Hesss Law

(1) Find the H for the reaction below, given the following reactions and
subsequent H values:
PCl
5
(g) PCl
3
(g) + Cl
2
(g)
P
4
(s) + 6Cl
2
(g) 4PCl
3
(g) H = -2439 kJ
4PCl
5
(g) P
4
(s) + 10Cl
2
(g) H = 3438 kJ
answer = 249.8 kJ

(2) Find the H for the reaction below, given the following reactions and
subsequent H values:
2CO
2
(g) + H
2
O(g) C
2
H
2
(g) + 5/2O
2
(g)
C
2
H
2
(g) + 2H
2
(g) C
2
H
6
(g) H =-94.5 kJ
H
2
O(g) H
2
(g) + 1/2O
2
(g) H =71.2 kJ
C
2
H
6
(g) + 7/2O
2
(g) 2CO
2
(g) + 3H
2
O(g) H =-283 kJ
answer = 235 kJ

(3) Find the H for the reaction below, given the following reactions and
subsequent H values:
N
2
H
4
(l) + H
2
(g) 2NH
3
(g)
N
2
H
4
(l) + CH
4
O(l) CH
2
O(g) + N
2
(g) + 3H
2
(g) H = -37 kJ
N
2
(g) + 3H
2
(g) 2NH
3
(g) H = -46 kJ
CH
4
O(l) CH
2
O(g) + H
2
(g) H = -65 kJ
answer = -18 kJ

(4) Find the H for the reaction below, given the following reactions and
subsequent H values:
H
2
SO
4
(l) SO
3
(g) + H
2
O(g)
H
2
S(g) + 2O
2
(g) H
2
SO
4
(l) H = -235.5 kJ
H
2
S(g) + 2O
2
(g) SO
3
(g) + H
2
O(l) H = -207 kJ
H
2
O(l) H
2
O(g) H = 44 kJ
answer = 72 kJ


(5) Find the H for the reaction below, given the following reactions and
subsequent H values:
2C
2
H
4
O(l) + 2H
2
O(l) 2C
2
H
6
O(l) + O
2
(g)
C
2
H
6
O(l) + 3O
2
(g) 2CO
2
(g) + 3H
2
O(l) H = -685.5 kJ
C
2
H
4
O(l) + 5/2O
2
(g) 2CO
2
(g) + 2H
2
O(l) H = -583.5 kJ
answer = 204.0 kJ

(6) Find the H for the reaction below, given the following reactions and
subsequent H values:
N
2
(g) + 2O
2
(g) 2NO
2
(g)
N
2
(g) + 3H
2
(g) 2NH
3
(g) H = -115 kJ
2NH
3
(g) + 4H
2
O(l) 2NO
2
(g) + 7H
2
(g) H = -142.5 kJ
H
2
O(l) H
2
(g) + 1/2O
2
(g) H = -43.7 kJ
answer = -83 kJ

(7) Find the H for the reaction below, given the following reactions and
subsequent H values:
CO
2
(g) C(s) + O
2
(g)
H
2
O(l) H
2
(g) + 1/2O
2
(g) H = 643 kJ
C
2
H
6
(g) 2C(s) + 3H
2
(g) H = 190.6 kJ
2CO
2
(g) + 3H
2
O(l) C
2
H
6
(g) + 7/2O
2
(g) H = 3511.1 kJ
answer = 886 kJ

(8) Find the H for the reaction below, given the following reactions and
subsequent H values:
N
2
H
4
(l) + CH
4
O(l) CH
2
O(g) + N
2
(g) + 3H
2
(g)
2NH
3
(g) N
2
H
4
(l) + H
2
(g) H = 22.5 kJ
2NH
3
(g) N
2
(g) + 3H
2
(g) H = 57.5 kJ
CH
2
O(g) + H
2
(g) CH
4
O(l) H = 81.2 kJ
answer = -46.2 kJ



(9) Find the H for the reaction below, given the following reactions and
subsequent H values:
1/2H
2
(g) + 1/2Cl
2
(g) HCl(g)
COCl
2
(g) + H
2
O(l) CH
2
Cl
2
(l) + O
2
(g) H = 47.5 kJ
2HCl(g) + 1/2O
2
(g) H
2
O(l) + Cl
2
(g) H = 105 kJ
CH
2
Cl
2
(l) + H
2
(g) + 3/2O
2
(g) COCl
2
(g) + 2H
2
O(l) H = -402.5
kJ
answer = -230 kJ

(10) Find the H for the reaction below, given the following reactions and
subsequent H values:
C
2
H
2
(g) + 5/2O
2
(g) 2CO
2
(g) + H
2
O(g)
C
2
H
6
(g) C
2
H
2
(g) + 2H
2
(g) H = 283.5 kJ
H
2
(g) + 1/2O
2
(g) H
2
O(g) H = -213.7 kJ
2CO
2
(g) + 3H
2
O(g) C
2
H
6
(g) + 7/2O
2
(g) H = 849 kJ
answer = -705 kJ

(11) Find the H for the reaction below, given the following reactions and
subsequent H values:
HCl(g) + NaNO
2
(s) HNO
2
(l) + NaCl(s)
2NaCl(s) + H
2
O(l) 2HCl(g) + Na
2
O(s) H = 507 kJ
NO(g) + NO
2
(g) + Na
2
O(s) 2NaNO
2
(s) H = -427 kJ
NO(g) + NO
2
(g) N
2
O(g) + O
2
(g) H = -43 kJ
2HNO
2
(l) N
2
O(g) + O
2
(g) + H
2
O(l) H = 34 kJ
Answer = -78 kJ

(12) Find the H for the reaction below, given the following reactions and
subsequent H values:
Zn(s) + 1/8S
8
(s) + 2O
2
(g) ZnSO
4
(s)
Zn(s) + 1/8S
8
(s) ZnS(s) H = -183.92 kJ
2ZnS(s) + 3O
2
(g) 2ZnO(s) + 2SO
2
(g) H = -927.54 kJ
2SO
2
(g) + O
2
(g) 2SO
3
(g) H = -196.04 kJ
ZnO(s) + SO
3
(g) ZnSO
4
(s) H = -230.32 kJ
Answer = -976.03 kJ