and Landolt-Bornstein Tabellen have been useful
in checking the tables for accuracy and completeness. In several instances data have been obtained
from the Tables of Dielectric Materials, volume
III, prepared by the Laboratory of Insulation
Research, Massachusetts Institute of Technology,
Cambridge, Mass., 1948.
Section A contains values of the dielectric constant at selected temperatures for 10 substances
that are recommended as reference liquids because
of their chemical stability, availability, and the
reliability of the data. The probable 'accuracy is
estimated to be about 0.2 percent for methanol
and nitrobenzene and about 0.1 percent in the
remaining cases. Values of a or a are included
for interpolating or for extrapolating over a
limited range of temperature without materially
altering the accuracy. Additional (lata for these
substances are contained in sections B or C.
2. Description of the Table
2.3. Chemical Formulas and the Order of
The table consists of three sections: A, Standard

Liquids, B, Inorganic Liquids, C, Organic Liquids.
The (dielectric constants are intended to be the
limiting values at low frequencies, the so-called
"static" values. Data obtained at such high frequencies that anomalous dispersion was evident
are not included. In questionable cases the fre-
Listing Substances
Formulas for the inorganic substances are
written in the usual manner. The order of listing
compounds in section B is alphabetical according
to the symbols for the elements in these formulas
with consideration also given to the number of
atoms of each kind.
bp=boiling point
2.2.
Standard Liquids
lII
IV
INTRODUCTION
Formulas for the organic compounds are written

with carbon first and hydrogen, if present, second.
Symbols for all remaining elements then follow ill
alphabetical sequence The arrangement of these
compounds in section C is determined first by the
number of carbon atoms, secondliv b% tile nulnber
of hydrogen atoms, and finally by thle symbols for
the remaining helements in alphal)etical order.'
2.4.
Estimated Accuracy of the Values

of Dielectric Constant
Values of dielectric constant recorded in sections

B and C have an estimated accuracy indicated by
tie number of figures retained.
(a) Values listed to four figures are considered
probably accurate to 0.5 percent or better,
(b) Values listed to three figures are considered probably accurate to 2 percent or better.
(c) Values listed to two figures are considered
probal)ly less accurate than 2 percent.
However, where lack of detailed information
makes any assignment of accuracy difficult or
where excessive rounding off is undesirable, an
additional figure is often retained which is not to
be counted in determining the probable range of
accuracy. Such figures are printed in smaller
type as subscripts. They are also retained when
significant with respect to variations of dielectric
constant with temperature or to differences
between isomeric or other closely related compounds in a series of measurements.
These estimates of accuracv were assigned
arbitrarily after considerations of the investigators' apparatus and methods, precision, probable purity of materials, and comparisons, where
possible, with the results of others,
Exception is made for certain series of polymers (e. g., polysiloxanes)
which may he represented by the general formula (X). or .4(X).H. where
n = 1, 2. 3. etc. The location of all compounds of such a series is determined
hy the formuia corresponding to n-l.
2.5. Variation of Dielectric Constant With

Temperature
Where
feasible,
the variation
of dielectric
constant with temperature is represented by one
of the following equations:
g1
0 et-Log, 0 f,-a(t'-t
(2)
where ,, 1, and a (or a if the value is followed

immediately by a in parentheses) are specified in
the table. Occasionally other equations are indicated in footnotes.
The range of temperature over which the equation is considered satisfactory appears under the
heading t,, t 2. This range was chosen such that
the deviations between the calculated and reported
values of e are not greater than one-fourth of the
accuracy assigned to E. Thus if E is listed to four
figures (discounting figures in smaller type), the
equation fits the reported data to 0.13 percent or
better over the specified range of temperature;
and, if e is listed to three figures (discounting
figures in smaller type), the equation fits the data
to 0.5 percent or better. Values of e falling outside of this range of temperature are listed at
selected temperatures.
2.6. Literature Reference in Table
All tabulated data are based on the references
indicated by numbers not enclosed in brackets.
The numbers refer to the bibliography following
the table. Some additional references not employed for one reason or another are enclosed in
brackets. These latter references are not intended to be complete with regard to data published for each substance but have been selected
on the basis that they probably merit consideration in any revision of the tabulated data.

of Pure Liquids
A. STANDARD LIQUIDS
E DO c
a (or a)
2o 0
CGH12
Cyclohexane ............................................
2.023
2.015
0.0016
CC14
Carbon tetrachloride ...................................
2.238
2.228
.0020
CoNs
Benzene ................................................
2.284
2.274
.0020
Cam0 Ce
Chlorobenzene ..........................................
5.708
5.621
.00133
C2H4Ca
1,2-Dichloroethane .....................................
10.65
10.36
.00240 (a)
CN4 O
Methanol ...............................................
33.62
32.63
.00260 (a)
CGNHN0 2
Nitrobenzene ...........................................
35.74
34.82
.00225 (q)
"2 0
Water ..................................................
80.37
78.54
.00200 (a)
H2
Hydrogen ...............................................
1.228 at 20.14 K
.00314
02
Oxygen ................................................
1.507 at 80.OK
.0024
(a)
*The values of a or a given in this table are derived from data in the vicinity of room temperature and
are not necessarily identical with the values listed in Parts 8 and C. They may be used to calculate values
of dielectric constant between 150 and 300 C without introducing significant error.
(1)
B. INORGANIC LIQUIDS
a (or a)
x10
toc
Substance
Range
References
t2.tr
0.34
-191,-184
0.33
100,240
93
Argon ........................
1.53o
AIBr 3
Aluminum bromide .............
3.38
100
AsBr
Arsenic tribromide ...........
9.0a
35
....................
17,20
AsC1 3
Arsenic trichloride ..........
12.e'
20
....................
14,17,20
ASH3
Arsine .......................
2.50
Asl
Arsenic triiodide ............
7.. 0
150
BBr3
Boron bromide ................
2.58
0.28
Br 2
Bromine ......................
3.09
20
0.7
C0 2
Carbon dioxide ...............
1.60c
20
C12
Chlorine ......................
2.101
-50
0.31
-65,-33
193
1.91
1.7,
1.54
111
77
142
0.32
-22,114
5,10,19
20
Cr0 2CI 2
Chromyl chloride .............
2.6'
D,
Deuterium ....................
1.277
D20
Deuterium oxide ..............
F,
Fluorine .....................
1.54
GeC1 4
Germanium tetrachloride ......
2.430
HBr
Hydrogen bromide .............
7.00
MCI
Hydrogen chloride ............
HF
Hydrogen fluoride ............
20 0 K
25
0.26(a)
-85
-73
-142
-27
0
....................
-50
22
0.8
....................
Hydrogen .....................
1.228
H20
Water ........................
20.4
78.54
25
34.5,
200
84.2
f= 4x 10 cycles/sec.
b 1=3.6 X10" cycles/sec.
SAt presure of 50 atmospheres.
4
E =78.25 [1 - 4.617(10-3)(t- 25) +1.22(10-5)(t- 25)2
(2)
0.240
25
0.288(a)
....................
....................
H2
av. dev. 0.0O4%.
0.19
-202
-15
-113
28
3.39
2.9b
-2.7(10-8)(t-25)3];
(d)
6.35
12.
4.6
Hydrogen iodide ..............
0.4
....................
HI
265
-70,80
64,87,226
0,50
39 [10,313
17
..................
25
17,.
20
....................
0.34
(')
(
(?)
226
183 [30]
-116,-72
....................
3.8b
Ill.
84.
Hydrogen peroxide ............
0.43
-100
78.25
134.
H2 0 2
-191
18.8,21.2-K 249
210 [135]
0.4,98
-216,-i9O
0,55
193
147
137 [296]
-85,-70
25
173
101,137,193
25
-85,-15
75
137
25
-51,-37
14,21-K
47,58,220,229,249
0,100
89,99,210,218 [50a,
105,112,118,264]
900,370
1)
284
291 [119]
-30,20
3
[I - 4.579(l0- )(t- 25) +1.19(10-5)
(t-25f- 2.8 (10-)(t - 25)3]; av. dev. +0.03%.
YE =5321/T+233.76- 0.9297T+0. 001417T
3
-0-0000008292T .
E =78.54
"E84.2- 0.62t+O.0032t
B.
INORGANIC LIQUIDS-Continued
a (or a)
tReferOence 2
Substance
References
Range
HS
Hydrogen sulfide .............
9.26
9.05
He
Helium .......................
1.0555
1.0559
1.0553
1.0539
1.051e
1.048
12
Iodine .......................
11.1
II.?
13.o
118
IIto
168
........
..........
117
NH3
Ammonia ......................
25.
-77.7
........
..........
152
22.4
-33. 4.
-85.5
-78.5
..................
...................
2.060 K .
2.30O
2.63
3.09
3.58
4.19
18.9
17.8
16.9
5
15
25
16.3
35
152
165
46,72,73 [290]
..................
...................
144
....................
175
NOBr
Nitrosyl bromide .............
13.4
15
....................
252
NOCl
Nitrosyl chloride ............
18.2
12
....................
252
N2
Nitrogen ......................
N2H4
Hydrazine ....................
N20
Dinitrogen oxide .............
1.454
52.9
1.97
-203
20
1.61
0
15
Dinitrogen tetroxide .........
2.5seb
02
Oxygen .......................
1.507
Phosphorus ...................
4.10
4.06
3.86
34
46
85
PBr 3
Phosphorus tribromide ........
3.9b
20
PCi
Phosphorus trichloride .......
3.43
25
PCl5
Phosphorus pentachloride.....
2.85
160
PH 3
Phosphine ....................
2.5,b
2.7,b
P13
Phosphorus triiodide .........
4.1b
POC1 3
Phosphoryl chloride ..........
PSCI 3
PbCl 4
Thiophosphoryl chloride ......

Lead tetrachloride...........
13.3
5.8
2.78
0.21(a)
-90
N2 04
0.29
0,25
....................
0.6
0.214
.
-6,14
-218,-183
59,193,224
126 E20]
....................
.........
123
20
..................
0.84
54,205,229 L93J
11,93
....................
-193
-60
-25
-210,-195
20
1',60
.........
...................
120 L14,20,26]
120 1108]
28
65
....................
20
22
....................
14,26
22
20
....................
..........
.........
26
65
f =3.6 X 10" cycles/sec.
rLiquid transition and discontinuity in variation of dielectric constant with temperaturb at 2.2950 K.
Values reported in reference 290 agree closely with those listed.
955049 0 - 51 - 2
B.
INORGANIC LIQUIDS-Continued
Substanco
SulfI
SOrta
......................
3.52
3.48
fig
231
Thionyl bromide ..............
9.06
20
SOcla
Thionyl chloride .............
9.25
20
SO,
Sulfur dioxide ...............
17.6
-20
125 [95J
3.0
at 20
203
3.9
at 20
203 [l14
0.287(a)
-65,-15
299
20
154h
3.11
4.79
is
Is
.........
..........
0.1 6(c)
-41,15
197 f1q1j
92 L114,26]
22
....................
26 [14.171
100
....................
20
Sulfuryl chloride ............
I0.o
Sb8r 3
Antimony tribromide ..........
20
SbC1 3
Antimony trichloride .........
33.b
SbCl5
Antimony pentachloride .......
3.22
SbH3
Stibine ............
2.9
.9b
3b
2 . 58
Se
.........
(9)
14.1
2.1o
SOaC1 2
Antimony triiodide ...........
References
Sulfur trioxide ..............

