layerwise fabrication of parts or prototypes from a computer aided design (CAD) representation without the use of any part-specic tooling. There was an explosion in the number of SFFprocesses over the last decade of the twentieth century. The major application of most of the SFF processes has been in the eld of prototyping and hence, many of the SFF techniques are also called rapid prototyping techniques. As rapid prototyping implies, the advent of the various SFF techniques has resulted in tremendous time saving, especially for complicated models\compo- nents. Typically, very complex models that would take several months to fabricate by traditional methods can be made in a few days or less with SFF techniques (Kai and Fai 1997). There are, in general, two types of prototyping applications. One type of prototyping is used to test the design for form and t. In this case the primary concern is with the dimensions of the fabricated prototype. In the other types of prototyping, com- ponents (or prototypes) are made to test their func- tional performance and not just the form or t. This sort of prototyping is called functional prototyping. Recently, there has been a thrust, especially in the USA, to develop SFF techniques for prototyping and manufacturing of functional components made of ceramics or metals. Some of the more important SFF techniques that have been developed in this category are stereolithography (SLA) of ceramics (Grith and Halloran 1997, Grith et al. 1997 p. 403), selective laser sintering (SLS) (Manriquez-Frayre and Bourell 1990, Nutt 1991, Subramanian et al. 1993, Laksh- minarayan et al. 1990, Carter and Jones 1993, Vail and Barlow 1991), computer aided manufacturing of layered engineering materials (CAM-LEM) (Cawley et al. 1995, 1998, Liu et al. 1999), three-dimensional printing (Sachs et al. 1995, 1992, Grau et al. 1997) and fused deposition of ceramics and metals (FDC and FDMet) (Danforth et al. 1998, Agarwala et al. 1996, Bandyopadhyay et al. 1997, Wu et al. 1999). In the following sections these important SFF processes will be introduced. 1. Stereolithography Stereolithography (SLA) of polymers is considered to be the rst SFF technique and was developed by 3-D systems, Inc. (CA, USA) in 1988 (Kai and Fai 1997). A schematic of the SLA process is shown in Fig. 1. SLA involves UV-assisted photopolymerization of liquid monomers. A UV laser is scanned over a layer of the liquid monomer to cure the monomer in selected areas as dictated by the tool paths. After completion of one layer, another layer of resin is coated on top of the cured layer. This process is called recoating. The process of recoating and curing is repeated until the part is completed. In 1996, Halloran et al. of the University of Michigan modied the SLA process to produce ceramic parts (Grith and Halloran 1996). In this process, a ceramic particle lled photocurable resin is used in place of the virgin resin. They successfully demonstrated the use of a variety of ceramic materials such as silica, alumina, silicon nitride, and hydroxy- apatite in the SLA of ceramics (Brady et al. 1996). There are still some problems regarding SLA due to the lower cure depth encountered in ceramic suspen- sions in comparison with polymer suspensions (Brady et al. 1997). One of the key advantages of the SLAof ceramics is the possibility of fabricating ceramic parts with ne features of about 100m. Another advantage of the process is the ability to make parts with excellent surface nish. Surface roughness values as lowas 4m have been achieved for the top surface and 27.5mfor the side surfaces (Brady et al. 1998). 2. Three-dimensional Printing Three-dimensional printing (3DP) was invented at the Massachusetts Institute of Technology in 1988. The basic idea of 3DP is to build a ceramic or metal green part by printing binder onto a layer of deposited powder. A schematic of the 3DP process is shown in Fig. 2 (Sachs et al. 1998b). The binder is printed using an ink jet printer. Both drop on demand and continuous jet printing tech- niques were tried with 3DP, but continuous jet was chosen due to its higher rate of binder deposition. The binder has to meet a number of requirements to be Figure 1 Schematic showing the operation of a typical stereolithography (SLA) apparatus. 1 Rapid Prototyping Figure 2 Schematic showing the dierent steps involved in the fabrication of a component via three-dimensional printing (3DP) technique (Sachs et al. 1998). useful in 3DP (Sachs et al. 1998a). First, the binder solution has to be of suciently low viscosity for successful droplet formation. In addition, the binder must dry before the next layer is deposited. In this technique, a continuous stream of droplets emerges from the nozzle. Some of the droplets in the emerging stream may be charged. The uncharged droplets will follow a straight path through the deection plates to be deposited on the part being built, while charged droplets will be deected to the side away from the deposition site on the part. There are essentially two types of 3DP processes depending on the type of powder bed used. His- torically, the rst type is the dry powder process. In this process, a dry powder is deposited from a roller drum. The powder is fed into the interior of a drum and, as the drum rotates and traverses a substrate, the powder is then dispensed out of the drum through a screen (Sachs et al. 1998b). The drum also acts as the compacting device. Upon dispensing the powder, the drum is traversed over the powder bed once more to accomplish compaction. The drum is vibrated for the compaction purposes. The powder has to be selected with the right properties, such as the particle size and size distribution to get good dispensing and packing behavior (Sachs et al. 1998b). In the second method, a wet slurry