Copy Cikgu Marzuqi Mohd Salleh Guru Cemerlang Kimia
MODUL KIMIA SPM 2014/2015 KERTAS 2 [100 markah]
KELAS INTENSIF Sekolah Kluster Kecemerlangan Kimia A+
Written by: Cikgu Marzuqi Mohd Salleh M.Sc. Ed USM BSc (hons) Ed (Chemistry) USM GURU CEMERLANG KIMIA MODUL 1 TINGKATAN 5
CHAPTER 1: RATE OF REACTIONS KADAR TINDAK BALAS MODUL 1 TINGKATAN 5 Chapter 1: Rate of Reaction Copy Cikgu Marzuqi Mohd Salleh Guru Cemerlang Kimia CHAPTER 1: RATE OF REACTIONS Kadar Tindak Balas
A Rate of Reaction Kadar tindak balas
Activity 1: What is rate of reaction? Apa itu kadar tindak balas?
Rate of reaction is the at which reactants are converted into . in a chemical reaction. Kadar tindak balas berlaku dengan .. di mana bahan tindak balas ditukar ke dalam .. tindak balas kimia.
The rate of reaction is a measurement of the change in the quantity of . or . against time. Kadar tindak balas adalah ukuran perubahan dalam kuantiti .. atau dalam satu unit masa.
Activity 2: Determine the slow and fast reactions Tentukan tindak balas perlahan dan cepat
[6 markah] MODUL 1 TINGKATAN 5 Chapter 1: Rate of Reaction Copy Cikgu Marzuqi Mohd Salleh Guru Cemerlang Kimia Activity 3: Observable changes for measuring the rate of reaction Perubahan yang dapat diperhatikan untuk mengukur kadar tindak balas
The change in amount of reactant / product that can be measured by: Perubahan dalam jumlah bahan tindak balas / hasil yang boleh diukur oleh:
For each of the reactions below, write a chemical equation and state the observable change/changes can be used as selected quantities to measure the rate of reaction: Bagi setiap tindak balas berikut, tuliskan satu persamaan kimia dan nyatakan perubahan yang dapat diperhatikan/ perubahan yang boleh digunakan sebagai kuantiti untuk mengukur kadar tindak balas:
Example 1: The reaction between marble chip with hydrochloric acid to produce carbon dioxide gas and chloride salt. Tindak balas antara serpihan marmar dengan asid hidroklorik untuk menghasilkan gas karbon dioksida dan garam klorida.
Chemical Equation: . Persamaan kimia
Changes:
(i) ...(reactants/ bahan tindak balas) (ii) ..(product/ hasil)
Example 2: Reaction between sodium thiosulphate solution with sulphuric acid to produce yellow precipitate of sulphur, water, sulphur dioxide and sodium sulphate solution. Tindak balas antara larutan natrium tiosulfat dengan asid sulfurik untuk menghasilkan mendakan kuning sulfur, air, sulfur dioksida dan larutan natrium sulfat.
Chemical equation: .. Change: (i) (product/ hasil) .. in the mass of reactant .............................................. jisim bahan tindak balas
.. in mass of product .............................................. jisim hasil tindak balas
.. in volume of gas released .............................................. isi padu gas yang dibebaskan .. of precipitate ............................................. mendakan sebagai hasil tindak balas
Change in pH, temperature or electrical conductivity Perubahan pH, suhu atau kekonduksian elektrik
.. pressure
tekanan MODUL 1 TINGKATAN 5 Chapter 1: Rate of Reaction Copy Cikgu Marzuqi Mohd Salleh Guru Cemerlang Kimia Example 3: Decomposition of hydrogen peroxide to produce water and oxygen gas. Penguraian hidrogen peroksida untuk menghasilkan air dan gas oksigen.
Chemical equation: .. Change: (i) (product / hasil)
Activity 4: Measusement of the Rate of Reaction. Pengukuran Kadar Tindak Balas
Average Rage of Reaction/ Kadar Tindak Balas Purata
Instantaneous Rate of Reaction = Gradient of the graph Kadar Tindak Balas Pada Masa Tertentu = kecerunan tangen pada graf
The reaction between zinc and hydrochloric acid, HCl release 25 cm 3 of hydrogen gas and the gas is collected in 60 seconds. Tindak balas antara zink dengan asid hidroklorik, HCl membebaskan 25 cm 3 gas hidrogen dan gas dikumpulkan dalam masa 60 saat.
