Pits 01 Kgs Final PCM (Test 10.06.12)

Performance Improvement Test Series-1
IIT JEE, 2013

Time: 3 hours Maximum Marks: 270
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
You are not allowed to leave the examination hall before end of the test.
INSTRUCTIONS
A. General
1. This booklet is your uestion Paper.
!. This uestion Paper contains "# $uestions. Attempt A%% the $uestions.
&. The uestion Paper contains blank spaces for your rou'h work. (o additional sheets will be
provided for rou'h work.
4. Blank papers, clip boards, log tables, slide rule, calculators, cellular phones, pagers and
electronic gadgets, in any or!, are NOT allo"ed.
5. )rite your (ame and *nrolment (o. in the space provided at the bottom of this sheet.
+. This booklet also contains the answer sheet ,-..
/. 0illin' in the ,-.1
2. ,n the ,-.3 write in ink your (ame3 *nrolment (o.3 (ame of the 4entre and put your 5i'nature
in the appropriate boxes.
6. *very $uestion has four choices for its answer 7A83 7/83 748 9 7:8.
". ,nly ,(* of them is the ri'ht answer.
1#. ,n the ,-.3 for each $uestion number3 darken ,(%Y one bubble correspondin' to what you
consider to be the most appropriate answer3 from amon' the four choices.
4. -arkin' 5cheme1
11. a8 0or each $uestion you will be awarded & marks if you have darkened only one bubble
correspondin' to the ri'ht answer.
b8 ;n case you have not darkened any bubble you will be awarded # mark for that $uestion.
c8 ;n all other cases you will be awarded <1marks.
Name of the candidate : ____________________________________________
Batch : ____________________ Date of Examination: _____________________
Enrolment Number : ____________________________________________
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fitjee.com
#aper Code
$%$&.'

SECTION I: PHYSICS SECTION I: PHYSICS
1. 0i'ure shows a plank with a block placed on it. There
exists friction between plank and block but hori=ontal
surface on which plank moves is smooth. A variable
force which 'rows with time is applied on plank as
shown ;t was observed that at time t > t# relative
slippin' between block and plank starts and at t > !t#3 block separates from plank. 5peed of block at
this instant as observed from frame of plank is
7A8
! !
m'
!
k
towards left 7/8

! !
& m'
k
towards left
748
! !
" m'
!k
towards ri'ht 7:8 (one of these

!. There is a trian'ular wed'e as shown in the fi'ure. There
are two ima'inary planes that divide the wed'e into three
portions. %et and be the inclination of these two planes
with respect to the hori=ontal as shown in the fi'ure. The
two portion of the wed'e divided by plane ; are havin'
reaction vector
1
.
r
3 similarly reaction vector between two
portion divided by plane ;; is
!
.
r
)hat are the possible an'les between
1 !
. and .
r r
7A8 # 7/8
!
+
748
+
7:8
&. Two particles start movin' at t > # from the same point3 in a 'ravity free space3 with e$ual speeds v
directed3 respectively alon' the ?x and the ?y axes. ;f a third particle starts movin' simultaneously
from the same point alon' a strai'ht line in the x@y plane inclined at an an'le of 1&5 with the x@axis
such that all the three remain collinear for all values of t3 then the speed of the third particle will be
7A8 ! v 7/8
v
!
748 !v 7:8 !! v
A. The fi'ure shows two rods /4 and ,A hin'ed from / and , respectively.
.od /4 has a 'roove in which point A of rod ,A can slide smoothly. At a
'iven instant3 the rod /4 has an an'ular velocity #. The speed of end ,A
of the rod A at this instant will be
7A8 #l 7/8 !#l
748 &#l 7:8 (one of these.
!ace for rou"h #ork
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5. A small body slides from rest alon' two e$ually rou'h circular surfaces in
the vertical plane from A to / throu'h path 1 and ! of e$ual radius if v1 and
v! are the speed of the block at point / via path 718 and 7!83 then
7A8 v1 B v! 7/8 v1 C v!
748 v1 > v! 7:8 canDt be predicted
+. A proEectile is thrown with speed u from ori'in , in a vertical plane as
shown in the fi'ure. ;f r
r
is the position vector of the proEectile and v
r
is
its velocity vector at any instant t. The distance of the proEectile from the
ori'in always increases with time durin' its motion. 4hoose the correct
statement.
7A8 r v # <
r r
7/8 r v #
r r
748 r v # >
r r
7:8
r v # >
r r
2. Two inclined planes ,A and ,/ of inclinations to the
hori=ontal are and 3 each e$ual to &# as shown in the
fi'ure. A particle is proEected at an an'le of "# with plane
,A from point A and its strikes the plane ,/ at point /
normally. Then find the speed of proEection in mFs. 7'iven
that ,A > ,/ > !# cm and ' > 1# mFs
!
8
7A8 ! 7/8 5
748 1# 7:8 !#
6. /lock of mass m > 1# k' is suspended by two sprin's as shown in the
dia'ram. Acceleration of block Eust after cuttin' the ri'ht sprin' is
7A8
5 &
!
mFs
!
7/8 1# mFs
!
748 5& mFs
!
7:8 5 mFs
!
". Two persons namely .am3 and .ahim3 who have 'one to picnic.
0indin' a beautiful place they rush towards it simultaneously. %et us
take the time when they start simultaneously at t > #. At this instant3
the position of .am and .ahim be x > # and x > ? A6 respectively.
.am maintains a uniform velocity of ?1# mFs throu'hout the Eourney
whereas .ahim starts from rest and continuously accelerates with ? 1
mFs
!
3 ;f the position@time 'raph for two persons . and . be depicted
as shown in the dia'ram then choose the correct alternative
7A8 ;nitially3 . and . are at relative rest
7/8 The minimum separation between . and . is A4
748 The minimum separation between . and . is A/
7:8 The speed of . and . continuously increases
!ace for rou"h #ork
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1#. An ant carryin' a char'e has to crawl alon' the inner surface of a cube of side a . 5tartin' from one
corner of the cube it has to 'o from the dia'onally opposite corner in least possible time . Assumin'
that the ant crawls with a constant speed v 3 find the maximum ma'netic field produced by the ant at
the centre of the cube .
7A8
#
!
5 $v
+ $
7/8
#
!
5 $v
+ $
748
#
!
5 $v
+ $
7:8 (one of these