process, a slurry of the powder is sprayed onto a substrate to form the powder bed. The powder bed is then dried and the binder is printed into the dried powder bed. After part completion, the unprinted regions are removed through redispersion in an ultrasonic bath. Due to the use of a liquid bath to remove the unprinted powder, there are some additional requirements for the binder. The binder should be insoluble in the liquid used for redispersion (essentially water). Also, the binder has to penetrate the powder bed fully and bond with enough strength to withstand ultrasonication. Various binders have been tried for this purpose, including latex, wax emulsions, and homogeneous solution phase binders. There are various applications for which 3DP is used. Metal parts and tools are fabricated using the dry powder method. A colloidal latex binder solution 2 Rapid Prototyping is used along with stainless steel or tool steel powder for the purpose of fabricating metal parts or tooling (Sachs et al. 1998b). The part is usually red to obtain a sintered skeleton which is then inltrated with a low melting metal, such as copper or copper alloys to obtain a fully dense part with minimum shrinkage (Sachs et al. 1998b). This technology to manufacture metal parts and tools has been licensed by Extrude- Hone (Irwin, PA). Another major application is the manufacturing of ceramic casting cores or shells for investment casting of metals. Typically, alumina, or silica with amor- phous or colloidal silica binder solution is used (Yan and Gu 1996). Soligen Technologies has licensed this MIT technology. Z Corporation (Somerville, MA) uses a modica- tion of the 3DP dry powder process. In their process, they use starch powder and a proprietary water-based binder to manufacture concept models, which are very simple models for the early stages of prototyping. The models, made of starch, are then impregnated with a resin to give them mechanical strength. Although the 3DP process is well developed and exible, there are still some important issues that need to be improved. One of the major areas of research is concerned with improving the dimensional accuracy and control of the parts made by 3DP. At present, the typical shrinkage values of metal parts made by 3DP are about 2% and eorts are underway to reduce that value to about 0.2%. As the absolute value of shrinkage is reduced, it will cause a decrease in the value of uncertainty in shrinkage (Sachs et al. 1999). A decrease in the uncertainty of shrinkage corresponds to better dimensional control. In addition to this, there are also problems associated with the removal of loose powder from the fabricated part, especially when the part has a large number of narrow passages. One of the biggest advantages of 3DP is that it can be used to build almost any geometry including undercuts, overhangs, and through-holes as the un- bound powder acts as the support for the rest of the part. Also, 3DP can be used to make very ne features, as small as 100m. 3DP is also a very exible (many materials and geometry) and well-controlled process. 3. Selective Laser Sintering Selective laser sintering (SLS), like SLA, is one of the pioneering SFF techniques. It was commercialized around 1987 by DTM Corporation (Austin, Texas), who purchased the patents and licenses from the University of Texas at Austin (Kai and Fai 1997). The actual process could be thought of as a hybrid of 3DP and SLA, in the sense that it involves deposition of a layer of dry powder, which is then sintered using a laser. The schematic of a typical SLS process is shown in Fig. 3. In SLS, a thin layer (approximately 100 200m) of powder is spread on a surface using a cylindrical roller (Lakshminarayan et al. 1990). Alaser is then scanned over the powder bed, which heats the powder locally and sinter-bonds the adjacent particles to formone layer of the part. The intensity of the laser beamis modulated according to the computer-dened cross-section of the part. Typically, the laser is turned on where the powder needs to be bonded to form a solid section and turned o where no bonding is required. The non-sintered particles act as a support for any hollow section, overhangs or undercuts in the part (like in the case of 3DP). After the formation of the rst layer, the next layer of powder is spread over the rst layer followed by scanning of the laser. The laser has to have enough intensity to sinter the particles to the adjacent particles and to the previously fabri- cated layer. Upon completion of a part, it is removed from the chamber, the loose powder removed and the part is post processed, if necessary. The commercialized SLS process predominantly uses thermoplastic materials such as ABS, poly- carbonates, nylon, and wax (Kai et al. 1997). There has been extensive research at the University of Texas at Austin to extend this process to include metals and ceramics. The basic problem associated with metals and ceramics is that they have much higher melting points than polymers and, therefore, require much higher energy input for sintering. Two dierent approaches have been developed to overcome this problem, which can be classied into indirect and direct sintering approaches. Inthe case of ceramics, there are twodistinct indirect sintering approaches: (i) using an inorganic binder (Lakshminarayan et al. 1990, Lakshminarayan and Marcus 1991); and (ii) using an organic binder (Subramanian et al. 1993, Vail and Barlow 1991). In the case of the inorganic binder, the laser melts the binder, which then binds the particles together in the green body. In the case of the organic binder, a polymer coated ceramic or metal powder is used to form the powder bed. The laser softens or melts the polymer and bonds the particles in the green body. At the end of build, further post