0.2 g of magnesium ribbon reacts completely with dilute hydrochloric acid in 40 seconds. What is the rate of reaction? 0.2 g pita magnesium bertindak balas sepenuhnya dengan asid hidroklorik cair dalam 40 saat. Berapakah kadar tindak balas? Calculate the average rate of reaction for the reaction between 2.6 g of zinc and 50 cm 3 of 1.0 mol dm -3 hydrochloric acid. Hitung kadar tindak balas purata bagi tindak balas antara 2.6 g zink dengan 50 cm 3 asid hidroklorik 1.0 mol -3 .
Calculate the average rate? / hitung kadar tindak balas purata? Time 0 20 40 80 120 Mass of CaCo 3
0.0 0.048 0.116 0.164 0.164 Rate of reaction = Change in quantity of reactant or Product / perubahan bahan tindak balas atau hasil Kadar tindak balas Time taken/ masa diambil Instantaneous rate = Change of volume in y axis / perubahan isi padu paksi y Change of volume in x axis / perubahan isi padu paksi x V 2 V 1
T 2 T 1
MODUL 1 TINGKATAN 5 Chapter 1: Rate of Reaction Copy Cikgu Marzuqi Mohd Salleh Guru Cemerlang Kimia The results for the experiment of decomposition of hydrogen gas liberated are given below. Keputusan eksperimen tentang penguraian gas hidrogen dibebaskan seperti yang ditunjukkan di bawah.
Time (s) 0 30 60 90 120 150 180 210 240 270 300 330 360 Volume of gas liberated (cm 3 )
0
7.50
11.75
14.50
16.50
18.25
19.75
21.00
21.75
22.50
23.25
23.75
24.00
Calculate the average rate of reaction in the first 2 minutes. Kirakan kadar tindak balas purata dalam masa 2 minit pertama.
Calculate the average rate of reaction in the second minute. Kirakan kadar tindak balas purata dalam minit kedua. Calculate the instantaneous rate of reaction at 30 seconds. Kira kadar tindak balas pada masa tertentu dalam masa 30 saat.
Calculate the instantaneous rate of reaction at 90 seconds. Kira kadar tindak balas pada masa tertentu dalam masa 90 saat.
MODUL 1 TINGKATAN 5 Chapter 1: Rate of Reaction Copy Cikgu Marzuqi Mohd Salleh Guru Cemerlang Kimia A graph of the volume of hydrogen gas liberated against time Graf isi padu gas hidrogen dibebaskan melawan masa
MODUL 1 TINGKATAN 5 Chapter 1: Rate of Reaction Copy Cikgu Marzuqi Mohd Salleh Guru Cemerlang Kimia B FACTORS AFFECTING THE RATE OF REACTION Faktor-faktor yang mempengaruhi kadar tindak balas
Activity 6: Factors affecting the rate of reaction. Faktor-faktor yang mempengaruhi kadar tindak balas.
State five factors that affect the rate of reaction / Nyatakan lima faktor yang mempengaruhi kadar tindak balas:
(a) . (b) .. (c) . (d) .. (e) .
Activity 7: What is catalyst? Apa itu pemangkin?
State three characteristics of the catalyst / Nyatakan tiga ciri-ciri pemangkin:
1.
2.
3.
Industrial applications of Catalysts Penggunaan mangkin di dalam aplikasi industri
MODUL 1 TINGKATAN 5 Chapter 1: Rate of Reaction Copy Cikgu Marzuqi Mohd Salleh Guru Cemerlang Kimia Activity 8: Shapes of curve depend on the volume and concentration of reaction Bentuk lengkung bergantung kepada isi padu dan kepekatan tindak balas
Experiment
Initial rate of reaction Kadar tindak balas awal Maximum volume of hydrogen gas I si padu maksimum gas hidrogen Graph Set I 1 g of excess Zn powder + 50 cm 3 of 0.10 mol dm -3 HCl 1 g serbuk Zn berlebihan + 50 cm 3 0.10 mol dm -3
HCl
Set II 1 g of excess Zn powder + 30 cm 3 of 0.20 mol dm -3 HCl 1 g serbuk Zn berlebihan +30 cm 3 0.20 mol dm -3
HCl
The initial rate of set I is l .. than that of set II. Kadar awal set I adalah lebih . daripada set II.