Sulfur monochloride ..........
Sb1 3
Range
15.08
s0o
SaCla
; .........
a (or ')
a2C
7.7
75
..........
20
0.46
-80
-50
,b
175
Selenium .....................
5.40
250
13
....................
294
14,110
.........
2,47
5,10,15 [l4-j
14
108 [lit]
....................
28
....................
20
0.25
237,301
SiCl
Silicon tetrachloride ........
2.4o
16
SnCl
Tin tetrachloride ............
2.87
20
0.30
-30,20
65,124 L14,22,26]
TiC1 4
Titanium tetrachloride .......
2.80
20
0.20
-20,20
65,124 [22]
VC14
Vanadium tetrachloride .......
VOBr 3
Vanadium oxybromide ..........
3.05b
.4 b
6b
25
3..
4b
25
3.
VOCl
Vanadium oxychloride .........
b f =3.6 xlO1
25
-70
....................
209
20
....................
33
....................
33
....................
33
cycles/sec.
'Graphical data in the

hCritical temperature.
range 118
-350 0 C show a minimum near 1600 and a broad maximum near 2000.
C. ORGANIC LIQUIDS
a (or ci)
xO
tC
Substac
References
Range
tt
CI
CCIO
Phosgene .....................
CC14
Carbon tetrachloride .........
.7 2 b
4.3 4 b
0
22
2.238
20
.........
0.200
.........
52
-10,60
146,169,233,240a,
245,292
CNO,
Tetranitrooethane ............
2.52,
25
CO
Carbon dioxide ...............
1.60,'
CS,
Carbon disulfide .............
2.641
3.001
20
-110
CNBr
CHC1,
0.268
-90,130
16,146,188,196,204,
240a,292
[80,200,20o7
2.19
180
Bromoform ....................
4.39
20
0.105(a)
10,70
97,156,160
Chloroform ...................
4.806
20
0.160(a)
0,50
85,146,169
6.76
-60 .
...................
70,94,187 E36,801
6.12
5.61
3.71
-40
-20
100
.......... ..........
16
3.3,
140
2.9,
ISO
158.1
I I.q
0
20
(1)
0.63(,)
Hydrocyanic acid .............
CH2 Br2
Dibromooethane ...............
7.77
6.68
10
40
CHICI
Dichloromethane ..............
9.08
20
(J)
CH2 1
Diiodomethane ................
5.32
25
....................
CH20
Formic acid ..................
58.5a
16
9.82
139 [10,31]
....................
CNN
225 [26]
...................
....................
94,123
(i)
-70,40
94 E12,41,1601
CHANO
Formamide ....................
CHSK0 2
Nitromethane .................
35.87
30
0.189(a)
CHNOs
Methyl nitrate ...............
23.,b
18
...................
CH,
Methane ......................
ChN0
Methanol .....................
1.70
32.63
64.
54.
40.
"f= , x log cycles/sec.

b f= 3.6 X 109 cycles/sec.
cAt pressure of 50 atomspheres.
Log o c = 2.199 - 0.0079t +0.00005t2
-173
72.
0.2
25
-113
-80
-20
7 E4,27-I
-70,-20
lodomethane ..................
20
97 [12"
(1)
Cthi
109.
94,285
94 [2821
Chloromethane ................
20
97
-80,0
CHC]
-20
255 r39,761
(k)
Bromomethane .................
7.00
-80,25
..................
CH38r
12.6
-13,18
18,26
0.264(a)
..........
18,25
270,280
12.92
78,295 [411
14
-181,-159
5,55
.........
93
218,264 [7t,112,207]
9
J 6 = (3320/T) - 2.24
k 6 = (3320/T) - 2.34
' e= 12.6-0.061 (t+20) f0.0005 (t +20)2
ffiE=(2160/ T) - 0.39
()
6
C.
ORGANIC LIOUIDS-Continued
Substanc
Methylamine ....................
CHN
a (or a)
X102
toC
i.1A
9.14
10
25
0.26(Q)
..........
....................
Range
ti~ta
References
-30,-10
123
..........
268
C2
C2 C12 02
Oxalyl chloride ..............
3.47
21
C2 C04
Tetrachloroethylene ..........
2.30
25
CIN 2
Cyanogen .....................
2.5,
23
..................
14
C2 HBr 3 O
Bromal .......................
7.6"
20
..................
27
C2HC1S
Trichtoroethylene ............
3.142
ca 16
...................
45
C 2 HC
Chloral ......................
4.94
7.6
4.2
20
-I0
62
0.17(Q)
C2 HC1 3 0 2
Trichioroacetic acid .........
4.6
60
.....................
C2 HCi 5
Pentachloroethane ............
3.73
20
30
C2 HF,0
C2 HaBrCl
Trifluoroacetic acid .........
39.5
26.2
20
-II
0.20
107
25,90
[1,71
E4
15,45
26
45,57,156
....................
-50.
100,196,279 [741
0,28
297
cis-I-Bromo-2-chloroethylene...
7.3,
17
....................
49
trans-I-Bromo-2chloroethylene
2.5o
17
....................
49
cis-l,2-Dibromoethylene ......
7.72
7.0,
0
25
...................
148
[It9
trans-I,2-Dibromoethylene ....
2.97
....................
18
[1491
2.8R
25
20
...................
17
8.6
...................
26
7.0
22
1,1-Dichloroethylene .........
4.67
16
....................
149
cis-1v2-Dichloroethylene .....
9.20
25
....................
227 [45,18,09,148]
trans-I,2-Dichloroethylene...
2.14
25
..................
196,227[05,4S,-49,18]
C2 112 C102 0 2
Dichloroacetic acid ..........
8.2
7.8
22
61
....................
26 [271
C2 H2C0 4
1,1,2,2-Tetrachioroethane ....
8.20
20
...................
53
C2H212
cis-i,2-Diiodoethylene .......
1.110
83
....................
48
3.1,
83
....................
48
20..
...................
17
C2 H2 Br 2
C2 H2 Br 2 0
Bromoacetyl
C2 H2 8r
l,I,2,2-Tetrabromoethane .....
C2 HIC1 2
bromide ..........
trans-l,2-Diiodoethylene .....
C
2 8r0
Acetyl bromide ...............
* f = 4 x 108 cycles/sec.
" f =5 x 10 cycles/sec.
122.4
16.s'
[45,571
7
C. ORGANIC LIQUIDS-Continued
la -(or a)
Substance
CHClO
C2H 3CI0
C2 H3Cl3
toC
Acetyl chloride ..............
16.9
15."
2
22
Chloroacetic acid ............
12.3
60
1,1,1-Trichloroethane ........
a (
xlO0
Range
...................
2.
7.1o
3.6
7.52
20
..........
References
t)
tt~t
26 [7,171
123 [1811
60,80
-33,2
234
.........
156
C2H 3 N
Acetonitrile .................
37.5
26.,
20
82
16.
C2 H3NO
Glycolonitrile ...............
68.'
20
..........
C2 NsNS
Methyl thiocyanate ...........
35.a
16
...................
17,18,22
Methyl isothiocyanate ........
19.3a
38
...................
17,18,22
7.14
7.98
20
-10
0.O140(a)
.78
4.09
25
131
0.60
.........
10,55
.........
12,144,156,199,272
41
18
.........
.........
1,27
C2 H4BrCl
I-Bromo-2-chloroethane .......
C2 H4 Br2
1,2-Dibromoethane ............
C2 H4C12
5,I-Dichloroethane ...........
.0.0
1,2-Dichloroethane ...........
10.65
10.36
10.3 6
12.7
20
25
25
-10
...................
0.235(a)
15,25
13,26,41,123
.........
17
10,90
I10
138,170,263
10,55
123,133,254,272
C2 H4 N20
Ethylene nitrate .............
28.,
20
..................
C2H4 0
Ethylene oxide ...............
13.,
-1
.........
.........
26
Acetaldehyde ..................
21.,-
10
.........
.........
21.1a
21
13.a
20
...................
6.15
20
.........
6.29
6.62
40
70
8.5
20
5.
20
0.196(a)
C2 H4 03
Ethanethiolic acid ...........
244
[41
17 E[87
(Thioacetic acid)
C2114 0 2
Acetic acid ..................
Methyl formate ...............

C2 H5Br
CHC1
C21sClO
Bromoethane ..................
Chloroethane .................
2-Chloroethanol ..............
(Ethylene chlorohydrin)
9.39
16.1
-90
13.6
-60
6.29
6.0,
5.13
170
179
4..6,
18 5 . 5 h
25.,
13.2
.........
0,20
-30,30
96,207 E7,1811
7,26
34,70,94 127,272
[207,2281
.........
.........
15
183
25
132
..................
41
Sf=4X JOs cycles/sec.

h Critical temperature.
"Value
chosen to conform with the remainder of the tabulated data for this substance.
8
Is
Substancft
CaH l
C218NO
lodoethane ...................
Acetamide ....................
Acetaldehyde oxime ...........
a (or a)
I X102
7.82
12.3
20
-90
0.150(a)
10.2
-50
59.4
83
.........
3.0
23
...................
-20,70
81,207 [7,12,1601
.........
17
26 [17,271
C2 N110
2
Nitroethane ..................
28.0,
30
II.4
30,35
CY N110
5
Ethyl nitrate ................
19.4
20
9.
0,50
C2 H.N2O
N-Nitrosodimethylamine .......
53.4
20
C2 H6 0
Ethanol ......................
24.30
24.3z
41.0'
25
25
-60
25
110
120
125
126.1
127.6P
References
Range
t 'ts
295
7,17,26 [4,141
....................
.
Lilt]
17
..................
0.270(a)
-5,70
0.297(a) -110,-20
111,174
111,112,207
81 [971
2.38
161
Methyl ether .................
5.02
2.97
2.64
2.37
2.26
1.90
25,100
n =4
OctamethylcycIotetrasiloxane..
2.39
20
....................
266
n=
Doecanethylcyclopentasiloxane
2.50
20
...................
266
n =6
Dodecamethylcyclohexasiloxane
2.59
20
....................
266
n =7
Tetradecamethylcycloheptasiloxane
2.68
20
...................
266
n =8
Nexadecamethylcyclooctasiloxane
2.74
20
....................
266
37.7
25
0.224(a)
60.,
- 30
...................
122 L17,26,1431
236
(C 2H6 OS')n
CA
2 N5 02
C2 H6 04 S
l.(,
......
Methyl sulfate ...............
48.3
42.s
C2NAS
C2OIN
C211N2
0
20
Ethanethiol ..................
6.91
15
...................
Methyl sulfide ...............
6.2'
20
..........
Ethylamine ....................
6.94
10
(0)
Dimethylamine ................
6.32
5.26
0
25
..........
20
10.
1,2-Ethanediauine ............
a f=1,xlO cycles/sec.
o E -6. 94-0.O036( t- 10) +O.O0004(t-
14.2
112 [26,131, 142,2361
20,100
.........
17
-20,10
123
.........
268
10,27
1O)2
'Critical temperature = 126.9 0 C.