processing is required to obtain a fully dense body. More recently, there has been a thrust to develop a direct sintering approach to sinter ceramic materials. The basic idea behind this approach is to use a high power laser (1kW, CO # laser) and a preheated powder feed to achieve the high temperatures needed for sintering ceramics (Das et al. 1991). One key advantage of the SLS technique is its relatively fast build rates compared with SLA of ceramics or 3DP (a typical 1000cm$ ceramic or metal part can be built in about 610 hours depending on its complexity). As the SLS part is built from a powder bed, the surrounding loose powder acts as the support material and enables one to build very complex geometries. As mentioned before, SLS can also be 3 Rapid Prototyping Figure 3 Schematic of the operation of selective laser sintering (SLS) process (Lakshminarayan et al. 1990). used to process a wide variety of materials such as polymers, metals, and ceramics. 4. Laminated Object Manufacturing and CAM-LEM Laminated object manufacturing (LOM) and com- puter aided manufacturing of laminated engineering materials (CAM-LEM) are two closely related SFF processing techniques. Both techniques build a part by the lamination of sheet feedstock, which is cut by a laser along contours denedby the CADle-generated tool path. The sequence in which the cutting and lamination (or stacking) of the sheet feedstock is accomplished dierentiates the two techniques. The general approach of LOM is to stack then cut, as opposed to the cut-then-stack approach of CAM- LEM (Kai and Fai 1997, Klosterman et al. 1996, 1997a). In LOMof ceramics, ceramic tapes are used as the sheet feedstock. The tapes are sprayed with a solvent and then stacked (Klosterman et al. 1996, 1997a). The solvent acts as an adhesive, helping bond the tapes together. A heated roller is used to further bond the tapes through thermocompression. Alaser is then used to cut the tape according to the tool path le. The area of the tape outside the build contour is cut in a crosshatch fashion. At the end of the build, the part is manually removed by cutting the crosshatched region from the main part by a process called decubing (Kai and Fai 1997, Klosterman et al. 1997a). After assembly, the layers are laminated by warm isostatic pressing (or other suitable method) to achieve intimate interlayer contact, promoting high- integrity bonding in the subsequent sintering oper- ation. The laminated green object is then red (with an optimized heating schedule) to densify the object and fuse the layers and particles within the layers into a monolithic structure. Although LOM is attractive, there are some prob- lems. The need to decube makes it labor intensive and it usually involves long processing times (Klosterman et al. 1997a). Also, decubing of ceramic parts is dicult and damage to the green part can occur (Klosterman et al. 1997a). Research in LOM is being conducted by the University of Dayton Research Institute in colla- boration with Helisys, and is focused on trying to overcome the above problems and make LOM of ceramics an automated process (Kai and Fai 1997, Klosterman et al. 1997a). Some of the materials so far usedin LOMare Si $ N % , SiC, SiCber\SiCcomposites, and hydroxyapatite (Kai and Fai 1997, Klosterman et al. 1996, 1997a, 1997b, Pope et al. 1997, Steidle et al. 1997). These materials have been used to make parts such as bone implants, turbine blades, and ceramic matrix composites. Ceramic preforms using LOM of Al # O $ and silica have also been fabricated (Agarwala et al. 1999). CAM-LEM is a solid freeform fabrication tech- nique capable of fabricating functional components from engineering materials such as ceramics, metals, and engineering plastics. The process was developed as a result of collaboration between Case Western 4 Rapid Prototyping Figure 4 Schematic of the dierent steps involved in the building of parts by computer-aided manufacturing of laminated engineering materials (CAM-LEM) (Cawley et al. 1998). Reserve University and CAM-LEM, Inc., Cleveland, OH (Cawley et al. 1995). A schematic of the process is shown in Fig. 4 (Cawley et al. 1995). The process uses a powder lled sheet feedstock, which is laser cut using a lowpowered CO # laser along the contours dened by the CAD le-generated tool path. The cut sheets are then robotically stacked to formthe three-dimensional object, which undergoes subsequent post-processing to obtain the fully dense functional component. Some of the materials used in CAM-LEM are alumina, PZT (lead zirconate titanate), silicon nitride, and stainless steel (Liu et al. 1999). One important issue in the development of the CAM-LEM technique is feedstock development. The sheet feedstock used in CAM-LEMis fabricated either by tape casting or by compression molding (Cawley et al. 1998). Another issue that has been studied ex- tensively is that of tacking, alignment, and lamination. The purpose of tacking is to ensure that the ceramic tapes are bonded prior to (or during) lamination. Several techniques have been used to ensure that the stacked tapes stay in place (Cawley et al. 1995, 1998, Liu et al. 1999). In one technique, a thin coating of a heat-sensitive adhesive is applied to the surface of the green tapes. Tacking is achieved by application of heat and\or pressure that diuses the thin coating into the adjacent layers, and produces a bond between them. One of the important advantages of CAM-LEM is the fabrication of multi-material parts both from layer-to-layer and within a layer. During the normal build in CAM-LEM, a fugitive material can also be used in conjunction with the build material. The fugitive sheet is usually cut along contours, which are complementary to the build material contours. The cut sheets of the fugitive material are then stacked along