This is because the concentration of HCl in set I is .. than that in set II. Kerana kepekatan HCl dalam set I adalah lebih .. daripada set II. Zinc is excess. zink berlebihan. Set I
= ..
Set II
=
The number of mole HCl in set I is l than that in set II. Bilangan mol HCl dalam set I adalah lebih daripada set II.
Hence, maximum volume of H 2 released in set I is .. than that in set II. Oleh itu, isi padu maksimum H 2 dibebaskan dalam set I adalah lebih .. daripada set II.
Set I 1 g of excess Zn powder + 50 cm 3 of 0.10 mol dm -3 HCl 1 g serbuk Zn berlebihan + 50 cm 3 0.10 mol dm -3
HCl
Set III 1 g of excess Zn powder + 150 cm 3 of 0.05 mol dm -3 HCl 1 g serbuk Zn berlebihan + 150 cm 3 0.05 mol dm -3
HCl
The initial rate of set I is .. than that of set III. Kadar awal set I adalah lebih .. daripada set III.
This is because the concentration of HCl in set I is .. than that in set III. Kerana kepekatan HCl dalam set I adalah lebih .. daripada set III. Zinc is excess. zink berlebihan. Set I = ..
Set II = ...
The number of mole HCl in set I is than that in set III. Bilangan mol HCl dalam set I adalah lebih . daripada set III.
Hence, maximum volume of H 2 released in set I is . than that in set III. Oleh itu, isi padu maksimum H 2 dibebaskan dalam set I adalah lebih .. daripada set III.
MODUL 1 TINGKATAN 5 Chapter 1: Rate of Reaction Copy Cikgu Marzuqi Mohd Salleh Guru Cemerlang Kimia Set I 1 g of excess Zn powder + 50 cm 3 of 0.10 mol dm -3 HCl 1 g serbuk Zn berlebihan + 50 cm 3 0.10 mol dm -3
HCl
Set IV 1 g of excess Zn powder + 25 cm 3 of 0.15 mol dm -3 HCl 1 g serbuk Zn berlebihan + 25 cm 3 0.15 mol dm -3
HCl
The initial rate of set I is .. than that of set IV. Kadar awal set I adalah lebih .. daripada set IV.
This is because the concentration of HCl in set I is .. than that in set IV. Kerana kepekatan HCl dalam set I adalah lebih .. daripada set IV. Zinc is excess. zink berlebihan. Set I
= ..
Set IV
=
The number of mole HCl in set I is than that in set IV. Bilangan mol HCl dalam set I adalah lebih daripada set IV.
Hence, maximum volume of H 2 released in set I is l than that in set IV. Oleh itu, isi padu maksimum H 2 dibebaskan dalam set I adalah lebih daripada set IV.
Set I 1 g of excess Zn powder + 50 cm 3 of 0.10 mol dm -3 HCl 1 g serbuk Zn berlebihan + 50 cm 3 0.10 mol dm -3
HCl
Set V 1 g of excess Zn powder + 100 cm 3 of 0.05 mol dm -3 HCl 1 g serbuk Zn berlebihan + 100 cm 3 0.05 mol dm -3
HCl
The initial rate of set I is .. than that of set V. Kadar awal set I adalah lebih ..daripada set V.
This is because the concentration of HCl in set I is .. than that in set V. Kerana kepekatan HCl dalam set I adalah lebih .. daripada set V. Zinc is excess. zink berlebihan. Set I
= ..
Set V
=
The number of mole HCl in set I is than that in set V. Bilangan mol HCl dalam set I adalah lebih daripada set V.
Hence, maximum volume of H 2 released in set I is l than that in set V. Oleh itu, isi padu maksimum H 2 dibebaskan dalam set I adalah lebih .. daripada set V.