'Value chosen to conform with the remainder of the tabulated data for this substance.
199
[l11
Sustnc
Substanco
lO= a)
a (or
References
it
Range
C3
C3 2N
N2
Malononitrile ................
46.b
36
....................
is
C 3 1 4 C02 0
I,I-Dichloro-2-propanone .....
I14.,"
20
...................
27
C 3 H 5 Br
3-Iromo-l-propene ............
7.4
7.0
I
19
...................
26
CM,6rO,
a-Bromopropionic acid ........
21
....................
27
CH
1,2,3-Tribromopropane ........
6.45
20
...................
244
3-Chloro-l-propene ...........
8.7
8.2
I
20
...................
26 [271
C 31 5C1N,0 6 3-Chloro-l,2-propanediol
17.5
20
...................
244
I-Chloro-2-propanone .........
30.n
19
...................
27
3-Chloro-l,2-epoxypropane ....
(Epichlorohydrin)
25
.,
22.,
1
22
..................
26 [271
Ethyl chloroformate ..........
II.o.
20
....................
17 [27]
Methyl chloroacetate .........
12. "
21
...................
27
13.3
20
...................
2414
27
5 Br3
C3 N5 Cl
.lI.o.
dinitrate
COHIClO
C3 H5 C10 2
C3 15C0 2 N10 1,3-Dichloro-2-propanol

nitrate
COHICl 3
1,2,3-Trichloropropane .......
7.5n
20
...................
C3 "11
3-1odo-l-propene .............
6.1n
19
..........
.........
27
CimN
Propionitrile ................
31.0
27.2
214.3
0
20
50
.........
.........
13,17,26
C3 H5 NO
Lactonitrile .................
38.4
20
.........
.........
17
C3 HINS
Ethyl thiocyanate .............
34.5
29.3
3
21
....................
26 [17,18,22]
Ethyl
23.4
19."
2
21
....................
26 [17,18,221
19.3
20
...................
244
1.87,
1.79
1.69o
20
145
65
.........
1.53o
I.1411
1.33,
85
90
91.9h
4.3"
20
isothiocyanate .........
C015 N309
1,2,3-Propanetriol
(Nitroglycerin)
Propene ......................
C3 NHBr2
1,2-Dibromopropane ...........
f=14x I0s cycles/sec.

= 3.6 X 10 cycles/sec.
" f= 5 x 108 cycles/sec.
trinitrate
...................
.........
161
27
10
a (or a)
Substance
C35.C12
1,2-Dichloropropane ..........
2,2-Dichioropropane ..........
C3H1N6142
C3 NO
8.93
26
.10.1,
References
Range
x|O
10sReeene
.........
20
0.247(a)
.........
107
-33,20
234
1,2-Propanediol dinitrate ....
26.,
20
....................
1,3-Propanediol dinitrate ....
19.0
20
..........
2-Propen-l-ol
21.,
15
..........
20.7,
25
0.205(a)
17.7
56
.........
.........
Propionaldehyde ..............
18.59
17
.........
.........
7 E41
Propionic acid ...............
3.30
3.41
10
140
.........
149 [5,7,271
Ethyl formate ................
7.1,
25
.........
.........
160 [1,77
Methyl acetate ...............
6.68
25
2.2
(Allyl
alcohol)
Acetone ......................
C3 A02
.........
244
..
p5,240,271
,2071
-60,40
25,40
63,260
C3 H7 Br
I-Bromopropane ...............
8.09
25
2-Bromopropane ...............
9.46
16.1
25
-85
4.40
....................
CHCI
I-Chloropropane ..............
7.7"
20
....................
27
C041C102
3-Chloro-l,2-propanediol .....
3
19
...................
26
CNH
7
I-lodopropane ................
7.00
20
...................
242
2-lodopropane ................
8.19
20
....................
242
I-Nitropropane ...............
23.24
30
10.1
30,35
295
2-Nitropropane ...............
25.5,
30
10.9
30,35
295
Ethyl carbamate (Urethan) ....
14.2
50
5.2
50,70
123 [141
Isopropyl
12. b
19
.........
13.,b
18
....................
1.61
nitrite ............
CIH7 N03
Propyl nitrate ...............
COSI
Propane ......................
C3118
I-Propanol ...................
20.1
38.
29.
2-Propanol ....................
a f= 4x 1Oe cycles/sec.
b f 3.6 x l10 cycles/sec.
n f= 5 X S0s cycles/sec.
18.3
....................
27J
di-Lactic acid ...............
37.
31.
17
.........
C3 H6 03
CH1NO,
22.
..........
21414
3.35
0.20
25
0.293(a)
-80
-311
....................
25
0.310(a)
4,8 [7]
1,55
272
1,55
272
211
.........
14
14
-90,15
172
20,90
112,222,279
[DI,,51,157, 1771
9
20,70
112,222
[1571
II
Substance
Ca3sO2
a (or a)
slOt
taC
Range
References
1,2-Propanediol ..............
32.0
20
0.27(a)
at20
232 [1421
1,3-Propanediol ..............
35.o
20
0.23(a)
at20
232
2-Methoxyethanol .............
16.0
30
....................
261 [1151
20
...................
17
25
-
0.208(a)
Dimethoxymethane (Nethylal)..
2.7a
C31H8 0
Glycerol .....................
C01
9 803
Trimethylborate ..............
8.0a
20
....................
CH1
0
Isopropylamine ...............
5. 5 b
20
..........
Trimethylamine ...............
2.414
25
0.52
2.55
25
....................
279
42.5
0,100
40,112,185
E38,103,142,1771
17
.........
14
0,25
268 [4l1
C4
C4 C16
Nexachloro-1,3-butadiene .....
C4 N102
Maleic anhydride .............
50.a
60
....................
17
C4 H4 N%
Succinonitrile ...............
56.5
53.6
52.3
57.4..
67.7
78.2
...................
199 [14,17]
..................
153
Pyrazine .....................
2.80
50
C4 H4 0
Furan ........................
2.95
25
.........
C4 WHS
Thiophene ....................
2.76
16
...................
C4 HC15 0
a,a,a.-Trichlorobutyraldehyde
(Butyl chloral)
I0.o"
18
C4 11C5030
Ethyl trichloroacetate .......
7.8
20
CCNoN
Crotononitrile'
36.1
ca20
...................
48
28.,
ca 20
...................
48
Crotononitrile'
(bp
108C)...
(bp
122 C)...
Pyrrole ......................
7.48
8.
.........
121
12,283 [181
....................
2.8
27
2,60
.........
.........
26
171
C4 H1
5 10
Methyl cyanoacetate ..........
28.,-
20
...................
17
C4 HNS
Allyl isothiocyanate .........
17.2b
Is
...................
18,22
C4 N0Ci,0 2
Ethyl dichloroacetate ........
1..s
...................
26
10.3
22
Vinyl ether ...................
3.94
20
..................
121
Ethoxyacetylone ..............
8.05
25
....................
257
I
19
..................
26 E17,27,1661
C4 NO0
C4 HsO,
Acetic anhydride .............
22.,
20..
Sf =-4 x o0 cycles/sec.
bf-3.6 XION cycles/sec.
"
"I>
IN
I
f-5x108 cycles/sec.
4 cis- trans Isomers.
40
CI
955049 0- 51 - 3\
t
12
* (or a=)
Subs tance
toc
Range.eerne
References
(bp 95*C)..
5.8,
ca20
...................
.8
(bp 86C)..
5.0
ca20
...................
.8
6.7,
ca20
2-Bromo-2-butene" ............
5.3.
ca20
...................
48
CNHBrOa
a-Bromobutyric acid ..........
7.20
20
...................
27
C0HC1102
Propyl chloroformate .........
20
...................
27
CN,Br
I-Sroao-l-butene'
I-Bromo-l-butene'
2-8romo-2-butene
.. . . . . . . . . . . .
.II.,-
...................
48
Ethyl chloroacetate ..........
Il1.4'
21
....................
27
Butyronitrile ................
20.,b
21
....................
13
Isobutyronitrile .............
20.4.b
24
...................
13
meso-2,3-0ibrouobutane .......
6.214
25
...................
238
dl-2,3-Dibromobutane .........
5.75S
25
...................
238 [1841
I,2-Dibromo-2-methylpropane..
14.1I
20
....................
27
I,F1-Oichlorobutane ...........
8.90
25
i, 2-1ichl oro-2-methy I propane
14.0
10.8
8.71
7.22
-100
-60
-20
20
...................
2117
CHCIO
,6,,8'-Dichlorod iethyl ether...
21.2
20
...................
156
CH1811 306
1,3-Butanediol dinitrate .....
18.,
20
...................
244
2,3-Butanediol dinitrate .....
28.,
20
...................
214
2-Butanone ...................
18.5t
20
0.207(a)
Butyraldehyde ................
13.4
10.8
26
77
...................
Ca117N
Ca,,sr,
CHCI,
CI,0
C1H110
CaNeO,
3.07
1,55
-60,60
E18414
272
20 ['41,814,1231
.I1
Butyric acid .................
2.97
20
-0.23
Isobutyric acid ..............
2.71
2.73
10
40
...................
149 [2,7]
Propyl formats ...............
7.72a
19
...................
Ethyl acetate ................
6.02
25
77
...................
....................
. 3o
Methyl propionate ............
5.50
i9
I,14-Dioxane ..................
2.209
25
O-Nydroxyethyl acetate
(Glycol monoacetate)
f.
jxIS0 cycles/sec.
3.6 x I0' cycles/sec.
f *5x10
cycles/sec.
b f
"
13.0
30
1.5
0.170
10,70
at25
96,149 [2,71
8,63,276
.1
27
20,50
...................
4 cis-trans isomers.
I Br and CIis tramw.
*Br and CBH cis.
i144,156,196,230,231,
240a, 258,271,276
261
13
toe
u exl02
SubstancE
C4 BBr
97,243,272
7.88
-10
I-Bromo-2-methylpropane ......
7.18
25
2.8
1,55
272
2-Bromobutane ................
8.64
25
3.30
1,55
272
10.1,
25
5.20
-15,55
213,243,272
20
0.173(a)
-10,70
97,242
I-Chlorobutane ...............
I-Chloro-2-methylpropane .....
7.39
-90
-50
-30
7...................
247
12.2
-120
10.1
-89
7.87
-38
6.149
14
10.95
0.225(a)
I-Iodobutane .................
6.22
8.89
7.53
4.52
20
-80
-40
130
0.135(a)
I-lodo-2-methylpropane.......
6.147
20
....................
2-lodopropane ................
7.87
20
..........
.........
242
8.42
10.5
20
-33
,..........
..........
.........
.........
242
213
2-Chloro-2-methylpropane.....
2-Iodo-2-methylpropane .......
C4 119NO3
10,90
20
-90
-50
9.94
9.07
C4 H9 NO
0.150(a)
References
7.07
12.2
C4 11*I
Range
t .ta
11.1
9.26
I-Bromobutane ................
2-Bromo-2-methylpropane ......
C4 HC3
a (or a)
2-Butanone oxime .............
3.14
20
..................
Morpholine ...................
7.33
25
.........
20
....................
Butyl nitrate ................
13.,
-23,30
0,80
109,213
41,97,242
242
27
.........
225
241
ILI
19 ...........................
Isobutyl nitrate .............
1 1.,b
C4 HioHg
Diethyl mercury ..............
2.3
23
....................
C4 H1 0 0
I-Butanol .....................
17.8
17.1
8.2
20
25
118
0.300(a)
0.335(a)
..........
-140,20
25,70
..........
81,222,278
279
41
2-Methyl-I-propanol ..........
17.7
314.
25
-80
0.377(a)
..........
20,90
..........
12,85,103,112,222
9
26.
-34
2-8utanol.....................
b f= 3.6 x 108 cycles/sec.

