3. (a)ards Identification *mer$ency +,er,ie- 00000000000000000000000000 #A."I"/0 %1AMMA21* 1I34I5 A"5 6AP+.. (A.M%41 I% S#A11+#*57 I"(A1*5 +. A2S+.2*5 8(.+4/( S9I". 6AP+.S !A4S* .*SPI.A8+.: 8.A!8 I..I8A8I+" A"5 S*6*.* *:* I..I8A8I+". 1I34I5 !A4S*S S9I" I..I8A8I+"7 S*6*.* *:* I..I8A8I+" A"5 P+SSI21* *:* 24."S. A%%*!8S !*"8.A1 "*.6+4S S:S8*M. SA%;8;5A8A (tm) 1atin2s (Pro3ided here 4or your con3enience) 00000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000 %ealth 1atin2: . 0 Moderate (5i4e) 6lammability 1atin2: . 0 Moderate 1eacti3ity 1atin2: " 0 Sli2ht $ontact 1atin2: - 0 Se3ere 5ab Protecti3e 78uip: 9&9957S : S%I75D; 5A) $&A( : AP1&N; ;7N( %&&D; P1&P71 95&;7S; $5ASS ) 7<(IN9=IS%71 Stora2e $olor $ode: 1ed (6lammable) 00000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000000 Potential (ealth *ffects 0000000000000000000000000000000000 Inhalation Inhalation o4 3apors can irritate the nose> throat> and upper respiratory passa2es %i2her concentrations ha3e a narcotic e44ect and may cause headache> nausea> 3omitin2> di??iness> double 3ision> shortness o4 breath> and delirium In se3ere cases> inhalation may be 4atal May cause pulmonary edema> a medical emer2ency May cause heart e44ects In$estion Moderately toxic by in2estion> can cause headache> nausea> delirium and methemo2lobin 4ormation in the blood &ther symptoms may parallel those 4rom inhalation exposure ;omitin2 may cause aspiration into lun2s and result in chemical pnuemonia S<in !ontact S*in contact causes irritations and possibly burns i4 contact is repeated or prolon2ed May be absorbed throu2h the s*in *ye !ontact ;apors cause se3ere irritation Symptoms may include tearin2> pain> redness> s@ellin2 5i8uid contact causes se3ere irritation and possible burns !hronic *x&osure 1epeated inhalation o4 aerosols may result in lun2 and *idney inAury $hronic exposure may cause s*in e44ects A$$ra,ation of Pre;existin$ !onditions Persons @ith pre0existin2 s*in disorders or eye problems> or impaired li3er> *idney or respiratory 4unction may be more susceptible to the e44ects o4 the substance =. %irst Aid Measures Inhalation 1emo3e to 4resh air I4 not breathin2> 2i3e arti4icial respiration I4 breathin2 is di44icult> 2i3e oxy2en 9et medical attention In$estion I4 s@allo@ed> D& N&( IND=$7 ;&MI(IN9 9i3e lar2e 8uantities o4 @ater Ne3er 2i3e anythin2 by mouth to an unconscious person 9et medical attention immediately S<in !ontact Immediately 4lush s*in @ith plenty o4 @ater 4or at least "# minutes @hile remo3in2 contaminated clothin2 and shoes 9et medical attention Bash clothin2 be4ore reuse (horou2hly clean shoes be4ore reuse *ye !ontact Immediately 4lush eyes @ith plenty o4 @ater 4or at least "# minutes> li4tin2 lo@er and upper eyelids occasionally 9et medical attention immediately >. %ire %i$htin$ Measures %ire 6lash point: --$ (+"6) $$ Autoi2nition temperature: -,,$ (#C.6) 6lammable limits in air D by 3olume: lel: ".; uel: ",, 5isted 4ire data is 4or amyl alcohol ($AS C"0E"0,) 6lammable =pper explosi3e limit is 4or ",,$ (.".6) $ontact @ith stron2 oxidi?ers may cause 4ire *x&losion Abo3e 4lash point> 3apor0air mixtures are explosi3e @ithin 4lammable limits noted abo3e ;apors can 4lo@ alon2 sur4aces to distant i2nition source and 4lash bac* Sensiti3e to static dischar2e %ire *xtin$uishin$ Media Dry chemical> 4oam or carbon dioxide Bater spray may be used to *eep 4ire exposed containers cool Bater may be ine44ecti3e S&ecial Information