MODUL 1 TINGKATAN 5 Chapter 1: Rate of Reaction Copy Cikgu Marzuqi Mohd Salleh Guru Cemerlang Kimia Activity 9: Shapes of curve depend on the volume and temperature of reaction Bentuk lengkung bergantung kepada isi padu dan suhu tindak balas
Experiment
Initial rate of reaction Kadar tindak balas awal Maximum volume of carbon dioxide gas liberated I si padu maksimum gas karbon dioksida dibebaskan
Set I 3 g of excess marble chips + 50 cm 3 of 0.5 mol dm -3 nitric acid at temperature of 27.0 o C 3 g ketulan marmar berlebihan + 50 cm 3 0.5 mol dm -3 asid nitrik pada suhu 27.0 o C
Set II 3 g of excess marble chips + 50 cm 3 of 0.5 mol dm- 3 nitric acid in hot water bath a constant at temperature of 60.0 o C 3 g ketulan marmar berlebihan + 50 cm 3 0.5 mol dm -3 asid nitrik dalam air panas yang tetap pada suhu 60.0 o C
The initial rate of set I is l .. than that of set II. Kadar awal set I adalah lebih . daripada set II.
This is because the temperature of the reaction for set I is than that for set II kerana suhu tindak balas bagi set I adalah lebih . daripada set II Marble chips are excess. Ketulan marmar berlebihan. Set I
= ..
Set II
=
Quantities of marble and nitric acid used, in mol, in both sets I and II are the . Kuantiti marmar dan asid nitrik digunakan, dalam mol, kedua-dua set I dan II adalah ...................
Hence, maximum volume of carbon dioxide gas liberated in both sets I and II are the Oleh itu, isi padu maksimum gas karbon dioksida dibebaskan dalam kedua-dua set I dan II adalah ............... Graph
MODUL 1 TINGKATAN 5 Chapter 1: Rate of Reaction Copy Cikgu Marzuqi Mohd Salleh Guru Cemerlang Kimia Activity 10: Shapes of curve depend on the volume and catalyst of reaction Bentuk lengkung bergantung kepada isi padu dan pemangkin tindak balas
Experiment
Initial rate of reaction Kadar tindak balas awal Maximum volume of hydrogen gas liberated I si padu maksimum gas hydrogen dibebaskan
Set I 2 g of granulated zinc + 25 cm 3 of 0.1 mol dm -3 of copper(II) sulphate solution. 2 g pasir zink + 25 cm 3
0.1 mol dm -3 larutan kuprum (II) sulfat.
Set II 2 g of granulated zinc + cm 3 of 0.1 mol dm-3 hydrochloric 2 g pasir zink + 25 cm 3
0.1 mol dm-3 hidroklorik
The initial rate of set I is l .. than that of set II. Kadar awal set I adalah lebih . daripada set II.
This is because copper(II) sulphate solution in set I acts as a catalyst to speed up the reaction. kerana larutan kuprum (II) sulfat dalam set I bertindak sebagai pemangkin untuk mempercepatkan tindak balas
.The use of copper(II) sulphate as a catalyst does not change the amount of products formed. Penggunaan kuprum (II) sulfat sebagai pemangkin tidak mengubah jumlah hasil yang terbentuk. Marble chips are excess. Ketulan marmar berlebihan. Set I
= ..
Set II
=
Quantities of zinc and hydrochloric acid used, in mol, in both sets I and II are the . Kuantiti zink dan asid hidroklorik digunakan, dalam mol, kedua-dua set I dan II adalah ...................