with the build material in each layer similar to a jigsaw puzzle to form a at layer. This method of fabricating a part with the fugitive material is unique 5 Rapid Prototyping to the CAM-LEM technology. The fugitive material serves as a support during build, and also during post- processing steps. In addition to performing as a support, the fugitive material enables proper pressure transmittance if a thermocompressive lamination pro- cedure is employed (Cawley et al. 1995). Some of the typical fugitive materials used are graphite and starch (Cawley et al. 1995, 1998). The other signicant advantage of the cut-then-stack approach is that a de-cubing step is not necessary to remove the excess material as the shape of each layer is cut prior to stacking. The lack of this step in the CAM-LEM process leads to less material loss. This loss may not be important if one uses paper, but in case of some ceramic feedstock, the decrease in material loss during build can lead to a signicant reduction in the overall cost of the process. CAM-LEM has been used to fabricate a variety of products such as uidic devices, ceramic turbine blades with internal cooling channels, and a dog femur (Liu et al. 1996). This technique is a very versatile process with a lot of advantages such as its ability to build multi-material parts. 5. Fused Deposition Modeling and Fused Deposition of Ceramics Fused deposition modeling (FDM), developed by Stratasys, Inc. (Eden Prairie, MN), uses a 1.78mm diameter thermoplastic lament feedstock. A sche- matic of the process is shown in Fig. 5. The lament feedstock is drawn from a spool and fed into a heated liqueer via a pair of counter-rotating rollers as shown in Fig. 5. The liqueer is in essence a cylindrical barrel that is resistively heated. The thermoplastic lament melts during its passage through the barrel, and is extruded through a nozzle (i.e., the lament acts as the piston). The liqueer moves in the XY plane (Fig. 5) and deposits the extruded material in elliptical cross- section elements, called roads, along paths dened by the CAD le-generated tool path. A single layer is built by repeated deposition of these roads. Upon completion of one layer, the build platform indexes down and the whole process of depositing roads is repeated. The ambient temperature of the build envelope is also controlled above room temperature and below the melting point of the thermoplastic material so that the material can solidify to form a rigid part at the end of the fabrication. The build envelope temperature is also maintained above room temperature (25mC) to allow for sucient bonding between the deposited roads and layers. The rst commercial FDM machine released was called the three-dimensional modeler. It primarily used crystalline waxes and nylon-based materials (Kai and Fai 1997). Prototypes fabricated with these materials tended to exhibit time-dependent dimen- sional changes (Yardimci 1999). After a few software updates and hardware changes, the next generation of machines, the FDM 1600 and FDM 1650 was de- veloped. The FDM1650 has a two-material deposition capability. One material is used as the build material and the other as the support material. Originally, the support structure created using FDM machines need- ed to be removed manually at the end of a build. Stratasys later introduced a new system called FDM 3000 that uses a water-soluble support material that enables one to remove the support by washing it in a water-based solution (Stratasys Homepage). Another interesting new introduction to the line of FDM products is the FDM Quantum. The FDM Quantum is a machine designed to produce large parts (600mmi500mmi600mm) in a short time (Stratasys Homepage). The machine uses patented high speed electromagnetic drives to rapidly move and control the extrusion head (Stratasys Homepage). The use of electromagnetic drives eliminates mechanical parts such as bearings, cables, and gears. This use allows for faster and more accurate movement of the extrusion head compared with the other FDMsystems (Stratasys Homepage). The materials in use include wax, nylon, ABS, MABS (medical grade ABS), and wide variety of elastomers (Kai and Fai 1997). The FDM process is used to make prototypes, patterns for mold making, molds for investment casting and more recently for making medical equipment with the MABS material (Kai and Fai 1997, Stratasys Homepage). Stratasys commercialized a systemthat uses an alternative to the lament-feed mechanism. The machine is called Genisys and is based on a screw-pump mechanism developed by IBM (Kai and Fai 1997, Stratasys Homepage). The use of a screw-pump mechanism removed some of the restrictions placed on the materials used due to lament fabrication and use. Also, due to the use of a screw pump the magnitude of the extrusion pressure achievable is greater, making the process more robust (Stratasys Homepage). The Genisys systemuses three materials (Kai and Fai 1997, Stratasys Homepage): a general purpose polymer for design verication purposes, a nylon-like polymer used to make masters for other processes such as investment casting, and elastomers used, e.g., in door seals. FDC and FDMet are SFF techniques capable of fabricating functional ceramic and metallic com- ponents. The process was invented at Rutgers Uni- versity in 1994 (Danforth et al. 1998) and is based on a commercial FDMtechnique. The basic idea is to use a particle-loaded thermoplastic lament as the feed- stock in place of pure polymer laments. The use of a wide variety of materials in FDC such as, Si $ N % , Al # O $ , PZT (lead zirconate titanate), PMN-PT (lead magnesium niobatelead titanate), stainless steel, and hydroxyapatite for structural, electronic, and biostructural applications, has been demonstrated (Agarwala et al. 1996, Bandyopadhyay