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This Test Method covers the determination of the Solubility of Pentachlorophenol wood preservative in heavy hydrocarbon solvent. It does not purport to address all of the safety concerns, if any, associated with its use. The user of this standard must establish appropriate safety and health practices.
This Test Method covers the determination of the Solubility of Pentachlorophenol wood preservative in heavy hydrocarbon solvent. It does not purport to address all of the safety concerns, if any, associated with its use. The user of this standard must establish appropriate safety and health practices.
This Test Method covers the determination of the Solubility of Pentachlorophenol wood preservative in heavy hydrocarbon solvent. It does not purport to address all of the safety concerns, if any, associated with its use. The user of this standard must establish appropriate safety and health practices.
Solubility of Pentachlorophenol in Heavy Hydrocarbon Solvents 1 , 2 This standard is issued under the xed designation D 2606; the number immediately following the designation indicates the year of original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A superscript epsilon (e) indicates an editorial change since the last revision or reapproval. 1. Scope 1.1 This test method covers the determination of the solu- bility of pentachlorophenol wood preservative in heavy hydro- carbon solvent. 1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appro- priate safety and health practices and determine the applica- bility of regulatory limitations prior to use. 2. Referenced Documents 2.1 ASTM Standards: D 86 Test Method for Distillation of Petroleum Products 3 D 2085 Test Method for Determining Chloride Used in Calculating Pentachlorophenol in Solutions or Wood (Lime Ignition Method) 4 2.2 AWPA Standards: 5 P8 77 Standards for Oil-Borne Preservatives P9 77 Standard for Solvents for Organic Preservative Systems 3. Summary of Test Method 3.1 Aweighed amount of hydrocarbon solvent, or a residual fraction thereof, at a specied temperature, is observed for undissolved pentachlorophenol. 4. Signicance and Use 4.1 This is a test to determine that the solvent has sufficient solubility for pentachlorophenol to ensure it will remain in solution during treating process and in the treated wood. 5. Procedure 5.1 Add 10 g (60.1 g) of pentachlorophenol to 90 g (61.0 g) of hydrocarbon and maintain the mixture at 150F (65.5C) with constant stirring for 30 min. If there is visual evidence of undissolved pentachlorophenol remaining at the end of the heating period, regard the petroleum as nonconforming. 5.2 If there is no evidence of undissolved pentachlorophenol and in cases of doubt, cool the solution to 75F (24C) and maintain it at this temperature for 4 h. During the rst 2 h, stir the solution at intervals of 15 min. During the last 2 h, permit it to stand undisturbed to allow any undissolved pentachlo- rophenol to settle to the bottom. If a centrifuge is available, the solution may be centrifuged for 10 min as an alternative for the nal 2-h period. In either case, a sample of the solution shall be removed from the supernatant liquid and analyzed by Test Method D 2085. 5.3 Add 6 g (60.1 g) of technical pentachlorophenol (AWPA P8) to the Hydrocarbon Solvent Type A (AWPA P9) fraction undistilled above 500F from a 100-mL Method D 86 distillation, and maintain the mixture at 150F with constant stirring for 30 min. After mixing, continue with the test procedure as in 5.1. 5.4 When it is desired to test the maximum solvency of a Hydrocarbon Solvent Type A, prepare a gradient series of penta solutions in 1 % concentration intervals spanning the range of anticipated solvency. When the approximate solvency is esti- mated using the method in 5.1, if desired, prepare another series to determine the solvency to the nearest 0.1 % by preparing solutions in 0.1 % concentration intervals and pro- ceed as in 5.1. 6. Keywords 6.1 hyrdrocarbon solvent; pentachlorophenol 1 This test method is under the jurisdiction of ASTM Committee D-7 on Wood and is the direct responsibility of Subcommittee D07.06 on Treatments for Wood Products. Current edition approved July 15, 1994. Published September 1994. Originally published as D 2604 67. Last previous edition D 2604 86 (1992) e1 . 2 This test method is essentially the same as Paragraph 4, Determination of Pentachlorophenol Solvency in Petroleum of the American Wood-Preservers Association Standard A 5 91, Standard Methods for Analysis of Oil Preserva- tives. 3 Annual Book of ASTM Standards, Vol 05.01. 4 Annual Book of ASTM Standards, Vol 04.10. 5 Available from the American Wood-Preservers Assn., P.O. Box 286, Wood- stock, MD 21163-0286. 1 Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States. ASTM International takes no position respecting the validity of any patent rights asserted in connection with any item mentioned in this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the risk of infringement of such rights, are entirely their own responsibility. This standard is subject to revision at any time by the responsible technical committee and must be reviewed every ve years and if not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standards and should be addressed to ASTM International Headquarters. Your comments will receive careful consideration at a meeting of the responsible technical committee, which you may attend. If you feel that your comments have not received a fair hearing you should make your views known to the ASTM Committee on Standards, at the address shown below. This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the above address or at 610-832-9585 (phone), 610-832-9555 (fax), or service@astm.org (e-mail); or through the ASTM website (www.astm.org). D 2606 2