Hence, maximum volume of hydrogen gas liberated in both sets I and II are the
Oleh itu, isi padu maksimum gas hidrogen dibebaskan dalam kedua-dua set I dan II adalah ............... Graph
MODUL 1 TINGKATAN 5 Chapter 1: Rate of Reaction Copy Cikgu Marzuqi Mohd Salleh Guru Cemerlang Kimia Activity 11: Solving problems involving the factors effecting the rate of reaction Penyelesaian masalah faktor-faktor yang melibatkan kadar tindak balas
Set Reacting condition / keadaan tindakan I 5 g of excess zinc powder + 100 cm 3 of 0.4 mol dm -3 sulphuric acid + 5 cm 3 of 1 mol dm -3
copper(II) sulphate solution at room temperature 5 g serbuk zink berlebihan + 100 cm 3 0.4 mol dm -3 asid sulfurik + 5 cm 3 1 mol dm -3 larutan kuprum (II) sulfat pada suhu bilik II 5 g of excess zinc powder + 50 cm 3 of 0.4 mol dm -3 sulphuric acid at room temperature 5 g serbuk zink berlebihan + 50 cm 3 0.4 mol dm -3 asid sulfurik pada suhu bilik III 5 g of excess zinc powder + 70 cm 3 of 0.4 mol dm -3 sulphuric acid at room temperature 5 g serbuk zink berlebihan + 70 cm 3 0.4 mol dm -3 asid sulfurik pada suhu bilik
Sketch the graphs of volume of hydrogen gas liberated against time for sets I, II, and III on the same axes. Explain how you obtain your answer. Lakarkan graf isi padu gas hidrogen dibebaskan melawan masa untuk set I, II, dan III pada paksi yang sama. Terangkan bagaimana anda mendapatkan jawapan tersebut.
Solution / penyelesaian:
Step 1: Compare the yield / bandingkan hasil:
Set Mass of zinc / jisim zink Number of moles of sulphuric acid / bilangan mol asid sulfurik I
II
III
Number of moles of sulphuric acid reacted in set . > .. > Bilangan mol asid sulfurik bertindak balas dalam set Hence, the maximum volume of hydrogen gas liberated in set > > .. Oleh itu, isi padu maksimum gas hidrogen dibebaskan dalam set
Step 2: Compare the rate / bandingkan tidak balas:
Set Surface area of zinc Luas permukaan zink Concentration of hydrochloric acid / kepekatan asid hidroklorik Catalyst / mangkin I
II
III
MODUL 1 TINGKATAN 5 Chapter 1: Rate of Reaction Copy Cikgu Marzuqi Mohd Salleh Guru Cemerlang Kimia Initial rate of reaction for set > set because of the pressure of catalyst in set Kadar tindak balas awal bagi set ......> set ...... kerana tekanan pemangkin dalam set ......
Initial rate of reaction for set > set because of the total surface area of zinc used in set .. is larger than that in set . Kadar tindak balas awal bagi set ......> set ...... kerana isi padu luas permukaan zink yang digunakan dalam set .............. adalah lebih besar daripada set ..........
Hence, the initial of reaction for set ... > set .. . > set . Oleh itu, tindak balas awal bagi set .........> set ......... > set .......
This means that the initial gradient of the curve for set . > set . > set . Ini bermakna kecerunan awal lengkung bagi set ....... > set ....... > set .......
Step 3: sketch the graph / lakar graf:
C COLLISION THEORY / TEORI PERLANGGARAN
Activity 12: What is an Effective Collision / Apa itu Perlanggaran Berkesan?
What is definition of Activation Energy / Takrifan bagi Tenaga Pengaktifan?
Draw an energy profile diagram for the reaction/ lukis satu gambar rajah profil tenaga untuk tindak balas Activation energy without a catalyst / Tenaga pengaktifan tanpa mangkin, E a
Activation energy with a catalyst / Tenaga pengaktifan dengan mangkin, E a
MODUL 1 TINGKATAN 5 Chapter 1: Rate of Reaction Copy Cikgu Marzuqi Mohd Salleh Guru Cemerlang Kimia Activity 13: Two sets of experiments are carried out as shows below: Dua set eksperimen yang telah dijalankan seperti di bawah:
Set I 1.0 g of granulated zinc is added to 20 cm 3 of 0.5 mol dm -3 sulphuric acid at 27.0 o C Set II 1.0 g of zinc powder is added to 20 cm 3 of 0.5 mol dm -3 sulphuric acid at 27.0 o C Set I 1.0 g ketulan zink ditambah kepada 20 cm 3 0.5 mol dm -3 asid sulfurik pada 27.0 o C Set II 1.0 g serbuk zink ditambah kepada 20 cm 3 0.5 mol dm -3 asid sulfurik pada 27.0 o C
The initial rate of liberation of hydrogen gas in set II is higher than that in Set I. Explain the difference in rate using the collision theory. Kadar awal pembebasan gas hidrogen dalam Set II adalah lebih tinggi daripada di Set I. Terangkan perbezaan dalam kadar dengan menggunakan teori perlanggaran. [5 marks] Particle size of zinc powder in Set II is .. than that of granulated zinc in Set I. Saiz Zarah serbuk zink di dalam Set II adalah lebih daripada pasir zink di Set I.