"f 5x 10 cycles/sec.
15.8
25
...................
17,22
222
114
Substance
toc
a (or 2a)
Range
References
r ItI 2
C4Ho,
0 0-Con.
2-Nethyl-2-propanol ..........
Ethyl ether ..................
10.9
8.49
6.89
30
50
70
'.335
20
2.0
4.341
20
0.217(a)
-116
10.4
3.97
2.12
1.8
1.53
C4Hto02
1,14-Butanediol ...............
C4111 002
I,I-Dimethoxyethane ..........
CH
Ethyl sulfite ................
C4 1 10 04
-40,30
207 [36,80,143,1871
0.170(a)
180
16 L15,19,791
40,1140
.3h
15
30
....................
236
20
...................
298
17.,
15.,
13.1
I
20
50
...................
26
Erythritol (1,2,3,4Butanetetrol)
28.2
120
....................
131,142
C4 H1 0 04 S
Ethyl sulfate ................
29.2
20
0.24(a)
C4H 1 0 3
I-Butanethiol ................
4.95
4.59
25
50
...................
I"40
Ethyl sulfide ................
5.72
5.24
25
50
....................
140
C4 HN0 Zn
Diethyl zinc .................
2.5a
20
.........
.........
132
C4H11 N
Butylamine ...................
5.3b
21
.........
.........
14
Isobutylamine ................
. 4.1b
21
...................
Diethylamine .................
3.6b
22
..........
Tetramethyl silicate .........
6.
10 0,S
C4 N1 2 0,Si
32..
30.2
12,35,62,96,251
at2o
....................
40
180
190
193
109 ['3,112,142,
157,261]
....................
3.49
ca 20
2.60
20
-25,20
122
14
.........
...................
114,22
22
C5
C5FeO5
Iron pentacarbonyl ...........
ClH40 2
Furfural .....................
6.,
41.,
34.,
CeHsN
Pyridine .....................
12.3
9.14
CaHNOa
Ethyl cyanoacetate ...........

.a-Cyanoethyl acetate .........
26.,
I18.a
...................
1.
20
50
25
116
20
20
114
.........
.........
26 E71
..................
..........
.........
51,53,159 [166]
41
...................
...................
7,17,26
17
a f= x tOo cycles/sec.
b f= 3.6 x l10 cyclesfsec.
'
Value chosen to conform with the remainder of the tabulated data for this substance.
15
Substance
C5 He
a (or a)
X0
tC
1,3-P'+adiene t . . . . . . . . . . .
2-Methyl-I,3-butadione ......
(Isoprene)
. .
2.32
2.10
25
25
.....................
0.24
-. 51
.....................
Range
ti.ta
-75,25
References
1011,130
129
C5 NeO
Cyclopentanone ..............
16.,
C8HO18
2,4-Pentanedione ............
(Acety I acetone)
25.7,
20
....................
7,17,18
Cai 8 0 4
Dimethyl malonate ...........
10.'"
20
.....................
17 [27]
C5 HBrO,
a-Bromoisovaleric acid ......
6.5"
20
....................
27
.....................
26 [27]
Ethyl a-bromopropionate .....
I0.o
9.3
22
Isobutyl chloroformate ......
9.1n
20
....................
27
Ethyl a-hloroproplonate ....
10.,"
20
....................
27
8.6"
20
.....................
27
C'1oClO,
CH,10s
Ethyl /)-iodopropionate ......
CHN
Valeronitrile ...............
17.4b
21
Isovaleronitrile ............
18.,b
22
.....................
Ca11o
C,,H,3r,
CAP1o9
.....................
I-Pentene ...................
2.100
20
..........
2-Methyl-I-butene ...........
2.197
20
.....................
Cyclopentane .................
1.965
20
..........
13
13
..........
248 [151]
248
..........
248
Ethylcyclopropane ...........
.1.933
20
.....................
248
1,2-Dibromopentane ..........
.4.39
25
.....................
150
.....................
238 [150j
dl-erythro-2,3-.............
Di bromopentane
5.4 o
25
dl-threo-2,3 ................
Di bromopentane
6.50,
25
.........
Cyclopentanol ...............
18.0
25.,
20
-20
2-Pentanone .................
15.4,
22.0
20
-60
0.195(a)
3-Pentanone .................
17.0,
20
0.225(a)
19.4
-20
19.8
-140
0.38(a)
..........
10.1&
17
..........
Valeric acid ................
2.6s
20
.....................
Isovaleric acid .............
2.64
20
..........
Valeraldehyde......
CSH1 oO2
237
"f= 4X108
b f =3.6 x l10
cycles/sec.
cycles/sec.
n f=5x108 cycles/sec.
'Mixture of cis-trans isomers.
.........
..........
238
at2O
..........
232
237
-40,80
0,80
..........
240 E7,814]
240 [7,81]j
7 [4']
2,7,27
..........
16
Substance
toc
r a)
Range
References
C5 1110 0,-Con.
7
6.14,
19
Propyl acetate ..............
5.69
19
0.8
atl9
7,8
Ethyl propionate ............
5.65
19
1.8
atil9
7,8
Methyl butyrate .............
5.6m
20
C8 91 0 02
Diethyl carbonate ...........
2.82
20
CBN 1 1 8r
I-Bromopentane ..............
6.32
9.90
25
-90
6.05
10.2
8.04
20
-107
-56
I-Brono-3-methylbutane ......
C'M1 ,C!
....................
L1]
Isobutyl formats ............
27
..................
298
....................
- 45,55
211,272
2.3
-18,23
212
120.6
...................
2-Bromo-2-methylbutane ......
9.1n
19
....................
27
I-ChIoropentane .............
6.6
II.
..................
I-Chloro-3-methylbutane .....
6.05
10.0
8.63
20
-100
-70
2-Chloro-2-methylbutane .....
12.3
-60
9.3
16
I-Fluoropentane .............
4.21
20
2-Fluoro-2-methylbutane .....
5.89
I-odopentane
...............
0.160(a)
-40,23
0.32(a)
-77,-
247
50
217
2
....................
L27J
..................
243
20
....................
243
6.81
20
..........
I-Iodo-3-mothylbutane .......
5.6.
19
....................
27
3-lodopentane ...............
7.43
20
....................
242
2-Iodo-2-methylbutane .......
8.19
20
...................
242
CSHIIN
Piperidine ..................
5.Sb
22
..................
1I
C5 1111NO
2-Pentanone oxime ...........
3.3"
20
...................
27
CH 1 MNO,
Amyl nitrate ................

(bp I140-II45oC)
9.0"
18
....................
22
C8 NHsF
CH
11
Can-Pentane
...................
2-Methylbutane ..............
f , I X 10 cycles/sec.
bf=3.6x10s cycles/sec.
ff 5 x 108 cyles/sec.
1.8s1
2.011
1.984
20
-90
-70
1.843
20
0.160
L7,22J
0.152(a)
4.70
L27]
..................
.........
-50,30
242
88
196
17
(or a)
Substancea
C5 H1 O
I-Pentanol ..................
13.9
25
0.23(a)
References
Range
j,.xL
15,35
142,177,222
3-140thy I -I-butanol ..........
.14.7
5.8s
25
132
....................
11,51,63,276
2-Methyl-2-butanol ..........
5.82
25
...................
51,85,276 [2613
CH1
120
Xylitol .....................
CsN1 3S
I-Pentanethiol ...............
4.55
4.23
25
so
..................
1S40
CsN 1 2S 4
Tetramethylthionothane ......
2.82
70
..................
250
CN
Amylamine (bp 950C) .........
.5 b
22
...................
14
I-Broeo-2-chlorobenzene .....
6.80
20
....................
83
I-Broso-3-chlorobenzene.....
.. 4.5,
20
...................
83
o-Olbromobenzene ............
7.35
20
....................
55,63
m-Dibroeobenzene ............
4.80
20
..................
55,83
p-Oi bromobenzene ............
2.5,
95
...................
55
37.,
so
..................
176 [32]
31.6
80
27.,
23.7
110
140
21.s
163
18 N
[9]
40.
20
........
..........
131,142
[I'4,163
C6
CI4,BrCI
CH 4 8rs
CN 4 CINO,
I-Chloro-2-nitrobenzene .....
I-Chloro-3-nitrobenzene.....
20.,
18. 1
15.,
14.1
13.0
CHCI,
CNHl,
CeHBr
s
80
sIo
...................
176 [260]
140
160
I-Chloro-4-nitrobenzene .....
8.0,
120
0.16(a)
85,160
o-Dichlorobenzeno ...........
9.93
25
0.194(a)
0,50
69 [53,55,61,1793
m-Oichlorobenzene ...........
5.04
25
0.120(a)
0,50
69
p-Di ch lorobenzene ...........
2.41
50
0.18
o-Dilodobenzene .............
.5.7
20
...................
50,80
176 [32]
55,94 [61]
55
m-Dilodobenzene .............
4.25
25
.........
.......... 55
p-Oiiodobenzene .............
2.8,
120
.........
.......... 55
Bromobenzene ................
5.40
25
bf:3.6 X 10
cycles/see.
0.115(a)
j55,61"]
0,70
60,61,86,194,272
Subtan
Substance
CH
C1
Chlorobenzene ................
tCW)~
5.708
5.621
a (or
20
25
..........
0.130(a)
ti.ta
Range
.........
0,80
References
60,138,170.251
41,69,70,86,123,133
187,194,207
5.71
7.28
6.30
4.21
20
-50
- 20
130
o-Chlorophenol ...............
6.31
25
2.7
25,58
57,61,261
p-Chlorophenol ...............
9.47
55
3.7
55,65
61,261
CHF
Fluorobenzene .................
5.42
4.76
25
60
..................
C6 15 1
lodobenzene ..................
4.63
20
.........
CeHnNO,
Nitrobenzene .................
34.82
25
0.225(a)
10,80
20.8
24.9
22.7
130
90
110
0.1614(x)
130,211
207
17.,
50
6.4
50,60
261
2.284
20
0.200
10,60
12,77,138,190,2504,
263,273,283a,292
2.073
1.966
129
182
C6 H5 ClO
C'HNO,
o-Nitrophenol ................
CeHs
Benzene ......................
..........
153,255a 83
.........
.........
243,83
85,138 [12,38,41,
78,141,1914,251]
16
27
-Bromoaniline ...............
13.0n
19
...................
CHCIN
m-Chloroaniline ..............
13.,-
19
.........
CIIC16
a-Hexachlorocyclohexane ......
(mp 1560c)
4.7,
156
Ce He N,0,
o-Nitroaniline ...............
34.,
90
3.
90,110
260
p-Nitroaniline ...............
56.3
160
6.
160,180
260
CeHeBrN m
Phenol .......................
9.78
60
0.32(a)
CNN
Aniline ......................
6.89
20
0.1148(a)
5.93
70
CGH@
2-Methylpyridine (a-Picoline)
9.8b
1,3-Cyclohexadiene ...........
2.6e
b f = 3.6 x 108 cycles/sec.
a f=Sx i0 cycles/sec.
184.6
20
-89
27
237
...................
C0 HO
1..5k1
.........
t40,70
0,50
61,123,145,
194
6,66,122,159,171,251
.........
.........
l914
..........
.........
141 [38]
...................
.........
14
.........
237
19
tQC
Substance
CaH6 142
a (or a)
X1O2
Range
References
tlt
12 [22,27]
Phenylhydrazine ..............
7.2
23
....................
2,5-Dimethylpyrazine .........
2.436
20
0.13
20,50
153
2,6-Dimethyloyrazine .........
2.653
35
0.30
35,65
153
4.4
78
....................
237
CaHmo0
I,4-Cyclohexadione ...........
CtlCIlO
cis-Ethyl 3 -chlorocrotonate..
7.67
18
....................
49
trans-Ethyl ,3-chlorocrotonate
4.70
18
....................
49
Cyclohexene ..................
2.220
25
..........
2.6,
105
....................
237
2,'-Hexadienet ...............
2.22
25
....................
130
2-Methyl-l,3-pentadienel .....
2.42
25
....................
104,130
3-Methyl-l,3-pentadienet .....
2.43
25
....................
104,130
4-Methyl-1.3-pentadiene" .....
3.16
2.81
2.60
2.49
75
25
25
50
....................
129,130
2,3-Dimethyl-l,3-butadiene...
2.10
25
cot"o
35.98
237
....................
232
15.1&
20
....................
17
Butoxyacetylene ..............
6.62
25
....................
257
CaH1 0 0 2
Ethyl crotonate ..............
5.4n
20
....................
27
CaH oo
Propionic anhydride ..........
18.8.3
16
....................
27
Ethyl acetoacetate ...........
15.,-
22
.....................
Diethyl oxalate ..............
8.11
21
....................
Dimethyl succinate ...........
5.1
20
....................
32
Bromocyclohexane .............
7.92
25
0.140(a)
65
....................
237
7.414
25
...................
238
7.269
25
C6 N,,Br
4-Nethyl-'-penten-2-one ......
(Mesityl oxide)
15.,
129,130
....................
....................
CNIoO
0 4
18.3
19.,
-50,50
271
20
40
C6 HoO
Cyclohexanone ................
0.17
.........
11.0
C6 HBrO
2
dl-threo-2-Acetoxy-3-.........
1,55
272 [98]
bromobutane
dl-erythro-2-Acetoxy- .........
3-bromobu tane
'f=4XI10
cycles/sec.
*f=5 x10S cycles/sec.

