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_ m
H2O
c
pH
2
O
T
out
T
in
_ m
pellets
LHV
pellets
(4)
where _ m
H2O
is the water mass ow rate, c
pH
2
O
is the water heat
capacity, T
out
and T
in
are the boiler outlet and inlet water temper-
atures, _ m
pellets
is the pellets mass ow rate and LHV
pellets
is the
pellets low heating value.
3. Results and discussion
3.1. Boiler performance ring pine pellets
Fig. 2 shows the inuence of the boiler thermal input on the
gaseous pollutant emissions for the conditions showed in Table 1.
The CO, HC and NO
x
emissions displayed in the gure were cor-
rected to 13% of oxygen in the exhaust gases and calculated for
standard conditions. It should be stressed that each data point in
the gure represents the average of, at least, three runs. The
duration of each run was, at least, 30 min. Data repeatability was,
on average, within 10% of the mean value. Fig. 2 includes also the
limits for the CO emissions established by the EN 14785 [19],
referred to earlier in Section 2.1. Note that the combustion air ow
is kept constant regardless of the pellets feed rate so that the O
2
ue-gas concentration decreases with the thermal input down to z
13% for the maximum boiler thermal input (Fig. 2). In spite of the
high availability of O
2
at low boiler thermal inputs, CO and HC
Table 2
Operating conditions used to examine the boiler performance ring pine pellets.
Test no. Pellets
type
Pellets
load
(kg/h)
Thermal
input
(kW)
Flue-gas O
2
(dry volume %)
Flue-gas
temperature
(
C)
1 Pine 2.5 11.8 16.70 127
2 2.8 13.1 16.04 140
3 3.0 14.0 15.50 150
4 3.3 15.8 14.93 162
5 3.6 17.3 14.25 168
6 3.7 17.6 13.55 167
7 4.4 20.9 13.22 168
Table 3
Operating conditions used to examine the inuence of the pellets type on boiler
performance.
Pellets type Thermal
input (kW)
Excess air
coefcient
Boiler thermal
efciency
Pine 13.8 3.86 0.83
17.3 2.84 0.86
Industrial
wood wastes
14.5 4.77 0.77
17.6 3.26 0.82
Peach stones 13.7 4.11 0.75
17.9 2.78 0.83
Fig. 2. Inuence of the boiler thermal input on the gaseous pollutant emissions.
M. Rabaal et al. / Renewable Energy 51 (2013) 220e226 223
emissions present the highest values at these conditions. As the
thermal input increases and the excess air level decreases, the CO
and HC emissions decrease, indicating that enhanced combustion is
accomplished at higher boiler thermal inputs. The temperature has
an important inuence on the oxidizing reaction rates, acting as
limiting factor if too low [15,28]. In addition, low excess air levels
can also be a limiting factor leading to increased COemissions, even
at high temperatures [5,11,15], due to low oxygen availability.
Returning to Fig. 2, at lower thermal inputs, the higher excess air
levels cool down the combustion chamber, which reduce the
reactions rates, and the residence times, which are not enough to
ensure complete oxidation of the unburned species leading to
higher CO and HC emissions.
Fig. 2 also reveals that the NO
x
emissions have a marginal
dependence of the boiler operating conditions. Although the
operating conditions may affect the conversion of volatile-nitrogen
and char-nitrogen to NO and, consequently, the NO
x
emissions
[5,9,16], the nitrogen content of the present pine pellets is too low
to have a signicant contribution to the NO
x
emissions through the
fuel-NO mechanism.
3.2. Inuence of the pellets type on boiler performance
Fig. 3aeb shows the CO, NO
x
and HC emissions, corrected to 13%
of oxygen in the exhaust gases and calculated for standard condi-
tions, for the three types of pellets studied for a reduced and
a higher boiler thermal input, respectively. Again, each data point in
the gure represents the average of, at least, three runs, being the
duration of each run, at least, 30 min. It is observed that, at the
higher boiler thermal input, the performance of the pine pellets is
superior to the performance of both the industrial wood wastes and
peach stones pellets; specically, the pine pellets yield lower CO,
NO
x
and HC emissions (Fig. 3b) and presents a higher boiler
thermal efciency (Table 3). At the reduced boiler thermal input, it
is seen that, while the performance of the pine pellets is still
superior to the other two types of pellets, the differences are now
inferior (Fig. 3a and Table 3).