et al. 1997, 6 Rapid Prototyping Figure 5 Schematic showing the basic mechanism of operation of a fused deposition machine. The X, Y, Z directions are indicated in the gure to enable the reader to understand the directions of motion of the liqueer assembly and the build platform (Danforth et al. 1998). Safari et al. 1998). A large amount of work was conducted over the last six years of the twentieth century in developing the FDC process. The research spans the various components of the FDC process including development of suitable binders, coating of powders, lament fabrication, FD part building, and post build processes. Two dierent binder systems, RU9 and ECG, are in use in FDC (Agarwala et al. 1996b). The RU9 and ECG binders consist of four major components: a polymer backbone, a wax component that acts as a viscosity modulator and provides stiness, a tackier component that enables the deposited material to bond, and an elastomer component to impart exi- bility. A particular binder, termed ECG9, is the more commonly used binder. The RU9 systemhas primarily been used with Si $ N % and Si $ N % \SiC. The various powders used with ECG systems are: PZT, PMNPT, Al # O $ , hydroxyapatite, and stainless steel. The selection of the binder is only the rst in a series of steps necessary to fabricate the laments. The quality and uniformity of the extruded lament is another important step that will determine the quality of the FDC process and the fabricated part. A number of processing studies have been conducted on the RU9\Si $ N % and ECG9\PZTsystems. These studies have enabled the development of a well-controlled lament fabrication process capable of making hun- dreds of meters of laments with uniform properties. Also, there are a variety of parameters related to the software, hardware, and feedstock material that aect the quality of the fabricated part. In the FDC process in order to build a part, the perimeter or the boundary of a layer (slice) is built rst. Then the interior of the part is built using a contour ll, or a vector ll, or a combination ll. There are many parameters associated with building a part: slice thickness, road width, road oset values, angle of vectoring, motion parameters, and ow parameters. Liqueer temperature, build envelope temperature, and nozzle diameter also aect the quality. One of the important issues involved in FDC is the buckling of lament during building. The buckling of lament is a serious obstacle to the development of a continuous FDCprocess. An empirical quantity based on the ratio of modulus of lament to the motor torque during FDC has been used to dierentiate between laments that buckle and those that do not buckle. Although, the quantity is useful it does not 7 Rapid Prototyping provide a scientic understanding of the material- and machine-related issues that may aect the buckling of laments during FDC (Venkataraman 2000, Venka- taraman and Rangarajan 1999). One of the important stages in post processing is the binder removal stage. Detailed studies based on design of experiments have been conducted on the RU9 Si $ N % system to establish a standard N # heating cycle, ow rate of N # , the heating cycle in air, and various other procedures involved in the burnout cycle (Bhargava et al. 1997). In the case of the ECG-based system, the binder removal is conducted entirely in static air. The basic process involves slow heating in air to a suciently high temperature to remove the polymer. Some part\ powder specic modications to the basic cycle have been developed. These modications essentially in- volve dierent heating rates and hold steps to solve some of the binder removal related problems such as slumping, cracking, and bloating. Upon sintering, the dimensional changes (as-built to nal sintered part) are 17% along build plane directions and 20% along the build direction (McIntosh and Danforth 1997). The corresponding shrinkage values for PZT are 16% and 20%, respectively (Lous et al. 2000). As can be seen from the shrinkage values for silicon nitride and PZT, there is signicant anisotropy in the shrinkage. The shrinkage in the build direction tends to be higher than in the build plane directions (McIntosh and Danforth 1997, Lous et al. 2000). The extrusion freeformfabrication (EFF) process, a method that adapted the basic FDM technique, was developed at Advanced Ceramics Research, Inc. (Ventura and Narang 1998, Prinz and Weiss 1998, Dimos et al. 1997). This process uses a piston and plunger-based high-pressure delivery system. A rod- type feedstock (5\8 inch diameter, 6 inches long) is fed into the extruder chamber where it is melted and extruded. A number of high-melting engineering thermoplastics, ceramic (silicon nitride) particle- loaded, and short ber-loaded thermoplastics are being used with the system(Ventura and Narang 1998, Prinz and Weiss 1998, Dimos et al. 1997). The piston plunger mechanism is not a continuous process, whereas the lament-feed mechanism is. This di- erence has led to restrictions on the part size that can be built. Researchers at the University of Southern Cali- fornia have developed a process that is based on the FDM approach called contour crafting (Khoshnevis 1999). The process uses a nozzle (usually larger than the ones used in FDM) to lay down the roads corresponding to the outer surface contour of the part. The contour is shaped using typical shaping tools such as trowels to obtain a smooth surface. Once a smooth contour is built the interior of the part can be lled with the material to make the nal part. The process is primarily concerned with making parts with a smooth outer surface and in case of hollowparts smooth inner and outer surfaces. As the process uses nozzles much larger than the ones used in FDM, it is typically not useful for making parts