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1 test ms
1.
(a)
(b)
(i)
(ii)
3 (1)
(iii)
8 (1)
(i)
(ii)
2 (1)
0 (1)
(iii)
(iv)
k=
Rate
3.5 10 4
=
(1)
[A]2
( 0. 2) 2
3
1 1
2.
(a)
k = rate/[CH3CH2COOCH3][H ] or
=
1 15 10 4
(0.150)(0.555)
3
= 1.38 10 to 1.4 10
1
3 1
mol dm s
(b)
3.
(a)
(b)
(i)
rate = k[R][S]
(if wrong expression, no further marks)
4
2
rate = (4.2 10 ) 0.16 0.84
5
3 1
= 4.7 10 (mol dm s )
ignore units even if wrong
(ii)
rate
8.110 5
R S 2 0.76 0.982
= 1.1 10
(iii)
T1
4
4.
(a)
(i)
Experiment 2
Experiment 3
Experiment 4
(ii)
k=
2.60 10
2
0.60 10
2
11.4 10
10.4 10 3
(4.80 10 2 )(6.60 10 2 ) 2
= 49.7
(Allow 49.8 and 50)
2
6 1
mol dm s
(b)
No change
[7]
5.
(a)
(b)
Rate constant: k =
1
2 10 5
4
= 4.4(4) 10 (1)
2
(1.5) (3 10 )
3 1
6.
(a)
(i)
(ii)
(iii)
sum of
nd
dependent on 2 mark or reference to orders (1)
powers in rate equation (1)
allow reference to annotated rate equation
(b)
(i)
(H2) 1 (1)
eg rate trebles as [H2] trebles not rate doubles as [H2] doubles (1)
(I2) 1 (1)
eg rate doubles as [I2] doubles (1)
mark these points independently
allow 1 mark for orders if not clear that both are first order
(ii)
(iii)
3 1
4 10 (1)
allow e.c.f. from (b)(ii) and (b)(iii)
could be worked by ratio from values in table or from rate equation
[13]