The higher emissions of CO and HC yield by the industrial wood
wastes and peach stones pellets, at both thermal inputs, indicates
poorer combustion conditions since these emissions are related
with incomplete combustion. Table 1 shows that the pine pellets
present the highest volatile content, which probably contributes to
its superior performance. In fuels with a high volatile content, the
volatile combustion phase is dominant, which is characterised by
a rapid and signicant heat release contrary to the long heteroge-
neous char phase [18], contributing to the temperature rise and
increase of the oxidizing reaction rates. It is interesting to note that
the pellets of peach stones have a contrary behaviour in relation to
the other two types of pellets, showing an increase of CO and HC
emissions with the increase of the thermal input. One possible
explanation might be related with the mechanical properties of the
pellets. It was observed that the pellets of industrial wood wastes
and, to a lesser extent, the pellets of pine showed an easier
tendency to break and that the bags containing them had relatively
high amounts of nes. In contrast, the amount of nes in the bags
containing the peach stones pellets was marginal, which indicates
that these pellets present high durability and mechanical strength.
During the operation of the boiler, these characteristics of the peach
stones pellets inhibited particle fragmentation, when compared
with the other two types of pellets. As a result, the peach stones
pellets kept their original size for longer time during the combus-
tion process. The particle size has a signicant inuence on the
conversion of a packed bed [29]. The conversion processes (drying,
devolatilisation and char combustion) are overlapped for large
particles, while they are sequential for small particles. The rate of
propagation of the reaction front through the fuel bed is slower for
larger particles since particles in the lower part of the bed consume
large amounts of oxidizer and limit its diffusion upwards causing
oxygen depletion in the top of the bed. Ultimately, this will lead to
higher CO emissions.
Fig. 3aeb also reveals that the NO
x
emissions are related with
the fuel nitrogen content (Table 1) as expected. Once more, there is
no clear indication of inuence of the operating conditions on the
NO
x
emissions.
Finally, it is interesting to note that the pellets of peach stones
and industrial wood wastes present a boiler thermal efciency
similar to that of the pellets of pine, at both thermal inputs, which
reveals their potential to be attractive alternative fuels for use in
domestic boilers, despite the signicantly higher CO and HC
emissions observed at higher boiler thermal input.
a
b
Fig. 3. CO, NO
x
and HC emissions for the three pellets studied. a) Reduced boiler
thermal input, b) Higher boiler thermal input.
Fig. 4. Emissions of CO and NO
x
from various residential boilers using different pellet
fuels.
M. Rabaal et al. / Renewable Energy 51 (2013) 220e226 224
To assess further the potential of the raw materials studied here
as alternatives to conventional wood pellets, Fig. 4 shows
a comparison between the CO and NO
x
emissions from this study
and those available in the literature for comparable cases. For all
cases, both the CO and NO
x
emissions were corrected to 13% of
oxygen in the exhaust gases and calculated for standard conditions.
Table 4 summarizes the conditions for the literature cases and
includes data for pellets made from three types of wood, skins and
seeds of tomato, sorghum and citrus pectin wastes. Note that in the
case of the present tests only the data corresponding to the reduced
boiler thermal input is represented in Fig. 4 in order to compare
data for similar boiler thermal inputs. The thermal input of the
literature cases varies between 13.3 kW and 15.2 kW, while the
excess air coefcient varies from 1.6 to 2.56.