'Mixture of cis-trams isomers.
"Some polymerization at the higher temperatures.
955049 0 - 51 - 4
I,
....................
238
20
C. ORGANIC LIQUIOS-Continued
Range
tilts
a (or 2i)
ubstanc
10
References
CON 1, BrO2 -Con.
CH 11 Cl
Ethyl a-Dromobutyrate ........
8.0M
20
...................
27
Ethyl a-bromoisobutyrate .....
7.9n
20
...................
27
Chlorocyclohexane ............
7.6
25
10.9
...................
-477
98
....................
237
COHIIC10 2
Isoamyl chloroformate ........
7.80
20
...................
27
C'HNIN
Isocapronitrile ..............
15.,b
22
....................
13
COH 1 1N0
Cyclohexanone oxime ..........
3.04
89
...................
237
C6H11 N1
Amyl thiocyanate .............
19.5
....................
18
(bp
CH12
C6 H,2 Br2
CH11 2 0
C H62 02
17.1 b
1959C)
Cyclohexane ..................
2.023
20
Methylcyclopentane ...........
1.985
20
Ethylcyclobutane .............
1.965
20
cis-3-Nexene .................
2.062
25
trans-3-Hexene...............
2.000
25
...................
239
dl-3,4-Dibromohexane .........
6.732
25
...................
238
meso-3,1-Dibrobohexane .......
4.67'
25
...................
238
25
100
150
0.437(a)
Cyclohexanol .................
15.0
7.24
4.88
I-Methyl-i-cyclopentanol .....
6.97
34.6
2-Hexanone ...................
14.6
14.5
4-Methyl-2-pentanone .........
13.11
18.8
3,3-Dimethyl-2-butanone ......
(Pinacolin)
13.1
...................
248
..................
239
20,66
35,98,207 [84,261]
....................
237
..................
84
0.210(a)
-20,100
240
84 [7,18]
....................
192 [27]
..................
160 [7]
Amyl formate ..................
6.4,
25
Butyl acetate ................
5.01
20
1.4
20,40
7,8,10,37,260
-73
Isobutyl acetate ............
5.29
20
Propyl propionate ...........
4.7n
20
Ethyl butyrate ..............
5.10
18
bf=3.6X108 cycles/sec.
f = 5 X 10 cycles/sec.
"Extrapolated from mixtures containing both isomers.
LI
248
....................
71
"
81,146,188,190,196.
259,292
111.5
2.63
. 8k
10,60
...................
20
-60
Caproic acid .................
0.160
1.6
at20
...................
1.0
7,8,10,57
27
at20
7,8
21
Substance
to0
a (or a)
1101
COH
Range
t .ta
References
1 2 0 2 -Con.
C6 1H
12 0,
Methyl valerate ..............
4.3f
19
....................
tt-Hydroxy-1-methyl-2-.........
pentanone (Diacetone alcohol)
18.2
25
.........
7.57
30
3.1
13.9
6.29
25
128
6-Ethoxyethyl acetate ........

("Cellosolvel acetate)
Paraldehyde ..................
C.H13 8r
I-Bromohexane ................
.5.82
6.30
25
I
C,113 l
I-lodohexane .................
5.37
20
CH,
1 N
Cyclohexylamine ..............
5.37
-21
CS"14
n-Nexane .....................
1.890
2.044
1.990
20
-90
-50
CHs140
I-Hexanol ....................
COH1402
.........
30,50
..................
1.73
25,55
.........
.........
237
- I0,;rC
88 [35,116,207]
3.3,
26
Isopropyl ether ..............
3.88
25
1.8
0,25
30
14.5
30,35
25
...................
3.80
272
242
Propyl ether .................
24.4
E17,26]
.........
25
75
2-Methyl-2,'-pentanediol .....
260
.........
0.155
0.35(a)
115
11
13.3
8.55
I,I-Diethoxyethane ...........
Co1s40 6
27
15,35
..................
103,177
107
156,206 [107,198]
295 [232]
85,102 [7,26,298]
Sorbitol .....................
33.5
80
.........
.........
131,142
Mannitol .....................
24.6
170
.........
.........
131,142
.........
91
CeHsAl
Triethyl aluminum ............
2.9
20
..........
CeHysN
Dipropylamine ................
2.9b
21
....................
14,22
Triethylamine ................
2.42
25
...................
206 [26]
CeHisOSi,
(CH8 ) 3 Si [Si(CH,)2]ICH3
"n=I
Hexamethyldisiloxane .........
2.17
20
....................
266
n =2
Octamethyltrisiloxane ........
2.30
20
....................
266
n =3
Decamethyltetrasiloxane ......
2.39
20
....................
266
n= 4
Dodecamethylpentasiloxane ....
2.16
20
...................
266
Tetradecamethylhexasiloxane..
2.50
20
....................
266
2.72
20
n =66*
....................
b f= 3.6 X 106 cycles/sec.