Thus, the total exposed surface area of 1.0 g of zinc powder in Set II is ..than that of 1.0 g granulated zinc in Set I. Oleh itu, jumlah luas permukaan terdedah 1.0 g serbuk zink di dalam Set II adalah lebih daripada 1.0 g ketulan zink dalam Set I.
As a result, the frequency of collision between the hydrogen ions from sulphuric acid and the zinc atoms at the surfare of zinc powder in Set II is . than that occurring at the surface of granulated zinc in Set I. Hasilnya, kekerapan perlanggaran antara ion-ion hidrogen daripada asid sulfurik dan atom zink di surfare serbuk zink di dalam Set II adalah lebih daripada yang berlaku di permukaan pasir zink di Set I.
This causes the frequency of effective collision between hydrogen ions and zinc atoms in Set II to be .. than that in Set I. Ini menyebabkan kekerapan perlanggaran berkesan antara ion hidrogen dan atom zink dalam Set II lebih daripada yang di Set I.
Hence, the initial rate of liberated of hydrogen gas in Set II is .. than that in Set I. Akhir, kadar awal bagi gas hidrogen yang dibebaskan dalam Set II adalah lebih .. daripada di Set I.
Summary: Teori Perlanggaran Frekuensi Perlanggaran Berkesan dengan Kadar Tindak Balas Factors Faktor-faktor Effecting Kesan frequency of collision Frekuensi Perlanggaran frequency of effective collision Frekuensi Perlanggaran Berkesan Rate of reaction Kadar tindak balas Saiz bahan tindak balas Semakin kecil bahan, semakin luas jumlah permukaan yang terdedah kepada pelanggaran Meningkat Meningkat Meningkat Kepekatan larutan Semakin tinggi kepekatan larutan, semakin banyak bilangan zarah per unit isi padu Meningkat Meningkat Meningkat Suhu larutan Semakin tinggi suhu, semakin tinggi tenaga kinetik Meningkat Meningkat Meningkat Mangkin Mangkin menyediakan laluan alternative bagi tindak balas berlaku dengan merendahkan tenaga pengaktifan, Ea Meningkat Meningkat Meningkat MODUL 1 TINGKATAN 5 Chapter 1: Rate of Reaction Copy Cikgu Marzuqi Mohd Salleh Guru Cemerlang Kimia BAHAGIAN A SPM 2011 In an experiment to investigate the rate of reaction, 50.0 cm 3 of 2.0 mol dm -3 sodium thiosulphate solution and 5.0 cm 3 of 1.0 mol dm -3 of sulphuric acid, are used. The sulphur formed can be used to measure the rate of reaction. Dalam satu eksperimen untuk mengkaji kadar tindak balas, 50.0 cm 3 larutan natrium tiosulfat 2.0 mol dm -3 dan 5.0 cm 3 asid sulfurik 1.0 mol dm -3 digunakan.Sulfur yang terbentuk boleh digunakan untuk mengukur kadar tindak balas itu.
The equation for the reaction is given below. Persamaan tindak balas itu diberi di bawah.
Na 2 S 2 O 3 + H 2 SO 4 Na 2 SO 4 + SO 4 + S + H 2 O
(a) What is the colour of sulphur? Apakah warna sulfur?