11. A small block of mass m3 havin' char'e $ is placed on frictionless inclined
plane makin' an an'le with the hori=ontal. There exists a uniform ma'netic
field / parallel to the inclined plane but perpendicular to the len'th of sprin'. ;f
m is sli'htly pulled on the inclined in downward direction3 the time period of
oscillation will be 7assume that the block does not leave contact with the plane8

B
7A8
m
!
G
7/8
!m
!
G
748
$/
!
G
7:8
$/
!
!G
.
1!. A uniform conductin' rectan'ular loop of sides l 3 b and mass m
carryin' current i is han'in' hori=ontally with the help of two vertical
strin's. There exists a uniform hori=ontal ma'netic field / which is
parallel to the lon'er side of loop. The value of tension which is least is
7A8
mg Bb
2
7/8
mg Bb
2
+
b
B
l
748
mg 2iBb
2
7:8
mg 2Bb
2
+
.
1&. ;n fi'ure3 infinite conductin' rin's each havin' current i in the
direction shown are placed concentrically in the same plane
as shown in the fi'ure. The radius of rin's are r3 !r3 !
!
r3 !
&
r H.
. The ma'netic field at the centre of rin's will be
7A8 Iero
7/8
0
i
r
748
0
i
2r
7:8
0
i
3r
.
!ace for rou"h #ork
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1A. A particle of specific char'e
q
m
4Fk' is proEected from the ori'in towards positive x<axis with a
velocity of 1# mFs in a uniform ma'netic field
B 2k
r
T. The velocity v
r
of particle after time
1
t
12
s will be 7in mFs8

7A8 5J

i 3 j + K 7/8 57

3 i j + 8
748 5J

3 i j K 7:8 5J

i j + K
15. A thin metallic spherical shell contains a char'e on it. A point
char'e $ is placed at the centre of the shell and another char'e $1 is
placed outside it as shown in the fi'ure. The three char'es are
positive. Then choose the incorrect option
7A8 the net force on $ is =ero
q
d
Q
q
1
7/8 the force on $ due to $1 is
1
2
0
qq 1
4 d
towards left
748 the force on $ due to is =ero
7:8 the force on $ due to shell 7induced char'e8 is =ero
1+. 4onsider the network shown in the fi'ure. The current
in ! resistor is +A. Then
7A8 P: across a and b is A& L
7/8 current throu'h all A resistors is &A
748 power delivered in each of 1! resistor is 15+ )
7:8 current throu'h + resistor is 1# A
i
a
b
6
6 A
2
4
i
4
1 2
1 2
1 2
12. An electric dipole is placed in an electric field. Then choose the option which is not correct
7A8 the net electric force on the dipole may be =ero
7/8 the net tor$ue on the dipole may be =ero
748 the dipole may be in stable e$uilibrium
7:8 none of these
16. A small piece of radius r is removed from a char'ed spherical shell of radius . 7. BB r8 the electric
intensity at the midpoint of the aperture 7assumin' the density of char'es to be 8 is
7A8
0
directed towards centre 7/8

0
directed outwards
748
1
2
0
directed outwards 7:8 =ero

!ace for rou"h #ork
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1". 4onsider a spherical isolated conductin' body of radius r1 havin' a concentric cavity of radius r! with a
point char'e $ at the centre. *lectric field
E
r
will have ma'nitude
2
0
q
4 r
for a point at a distance r
from centre for
7A8 r B # 7/8
1
0 r r
748 # C r C r! 7:8 only for r B r1
!#. A uniform solid sphere 7A8 is surrounded symmetrically by a uniform thin spherical shell 7/8 of e$ual
mass but twice its radius 7i.e. r/ > !rA8. The 'ravitational field ' is plotted as a function of the distance
from the center of the solid sphere 7r8. )hich of the followin' shows the correct plotM
7A8
r
g
r
A
r
B
O
7/8
r
g
r
A
r
B
O
748
O
r
g
r
A
r
B
7:8
r
g
r
A
r
B
O
!1. A point char'e $ is placed at P7#3 #3 a8. The electric flux throu'h
4A/ due to the electric field of $ is . Then
7A8
0
q
48