In the e3ent o4 a 4ire> @ear 4ull protecti3e clothin2 and NI&S%0appro3ed sel40contained breathin2 apparatus @ith 4ull 4acepiece operated in the pressure demand or other positi3e pressure mode 6. Accidental .elease Measures ;entilate area o4 lea* or spill 1emo3e all sources o4 i2nition Bear appropriate personal protecti3e e8uipment as speci4ied in Section ! Isolate ha?ard area Feep unnecessary and unprotected personnel 4rom enterin2 $ontain and reco3er li8uid @hen possible =se non0 spar*in2 tools and e8uipment $ollect li8uid in an appropriate container or absorb @ith an inert material (e 2> 3ermiculite> dry sand> earth)> and place in a chemical @aste container Do not use combustible materials> such as sa@ dust Do not 4lush to se@erG I4 a lea* or spill has not i2nited> use @ater spray to disperse the 3apors> to protect personnel attemptin2 to stop lea*> and to 4lush spills a@ay 4rom exposures ' ( )a*er S&5=S&1)H sol3ent adsorbent is recommended 4or spills o4 this product 7. (andlin$ and Stora$e Protect a2ainst physical dama2e Store in a cool> dry @ell03entilated location> a@ay 4rom any area @here the 4ire ha?ard may be acute &utside or detached stora2e is pre4erred Separate 4rom incompatibles $ontainers should be bonded and 2rounded 4or trans4ers to a3oid static spar*s Stora2e and use areas should be No Smo*in2 areas =se non0spar*in2 type tools and e8uipment> includin2 explosion proo4 3entilation $ontainers o4 this material may be ha?ardous @hen empty since they retain product residues (3apors> li8uid); obser3e all @arnin2s and precautions listed 4or the product ?. *x&osure !ontrols'Personal Protection Air@orne *x&osure 1imits 0 AI%A Bor*place 7n3ironmental 7xposure 5e3el (B775): ",, ppm (-/, m2Im-)> !0hour> (BA 6entilation System A system o4 local andIor 2eneral exhaust is recommended to *eep employee exposures as lo@ as possible 5ocal exhaust 3entilation is 2enerally pre4erred because it can control the emissions o4 the contaminant at its source> pre3entin2 dispersion o4 it into the 2eneral @or* area Please re4er to the A$9I% document> Industrial Ventilation, A Manual of Recommended Practices> most recent edition> 4or details =se explosion0proo4 e8uipment Personal .es&irators ("I+S( A&&ro,ed) 6or conditions o4 use @here exposure to the substance is apparent and en2ineerin2 controls are not 4easble> consult an industrial hy2ienist 6or emer2encies> or instances @here the exposure le3els are not *no@n> use a 4ull04acepiece positi3e0pressure> air0supplied respirator BA1NIN9: Air puri4yin2 respirators do not protect @or*ers in oxy2en0de4icient atmospheres S<in Protection Bear imper3ious protecti3e clothin2> includin2 boots> 2lo3es> lab coat> apron or co3eralls> as appropriate> to pre3ent s*in contact *ye Protection =se chemical sa4ety 2o22les andIor a 4ull 4ace shield @here splashin2 is possible Maintain eye @ash 4ountain and 8uic*0drench 4acilities in @or* area A. Physical and !hemical Pro&erties A&&earance $lear> colorless li8uid +dor $haracteristic odor Solu@ility - D S&ecific /ra,ity ,!" J .,$IE$ &( No in4ormation 4ound B 6olatiles @y ,olume C 21! (7D%) ",, 2oilin$ Point "--$ (.C"6) Meltin$ Point No in4ormation 4ound 6a&or 5ensity (AirE1) -, 6a&or Pressure (mm ($) . J .,$ (/!6) *,a&oration .ate (2uAcE1) ,./ 1D. Sta@ility and .eacti,ity Sta@ility Stable at room temperature in sealed containers (a)ardous 5ecom&osition Products $arbon dioxide and carbon monoxide may 4orm @hen heated to decomposition $an 4orm aldehydes burnin2 in limited air (a)ardous Polymeri)ation Bill not occur Incom&ati@ilities Stron2 oxidi?ers Stron2 inor2anic acids %eat and sources o4 i2nition !onditions to A,oid %eat> 4lames> i2nition sources and incompatibles 11. 