with ne details. The process is primarily used to make large conceptual models from clay-based materials. A novel multimaterial FDC machine is being developed at Rutgers University. The project is funded under a ONR-MURI (Oce of Naval Research-Multi University Research Initiative). Apicture of the multi- material machine is shown in Fig. 6. One of the objectives of the MURI program at Rutgers Uni- versity is to develop an intelligent multi-material layered manufacturing system based on the FDC approach. Therefore, one needs to develop the necess- ary scientic knowledge of the various issues involved in FDC in order to begin developing an intelligent machine. The MURI machine, also calledanintelligent CAD- based system, is equipped with machine vision, which monitors the surface quality of layers during the fabrication. The machine vision is not in a closed loop with the rest of the system, but work is underway on closing the loop so that the defects detected can be removed and the appropriate compensations can be made for the next layer. Such an online process monitoring and control system is essential for the fabrication of high quality parts. 6. Other SFF Techniques for Ceramics and Metals In addition to the above more mature techniques, there are a few other techniques for fabrication of ceramics and metals being developed in various national laboratories and universities such as laser- engineered net shaping (LENS) (Grith et al. 1996, 1997, Brooks et al. 1999, Vasinonta et al. 1999), robocasting (Ceasarano et al. 1997, King et al. 1998, Ceasarano et al. 1998), multiphase jet solidication (MJS) (Kai and Fai 1997, Kupp et al. 1997, Greulich et al. 1995), direct photo shaping of ceramics (DPS) (Greulich et al. 1995), and shape deposition manu- facturing (SDM) (Prinz and Weiss 1998). The LENS process and robocasting are two tech- niques being developed at Sandia National Labora- tories. LENS is a laser-based process, where a high power laser beam (Nd:YAG) is focused on a metal substrate to create a weld pool. At the same time a stream of powder is injected into the weld pool. The laser beam melts the powder locally on top of the substrate. The substrate is then moved under the laser and the part is built line-by-line and layer-by-layer. LENS has been used to fabricate a variety of products ranging from prototypes to actual injection mold tooling using materials such as stainless steel, tool steel, and Inconel alloys (Grith et al. 1997). The typical build rate of the LENS process is about 20 hours for a 100cm$ part (Grith et al. 1997). The fabrication of multi-material graded and layered 8 Rapid Prototyping Figure 6 Photograph illustrating the deposition head of the MURI layered manufacturing machine with four liqueers. structures using multiple powder feeders has been demonstrated (Grith et al. 1997). Robocasting is a deposition-based process using a high-solids loading (50 vol.%) water-based slurry (Ceasarano et al. 1997). The slurry is pumped through an orice onto a moveable substrate to form a continuous bead. The part is subsequently built by the layerwise deposition of the slurry. The typical de- position rates of the slurry in robocasting are about 0.0060.01cm$ s
" (Ceasarano et al. 1997). The use of a
water-based slurry makes the processing environment friendly. Also, the use of a low volume fraction of organics makes it easier to post-process parts com- pared with parts made by FDC or other polymer- based forming methods. The process has been used to make parts of varying geometrical complexity using materials such as Al # O $ , kaolin, PZT, and ZnO (Ceasarano et al. 1998). Recently, the ability to deposit multi-materials in a sequential and graded fashion has been demonstrated (Ceasarano et al. 1998). MJS is a SFF technique used to fabricate ceramic and metallic components. It is comparable to the fused deposition process. The MJS process uses either a low melting alloy or a powder-binder mixture in granule or rod form as the feedstock (Kai and Fai 1997, Kupp et al. 1997). The feedstock is fed into a patented extrusion apparatus. The low melting alloy or the binder is melted and the low viscosity (200Pas) uid is deposited on a substrate (Kupp et al. 1997). The extruder head is then translated in the XY directions to fabricate the part line-by-line and layer-by-layer. Considerable research is being conducted at the Fraunhofer Institute for Applied Materials Research and Fraunhofer Institute for Manufacturing Engi- neering and Automation, to optimize the process so as to increase the part complexity and process temp- erature (Kai and Fai 1997). The list of materials used in MJS includes stainless steel, high speed steels, FeNi alloy, Ti and SiC (Kupp et al. 1997, Greulich et al. 1995). Eorts to fabricate directly high-melting-point metal alloy parts (without binder) and to include other ceramic materials such as Al # O $ and ZrO # are in progress (Kupp et al. 1997). Direct photo shaping of ceramics is a novel SFF technique developed at SRI International. The tech- nique involves the use of digitally projected visible 9 Rapid Prototyping light to cure layers of ceramic-loaded photocurable resins (Ventura and Narang 1998). The photocurable resin typically consists of 55 vol.