n f5
X 10 cycles/sec.
wSilicone oil of average molecular weight corresponding to this formula.
266
22
a (o
toc
Substance
a)
References
C7
CH C5O
Benzoyl chloride .............
C7NSCl
a,a,a-Trichlorotoluene .......
C.115 F3
a., a-Trifluorotoluene .......
C7 H1N
Benzonitrile .................
CH 9NO
Phenyl isocyanate ............
C7 H5 NS
Phenyl
29.
23.
0
20
.........
6.9"
21
....................
.........
43 [22]
22,27
9.18
30
8.09
60
25.20
24.02
22.10
25
40
70
0.157(a)
20
....................
22 E[8]
10.,6.9n
20
20
....................
.........
.........
17,22 [i8]
27
....................
26,56 E[',7,22]
8.
isothiocyanate ........
.........
.........
0,25
255a
85,138 [194]
C7H 602
a,a-Oichlorotoluene ..........
C.He0
Benzaldehyde .................
19.,
17.9
0
20
CH1
6 02
Salicylaldehyde ..............
17.
30
C7 H7 Br
o-Bromotoluene ...............
4.28
58
....................
61 [27]
m-Bromotoluene ...............
5.36
58
....................
61 [27]
p- Bromotoluene ..............
5.49
58
....................
61 [27,32]
C7 H7 BrO
p -Bromoanisole ..............
7.06
30
C7 H1C1
o-Chlorotoluene .............
1.6
30,40
261
[14,7,17]
260
.45
20
....................
83 [27]
58
....................
61
5.55
20
...................
83
5.014
58
....................
61
p-Chlorotoluene .............
6.08
20
....................
83 [27,32]
5.55
58
....................
61
a -Chlorotoluene .............
7.0
13
o -Fluorotoluene .............
4.22
30
3.88
60
5.42
30
60
.........
.........
255a
4.90
5.86
30
..........
.........
255a
5.34
60
.........
32
m -Fluorotoluene .............
P -Fluorotoluene .............
..........
.
p- lodotoluene ...............
4.4
35
.........
CYHTNO
Benzaldehyde oxime (trane)...
3.8
20
....................
f , 4 XI08 cycles/sec.
xlog cycles/sec.
b f3.6
cycles/sec.
.........
..................
COHOI
"f=5x108
30,40
4.16
m-Chlorotoluene .............
C7 H7 F
7.
2 7]
2 E27]
255a
8 [7,27]
23
a (or a)
Substance
tOC
References
Range
tlta
15.
at20
12,85 [50]
58
222
..........
..........
.........
.........
61
41
23.,
20
.........
.........
53 [27]
21.,
58
..........
.........
61
p-Nitrotoluene ..............
22.,
58
.........
.........
61 [32]
CAH
7N03
m -Nitrobenzyl alcohol .......
22.n
20
...................
CTHS
Toluene ......................
0
25
127
181
0.0455(a)
0.243
CHO
Benzyl alcohol ...............
C7 HNO,
o-Nitrotoluene ..............
m -Nitrotoluene ..............
27.4
20
21.,
11.8
2.438
2.379
2.15,
2.04,
27
-90,0
0,90
16,60,188,196,223,
229 [36,80,207]
20
..........
.........
26,56 [8,256]
9.47
70
..........
.........
194
6.6
132
..........
.........
117
o-Cresol ....................
11.5
25
m-Cresol ....................
11.8
25
13.1
II.
0.41(a)
p -Cresol ....................
9.91
58
.........
Methoxybenzene ...............
(Anisole)
4.33
25
1.1
3.89
70
..........
I1..7
28
....................
25,30
261 [61]
15,50
56,1145,261 [43,61]
.........
20,40
.........
61
66,!44,260,277
194
27
C7 11802
o -Methoxyphenol
CHN
Benzylamine ..................
5.5
4.6
4.3
I
21
50
.........
.........
26 [27]
o-Toluidine .................
6.34
18
.........
.........
171 [14,27,117]
5.71
58
..........
.........
61
4.00
200
..........
.........
41
5.95
18
.........
.........
171 [14,27]
5.45
58
..........
.........
61
p-Toluidine .................
4.98
54
.........
61,145 32
N-Methylaniline .............
5.97
22
.........
.........
159,171
I-Methyl-l-phenylhydrazine...
7.3n
19
....................
(Guaiacol)..
m-Toluidine .................
C7 1H1 oN
n f = 5 X 106 cycles/sec.
........
27
14,26
211
Substanc
C7H 11 F3
Cyclohexyltrifluoromethane
II .,
-85
CH,,O
2-Methylcycohexanone ........
16.,
- Is
3-Methylcyclohexanone ........
Is.,
l14.,
12.,
'4-1ethylcyctohexanone ........
is.,
12.,
C?"H1 X2
Cyclohexanecarboxylic acid...
C0H
1 2 03
a (or a)
xIo
tC
Range
ti . ts
...................
..................
20
.........
- 89
.........
-41
20
237
237
.........
..................
20
References
232
237
.........
232
....................
237
....................
232
2.6,
31.
Ethyl levulinate .............
II.. 6
21
C7H 1 2 O4
Diethyl malonate .............
8.03
25
CHlsClO,
Isoamyl chloroacetate ........
7.8n
20
...................
27
CHI4
Methylcyclohexane ............
2.020
20
....................
196 [107]
2.26
-129
...................
237
I-fleptene ....................
2.05
20
..................
151
2-Methyl-2-hexene ............
2.9,
20
.........
1,2-Dibromoheptane ...........
3.77
25
...................
150
2,3-Dibromohaptane ...........
5.08
25
....................
150
3,4-Dibromoheptane ...........
4.70
25
....................
150
Cyclohexanemethanol ..........
9.70
60
....................
256
8.0,
80
C,1H 4 Br.
CTHe 4 0
.........
.........
....................
3.
237
7
25,30
.........
260,276 [7,27]
283
2-Methylcyclohexanol ..........
13.,
20
0.56(a)
at20
232 [261]
3-4ethylcyclohexanol .........
12.,
20
0.43(a)
at2O
232 [261]
4-Methylcyclohexanol .........
13.,
20
0.41(a)
at20
232 [261]
22
....................
20
0.200(a)
Heptaidehyde .................
2-Neptanone ..................
9.07
11.9,
i4.3
7.10
3-Reptanone ..................
12.9
4-Heptanone ..................
12.5o
15.1
8.00
"If=1 X log
"nf.5 xIO
cycles/sec.
cycles/sec.
90
0,100
2410 [90]
-20
110
22
20
-20
120
.........
0.205(a)
.........
0,100
90
90,240 [7,814]
25
a (or a)
x10
Substance
C7 113,Os
CT
I,
CtHI
5 BrO
CHNaCi
CINlSI
C7 H1 6
References
Range
.ts
.........
192
*t20
7,8,10,57,
160
Heptanoic acid ...............
2.59
71
.........
Amyl acetate .................
4.75
20
1.2
Isoamyl acetate ..............
4.63
30
1.3
Propyl butyrate ..............
4.3"
20
..........
.........
27
Ethyl valerate ...............
..471
18
0.9
atl8
7,8 [27]
I-6romoheptane ...............
5.33
'4.148
25
90
1.40
5.96
5.58
-10
10
2-gromoheptane ...............
6.146
22
3-Bromoheptane ...............
6.93
4-Bromoheptane ...............
30,40
25,70
260,276
90,97,272
-70,-I0
97,286
..........
.........
90
22
..........
.........
90
6.81
22
..........
.........
90
I-Bromo-2-ethoxypentane ......
6.45
25
...................
2-Bromo-3-ethoxypentane ......
6.40
25
.........
3-Bromo-2-e~hoxypentane ......
8.24
25
...................
150
I-Chloroheptane ..............
5.48
22
...................
90
2-Chloroheptane ...............
6.52
22
...................
90
3-Chloroheptane ..............
6.70
22
...................
90
4-Chloroheptane ..............
6.54
22
....................
90
I-lodoheptane .................
4.92
22
...................
90,242
3-lodoheptane ................
6.39
22
..........
Heptane ......................
1.924
2.071
1.850
20
- 90
70
2-Methylhexane ...............
1.919
20
0.1i
at20
71
3-P4ethylhexane ...............
1.927
20
0.114
at20
71
3-Ethylpentane ...............
1.939
20
0.146
-120,80
71
2,2-Dimethylpentane ...........
1.912
20
0.146
-120,80
71
2,3-Dimethylpentane ..........
1.939
20
0.15
at20
71
1.914
20
0.15
at20
71
1.937
20
0.15
at20
71
2,2,3-Trimethylbutane ........
1.927
20
0.13
t20
71
nf=5 XIOs cycles/sec.
0.155(a)
0.140
ISO
.........
150
.........
90
-50,50
71,88,292
26
SubstancP
C7 H1 6 O
C?
7 H1 00
t0C
a (or a)
xO
References
Range
lt
I-Heptanol ...................
12.1o
22
.........
.........
90
2-Heptanol ...................
9.21
22
..........
.........
90
3-Heptanol ...................
6.86
22
.........
.........
90
4-Heptanol ...................
6.17
22
.........
.........
90
Ethoxypentane ................
3.6
23
...................
I-Ethoxy-3-methylbutane ......
3.96
20
1.3
120
..........
27.4
Glucoheptitol ................
29 E27]
20,50
.........
66
131,142
Ca
CsH2 C12 F6
4,5-Dichloro-i,3-bis .........
(trifluoromethyl)-benzene
CsH1C1F0
2-Chloro-I,3-bis-.............
(trifluoromethyl)-benzene
4-Chloro-1,3-bis-.............
(trifluorowiethyl)-benzene
3.1,
2.9,
30
60
...................
255a
3.2,
3.0o
30
60
..................
255a
5.44
'1.96
30
60
.........
.........
255a
.........
255a
CsH41F
1,3-bis-......................
(trifluoremethyl)-benzene
5.98
5.37
30
60
......... ..
CsH6
Ethynylbenzene ...............
(Phenylacetyleone)
2.98
25
....................
257
C8 HCl2
2,5-Dichlorostyrene ..........
2.58
25
...................
279
CsHO
Phenoxyacetylene .............
4.76
25
...................
257
CsH
6 e0
Phthalide .....................
75
.........
2..
...................
23
.........
.........
13
27
234
..........
.........
41 [7,13,17,26]
..........
..........
CsHCl,
3-Chloroethyl-2,5-di-.........
chlorobenzene
36.
5.20
o -Tolunitrile ...............
18., b
Phenylacetonitrile ...........
18.7
8.5
COH 7 NO
Mandelonitrile ...............
17.2
CsH7 NO4
Methyl o-nitrobenzoate .......
27.s
CsHs
Styrene ......................
(Phenylethylene)
CsHO
Phenylacetaldehyde ...........
C5 HN
Acetophenone .................
"f=4X10 8 cycles/sec.
bf= 3.6 x 1O0 cycles/sec.
27
....................
2.43
2.32
25
75
.........
4.8'
20
...................
17.39
25
4.
9.64
202
..........
.........
7
279
14
139]
107
.........
162,196,279
7
at25
.........
138,260 [12,26,117]
41
27
ORGANIC LIQUIDS-Continued
C.
a (or 2i)
Substance~
Ce"902
x10 2
tC
Phenyl acetate ...............
5.23
20
0.7
Methyl benzoate ..............
6.59
20
0.14(a)
p-Methoxybenzaldehyde ........
(Anisaldehyde)
22.3
10.4
22
248
Range
t~t
at20
20,50
...................
7,8,10,57
7,8,56,66,260
41 [17]
Methyl salicylate ............
9.41
30
Ce"1o
Ethylbenzene .................
2.412
20
o-Xylene .....................
2.568
20
0.266
- 20,130
3,107,116,196
m-Xylene .....................
2.371
20
0.195
- 40,180
3,12,16,35,107,116,
207,229
p-Xylene .....................
2.270
20
0.160
20,130
62,107,116,128,196,
248,271
I-Phenylethanol ..............
8.90
20
0.22(a)
20,90
256
2-Phenylethanol ..............
13.0
9.04
7.63
20
60
90
..........
Ethoxybenzene
(Phenetole)
11.22
20
0.90
o-Methoxytoluene .............
3.5,
20
...................
23 [22,27]
20
...................
23 [27]
m-Methoxytoluene .............
CON,
0 02
.4.0
30,40
261,276
CHIO
C'"'OG
3.1
References
....................
3,248
.........
20,50
135]
256
66,260 [56]
p-Methoxytoluene .............
4.03
20
...................
23 [27]
3,4-Dimethyl-I-hydroxybenzene
4.8n
17
...................
27
16
...................
4,8
2-Methoxy-tt-me thy I phenol

(Creosol)
II.
32
o-Dimethoxybenzene
(Veratrole)
4.5
23
Methylbenzylamine ............
4.4"
19
N-Ethylaniline ...............
5.76
20
2.
N,N-Oimethylaniline ..........
4.91
4.42
20
70
2.
.9"
20
...................
Ethyl fumarate ...............
6.56
23
...................
186 [167]
Ethyl maleate ................
8.6,
23
...................
186 [167]
C8 H11 N
2,4-Dimethylaniline ..........
CgH 1 2 04
"f=5XlO
cycles/sec.
....................
27
...................
0,20
at20
26,53 [27]
26,56,159,171,178,
194
114,22,27
28
a (or 2 )
Substance
COH 1 4 03
CuH 1 404
Clla
1
COHN1
COH 16 0
Range
References
0.t
Butyric anhydride ............
12.,-
20
....................
Isobutyric anhydride.........
13.-
20.
.....................
27
7 [27]
Diethyl succinate ............
6.64
30
meso-2.3-Diacetoxybutane.....
6.64,
25
....................
238
di-2,3-Diacetoxybutane .......
5.I0'
25
....................
238
cis-3-Octene .................
2.062
25
....................
239
trans-3-Octene...............
2.002
25
..........
.........
239
cis-4-Octene .................
2.053
25
..........
.........
239
trans-I4-octene ...............
2.004
25
....................
239
3-Methyl-2-heptene ...........
2.14t
20
....................
283
2,5-Dimethyl-2-hexene ........
2.43
20
....................
283
3,5-Dimethyl-2-hexene ........
2.65t
20
....................
283
2-Octanone ...................
10.39
12.5
1.0
0.215(a)
30,40
260
7.142
6.10
20
-20
100
160
Caprylic acid ................
2.,5
2.54
20
71
....................
...................
181
192
Isoamyl propionate ...........
4.2n
20
....................
27
Isobutyl butyrate ............
4.1"
20
....................
27
Propyl valerate ..............
q.0"
19
..........
0,60
240 [7,81]
.........
27
CH
1 7 Br
I-Bromooctane ................
6.35
5.00
-50
25
1.9
1.33
-55,39
1,55
286
272
CH
7 Cl
I-Chiorooctane ...............
5.05
25
1.70
1,55
272
I-Iodpoctane .................
.1.62
25
1.17
1.55
242,272
2-lodooctane .................
5.77
20
..........
n-Octane .....................
1.948
1.879
1.817
20
70
110
2,2,3-Trimethylpentane.......
1.96
20
2,2,4-Trimethylpentane .......
1.940
20
CON 1 7 1
CONIS
* f=4 XI08 cycles/sec.