7/8
0
q
48
<
748
0 0
q q
48 24
< <

7:8
0
q
24
>
O
x
y
z
P ( 0 , 0 , a !
B
(
a
,

0
,

0
!
A ( 0 , a , 0 !
" ( a , a , 0 !
!ace for rou"h #ork
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#aragraph or 0uestion Nos. )) to )4
A frame is formed by nine identical wires of resistance . each as
shown in the fi'ure.
A
B
"
# E
$
%
%
%
%
%
%
%
%
%
!!. The e$uivalent resistance between A and / is
7A8
&
%
11
7/8
1
%
11
748
1&
%
11
7:8
6
%
11
!&. 4hoose the incorrect statement.
7A8 the ratio of current throu'h 40 and :* is 1 7/8 the ratio of current throu'h 4: and 0* is 1
748 the ratio of current throu'h A4 and A: is
6
&
7:8 the ratio of current throu'h A4 and A: is
&
6
!A. 4hoose the correct statement.
7A8 4 and : are at same potential 7/8 L4 ? L* > LA ? L/
748 L: ? L0 C LA ? L/ 7:8 * and 4 are at same potential
!ace for rou"h #ork
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#aragraph or 0uestion Nos. ). to )1
Two points char'es $1 > ? 14 and $! > < !4 are placed at A and /
respectively as shown in the fi'ure. The distance between $1 and $! is A cm.
A
B
q
1
4 ' m
q
2
!5. A line of force emanates from $1 makin' an an'le "#N with A/. This line of force
7A8 enters $! at an an'le "#N 7/8 enters $! at an an'le +#N
748 enters $! at an an'le A5N 7:8 does not enter $! but 'oes off to
!+. The net electric flux will be =ero.
7A8 over any surface that encloses a volume includin' A and /3 but havin' very lar'e radius
7/8 over any surface that includes A twice and / once
748 over any surface that encloses a volume excludin' A and /
7:8 only over a surface that encloses =ero volume
!2. The electrostatic potential is =ero at
7A8 a point on the line A/ between $1 and $! but closer to $!
7/8 a point on the line A/ but not between A and /
748 infinitely many point in space
7:8 no point in space
#aragraph or 0uestion Nos. )% to -'
An obEect is thrown from a point A on hori=ontal
'round as shown Air blows from ri'ht to left so that it
imparts a constant acceleration Oa#P to obEect
towards left. Answer the followin'
!6. The value of Oa#P such that proEectile follows a strai'ht line path is
7A8 ' tan 7/8 ' cot
748 ' sin 7:8 ' cos
!". ;f condition in above case is satisfied then the maximum vertical hei'ht attained by obEect above
hori=ontal 'round is
7A8
! !
#
u sin
'

7/8
! !
#
u sin
!'

748
! !
#
!u sin
'

7:8 (one of these
&#. ;n the above case mentioned3 when obEect falls back on surface3 it will strike the surface
7A8 To the left of point A 7/8 To the ri'ht of point A
748 *xactly at point A 7:8 :ata insufficient
!ace for rou"h #ork
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SECTION II: CHEMISTRY SECTION II: CHEMISTRY
This section contains -' !ultiple choice 2uestions. *ach $uestion has four choices 7A83 7/83 748
and 7:8 out of which ON34 ON5 is correct.
1. The product of the followin' reaction is
4Q
&
,
&
Q ,
Product
+

7A8
,Q
4Q
&
,Q
7/8
,Q
4Q
&
,Q
748
4Q
&
,Q
7:8
4Q
&
,Q
4Q
&
!. The product / in the reaction is
! +
!
/ Q 4u
& & 52& G ,Q F : ,
74Q 8 4,Q A /

7A8
Q
&
4 4Q
&
4Q
&
,:
7/8
Q
&
4
4Q
&
Q
,Q
748
Q
&
4
4Q
&
Q
,:
7:8
Q
&
4
4Q
&
:
,Q
&. A few drops of Q
&
P,
A
were added to a hydrocarbon 4
&
Q
+
and heated with ben=ene. ,xy'en
'as was then passed throu'h the hot product to form 7A8. 7A8 was then further treated with
conc. Q
!
5,
A
to form 7/8. ;dentify the correct combination of final product 7/83 the
intermediate3 and oxidation number of oxy'en in 7A8.
O6idation nu!ber +7, Inter!ediate #roduct +B,
7A8 <! free radical phenol
7/8 <1 carbocation phenol ? acetone
748 <1 free radical phenol
7:8 <1 free radical phenol ? acetone
!ace for rou"h #ork
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A. A compound R:D 74
6
Q
1+
,8 has followin' observations1
7a8 ;t reacts with %ucas rea'ent within 5 minutes.
7b8 ,n heatin' in presence of acid 'ives a compound S3 which can decolouri=e G-n,
A
as
well as /r
!
F44l
A
.
7c8
,=onolysis (a,;
4ompound S Y ! moles of iodoform sodium salt of dibasic acid +
5odalime
n@butane
Then :3 S and Y are
7A8
,Q
3
3 ,
,
7/8
Q,
3
3
,
,
748
Q,
3
,Q
3
,
,
7:8
,Q
3
3
,
,
!ace for rou"h #ork
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5.
4Q
!
4Q
!
(-e
&
4l
4Q
&
,
)olffTishner
reduction
Product 7P8
-
The structure of 7P8 is
7A8
4Q
!
4Q
!
(-e
&
4l
4Q
&
7/8
4Q
&
,
4Q
!
748
4Q
&
4Q
!
7:8
4Q
&
,
4Q
!
+.
,
4Q
&
&
7i8 (aQF dry ether
7ii8 4Q ;
7A8
7maEor8

&
7i8 %:A
7ii8 4Q ;
7/8
7maEor8

Qence3 A and / are
7A8
,
Q
&
4 4Q
&
and
,
4Q
&
4Q
&
7/8
,
Q
&
4 4Q
&
,
4Q
&
4Q
&
and
748
,
4Q
&
Q
&
4
,
4Q
&
4Q
&
and
7:
8
,
4Q
&
4Q
&
,
4Q
&
4Q
&
and
!ace for rou"h #ork
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2.
,
Q
&
4 4Q
&
,
! &
a$ueous G 4,
-aEor product 7A8
Product 7A8 in the above reaction is
7A8
,Q
4Q
& 7/8
Q,
,
4Q
&
748
4Q
&
,Q
,
7:
8
Q,
4Q
&
,
6.
/r
Ph
alc. G,Q
U
Product
;dentify the product.
7A8
,Q
Ph
7/8
Ph
748
Ph
7:8
,Q
Ph
!ace for rou"h #ork
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". ;n the reaction se$uence
4
+
Q
5
< 4Q > 4Q @
,
;;
4
@4Q
&