%solids, a dispersant, photoactive monomers, photoinitiator, and a tackier (to help bond the successive layers). The build process consists of three basic steps. The rst step involves the dispensing of the ceramic-loaded photocurable resin. The resin is dispensed from a peristaltic pump and then uniformly applied by a doctor blade (Ventura and Narang 1998). The thickness of the layers is typically about 50m. In the curing step, the image of a particular cross-section of the part as dened by the CADle is digitally projected onto the dispensed layer of the photocurable resin. The portions of the layer exposed to the light cures to form the desired cross- section prole of the part. This sort of a curing is called curing through ood exposure. The above steps are then repeated to build the part layer-by-layer. The cured resin is then removed and the part sintered to full density in the subsequent post-processing steps. As mentioned earlier, the part is built by curing the resin through ood exposure to light instead of a rastering laser. Therefore, the build time for each layer in this technique is expected to be shorter than for rastering laser techniques such as SLAof ceramics (Ventura and Narang 1998). Typically, a layer of 1cmi1cm area can be cured in about 4s using the ood exposure technique as opposed to 10s for SLA of ceramics (Ventura and Narang 1998). The use of visible light with a digital projection system makes the process inexpensive. In addition, the visible light digital projection systemleads to high resolution (16m). The direct photo shaping method has been shown to be feasible for the fabrication of ceramic (silicon nitride, alumina), metal, and polymer parts (Ventura and Narang 1998). The method is also being applied to the fabrication of micro mechanical and electromech- anical devices containing multiple ceramic\polymer\ metal interfaces (Ventura and Narang 1998). SDM diers from all other SFF techniques de- scribed before in that it uses a combination of additive and subtractive processes to fabricate parts. The technique was developed at Stanford University (Prinz and Weiss 1998). The objective of the SDM approach is to combine the advantages of the additive techniques with that of the subtractive techniques. In general, the addition of material is accomplished by dierent techniques depending on the material to be deposited. A computer numerically controlled (CNC) machine is used for material removal. The part is decomposed into slices or compacts. Then each of the compacts is fabricated to near net shape using a particular deposition technique. During the addition process, a build and a support material are usually deposited. The deposited layer is then machined to net shape. The process is repeated layer-by-layer to build the part. The support material is then removed at the end of the build process to reveal the part. In this technique, the compacts are created in such a way that the compact for the support material has the complement to any undercuts present in the part. This way an undercut in the part is replicated by depositing the build material on the complement of the undercut present in the support region. In the case of ceramic parts, an extruder developed by Advanced Ceramics Research (ACR) is used (Prinz and Weiss 1998). The feedstock used with the extruder is a rod (15cmlong and 1.14cm diameter) (Prinz and Weiss 1998). The extruder is mounted on a commercially available CNC machine to create an integrated SDM machine. The extruder is used to deposit the support and the build material. This is accomplished by manually switching the extruder tubes preloaded with the materials of choice (Prinz and Weiss 1998). This process has been used to make parts from ceramics such as silicon nitride and alumina. The SDM method has also been used to make metal parts out of copper, nickel, and stainless steel. In case of metal parts, either a laser welder (for steel) or a microcaster (for copper) is used as the deposition device. The laser welder is similar to LENS where a YAG laser is used to create a weld pool into which a stream of powder is injected to build a layer. In a microcaster, a wire of material is fed into a plasma that creates superheated droplets of the metal. The droplets are then deposited onto the substrate to build a part. SDM is also being used to make microelectro- mechanical systems (MEMS). For this application, sputtering and electroplating are used as deposition methods and micro-CNC and electrical discharge machining (EDM) are used as shaping or removal methods. As mentioned before, SDM combines the advantages of additive and subtractive processes. It has been used with a wide variety of materials (metals, ceramics, and polymers) for a wide variety of appli- cations. The technique can also be used to fabricate multi-material parts. The process has also been demonstrated to fabricate parts with embedded elec- tronics (Prinz and Weiss 1998). There is yet another interesting SFFtechnique being developed at Sandia National Laboratories (Dimos et al. 1997). This technique is called Direct-Write. The Direct-Write method is being developed in order to fabricate multi-functional multi-material integrated ceramic components (MMICCs) (Yardimici 1999). The MMICCs usually involve a wide variety of devices such as capacitors, inductors, and conductors embed- ded in a ceramic substrate. The Direct-Write method is being developed as a rapid, low volume fabrication technique for these components. In the Direct-Write method, ceramic or metal-loaded slurries are printed onto a substrate. The substrate moves along the paths dened by a CADle to produce one layer of the part. The layer is then dried prior to printing the next layer. In this way, the complete green part (unsintered) is fabricated in a layerwise fashion. Co-ring or co- sintering of the green part produced by the Direct- Write method yields the nal integrated component. The Direct-Write method uses a commercial depo- 10 Rapid Prototyping sition technology called Micropen (Ohmcraft, Inc.). The Micropen system is an automated printing device for ceramic slurries. In Micropen, the ceramic-loaded (or metal particle-loaded) inks are printed through ne orices (about 2550m diameter). One of the interesting features of the Micropen systemis the force feedback control. This feature involves balancing the upward force exerted on the deposition head (pen) due to the extruding ink and the downward force applied by an electromagnet (placed above the pen). This sort of control allows one to print inks with reproducible thickness (Dimos et al. 1998). It also allows for printing inks with near constant thickness on subs- trates with variations in height. As mentioned earlier, the Micropen can be used to print inks in lines about 2550m wide and about 2550m high. The typical deposition rate of this technique is about 1i10
