Use the ideal gas law, PerV-nRT, and the universal gas constant R = 0.0821 L*atm to solve the following problems: K*mol If pressure is needed in Pa then convert b! multipl!ing b! 101.3kPa / 1atm to get R =8.31 L*kPa / (K*mole) "# $f $ have % moles of a gas at a pressure of &'( atm and a volume of ") liters, what is the temperature* 204.6 K )# $f $ have an unnown +uantit! of gas at a pressure of "') atm, a volume of ," liters, and a temperature of -. / 0, how man! moles of gas do $ have* 1.26 ol ,# $f $ contain , moles of gas in a container with a volume of (/ liters and at a temperature of %// 1, what is the pressure inside the container* 1.64 at %# $f $ have .'. moles of gas at a pressure of /'/2 atm and at a temperature of &( / 0, what is the volume of the container that the gas is in* 2!11 L &# $f $ have ". moles of gas at a temperature of (. / 0, and a volume of --'-2 liters, what is the pressure of the gas* ".4 at or "40 kPa (# $f $ have an unnown +uantit! of gas at a pressure of /'& atm, a volume of )& liters, and a temperature of ,// 1, how man! moles of gas do $ have* ." ol For chemistry help, visit www.chemfiesta.com 2000 Cavalcade Publishing - ll !ights !eserved .# $f $ have )" moles of gas held at a pressure of .- atm and a temperature of 2// 1, what is the volume of the gas* 1#.$ L -# $f $ have "'2 moles of gas held at a pressure of & atm and in a container with a volume of &/ liters, what is the temperature of the gas* 1602 K 2# $f $ have )'% moles of gas held at a temperature of 2. / 0 and in a container with a volume of %& liters, what is the pressure of the gas* 1.62 at or 164 kPa "/# $f $ have an unnown +uantit! of gas held at a temperature of ""2& 1 in a container with a volume of )& liters and a pressure of &(/ atm, how man! moles of gas do $ have* 142.% or 14! ol ""# $f $ have /').& moles of gas at a temperature of .& 1 and a pressure of "'.& atmospheres, what is the volume of the gas* .#% L ")# $f $ have .) liters of gas held at a pressure of ,'% atm and a temperature of ))& 1, how man! moles of gas do $ have* 1!.! ol For chemistry help, visit www.chemfiesta.com 2000 Cavalcade Publishing - ll !ights !eserved The Ideal and &o'(ned Gas Laws PV = nRT or P 1 V 1 = P 2 V 2 T 1 T 2 "se your #nowledge of the ideal and combined gas laws to solve the following problems. $f it involves moles or grams, it must be P% & n!' 1) If four moles of a gas at a pressure of 5.4 atmospheres have a volume of 120 liters, what is the temperature? 1973 K 2) If I initially have a gas with a pressure of 84 ka an! a temperature of "5 0
# an! I heat it an a!!itional 2"0 !egrees, what will the new pressure $e? %ssume the volume of the &ontainer is &onstant. 146.7 kPa ") 'y &ar has an internal volume of 2(00 liters. If the sun heats my &ar from a temperature of 20 0 # to a temperature of 55 0 #, what will the pressure insi!e my &ar $e? %ssume the pressure was initially )(0 mm *g. 850.8 or 851 mm Hg 4) *ow many moles of gas are in my &ar in pro$lem +"? 108 mol 5) % toy $alloon fille! with air has an internal pressure of 1.25 atm an! a volume of 2.50 ,. If I take the $alloon to the $ottom of the o&ean where the pressure is -5 atmospheres, what will the new volume of the $alloon $e? *ow many moles of gas !oes the $alloon hol!? .%ssume / 0 285 1) .0329 L .13 mol For chemistry help, visit www.chemfiesta.com 2000 Cavalcade Publishing - ll !ights !eserved
)I*+, G-. L-W. W/RK.0++T 1od(2(ed '3 )r. 4asann5 0reated b! Tara 3' 4oore at www'learning'mgccc'cc'ms'us5p5sciencedocs5gaslawwsheet'htm ,(rect(ons : 6nswer each +uestion below' Then wr(te the nae o2 the 6as law 7sed to solve each +uestion in the left margin ne7t to each +uestion' "' 6 gas occupies ,'&3 at )'& mm 8g pressure' 9hat is the volume at "/ mm 8g at the same temperature*