&
!
7i84Q -'/r
JSK
7ii8Q ,F Q
+
7maEor product8
S will be
7A8
4
+
Q
5
4 Q
&
4Q
&
,Q
7/8
Q
5
4
+
4Q
&
,Q
4Q
&
748
4
+
Q
5
4 Q
&
4Q
&
,
7:8
4
+
Q
5
4 Q
&
4Q
&
,Q
4Q
&
#7SS785
7ro!aticity
$uestions %0 to %%:
Aromatic compounds are more stable than their non@aromatic counterparts. There are different
ways to measure the so@called aromatic stabili=ation ener'y. The followin' experiment was
performed to compare the stabili=ation ener'y of ben=ene with that of naphthalene 7Aromatic
stabili=ation ener'y of naphthalene > +1 kcalFmol and that of ben=ene > &+ kcalFmol8.
40
&
0
&
4
(4 4(
b
G

40
&
40
&
4(
4(
40
&
0
&
4
(4 4(
n
G

40
&
40
&
4(
4(
1#. The relation between G
b
and G
n
at same temperature is 7G
b
and G
n
are e$uilibrium constants8
7A8 G
b
C G
n
7/8 G
b
B G
n
748 G
b
> G
n
7:8 :ata insufficient
!ace for rou"h #ork
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11.
!
/r
P
P can be
7A8
/r
/r
7/8
/r /r
748
/r
/r
7:8 (one of the above
1!.
4 Q
&
,
4,,4
!
Q
5
& !
7i8 (aQF TQ0 7i8 dil. G,Q
7ii8 4Q 4,4l 7ii8 Q ,F Q 3
7A8 7/8
+

The product 7/8 in the above se$uence of reaction is
7A8
4 Q
&
,
4,,4
!
Q
5
4,4Q
&
7/8
4 Q
&
,
4,,Q
4,4Q
&
748
4 Q
&
,
4Q
&
,
7:8
4 Q
&
,
4,,Q
!ace for rou"h #ork
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1&. A certain metal A has fcc structure with unit cell len'th &.1+
o
A3
the si=e of lar'est atom that
can be accommodated into the interstices of the metal without chan'in' the position of metal
atoms is
7A8
o
#.5& A
7/8
o
#."&5 A
748
o
#.1A" A
7:8 (one of the above
1A. ;n diamond3 the lattice is fcc with 4 atoms occupyin' lattice points as well as some of the
voids. )hich of the followin' statement7s8 isFare correct about the diamond structureM
7;8 ;n the diamond lattice3 half of the tetrahedral voids are occupied.
7;;8 Percenta'e space occupied 7packin' efficiency8 is 2AV.
7;;;8 ;n the diamond lattice all octahedral voids are occupied.
7A8 ,nly ; 7/8 ,nly ;;; 748 ;3 ;; and ;;; 7:8 ,nly ;;
15. ;n a fcc crystal3 which of the followin' shaded plane contains the followin' arran'ement of
atomsM

7A8 7/8
748 7:8
1+. ;n an ionic solid3 /
x<
ions constitute a ccp lattice3 if A
y?
ions occupy !5V of the tetrahedral
voids3 the possible ions in the solid are
7A8 A
?
and /
<
7/8 A
!?
and /
A<
748 A
!?
and /
<
7:8 A
A?
and /
<
12. ;n which type of voids ma'nesium and silicon is present respectively in asbestos J-'
&
5i
!
,
5
K
if
A
-' , 5i ,
r F r #.5" and r F r is
++ +

#.!".
7A8 tetrahedral 9 octahedral 7/8 both tetrahedral
748 octahedral 9 tetrahedral 7:8 both octahedral
!ace for rou"h #ork
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16. 5uppose you have a collection of 'lass marbles arran'ed in hexa'onal close packin'. ;f the
density of the 'lass is
&
!.+ 'F cm 3 what would be the avera'e density of matter in the
collection
7A8
&
!.& 'F cm 7/8
&
!.+ 'F cm 748
&
1."!5 'F cm 7:8
&
&.5 'F cm
1". ;f all 0e
!?
ions are replaced by 5r
A?
ions in #.1 mole of 0e
#."
,3 then number of vacancies
created are
7A8 #.#&5 (
A
7/8 #.#1 (
A
748 #.#2 (
A
7:8 #.1 (
A
7(
A
is Avo'adro number.8
!#. /aTi,
&
crystalli=es in perovskite structure. This structure may be described as a cubic
lattice3 with barium ions occupyin' the corners3 oxide ions at the face centres and titanium
ions in one of the octahedral holes. )hich of the followin' is correct about /aTi,
&
crystal
latticeM
7A8 Ti
A?
occupies the body centred octahedral hole.
7/8 Ti
A?
occupies the ed'e centred octahedral hole.
748 Ti
A?
can occupy any of the octahedral holes.
7:8 1F!nd of the octahedral holes are occupied.
!1. )hich one of the followin' is true for 5chottky defect in crystalsM
7A8 5chottky defects increases the density of the crystal.
7/8 5chottky defect is found in crystal havin' lar'e
r
r
+
ratio.
748 5chottky defects are non thermodynamic defects.
7:8 5chottky defect is shown by hi'hly ionic compounds havin' hi'h coordination number.
!!. The closest distance between two atoms amon' the followin' unit cells3 assumin' same
ed'e len'th RaD in each unit cell
7A8 :iamond unit cell 7/8 Primitive cubic cell 748 /44 unit cell 7:8 044 unit cell
!&. +."# 'm of metal carbonate were dissolved in +# ml of ! ( Q4l. The excess acid was
neutrali=ed by !# ml of 1 ( (a,Q. )hat is the e$uivalent wei'ht of metalM
7A8 A# 7/8 !# 748 1" 7:8 &"
!A. x ml of 5,
!
at (TP reduces 1## ml #.1 ( G
!
4r
!
,
2
in presence of Q
!
5,
A
. The value of x is
7A8 !!A ml 7/8 5+ ml 748 AA6 ml 7:8 11! ml
!ace for rou"h #ork
#ITS()'$)(#C*(+$%$&.',($/