[1 mark] (b) The number of moles of a solute can be calculated using formula, n = MV. [n= Number of moles of solute (mol), M= Molarity of solution (mol dm -3 ), V= Volume of solution (dm 3 )] Bilangan mol suatu zat terlarut boleh dihitung menggunakan rumus,n=MV. n=Bilangan mol zat terlarut (mol, M= Kemolaran larutan (mol dm -3 ), V= isi padu larutan (dm 3 )] Calculate / Hitung: (i) The number of mole of sodium thiosulphate in the solution. Bilangan mol bagi natrium tiosulfat dalam larutan itu. [1 mark]
(ii) The number of mole of sulphuric acid. Bilangan mol bagi asid sulfurik. [1 mark]
MODUL 1 TINGKATAN 5 Chapter 1: Rate of Reaction Copy Cikgu Marzuqi Mohd Salleh Guru Cemerlang Kimia (c) Based on the answers in (b)(i) and (b)(ii),name the reactant which determines the quantity of sulphur formed at the end of the reaction. Berdasarkan jawapan di (b)(i) dan (b)(ii), namakan bahan tindak balas yang menentukan kuantiti sulfur yang terbentuk pada akhir tindak balas itu.
.. [1 mark]
(d) (i) State three factors that can affect the rate of reaction in this experiment. Nyatakan tiga faktor yang boleh mempengaruhi kadar tindak balas itu dalam eksperimen ini.
1
2
3 [3 marks]
(ii) Using the collision theory, explain how any one of the factors in (d)(i) increases the rate of reaction. Menggunakan teori perlanggaran,terangkan bagaimana mana-mana satu daripada faktor di (d)(i) meningkatkan kadar tindak balas itu.
[2 marks]
MODUL 1 TINGKATAN 5 Chapter 1: Rate of Reaction Copy Cikgu Marzuqi Mohd Salleh Guru Cemerlang Kimia BAHAGIAN B SPM 2013 Diagram shows the energy profile diagram for the reaction between zinc and hydrochloric acid. Copper (II) sulphate solution is added to the reactants mixture to increase the rate of reaction. Rajah menunjukkan rajah profil tenaga bagi tindak balas antara zink dengan asid hidroklorik. Larutan kuprum(II)sulfat ditambahkan kepada campuran bahan tindak balas untuk meningkatkan kadar tindak balas.
Diagram Rajah (i) Which of the values r or s represents the activation energy for the reaction after adding copper(II) sulphate solution? Antara nilai r atau s yang manakah yang mewakili tenaga pengaktifan bagi tindak balas itu selepas penambahan larutan kuprum(II) sulfat? [1 markah] (ii) By using collision theory,explain how copper(II) sulphate solution increase the rate of reaction. Dengan menggunakan teori perlanggaran,terangkan bagaimana kuprum(II) sulfat meningkatkan kadar tindak balas. [4 markah] (iii) 100 cm 3 of 1.0 mol dm -3 hydrochloric acid and excess zinc are used in the reaction. Write the chemical equation for the reaction and calculate the volume of hydrogen gas released at room conditions. [1 mol of gas occupies 24 dm 3 at room condition] 100 cm 3 asid hidroklorik 1.0 mol dm -3 dan zink berlebihan digunakan dalam tindak balas itu. Tulis persamaan kimia bagi tindak balas itu dan hitung isi padu pada gas hydrogen yang dibebaskan pada keadaan bilik. [1 mol gas menempati 24 dm 3 pada keadaan bilik] [5 markah]
Products Hasil tindak balas Reaction path Lintasan tindak balas Reactants Bahan tindak balas Energy tenaga _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ r s _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ MODUL 1 TINGKATAN 5 Chapter 1: Rate of Reaction Copy Cikgu Marzuqi Mohd Salleh Guru Cemerlang Kimia (b) Table shows the information for three sets of experiment to investigate factors affecting the rate of reaction between calcium carbonate and hydrochloric acid. Jadual menunjukkan maklumat bagi tiga set eksperimen untuk menyiasat faktor-faktor yang mempengaruhi kadar tindak balas antara kalsium karbonat dengan asid hidroklorik.