8oxicolo$ical Information 6or amyl alcohol ($AS K C"0E"0,): &ral rat 5D#,: ..,, m2I*2; s*in rabbit 5D#,: L -.,, m2I*2; irritation s*in rabbit> standard Drai?e: -.,, m2I*2I.E% se3ere; eye rabbit> standard Drai?e: !" m2I.E% se3ere In3esti2ated as a muta2en 6or .0methylbutanol ($AS K "-C0-.0/): &ral rat 5D#,: ">,,, m2I*2; S*in rabbit> 5D#,: -#E, u5I*2 Isoamyl alcohol: &ral rat 5D#, "-,, m2IF2; S*in rabbit 5D#, -+C, u5IF2; Irritation s*in rabbit ., m2I.E% moderate; Irritation eye rabbit ., m2I.E% moderate In3esti2ated as a tumori2en --------(Cancer )ists(------------------------------------------------------ ---N*P Carcinogen--- Ingredient +no,n Antici-ated IA.C Category ------------------------------------ ----- ----------- ------------- Amyl Alcohol /71-41-00 No No None $-%ethyl&utanol /1'7-'$-0 No No None Isoamyl Alcohol /1$'-51-'0 No No None 12. *colo$ical Information *n,ironmental %ate Bhen released into the soil> this material is expected to leach into 2round@ater Bhen released into the soil> this material may biode2rade to a moderate extent Bhen released into the soil> this material may e3aporate to a moderate extent Bhen released into @ater> this material may biode2rade to a moderate extent Bhen released into @ater> this material may e3aporate to a moderate extent (his material has an estimated bioconcentration 4actor ()$6) o4 less than ",, (his material is not expected to si2ni4icantly bioaccumulate Bhen released into the air> this material is expected to be readily de2raded by reaction @ith photochemically produced hydroxyl radicals Bhen released into the air> this material may be remo3ed 4rom the atmosphere to a moderate extent by @et deposition *n,ironmental 8oxicity No in4ormation 4ound 13. 5is&osal !onsiderations Bhate3er cannot be sa3ed 4or reco3ery or recyclin2 should be handled as ha?ardous @aste and sent to a 1$1A appro3ed @aste 4acility Processin2> use or contamination o4 this product may chan2e the @aste mana2ement options State and local disposal re2ulations may di44er 4rom 4ederal disposal re2ulations Dispose o4 container and unused contents in accordance @ith 4ederal> state and local re8uirements 1=. 8rans&ort Information 5omestic (1and7 5.+.8.) 00000000000000000000000 Pro&er Shi&&in$ "ame P7N(AN&5S (a)ard !lass - 4"'"A =N"",# Pac*in2 9roup: III Information re&orted for &roduct'si)e -C#5) International (#ater7 I.M.+.) 00000000000000000000000000000 Pro&er Shi&&in$ "ame P7N(AN&5S (a)ard !lass - 4"'"A =N"",# Pac*in2 9roup: III Information re&orted for &roduct'si)e -C#5) International (Air7 I.!.A.+.) 00000000000000000000000000000 Pro&er Shi&&in$ "ame P7N(AN&5S (a)ard !lass - 4"'"A =N"",# Pac*in2 9roup: III Information re&orted for &roduct'si)e -C#5) 1>. .e$ulatory Information --------(Chemical In1entory Status - Part 1(--------------------------------- Ingredient *SCA 2C 3a-an Australia ----------------------------------------------- ---- --- ----- --------- Amyl Alcohol /71-41-00 #es #es #es #es $-%ethyl&utanol /1'7-'$-0 #es #es #es #es Isoamyl Alcohol /1$'-51-'0 #es #es #es #es