!5.
& ! ! !
(Q , ( Q , + +
;f molecular wei'hts of (Q
&
and (
!
are -
1
and -
!
respectively3 and their e$uivalent wei'hts
are *
1
and *
!
respectively3 then 7*
1
< *
!
8 is e$ual to
7A8
1 !
!- -
+
_

,
7/8 ( )
1 !
- -
748 ( )
1 !
&- -
7:8 ( )
1 !
- &-
!+. A metal oxide has A#V oxy'en. The percenta'e of chlorine in its chloride is
7A8 "#V 7/8 66.25V 748 2A.2V 7:8 &5V
!2. Gaseous ben=ene reacts with hydro'en 'as in presence of a nickel catalyst to form 'aseous
cyclohexane accordin' to the reaction3
+ + ! + 1!
4 Q 7'8 &Q 7'8 4 Q 7'8. +
A mixture of 4
+
Q
+
and
excess Q
!
has a pressure of +# mm of Q' in an unknown volume. After the 'as is passed
over a nickel catalyst and all the ben=ene converted to cyclohexane3 the pressure of the 'as
is &# mm of Q' in the same volume at the same temperature. The fraction of 4
+
Q
+
7by
volume8 in the ori'inal mixture is
7A8
1
&
7/8
1
A
748
1
5
7:8
1
+
!6. ,ne mole of a hydrocarbon havin' molecular wei'ht 26 is subEected to o=onolysis and the
Q
!
,
!
formed as a result is not removed from the reaction vessel. The product obtained3 on
further treatment with 4a
!?
ions3 'ave &6A ' of calcium oxalate. The hydrocarbon is
7A8
& &
4Q 4 4 4 4 4Q
7/8
! !
4Q 4 4Q 4Q 4 4Q
748
! &
4Q 4 4Q 4 4 4Q
7:8 ben=ene
!". ;f
1
m '
of a metal A displaces
!
m '
of another metal / from its salt solution and if their
e$uivalent masses are
1 !
* and *
respectively3 then the e$uivalent mass of A can be
expressed as
7A8
! !
1
1
m *
*
m
7/8
1 !
1
!
m *
*
m
748
1 !
1
!
m m
*
*
7:8
1 !
1
!
m *
*
m
&#. G,Q 7L
1
ml 3 x(8 is mixed with (a,Q 7L
!
ml 3 y(8 9 treated with #.1 ( Q4l. 1## ml of Q4l is
re$uired for complete reaction3 if L
1
1L
!
> 11! 9 x1y > !11. )hat fraction of Q4l is neutrali=ed
by (a,Q.
7A8 #.5# 7/8 #.!5 748 #.&& 7:8 #.+2
!ace for rou"h #ork
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SECTION III: MATHEMATICS SECTION III: MATHEMATICS
This section contains -' !ultiple choice 2uestions. *ach $uestion has four choices 7A83 7/83 748
and 7:8 out of which ON34 ON5 is correct.
1. ;f fractional part of
1
x
and x
!
for some x ( ) !3 & are e$ual then the value of x
A
<
&
x
is
7A8 & 7/8 5
748 2 7:8 #
!. The domain of function f7x8 >
1 1
1
sin x cos x

is
7A8 x
1
3 1
!
1
1
]
7/8 x
1
13
!
_

,
748 x
1 1
13 3 1
! !
_ 1

1
, ]
7:8 x J<13 1K <
1
!

' ;

&. %et f1 J!3 5K J!3 5K be an biEective function such that
( ) ( )
1
d
f x #
dx

> x J!3 5K3 then
( ) ( ) ( )
5
1
!
f x f x dx
is
7A8 # 7/8 A
748 5 7:8 !1
A. %et f7x8 > x ? sinx3 then
( )
1
1
a
f x dx
is e$ual to3 where a >

1 1
x #
1 1
lim sec sec
x x

1 _ _

1
, , ]
3 7where
J.K denotes the 'reatest inte'er function8
7A8 <! ? sin1 7/8 #
748 !71 ? sin18 7:8 &
!ace for rou"h #ork
#ITS()'$)(#C*(+$%$&.',($%

5. ;f the derivative of f7x8 w.r. t. x is
( ) x f
x sin
!
1
!
3 then f7x8 is a periodic function with period