" f=5X100 cycles/sec.
t,41xture of cis-trans isomers.
'Extrapolated
from mixtures containing both isomers.
0.130
..........
0.9142
.........
242
-50,50
88 [35]
.........
35
-100,100
71
29
C.
Substance
Com1s1
Substnce
I -Octanol ....................
t(:
10.34
11.3
20
- 10
10
12.0
- 10
13.3
2-Octanol ....................
a X
(or0aa)
ti ,ts
Ran"
0.4l10(z)
20,60
.........
.........
References
81,82
82,217
8.20
20
6.52
5.61
40
56
3-Octanol ....................
9.88
8.18
7.03
6.16
5.68
-20
0
20
40
54
4-Octanol ....................
8.97
7.76
5.97
5.12
4.70
4.51
- 3
-20
0
20
40
55
2-Methyl-I-heptanol ..........
8.23
6.28
5.15
ft. 48
It.15
-20
0
20
40
55
....................
82
.. 3.24
3.12
2.98
2.87
2.79
2.75
-32
-20
...................
82
6.40
5.30
4.53
'4.02
3.73
-20
....................
82
4-Methyl-l-heptanol ..........
..................
....
82
82
.....
0
20
40
55
0
20
40
59
7.47
5.37
20
55
0.430(a)
6-Methyl-i-heptanol ...........
10.2,
14.3
12.2
20
-20
0
0.104(a)
2-Methyl-2-heptanol ..........
3.46
3.149
3.38
3.38
25
-33
-13
-7
-0.30
-20,43
82
17,55
82
5,50
82
30
Subs tance
CeH1 6 O-Con.
3-Nethyl-2-hePtanol ..........
to
IE
a (or a)
Rn"t
0.23(a)
-8,30
References
7.33
10.8
9.13
20
- 44
-20
6.22
55
I,-Methyl-2-heptanol ..........
4.6
3.90
3.63
3.52
3.36
- Is
0
20
40
60
..........
.........
82
5-04ethy I-2-heptanol ..........
8.6
7.5
- 18
5
..........
.........
82
6-Methyl-2-heptan01 ..........
10.3
6.20
5.17
4.70
-20
20
40
55
..........
.........
82
3.37
20
-40
-12,35
82
2.71
2.88
-20
3.60
3.75
40
60
3.58
3.57
3.63
- 30
- 20
0
3.714
20
-1.30
....................
32
82
3.84
40
3.89
60
5.25
7.11
6.59
20
-52.5
-30
4.62
55
6.13
8.60
7.48
7.08
20
-'43
-20
0
0.185(a)
18,57
82
5.50
8.70
20
- 42
0.202(a)
17,55
82
7.16
-20
0,36
82
-143,0
5,55
82
14-MethyI-3-heptanol ..........
6.22
2-04ethyl-4-heptanol ..........
3.30
2.93
0.178(a)
-8,42
82
0
20
-1.05
-20
3.65
60
9.09
7.36
-20
20
0.248(a)
0.204(a)
31
Substanca
a)
(or
Xl1
0
C,11 1 O0-Con.
Range
References
t l, t a
2.87
2.53
2.59
2.70
3.27
20
-44
20
0
60
Butyl ether ...................
3.06
25
COH 19 N
Diisobutylamine ..............
2. 7 b
22
....................
Ik
CHo04 Si
Tetraethyl silicate ..........
1. lb
ca20
....................
22
9.00
5.05
25
238
..................
........
- 1.04
........
10,55
..........
82
I14,198
C9
CHtN
Quinoline ....................
41,156,159
Isoquinoline .................
10.7
25
CHO
Cinnamaldehyde ...............
16.9
24
....................
107
C9111
I-Phenyl-l-propene ...........
2.73
20
....................
215
2-Phenyl-l-propene ...........
2.2,
20
....................
215
3-Phenyl-f-propene ...........
2.6,
20
....................
215
a-Indanol (mp 550C) ..........
7.83
7.lo
6.74
60
80
90
....................
256
a-Indanol (mp 40oC) ..........
7.73
00
60
90
....................
256
7.11
6.4,
7.2,
80
....................
256
15. 5
17
....................
....................
27
CHoO
,5-Indanol (mp 70 0 C) ..........

I-Phenyl-I-propanone .........
(Propiophenone)
C9H11 0 0
COHNoO3
COHIS
..........
159
Benzyl acetate ...............
5.1"
21
Ethyl benzoate ...............
6.02
20
Methyl p-methylbenzoate ......
4.3
33
....................
32
Methyl o-methoxybenzoate .....
7.7&
21
...................
Ethyl salicylate .............
7.99
30
Propylbenzene ................
2.36,
20
Isopropylbenzene .............
(Cumene)
2.38,
20
....................
p-Ethyltoluene ................
2.240
25
0.19
4f=
X08 cycles/sec.
f=3.6 X108 cycles/sec.
"
f= 5 X108 cycles/sec.
2.1
2.
20,40
30,40
....................
7,8,56,178,189,260,
276
261 [7,8,27]
3,35 [1]
3,35 [1,7]
25,45
158
32
I'JC
Substance
CsN, 1 --Con.
.12,4-Trisethylbenzene
a (or o)
,ton
Range
tIt tt
References
2.42
17
....................
1,3
1,3,5-Trimethylbenzene
(Mesitylene)
2.27,
20
....................
196 [1,35]
C'H1 3 O
a-Ethoxytoluene
(Benzyl ethyl ether)
3.9n
20
....................
27
CH1 N
Benzylethylamine .............
20
....................
27
(Pseudocumene)
.1.3"
N,N-Dimethy]-o-toluidine .....
3.n
20
N,N-Dimethyl-p-toluidine .....
3.9n
20
....................
27
2411 [27,232]
...................
27
Cell140s
Glyceryl triacetate
(Triacetin)
7.1,
20
....................
COHIs0
Diethyl glutarate .............
6.66
30
2.7
di-erythro-2,3-Diacetoxypen tane
6.734
25
....................
238
di-threo-2,3-Diacetoxypentane..
5.22,
25
....................
238
t-Ethyl-3-heptenet ............
2.4,s
20
....................
283
2,6-Dimethyl-2-heptene ........
2.61
20
....................
283
3,6-0imethyl-3-heptenet .......
2.65
20
...................
283
14.5
...................
81
0"
20
....................
27
Isobutyl valerate .............
3.8n
19
.........
.........
27
CHlBr
I-Bromononane .................
5.112
4.74
-20
25
1.3
1.13
-35,16
1,55
286
272
CH 1 5 Br0
I-Bromo-2-ethoxyheptane .......
5.48
20
....................
150
2-Bromo-3-ethoxyheptane .......
5.22
25
...................
150
3-6romo-1-ethoxyheptane .......
6.241
25
....................
ISO
n-Nonane ......................
1.972
2.059
1.847
1.787
2-Methyloctane ................
1.97
20
....................
35
14-Methyloctane ................
1.97
20
....................
35
Collis
C9H1 s0
2,2,'4,1-Tetramethyl-3pentanone
(Hexamethyl acetone)
C91 1 8 0
Isoamyl butyrate ..............
Co"2o
f = 5 x106 cycles/sec.
tMixture of cic-trans isomers.
10.0
..
20
-50
110
150
0.135
30,40
- 10,90
260
88
[J5]
33
0
t C
Substance
a (or
a)
Range
References
CeNSo-Con.
2,4-Dimethylheptane ..........
1.89
20
..........
.........
35
2,5-Oimethylheptane ..........
1.8,
20
..........
.........
35
2,6-Dimethylheptane ..........
1.99
20
..........
.........
35
ClO
272 [7,12]
C1 0 H7 Br
I-Bromonaphthalene ...........
4.83
25
0.87
25,55
CIoNCI
I-Chloronaphthalene ..........
5.014
25
1.07
1,55
C10ts
Naphthalene ..................
2.54
85
.........
.........
196,246
C1 oNIoN2
2,3-Dimethylquinoxaline ......
2.28
25
..........
.........
153
C 1 0 N1 0 02
I-Allyl-3,4-methylenedioxybenzene (Safrole)
3.1'
21
...................
7 [22]
I-Propenyl-3,4-methylenedioxybenzene (Isosafrole)
3.36
21
...................
7 L22]
CIoNoO
0 4
Dimethyl phthalate ...........
8.5
24
....................
232
C1o
0
Dicyclopentadiene ............
2.43
40
0.20
k10,100
2111
1,2,3,11-Tetrahydronaphthalene (Tetralin)
2.757
20
0.29
10,40
163,196
12
C1o
1
0H
Ethyl phenylacetate ..........
Isobutylbenzene ..............
t-Butylbenzene ..............
I-Methyl-11-isapropylbenzene
(p-Cymene)
20
60
90
...................
256
8.17
6.76
5.2,-
21
...................
....................
103 E2.2]
10.5
4-Allyl-l-hydroxy-2methoxybenzene (Euqenol)
Clo01
....................
.II.
Tetrahydro-f/3-naphthol ........
C1 0 H1 2 0,
15
It.
Cumaldehyde
(p-Isopropylbenzaldehyde)
2.35
17
..........
.........
1,3
2.38
20
.........
.........
35
2.24,
20
C10 1H4 0
Carvone .......................
I1.b
CloH 1 4 02
di-2,3-Camphanedione .........
16.,
CIo1
15 N
CIoN 1 5 NO
272
22
2
0.16
.........
4,60
.........
3,100,158 E11,196]
22
203
...................
237
N,N-Dieth laniline ...........
5.5"
19
...................
27
Camphoric imide ..............
5.5
249
..................
237
a f = X 108 cycles/sec.
bf=3.6XlOs cycles/sec.
Sf=5 x lOb cycles/sec.
34
0
Substanc'ot
C1
H,
a (or 2a)
X10
Range
t~t
References
d-Camphene.....................
2.33
ca 0............. ......... 237 [24]
d-Pinene......................
2.64
25............. ......... 164 [204]
I-Pinene......................
2.76
20............. ......... 196 [24]
Terpinene.....................
2 .7 b
21............. ......... 22
d-Limonene....................
2.3,
20............. ......... 24
2.3,
20.......................24
di-Limonene (Dipentene) ....

C10H160
6T
Dihydrocarvone ................. 8.5,'
19.......................7
Carvenone.....................
19.
20............. ......... 7,8
Pulegone......................
9.5&
20............. ......... 7
Fenchone......................
12.8
21............. ......... 232
Thujone ...................... 10o."
0............. ......... 232
C10 H17 C1
di-8ornyl chloride .............
5.21
95.......................237
C10H11
5-Decyne (Dibutylacetylene).
2.173
25
0.148
25,125
154
cis-Decahydronaphthalene...
2.19,
20
0.11
20,100
128,275
trans-Decahydronaphthalene..
2.172
20
0.11
20,100
128,275
Menthone......................
8.8b
18............. ......... 22 [27]
C1011
180
11.8
C1 0H20
cis-5-Decele...................
2.071
trans-5-Docene ................. 2.030
-35.......................232
.........
25.............
239
25.......................239
5-lMethyl-4-nonenet .............
2.1s
20.......................283
2,4,6-Trimethyl-3-heptenet..
2.29
20.......................283
C10 " 20 0
I-a-Menthol....................
3.95
42............. ......... 237 [289]
C10 H20 02
Isoamyl valerate...............
3.6n
19............. ......... 27
C10H21 8r
I-Bromodecane..................'11.44
4.75
C1 0H2 2
n-Decane......................
1.991
2.050
1.844
1.783
2,7-Dimethyloctane .............
C10 " 22 0
1.07
25,55
272
20
-30
130
170
0.130
10,110
88
1.983
20
0.137
20,120
I'll[35]
1-Decapol......................
8.1
20............. ......... 142
Amy] ether....................
2.77
25
0.7
25,40
7,198,260
Isoamyl ether..................
2.82
20
0.50
20,50
66
&f=4 )(108 cyclIes/sec.