Experiment Eksperimen Reactants Bahan tindak balas Time taken to collect 40 cm 3 carbon dioxide gas (s) Masa yang diambil untuk mengumpul 40 cm 3 gas karbon dioksida (s) Set I 5 g calcium carbonate powder 5 g serbuk kalsium karbonat 50 cm 3 of 1.0 mol dm -3 hydrocloric acid 50 cm 3 asid hidroklorik 1.0 mol dm -3
33 Set II 5 g calcium carbonate chip 5 g ketulan kalsium karbonat 50 cm 3 of 1.0 mol dm -3 hydrocloric acid 50 cm 3 asid hidroklorik 1.0 mol dm -3
45 Set III 5 g calcium carbonate 5 g serbuk kalsium karbonat 25 cm 3 of 2.0 mol dm -3 hydrocloric acid 25 cm 3 asid hidroklorik 2.0 mol dm -3
25 Table Jadual
Based on the information in Table, compare the rate of reaction between (i) Set I and Set II (ii) Set I and Set III By using the collision theory, explain your answers.
Berdasarkan maklumat dalam Jadual, banding kadar tindak balas antara (i) Set I dan Set II (ii) Set I dan Set III Dengan menggunakan teori perlanggaran,terangkan jawapan anda [10 markah]
MODUL 1 TINGKATAN 5 Chapter 1: Rate of Reaction Copy Cikgu Marzuqi Mohd Salleh Guru Cemerlang Kimia BAHAGIAN C SPM 2012 A student carried out three sets of experiments to investigate the factors that affect the rate of reaction. Time taken to collect 40 cm 3 of hydrogen gas is recorded in Table. Seorang pelajar menjalankan tiga set eksperimen untuk mengkaji faktor yang mempengaruhi kadar tindak balas. Masa yang diambil untuk mengumpul 40 cm 3 gas hidrogen direkodkan dalam Jadual.
Set Reactant Bahan tindak balas Temperature of the mixture Suhu campuran Time taken to collect 40 cm 3 of hydrogen gas (s) Masa yang diambil untuk mengumpul 40 cm 3 gas hidrogen (s) I 25 cm 3 of 0.2 mol dm -3 hydrochloric acid 25 cm 3 asid hidroklorik 0.2 mol dm -3
+ excess zinc powder serbuk zink berlebihan
30 o C
90 II 25 cm 3 of 0.4 mol dm -3 hydrochloric acid 25 cm 3 asid hidroklorik 0.4 mol dm -3
+ excess zinc powder serbuk zink berlebihan
30 o C
55
II 25 cm 3 of 0.2 mol dm -3 hydrochloric acid 25 cm 3 asid hidroklorik 0.2 mol dm -3
+ excess zinc powder serbuk zink berlebihan
40 o C
30 Table Jadual
(a) Zinc, Zn reacts with hydrochloric acid, HCI to produce zinc chloride, ZnCI 2 and hydrogen gas, H 2 . Write a balanced chemical equation for the reaction and calculate the maximum volume of hydrogen gas produced in set I. [Relative atomic mass: Zn =65; 1 mol of any gas occupies 24 dm 3 mol -1 at room conditions] Zink, Zn bertindak balas dengan asid hidroklorik, HCI menghasilkan zink klorida, ZnCI 2 dan gas hydrogen, H 2 . Tulis persamaan kimia yang seimbang bagi tindak balas itu dan hitung isi padu maksimum gas hydrogen yang dihasilkan dalam set I. [Jisim atom relatif: Zn =65; 1 mol bagi sebarang gas menempati 24 dm 3 pada keadaan bilik] [4markah] MODUL 1 TINGKATAN 5 Chapter 1: Rate of Reaction Copy Cikgu Marzuqi Mohd Salleh Guru Cemerlang Kimia
(b) Based on Table, compare the rates of reaction Berdasarkan Jadual, bandingkan kadar tindak balas
(i) between set I and set II antara set I dan set II
(ii) between set I and set III antara set I dan set III
By referring to collision theory, explain your answer in (b)(i) or (b)(ii). Dengan merujuk kepada teori perlanggaran,terangkan jawapan anda di (b)(i) atau (b)(ii). [6 markah]
(c) Catalyst and size of reactants can also affect the rate of reaction between acid and zinc. Choose one of these two factors and describe an experiment to show how this factor affects the rate of reaction. Mangkin dan saiz bahan tindak balas juga dapat mempengaruhi kadar tindak balas antara asid dan zink. Pilih satu daripada dua faktor ini dan huraikan satu eksperimen untuk menunjukkan bagaimana faktor ini dapat mempengaruhi kadar tindak balas. [10 markah]