7A8 7/8 ! 748 F! 7:8 none of
these.
+. ;f lo'
&
7lo'
!
x8 ? lo'
1F&
7lo'
1F!
y8 > 1 and xy
!
> "3 then
7A8 x > !"2 7/8 x > 2!"
748 y > t
1
&&
7:8 1F1#
2. ;f 'raph of xy > 1 is reflected in y > !x to 'ive the 'raph 1!x
!
? rxy ? sy
!
? t > #3 then
7A8 r > 13 s > 1!3 t > !5 7/8 r > <13 s > 1!3 t > 1
748 r > <23 s > <1!3 t > !5 7:8 r ? s > <!"
6. ;f tan
@1
7x ? h8 > tan
@1
7x8 ? 7h siny8 7siny8 < 7h siny8
!
.
!
y ! sin
? 7h siny8
&
.
&
y & sin
? H.3
where x 7 #3 183 y 7FA3 F!8 3 then
7A8 y > tan
@1
x 7/8 y > sin
@1
x 748 y > cot
@1
x 7:8 y > cos
@1
x
". ;f a 7a
1
3 a
!
8 satisfy the condition that the point of local minima and point of local maxima is
less than A and 'reater than < ! respectively for the function f7x8 > x
&
< &ax
!
? &7a
!
<18x ? 13
then the value of a
!
< a
1
is
7A8 & 7/8 A
748 ! 7:8 5
1#. ;f x
!
? Ay
!
> A and ran'e of f7x3 y8 is J-
1
3 -
!
K3 where f7x3 y8 > x
!
? y
!
< xy3 then -
1
.-
!
is
7A8 6 7/8 "
748 + 7:8 2
!ace for rou"h #ork
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11.
1
1
]
1
,
_

1 n
n
n
1
1 ln 1 lim
is e$ual to
7A8 # 7/8 1
748 e 7:8 none of these
1!. %et f be a continuous and differentiable function in 7x
1
3 x
!
8. ;f f7x8 . f7x8 x ( ) ( )
A
1 f x
and
( ) ( )
1
!
x x
lim f x 1
+
and
( ) ( )
!
!
x x
1
lim f x
!
. Then minimum value of

! !
1 !
x x
1
]
is 7where J.K denotes
the 'reatest inte'er function8
7A8 & 7/8 1
748 ! 7:8 A
1&. %et y > k be a line that intersects the curve y > f7x8 atleast at two points. ;f
( ) ( )
x !
!
!
! x
x
f t dt t f t dt
!
+

3 then
7A8 k 7<13 18 < W#X 7/8 k .
748 k
{ }
1 1
3 #
! !
_

,
7:8 k .
?
1A. %et P
n
7n8 be a polynomial such that P
n
7x8 > P
n < 1
7x < n83 where P
#
7x8 > x
&
? A5x
!
< 22x < 63
then the coefficient of x in P
1#
7x8 is
7A8 < A5# 7/8 !1"#
748 1!"6 7:8 !"61
15. ;f 3 7where C 8 are the points of discontinuity of the function '7x8 > f7f7f7x8883 where
f7x8 >
1
1 x
3 then the points of discontinuity of '7x8 is
7A8 x > #3 1 7/8 x > 1 only
748 x > # only 7:8 x > #3 1
1+. ;f k >
! !
1
x 1
limsec
lnx x 1

,
exist3 then the minimum value of JYYK is 7where J.K denotes the
'reatest inte'er function8
7A8 ! 7/8 +
748 1 7:8 A
!ace for rou"h #ork
#ITS()'$)(#C*(+$%$&.',()'

12. ;f f7x8 > 7a
!
< &a ? !8
( )
! !
x x
cos sin a 1 x cos1
A A
_ _ _
+ +

, , ,
does not posses critical point then
the number of inte'ral values of RaD are
7A8 A 7/8 !
748 & 7:8 1
16. ;f f7x8 > 7x < 18
1##
7x < !8
!7""8
7x < &8
&7"68
H 7x < n8
1##
3 let k >
( )
( )
f 1#1
f 1#1
3 then
k
"2
5#
_

,
is
7A8 A 7/8 !
748 & 7:8 1
1". ;f !p
!
< &$
!
? Ap$ < p > # and a variable line px ? $y > 1 always touches a parabola whose
axis is parallel to x@axis. Then the e$uation of the parabola is
7A8 7y < A8
!
> !A7x < !8 7/8 7y < &8
!
> 1!7x < 18
748 7y < A8
!
> 1!7x < !8 7:8 7y < !8
!
> !A7x < A8
!
!#. ;f m
1
3 m
!
be the roots of the e$uation x
!
? 7 & ? !8x ? & < 1 > # and the area of the
trian'le formed by the lines y > m
1
x3 y > m
!
x and y > ! is && ? 3 then >
7A8 # 7/8 11
748 11 7:8 1!1
!1. A continuous3 even periodic function f with period 6 is such that f7#8 > #3 f718 > < !3 f7!8 > 13
f7&8> !3 f7A8 > &3 then the value of tan
<1
tanWf7<58 ? f7!#8 ? cos
<1
7f7<1#88 ? f7128X is e$ual to
7A8 ! < & 7/8 & < !
748 ! ? & 7:8 & <
!!. The value of
K x J
1 n n
x
e
1 nx x
lim
+ +

3 n ; is
7A8 1 7/8 #
748 n 7:8 n7n <18
!&. A:3 /* and 40 are the medians of trian'le A/4 whose centroid is G. ;f the points A3 03 G
and * are concyclic3 then
7A8 !b
!
> a
!
? c
!
7/8 !c
!
> a
!
? b
!
748 !a
!
> b
!
? c
!
7:8 !b
!
> !a
!
? c
!
!A. ;f # C p C ! and sin
<1
7sinp8 C
! !
x &y 1
y x 61xy
+ + x3 y .
?
3 then p
7A8 7#3 &8 7/8
&
13
!
_