.$%" L )' 6 constant volume of o7!gen is heated from "//0 to "-&0' The initial pressure is %'" atm' 9hat is the final pressure* ".0! at
,' 6 sample of )&3 of :8, gas at "/0 is heated at constant pressure until it fills a volume of &/3' 9hat is the new temperature in 0* 2#! &
%' 6 certain +uantit! of argon gas is under "( torr pressure at )&,1 in a ")3 vessel' 8ow man! moles of argon are present*
.012 ol
&' 6n unnown gas weighs ,%g and occupies ('.3 at ) atm and )%&1' 9hat is its molecular weight*
"1.1 68ol
(' 6n ideal gas occupies %//ml at )./ mm 8g and (&0' $f the pressure is changed to "'% atm and the temperature is increased to "//0, what is the new volume*
110.4 L or .110 L
.' 9hat is the volume of ),g of neon gas at "0 and a pressure of ) atm*
12.$ L
-' $f "" moles of 80l gas occupies "&3 at ,//0, what is the pressure in torr*
269220 torr
2' The pressure is ('& atm, )', mole of ;r) gas occupies 2', 3 ' 9hat is the temperature in 0*
%. 0
For chemistry help, visit www.chemfiesta.com 2000 Cavalcade Publishing - ll !ights !eserved "/' 6 (//m3 balloon is filled with helium at .//mm 8g barometric pressure' The balloon is released and climbs to an altitude where the barometric pressure is %//mm 8g' 9hat will the volume of the balloon be if, during the ascent, the temperature drops from )% to &0*
#$! L or .#$! L
""' 6n unnown gas has a volume of )//3 at & atm and -"%/0' 9hat is its volume at <TP*
20"2.6 or 20"! L ")' $n an autoclave, a constant amount of steam is generated at a constant volume' Under "'// atm pressure the steam temperature is "//0' 9hat pressure setting should be used to obtain a "(&0 steam temperature for the sterili=ation of surgical instruments* 21.22 kPa ",' 6ir contains o7!gen, nitrogen, carbon dio7ide, and trace amounts of other gases' 9hat is the partial pressure of o7!gen >P?)# at 101.!kPa o2 total :ress7re if it@s nown that the partial pressures of nitrogen, carbon dio7ide, and other gases are .2'"Pa, /'/%/Pa, and /'2%Pa, respectivel!* 9hat is the name of the gas law used for this* 21.22 kPa "%' A7plain wh! the rates of diffusion of nitrogen gas and carbon mono7ide gas are almost identical at the same temperature* .(nce the(r olar asses are the sae9 the(r rates o2 d(227s(on sho7ld 'e the sae accord(n6 the Graha;s law "&' 9hat distinguishes effusion from diffusion* 8ow are these processes similar* Biffusion is gas moving spontaneousl! from areas of high concentration to low concentration Affusion is diffusion of a gas escaping from a tin! opening "(' 9hich of the gases effuses faster at the same temperature: molecular chlorine, nitrogen dio7ide, ammonia or molecular nitrogen gas* 6nd wh!* <astest .lowest s(nce lower asses e227se 2aster =0 ! > = 2 > =/ 2 > &l 2
".' A7plain what each of the following changes would do to the pressure in a closed container >increase or decrease pressure#' 6# Part of the gas is removed, ;# The container si=e >volume# is decreased, and 0#Temperature is increased' -. 6as reo?ed decrease (n :ress7re @. Vol7e decrease (ncrease (n :ress7re &. Te:erat7re (ncrease (ncrease (n :ress7re "-' Betermine the total pressure of a gas mi7ture that contains o7!gen, nitrogen and helium in the following partial pressures of )'/atm for o7!gen, %'.atm for nitrogen and 2"!.2"kPa for helium' #.2 at or #!1.#6 kPa For chemistry help, visit www.chemfiesta.com 2000 Cavalcade Publishing - ll !ights !eserved