Overall, it is observed that wood pellets yield signicantly lower
CO emissions than agricultural residues derived pellets. With the
exceptionof the pellets of woodA, there is a correlationbetweenthe
excess air coefcient and the emissions of CO. Fig. 4 and Table 4
evidence that there is an excess air level below which boiler oper-
ation yields high CO emissions. Note that sorghumyields higher CO
emissions than tomato skins and seeds although the excess air
coefcient is similar. This is presumably due to the very high
moisture content of the pellets of sorghum, which lowers the
combustion temperature. A comparison between pellets of wood B,
wood C and citrus pectin wastes, burned under similar conditions,
reveals that the latter yields slightly higher COemissions, which can
also be related to its higher moisture content. Finally, Fig. 5 shows
the inuence of the nitrogen content of the pellets on the NO
x
emissions. Note that this gure includes data fromthe present study
and from other authors (see Tables 3 and 4). As expected, the NO
x
emissions are related with the fuel nitrogen content, conrming the
importance of the fuel-NO mechanism to the global NO
x
emissions.
Tables 3 and 4 allow concluding that although agricultural
residues and waste pellets might present high CO emissions, the
boiler thermal efciency obtainable with these residues is generally
similar to the traditional wood pellets, and sometimes even higher,
supporting their potential. The main impact of the pellets type on
the performance of the boiler is more pronounced on pollutant
emissions and rather marginal on the boiler thermal efciency.
Note that the boilers are originally designed to be red with wood
pellets and their operating conditions are adjusted to these type of
pellets. As seen in this study, emissions originated fromincomplete
combustion could be easily minimized through the regulation of
the boiler operating conditions, in particular of the excess air level,
which would make the pellets of industrial wood wastes and peach
stones, and many other types of residues, suitable for use in
domestic boilers. The use of non-wood pellets may, however, face
some issues regarding the fullment of quality norms regarding
their physical and chemical properties [4]. Blending wood and
residues might be an interesting solution to the incorporation of
the residues while assuring that quality criteria are satised.
4. Conclusions
The combustion and emission characteristics of a domestic
boiler red with pellets of pine, industrial wood wastes and peach
stones have been examined. Initially, a study on the boiler perfor-
mance ring pine pellets as a function of the thermal input was
performed. Subsequently, the inuence of the pellets type on boiler
performance was studied and the potential of using non-traditional
wood pellets in domestic boilers was assessed. Finally, to broaden
the assessment to other raw materials originated from residues,
data selected from the open literature from similar studies was
compared to the present results in order to assess the potential of
using pellets from sustainable origin in domestic boilers. The
following main conclusions may be withdrawn from this study:
Boiler operating conditions have a pronounced effect on the CO
and HC emissions. The fuel-NO mechanism is the main source
of NO
x
emissions and does not seem to be affected by the
specic boiler operating conditions.
The type of pellets affects signicantly the boiler performance,
particularly the emission characteristics.
The use of pellets made fromindustrial wood wastes and peach
stones affects only marginally the boiler thermal efciency.
Industrial wood residues and peach stones have an attractive
potential to be used as sustainable alternative fuels in domestic
pellets-red boilers. The emissions originated by incomplete
combustion, especially the CO emissions, can be minimized
through the optimization of the boiler operating conditions, in
particular the excess air level.
Acknowledgements
We thank Rui Paulo Carreira from Casal & Carreira Biomassa,
Lda, Alcobaa, Portugal, for making the pellets of industrial wood
wastes and peach stones.
Table 4
Main characteristics of the pellets, boiler operating conditions and ue-gas data.
Pellets type Pellets main characteristics Operating conditions
Low heating
value (MJ/kg)
Nitrogen
(wt %)
Moisture
(wt %)
Ash
(wt %)
Thermal
input (kW)
Excess air
coefcient
Boiler thermal
efciency
Sorghum [7] 15.4 0.80 25.7 2.7 14.0 1.70 0.85
Skins and seeds
of tomato [8]
22.5 3.40 7.0 3.5 15.2 1.90 0.91
Wood A [14] 18.0 0.10 7.1 0.4 15.0 1.60 0.93
Citrus pectin
wastes [10]
14.6 0.90 13.6 1.6 14.2 2.56 0.90
Wood B [5] 16.9 1.60 6.8 0.7 13.3 2.25 0.91
Wood C [5] 16.4 < 0.3 9.3 0.4 13.8 2.56 0.85
Fig. 5. Inuence of the nitrogen content of the pellets on the NO
x
emissions.
M. Rabaal et al. / Renewable Energy 51 (2013) 220e226 225
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