,
748
&
3 ! 1
!
_

,
7:8 7! < 13 !8
!ace for rou"h #ork
#ITS()'$)(#C*(+$%$&.',()$

#aragraph or 0uestion Nos. ). to )1
To the circle x
!
? y
!
> A two tan'ents are drawn from P7A3 #83 which touches the circle at T
1
and T
!
and a rhombus PT
1
PT
!
is completed.
!5. 4ircum centre of the trian'le PT
1
T
!
is at
7A8 7!3 #8 7/8 7!3 #8
748
&
3 #
!
_

,
7:8 none of these
!+. .atio of the area of trian'le PT
1
P to that the PT
1
T
!
is
7A8 ! 1 1 7/8 1 1 !
748 & 1 ! 7:8 none of these
!2. ;f P is taken to be at 7h3 #8 such that P lies on the circle3 the area of the rhombus is
7A8 + & 7/8 ! &
748 & & 7:8 none of these
#aragraph or 0uestion Nos. )% to -'
%et ( ) ( ) ( )
2 3
0 1 2 3
' x a a x a x a x and f x ' x 3 + + + f7x8 has its non@=ero local minimum and
maximum values at & and & respectively. ;f a
&

the domain of the function ( )

2
1
1
2
x
h x sin
x
_ +

,
.
!6. The value of a
1
? a
!
is e$ual to
7A8 &# 7/8 &#
748 !2 7:8 !2
!". The value of a
#
is
7A8 e$ual to 5# 7/8 'reater than 5A
748 less than 5A 7:8 less than 5#
&#. f71#8 is defined for
7A8 a
#
B 6&# 7/8 a
#
C 6&#
748 a
#
> 6&# 7:8 none of these
!ace for rou"h #ork
#ITS()'$)(#C*(+$%$&.',())

IIT JEE, 2013
7NS95RS
,,
1. B !. 7 &. B A. B
5. 7 +. C 2. 7 6. :
". C 1#. 7 11. 7 1!. C
1&. : 1A. B 15. : 1+. :
12. : 16. C 1". C !#. :
!1. B !!. C !&. 4 !A. B
!5. / !+. C !2. 4 !6. B
!". B &#. C
1. B !. C &. : A. 7
5. C +. B 2. / 6. C
". B 1#. A 11. / 1!. C
1&. : 1A. 7 15. C 1+. C
12. C 16. C 1". 7 !#. 7
!1. : !!. 7 !&. : !A. :
!5. 7 !+. C !2. : !6. :
!". B &#. 7
SE SE CTION III: MATHEMATICS CTION III: MATHEMATICS
1. B !. C &. : A. B
5. 7 +. B 2. C 6. C
". B 1#. C 11. 7 1!. B
1&. C 1A. C 15. : 1+. C
12. B 16. 7 1". C !#. B
!1. : !!. B !&. C !A. B
!5. 7 !+. : !2. 7 !6. C
!". B &#. 7
#ITS()'$)(#C*(+$%$&.',()-
#aper Code
$%$&.'

SOLUTION
1. t# can be found by e$uatin' pseudo force on block to static friction
*$n. for block w.r.t. plank 1
dv kt
m m m'
dt &m !
_ _

, ,
7after relative slippin' starts8
#
#
!t
v
# t
kt m'
m dv m dt
&m !
1 _

1
, ]

! !
& m'
v
k

7towards left8
!.
1
.
r
is vertical and
!
.
r
is also vertical
&. At any time t3 ,A > ,/ > vt. 0or third particle ,4 > ut. 0rom similar
trian'les A4: and A/,3
ut !
vt
>
ut
vt
!
vt
5implifyin'3 we 'et u >

v
!
A. ,A > !/4
2. 5ince >
A, > /, > !# cm
A/ >
! !
d d !d dcos1!# +
A/ > &d H.7i8
(ow A/ is the ran'e of the proEectile from A to /.
&d >
!
u sin!
'

&d >
!
u &
!'
Puttin' d > #.! m
u > ! mFs
11. There will be no effect of ma'netic force on time
period because the ma'netic force will be
perpendicular to the inclined plane.
q , m
1!. Takin' moments about point / to be =ero.
1
( ) ib B mg
2
+
l
l l
1
mg 2ibB
(
2
.
B
m g
(
1
(
2
A
#ITS()'$)(#C*(+$%$&.',()4

1&.
0 0 0
2
i i i
B )))))))
2r 2(2r! 2(2 r!

+
0
2 3
i 1 1 1
B 1 )))))
2r 2 2 2
1
+ +
1
]
0
i 1
B
1 2r
1
2
1
1
1
_
1

1
,
]
0
i
B
3r
.
1A. Time period
2 m
(
qB
2
( 1
2
s.
Thus particle will beat point P after
1
t
12
s.
P
v
y
x
3 0 *

v 10+',- 30i -i.30j/ +
r
3 1

v 10 i j & 3 i j
2 2
1
1
+ +
1
]
]
r
mFs.
!1. The flux is 'reater in the nearer half of the s$uare ,A4/.
!6. The 'iven condition is possible when net acceleration to direction of proEection is =ero
#
#
a sin 'cos
a 'cot

!". Zse
! !
v u !as alon' direction of proEection
&#. ;t follow strai'ht path up3 then down back to fall to same point A.
5. )olff<Gishner reduction involves 7(Q!(Q!FG,Q8 a very stron' base so3 alon' with the reduction of
,
to
'roup3 it also under'o *! elimination in presence of stron' base.
+. 5mall bases like (aQ abstract Q
?
ion from hi'hly substituted

carbon atom while bulky bases like
%:A abstracts Q
?
from less substituted

carbon atom.
Qence3 7/8.
2.
,
Q
&
4 4Q
&
,
! &
G 4,
7;ntramolecular aldol
condensation between a and b8

a
b
,Q
Q
&
4
, or
Q,
,
4Q
&

Product 7A8
#ITS()'$)(#C*(+$%$&.',().