f=3.6 X 100 cycles/sec.
nf =5 108 cycles/sec.
tMixture of cis-trans isomers.
b
25
1
35
Substanc*
Subtace
a xlO"
(or a)
ti.ta
Range
References
C1 oH"23
Amyl sulfide .................
3.83
3.59
26
50
..........
.........
I140
C10 1H4N
Diisoamylemine ...............
2.5b
18
..........
.........
22
I-Naphthonitrile .............
I6. 0 b
70
2-Naphthonitrile .............
1 6.9b
70
....................
I4
CII
ClIHN
0.16(a)
22,70
lit
C11i1o
I-Methylnaphthalene ..........
2.71
20
....................
113,202
C 1 1H12 02
Ethyl cinnamate ..............
6.1
Is
....................
8,56 [7,216,260]
C1 1 H1 203
Ethyl benzoylacetate .........
12.,
20
....................
8 [7,17]
ClIH1 4 02
Isobutyl benzoate ............
5.38
20
4-Propenyl-l,2-dimethoxybenzene (Methyl isoeugenol)
4.7
Is
....................
C11 H1 4 0,
Ethyl o-ethoxybenzoate .......
7.0&
21
....................
C1 11H1
I-Methyl- 4-tert-butylbenzene...
2.33
20
CIINIe0 4
dl-erythro-3,'4-Diacetoxyheptane
6.684
25
di-threo-3,' -Diacetoxyheptane
5.02,
25
CssH,20
2-Undecanone .................
8.14
14.5
C1 1 I1 5 ar
I-Bromoundecane ..............
4.73
C1 1 "H4
n-Undecane ...................
2.005
2.039
1.838
1.781
-.9
20
-10
150
190
1.1
0.20
at 20
7,8,10 [27]
167
7
0,60
...................
158
238
.....................
238
....................
84
...................
286
0.125
10,130
88
C1 2
C,,HO
Dibenzofuran .................
(Diphenylene oxide)
3.00
100
CIAH
1O
Diphenyl .....................
2.53
75
0.18
C15 H 0oO
Azoxybenzene .................
5.1
40
..........
C lsloO
5
Phenyl ether .................
3.65
30
0.7
C1 2H"1 N
Diphenylamine ................
3.3
52
....................
32
C1 2HI 2 0
I-Ethoxynaphthalene ..........
3.3"
19
....................
27
C1 2H 1 60
o-Cyclohexylphenol ...........
3.97
55
....................
237
p-Cyclohexylphenol .............
4.42
131
............
237
ff,4 X 10
b
cycles/sec.
3.6 XIO1 cycles/sec.
Sf =5 XlO1 cycles/sec.
....................
232
75,155
.........
30,50
67
289
66,260 [289]
36
C.
f
Substance
a (or 2 a)
x10
toC
Range
References
t.ta
C1 3 H1 602
Amyl benzoate ................
5.00
20
C12HIe0 3
Isoamyl salicylate ...........
5.n"
20
....................
27
C1 2 H1 00s
Bornyl acetate ...............
21
....................
232
C 1 2I22
6-Dodecyne
25
0.1I8
C1 2 H3 2 Oe
Dibutyl tartrate .............
9.4
C1 2 H2 ,Br
I-Bromododecane ..............
4.07
25
0.9
1,55
272
C,,HiC1
I-Chlorododecane .............
4.17
3.85
25
55
1.2
1,40
272
C121 2l
I-lodododecane ...............
3.93
20
C12 1H
2
n-Dodecane ...................
2.014
2.047
1.776
C12 "2 60
I-Dodecanol ..................
6.5
25
C12 H27 04 P
Tributylphosphate ............
7.95,
30
.1.6
(Diamylacetylene)
2.171
0.7
at20
25,125
....................
1.
20
-10
210
0.120
154
242
10,150
....................
2.74
L27]
232
....................
..
7,8,10
88
281 [112]
30,35
295
C13
C1 3Ho 0 0
Benzophenone ..................
C13 H 0 03
Phenylsalicylate .............
C13 H12
Diphenylmethane ..............
C1 3 HI 4 04
Ethyl a-benzoylacetoacetate
ClSH2oO
a-Ionone .....................
3
i -Ionone .....................
50.. .
....................
180 [26,260]
6.3
50
....................
289
2.57
25
0.14
12.
21
....................
. 10.
19
..........
11.7
25
20,50
8 [7]
.........
..................
C13H2 4 0 4
Diethyl azelate ..............
5.13
30
1.6
C1 3 H2e0 2
Ethyl undecanoate ............
3.55
20
0.83
C,3 H27 Br
I-Bromotridecane .............
4.20
10
2.72
I10
95
120
66,269
253
253
30,40
-22,28
260
201
....................
286
..................
246
..................
68 E32]
C14
C1 0
4
Phenanthrene .................
10
C1 4 H 0 02
13.0
Benzil .......................
12.1
C14 HI2 02
Benzyl benzoate ..............
C14HisOa
C1 4 11
C,4 H1 SN
4.9"
20
Benzyl salicylate .............
.14.5"
20
...................
1,2-Diphenylethane ...........
2.38
110
0.17
3.6b
20
..........
Dibenzylamine ................
bf
3.6 X 1OS cycles/sec.
" f=
5X 1O0 cycles/sec.
...................
27
27
57,178
........
67
114,22
37
t'xl=tCr
-Substance
a (or a)
Range
References
Diethyl benzalmalonate .......
8.0
7.6
5.9
0
20
70
CI4HaeO4
Diethyl sebacate .............
5.00
30
1.2
30,40
260
CI,4 H20 0
Ethyl dodecanoate
(Ethyl laurate)
3.44
2.73
20
143
0.65
20,100
67
C1 4 H3 *Sr
I-8romotetradecane ...........
3.84
25
0.80
1,55
272
C1 4 "30 0
I-Tetradecanol ...............
.72
38
C14 MI60
11.10
118
....................
....................
281
..................
221
....................
286
Cls
C1 5 12 4
Cedrene ......................
3.27
25
C1 H3
8 19r
I-Bromopentadecane ...........
3.89
20
C16
3
C1 6 H2 2 O4
Dibutyl phthalate ............
6.4
C1 8 H 30s
2
Palmitic acid ................
2.30
71
C1 61H 3 8r
I-Bromohexadecane ............
3.71
25
C16 H33 1
I-lodohexadecane .............
3.50
20
C 165
I-Nexadecanol ................
3.82
50
34 0
30
1.98
30,35
....................
0.7
181,192
25,55
....................
1.7
295 [267]
272,293
212 [27]
48,67
191,201
C17
C1 7 " 3 4 0
9-Neptadecanone ..............
5.3
60
....................
195
C1 7TN
Monomyristin .................
6.1
70
....................
214
35
....................
237
404
Cis
C1 8 H30 0 4
Dicyclohexyl adipate .........
't.8a
C1 0N3 ,02
Linoleic acid ................
2.61
2.71
2.70
2.60
20
70
120
C1 0
33 "NaO
2
C1 8 H3 4 02
C1,H 3 4 04
ff=
x 10
Sodium oleate ................

Oleic acid ....................
Dibutyl sebacate .............
cycles/sec.
2.8a
ep
2.46
20
2.45
2.41
60
100
4.540
30
..........
.........
....................
.........
208,235,262
21
.........
136,181,208,
235,262
1.07
30,35
295 [267,279]
38
C.
ORGANIC LIOUIDS-Continued
Substance
CIsH 3 6 02
a (or a)2
Stearic acid .................
2.29
2.26
70
100
Ethyl palmitate ..............
3.20
20
2.71
2.46
104
182
C,,11 8 Br
I-Bromooctadecane ............
3.53
30
C1 9 113 8 0
I-Octadecanol ................
3.42
3.35
58
63
....................
....................
0.4
67,181,192
262
20,40
201
67
....................
0.5
References
Rtne
27,58
....................
293
281
C19
C19 H16
Triphenylmethane .............
2.45
100
C1 ,H1304
Monopalmitin .................
5.34
5.09
67
80
0.114
.........
94,175
.........
67
287
C20
C20oH3 0,
Ethyl oleate .................
3.17
2.63
28
150
0.48
28,122
67
C2 0 114 0 0 2
Ethyl stearate ...............
2.98
2.69
2.48
40
100
167
0.6
32,50
67,201,260
C2 1
C2 ,13
0 4P
C2 1 "4 2 03
C2 1 "
42
04
Tricresyl phosphate ...........
6.9
40
....................
219
L-Methoxyethyl stearate .......
3.39
50
....................
260
Monostearin ..................
4.87
4.71
77
89
..................
287 [214]
..................
232
...................
26
C 22
C2 2 H42 02
Butyl oleate .................
4.0
25
C2 2 1H
4 2 03
Isobutyl ricinoleate
(Isobutyl 12-hydroxy-9octadecenoate)
4.7
21
C2 2 H4 4 02
Butyl stearate ...............
3.11,
30
0.53
30,35
295
C2 2 1 45 8r
I-Bromodocosane ..............
3.12
55
0.5
43,60
293
C2 2 H4 6
n-Docosane ...................
2.00
50
I-Docosanol ..................
2.96
70
C2
H4 6 O
..................
195
....................
281
C23
CzsH4eO
12-Tricosanone ...............
.. 4.0
80
I.
72,90
195
39
C.
Substance
(or a)
Range
References
C 214
C2 4 113 0 0 4
DibenzyT sebacate ............
4.6
25
....................
267
C2 4 "380
Dioctyl phthaate ............
5.1
25
....................
267
4.01
26
....................
279
2.82
25
....................
155
3.52
3.119
72
76
....................
288
C3 6 H,,Cu0 4 Copper oleate ................
2.8,-
mp
....................
21
CsB"He,04Pb Lead oleate ..................
3.7,-
mp
....................
21
3.32
3.29
78
82
....................
288
2.927
60
Triolein .....................
3.20
25
Tristearin ...................
2.78,
70
C2 6
C2 0 H5 o04
Dioctyl sebacate .............
C3 4
C3 4 "6
Tetratriacontadiene ..........
C35
C356l8 05
1,3-Dipalmitin ...............
C 36
C3 9
C3 917 6 0 5
1,3-Distearin ................
C5 1
C5 1 HOSOO
Tripalmitin ..................
0.32
60,70
288
C 57
C5 7 ",,
4 06
C57H11o0o
a f 14 x O08 cycles/sec.
..................
0.34
235 [2081
70,80
288 [262]
4. BIBLIOGRAPHY
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1925
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U.S. GOVERNMENT
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Di Electric Const. For Pure Liquids

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Di Electric Const. For Pure Liquids

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NBS CIRCULAR

Table of Dielectric Constants

UNITED STATES DEPARTMENT OF COMMERCE

PERIODICALS OF THE NATIONAL BUREAU OF STANDARDS

Technical News Bulletin

Basic Radio Propagation Predictions

Table of Dielectric Constants

Arthur A. Maryott and Edgar R. Smith

National Bureau of Standards Circular 514

1. Introduction ------------- -------------------------------2. Description of table ---.-------------------------------------2.1 List of svmhol

Table of Dielectric Constants of Pure Liquids

The preparation of additional tables

dipole moments is in progress.

The assemblage and evaluation of the data

of Standards with the assistance of 'I.

suggestions from M. E. Hobbs of Duke University,

2. Description of the Table

2.3. Chemical Formulas and the Order of

The table consists of three sections: A, Standard

Formulas for the organic compounds are written

Estimated Accuracy of the Values

Values of dielectric constant recorded in sections

2.5. Variation of Dielectric Constant With

constant with temperature is represented by one

of the following equations:

where ,, 1, and a (or a if the value is followed

Table of Dielectric Constants

Carbon tetrachloride ...................................

Aluminum bromide .............

Arsenic tribromide ...........

Arsenic trichloride ..........

Arsenic triiodide ............

Boron bromide ................

Carbon dioxide ...............

Chromyl chloride .............

Deuterium oxide ..............

Germanium tetrachloride ......

Hydrogen bromide .............

Hydrogen chloride ............

Hydrogen fluoride ............

av. dev. 0.0O4%.

Hydrogen iodide ..............

Hydrogen peroxide ............

Hydrogen sulfide .............

Nitrosyl bromide .............

Nitrosyl chloride ............

Dinitrogen oxide .............

Dinitrogen tetroxide .........

Phosphorus tribromide ........

Phosphorus trichloride .......

Phosphorus triiodide .........

Phosphoryl chloride ..........

Thiophosphoryl chloride ......

f =3.6 X 10" cycles/sec.

Thionyl bromide ..............

Thionyl chloride .............

Sulfur dioxide ...............

Sulfuryl chloride ............

Antimony tribromide ..........

Antimony trichloride .........

Antimony pentachloride .......

Antimony triiodide ...........

Sulfur trioxide ..............