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9 (a (i)) Oxidation number of Aluminium : +3
Oxidation number of Copper : +1
1
1
2
(ii) Aluminium oxide
Copper (I) Oxide
1
1
2
(iii) Oxidation number is not written as Al has only one oxidation
number.
Oxidation number of copper is written as Copper has more than
one oxidation number
1
1
2
1. Example :
CuSO
4
+ Zn ZnSO
4
+ Cu
2. Copper ion undergoes reduction
3. Oxidation number of copper decreases from
+2 to 0.
4. Zinc atom undergoes oxidation
5. Oxidation number of zinc increases from
0 to +2
6. NaOH + HCl NaCl + H
2
O
7. no change in oxidation number
8. The reaction is not a redox reaction
1
1
1
1
1
1
1
1
..8
(a) (i) 1. potassium hexacyanoferrat (III)- to detect Fe
2+
ion
2. Phenolfthalein - to detect OH
-
1
1
2
(ii) Fe Fe
2+
+ 2e 1 1
(iii) Test tube B.
Iron/Ferum is more electropositive than P.
1
1
2
(iv) Q, Fe, P 1
Total 20
10 (a)(i) Lead(II) nitrate: Acid reacts with base/ metal oxide/ metal
hydroxide/ metal carbonate/ metal
Lead(II) sulphate: Precipitation reaction
1
1
(a)(ii) Lead(II) nitrate solution and [any suitable solution which
contains sulphate ion, SO
4
2-
]
1+1
(b) 1. Pour [20 -100] cm
3
nitric acid to a beaker
2. Add PbO/PbCO
3
in small portion
3. Stirring after each addition
4. Until some solid remains unreacted
5. Filter off excess
6. Evaporate until a 1/3 of volume of solution.
7. Leave to cool until crystal form
8 .Filter and dried between filter paper
9.+ 10 . PbO + 2HNO
3
Pb(NO
3
)
2
+ H
2
O
PbCO
3
+ 2HNO
3
Pb(NO
3
)
2
+ CO
2
+ H
2
O
1
1
1
1
1
1
1
1
1+1
(c) 1. Add barium chloride solution to each solution
2. Sodium sulphate and sulphuric acid produce a white
precipitate
3. The one that does not produce a precipitate is hydrochloric
acid
4. Add sodium carbonate to the two remaining solutions
5. Sulphuric acid produces gas bubbles
6. Sodium sulphate does not produce gas bubbles
Note: There are other methods that can be used here.
1
1
1
1
1
1
Total 20