1!.
4 Q
&
,
4,,4
!
Q
5
(aQF TQ0

4 Q
&
,
4,,4
!
Q
5
&
4Q 4,4l

4 Q
&
,
4,4Q
&
4,,4
!
Q
5
7A8
7i8 dil. G,Q
7ii8 Q
?
4 Q
&
4Q
,
4,4Q
&
4,,Q
7 3 keto acid8
!
4,

4 Q
&
,
4Q
&
,
7/8
1A. ;n diamond3 all the carbon atoms are tetrahedrally bonded to one another so octahedral voids cannot
be occupied. Also3 the lattice points and the holes are occupied by carbon atoms. As a result the
packin' efficiency is less than 2AV.
12.
r
#.A1A #.2&!
r
+
3 4o. (o. A and +

r
#.!!5 #.A1A3
r
+
4o. (o < A
Qence 748
16. 5uppose vol. of the hexa'on
&
xcm
%et us assume that entire hexa'on is occupied by 'lass marbles without leavin' voids.
The wei'ht of halo'en
!.+ x 'm
/ut we know only 2A.#5V space is occupied in a hexa'on.
5o actual wei'ht of hexa'on
!.+ x 2A.#5
1##

:ensity of hexa'on
!.+ x 2A.#5
1## x

&
1."! 'F cm
1". ,n the basis of solution of . (o. &21
0e
!?
> #.#2 mole in #.1 mol of 0e#.",
5o to balance char'e3 some of the place has been left vacant as 0e
!?
is replaced by 5r
!?
.
#.#2 [ ! > x [ A
#.#2 !
x #.#&5
A

Lacant place > #.#2 < #.#&5 > #.#&5 (A
Qence3 7A8.
!!.
d
4
dt
:urin' meltin' of ice temperature remains constant. Therefore3 4 tends to infinity

!&. *$uivalent of Q4l taken > +# [ ! [ 1#
<&
*$uivalent of Q4l present after the reaction > !# [ 1 [ 1#
<&
*$uivalent of Q4l utili=ed > 1## [ 1#

<&
1## [ 1#
<&
e$uivalent of metal carbonate > +."# 'm
1 e$uivalent of metal carbonate

1
+."#
+" 'm
1#

*$uivalent wei'ht of metal > +" < &# > &"
#ITS()'$)(#C*(+$%$&.',()/

!A.
! ! 2 ! A ! ! A ! A & !
G 4r , Q 5, &5, G 5, 4r 75, 8 AQ , + + + +
1## ml #.1 ( G!4r!,2 > #.A" 'm
!"A 'm G!4r!,2 > & [ !!A## ml 5,! at (TP
#.A" 'm > 11! ml of 5,!

!2. P1 ? P! > +# mm Q' H718
After the reaction3 pressure of Q! > P! < &P1
Pressure of 4+Q1! > P1
P! < &P1 ? P1 > &# mm H7!8
5olvin' 718 and 7!83 we 'et fraction of ben=ene
1
+
&#. me$. of G,Q ? me$ of (a,Q > me$ of Q4l

xL1?yL! > 1#
!y
!
!
L
y L 1#
!
+
L!y > 53 xL1>5
SE SE CTION III: MATHEMATICS CTION III: MATHEMATICS
5. Given f7x8 >
( ) x f
!
1
x sin
!
+

f 7x8.f7x8 >
!
x ! cos
!
1 x sin !
!
+
( ) dx x ! cos
!
1
dx x f 8 x 7 f

or
( ) [ ]
A
x ! sin
c
!
x f
!
+
f7x8 > t ( ) c ! x ! sin
!
1
)hich is a periodic function with period .

Qence 7A8 is the correct answer
6.
( )
h
x tan h x tan
1 1
+
> sin
!
y < hsin
!
y.
!
y ! sin
? H.
(ow3 takin' limits of both sides as h #3 we 'et
y sin
x 1
1
!
!

+
x
!
> cosec
!
y < 1 > cot
!
y
x > coty 3 y > cot
@1
7x8
11.
1
1
]
1
,
_

1 n
n
n
1
1 lo' 1 lim
>
1
1
1
1
1
]
1
,
_

n
1
1
n
1
1
lo' 1 lim
n
n
>
1
1
]
1
,
_
+ +
,
_
+

n
1
1 lo'
n
1
1 lo' 1 lim
n
n
>
1
1
]
1
,
_
+
,
_
+ +

n
n n
n
1
1 lo' lim
n
1
1 lo' 1 lim
> 1 ? # < lo'e > 1 <1 > # .
!!.
K x J lim
x
>
[ ]
x
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#ITS()'$)(#C*(+$%$&.',()%

Pits 01 Kgs Final PCM (Test 10.06.12)

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Performance Improvement Test Series-1

IIT JEE, 2013

towards left 7/8

towards ri'ht 7:8 (one of these

7:8 (one of these

s will be 7in mFs8

directed towards centre 7/8

directed outwards 7:8 =ero

is e$ual to3 where a >

3 then f7x8 is a periodic function with period

. Then minimum value of

the domain of the function ( )

5implifyin'3 we 'et u >

3 4o. (o. A and +

:urin' meltin' of ice temperature remains constant. Therefore3 4 tends to infinity

*$uivalent of Q4l utili=ed > 1## [ 1#

1 e$uivalent of metal carbonate

#.A" 'm > 11! ml of 5,!

&#. me$. of G,Q ? me$ of (a,Q > me$ of Q4l

)hich is a periodic function with period .

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