--------(Chemical In1entory Status - Part $(--------------------------------- --Canada-- Ingredient +orea 4S) N4S) Phil5 ----------------------------------------------- ----- --- ---- ----- Amyl Alcohol /71-41-00 #es #es No #es $-%ethyl&utanol /1'7-'$-0 #es #es No #es Isoamyl Alcohol /1$'-51-'0 #es #es No #es
--------(6ederal7 State 8 International .egulations - Part 1(---------------- -SA.A '0$- ------SA.A '1'------ Ingredient .9 *P9 )ist Chemical Catg5 ----------------------------------------- --- ----- ---- -------------- Amyl Alcohol /71-41-00 No No No No $-%ethyl&utanol /1'7-'$-0 No No No No Isoamyl Alcohol /1$'-51-'0 No No No No
--------(6ederal7 State 8 International .egulations - Part $(---------------- -.C.A- -*SCA- Ingredient C2.C)A $15'' !/d0 ----------------------------------------- ------ ------ ------ Amyl Alcohol /71-41-00 No No No $-%ethyl&utanol /1'7-'$-0 No No No Isoamyl Alcohol /1$'-51-'0 No No No
Chemical :ea-ons Con1ention; No *SCA 1$/&0; No C4*A; No SA.A '11<'1$; Acute; #es Chronic; #es 6ire; #es Pressure; No .eacti1ity; No /%i=ture < )i>uid0 Australian (a)chem !ode -MNO Poison Schedule None allocated #(MIS (his MSDS has been prepared accordin2 to the ha?ard criteria o4 the $ontrolled Products 1e2ulations ($P1) and the MSDS contains all o4 the in4ormation re8uired by the $P1 16. +ther Information "%PA .atin$s %ealth: 2 6lammability: 3 1eacti3ity: D 1a@el (a)ard #arnin$ BA1NIN9G 65AMMA)57 5IP=ID AND ;AP&1 %A1M6=5 I6 SBA55&B7D> IN%A57D &1 A)S&1)7D (%1&=9% SFIN ;AP&1S $A=S7 17SPI1A(&1N (1A$( I11I(A(I&N AND S7;717 7N7 I11I(A(I&N 5IP=ID $A=S7S SFIN I11I(A(I&N> S7;717 7N7 I11I(A(I&N AND P&SSI)57 7N7 )=1NS A667$(S $7N(1A5 N71;&=S SNS(7M 1a@el Precautions Feep a@ay 4rom heat> spar*s and 4lame Feep container closed =se only @ith ade8uate 3entilation A3oid breathin2 3apor Do not 2et in eyes A3oid contact @ith s*in and clothin2 Bash thorou2hly a4ter handlin2 1a@el %irst Aid I4 s@allo@ed> D& N&( IND=$7 ;&MI(IN9 9i3e lar2e 8uantities o4 @ater Ne3er 2i3e anythin2 by mouth to an unconscious person In case o4 contact> immediately 4lush eyes or s*in @ith plenty o4 @ater 4or at least "# minutes @hile remo3in2 contaminated clothin2 and shoes Bash clothin2 be4ore reuse I4 inhaled> remo3e to 4resh air I4 not breathin2> 2i3e arti4icial respiration I4 breathin2 is di44icult> 2i3e oxy2en In all cases 2et medical attention immediately Product 4se 5aboratory 1ea2ent .e,ision Information No $han2es 5isclaimer ****************************************************************************** ****************** Mallinc<rodt 2a<er7 Inc. &ro,ides the information contained herein in $ood faith @ut ma<es no re&resentation as to its com&rehensi,eness or accuracy. 8his document is intended only as a $uide to the a&&ro&riate &recautionary handlin$ of the material @y a &ro&erly trained &erson usin$ this &roduct. Indi,iduals recei,in$ the information must exercise their inde&endent Fud$ment in determinin$ its a&&ro&riateness for a &articular &ur&ose. MA11I"!9.+58 2A9*.7 I"!. MA9*S "+ .*P.*S*"8A8I+"S +. #A..A"8I*S7 *I8(*. *GP.*SS +. IMP1I*57 I"!145I"/ #I8(+48 1IMI8A8I+" A": #A..A"8I*S +% M*.!(A"8A2I1I8:7 %I8"*SS %+. A PA.8I!41A. P4.P+S* #I8( .*SP*!8 8+ 8(* I"%+.MA8I+" S*8 %+.8( (*.*I" +. 8(* P.+54!8 8+ #(I!( 8(* I"%+.MA8I+" .*%*.S. A!!+.5I"/1:7 MA11I"!9.+58 2A9*.7 I"!. #I11 "+8 2* .*SP+"SI21* %+. 5AMA/*S .*S418I"/ %.+M 4S* +% +. .*1IA"!* 4P+" 8(IS I"%+.MA8I+". ****************************************************************************** ****************** Pre&ared @y 7n3ironmental %ealth : Sa4ety Phone Number: (-"E) /#E0"/,, (=SA)