& cm$ s
". Inks of silver (conductor), RuO
# (resi- stor), dielectric (Ferro 38N is the commercial name), lead zirconate titanate (dielectric and thick lm actu- ator) have been successfully printed using this tech- nique. Also, components such as integrated RC lters and voltage transformers have been fabricated (Dimos et al. 1997). A number of co-ring studies are being conducted to identify possible co-reable materials (and co-ring conditions) that can be used in Direct- Write method (Dimos et al. 1997). Bibliography Agarwala M K, Bandyopadhyay A, van Weeren R, Safari A, Danforth S C 1996a FDC, rapid fabrication of structural components. Am. Ceram. Soc. Bull. 75, 60 Agarwala M K, Danforth S C, van Weeren R, Bandyopadhyay A, Safari A, Priedeman W1996b. In: Bourell D L, Beamen J J, Marcus H L, Crawford R H, Barlow J W (eds.) Proc. SFF Symp. Austin, TX, Vol. 7, p. 56 Agarwala M, Klosterman D, Osborne N, Lightman A, Dzugan R, Rhodes G, Nelson C 1999 Hard metal tooling via SFF of ceramics and powder metallurgy. In: Bourell D L, Beamen J J, Marcus H L, Crawford R H, Barlow J W (eds.) Proc. SFF Symp. Austin, TX, Vol. 10, p. 759 Bandyopadhyay A, Panda R K, Janas V F, Danforth S C, Safari A 1997 Processing of piezocomposites by fused deposition technique. J. Am. Ceram. Soc. 80, 1366 Bhargava P, Bandyopadhyay A, Rangarajan S, Qi G, Dai C, Wu S, Danforth S C, Safari A 1997 Shrinkage, weight loss, and crack prevention during binder burn out of components produced by fused deposition of ceramics (FDC). In: Bourell D L, Beamen J J, Marcus H L, Crawford R H, Barlow J W (eds.) Proc. SFF Symp. Austin, TX, Vol. 8, p. 395 Brady G A, Chu T M, Halloran J W 1996 Curing behavior of ceramic resin for stereolithography. In: Bourell D L, Beamen J J, Marcus H L, Crawford R H, BarlowJ W(eds.) Proc. SFF Symp. Austin, TX, Vol. 7, p. 403 Brady G A, Chu T, Halloran J W 1997 Stereolithography of ceramic suspensions. Rapid Prototyping J. 3, 61 Brady G A, Halloran J W 1998. Naal Research Reiews, ONR, Vol. L, Three, p. 39 Brooks J, Robino C, Headley T, Goods S, Grith M 1999 Microstructure and property optimization of LENS deposited H13 tool steel. In: Bourell D L, Beamen J J, Marcus H L, Crawford R H, Barlow J W (eds.) Proc. SFF Symp. Austin, TX, Vol. 10, p. 375 Carter Jr W T., Jones M G1993 Direct laser sintering of metals. In: Bourell D L, Beamen J J, Marcus H L, Crawford R H, Barlow J W (eds.) Proc. SFF Symp. Austin, TX, Vol. 4, p. 51 Cawley J D, Liu Z, Mou J, Heuer A H 1998 Materials issues in laminated object manufacturing of powder-based systems. In: Bourell D L, Beamen J J, Marcus H L, Crawford R H, Barlow J W (eds.) Proc. SFF Symp. Austin, TX, Vol. 9, p. 503 Cawley J D, Wei P Liu Z E, Newman W S, Mathewson B B, Heuer A H 1995 Al # O $ Ceramics made by CAM-LEM (computer-aided manufacturing of laminated engineering materials) technology. In: Bourell D L, Beamen J J, Marcus H L, Crawford, R H, Barlow J W (eds.) Proc. SFF Symp. Austin, TX, Vol. 6, p. 9 Ceasarano III J, Baer T A, Calvert P 1997 Recent developments in freeform fabrication of dense ceramics from slurry de- position. In: Bourell D L, Beamen J J, Marcus H L, Crawford R H, Barlow J W (eds.) Proc. SFF Symp. Austin, TX, Vol. 8, p. 25 Ceasarano III J, King B H, Denham H B 1998 Recent de- velopment in robocasting of ceramics and multi-material deposition. In: Bourell D L, Beamen J J, Marcus H L, Crawford R H, Barlow J W (eds.) Proc. SFF Symp. Austin, TX, Vol. 9, p. 697 Danforth S C, Safari A, Agarwala M K, Bandyopadhyay A, van Weeren R 1998. US Patent No. 5,738,817 Das S, McWilliams J, Wu B, Beaman J J 1991 Design of a high- temperature workstation for the selective laser sintering process. In: Bourell D L, Beamen J J, Marcus H L, Crawford R H, Barlow J W (eds.) Proc. SFF Symp. Austin, TX, Vol. 2, p. 164 Dimos D, Yang P, Garino T J, Raymond M V, Rodriguez M A 1997 In: Bourell D L, Beamen J J, Marcus H L, Crawford R H, Barlow J W (eds.) Proc. SFF Symp. Austin, TX, Vol. 8, p. 33 Grau J, Moon J, Uhland S, Cima M, Sachs E 1997 High green density ceramic components fabricated by the slurry-based 3DP process. In: Bourell D L, Beamen J J, Marcus H L, Crawford R H, Barlow J W (eds.) Proc. SFF Symp. Austin, TX, Vol. 8, p. 371 Greulich M, Greul M, Pintat T 1995 Rapid Prototyping J. 1, 20 Grith M L, Halloran J W 1996 Freeform fabrication of ceramics via stereolithography. J. Am. Ceram. Soc. 79, 2601 Grith M L, Halloran J W 1997 Scattering of ultraviolet radiation in turbid suspensions. J. Appl. Phys. 81, 2538 Grith M L, Harwell L D, Romero J T, Schlienger E, Atwood C L, Smugeresky J E 1997 LENS processing of newmaterials. In: Bourell D L, Beamen J J, Marcus H L, Crawford R H, BarlowJ W(eds.) Proc. SFF Symp. Austin, TX, Vol. 8, p. 387 Grith M L, Keicher D M, AtwoodC L, Romero J A, Smugeresky J E, Harwell L D, Greene D L 1996 Freeform fabrication of metallic components using laser-engineered net shaping (LENS). In: Bourell D L, Beamen J J, Marcus H L, Crawford R H, Barlow J W (eds.) Proc. SFF Symp. Austin, TX, Vol. 7, p. 125 Kai C C, Fai L K 1997 Rapid Prototyping. John Wiley, Singa- pore Khoshnevis B 1999 Contour craftingstate of development. In: Bourell D L, Beamen J J, Marcus H L, Crawford R H, Barlow J W (eds.) Proc. SFF Symp. Austin, TX, Vol. 10, p. 743 King B H, Morisette S L, DenhamH, Ceasarano III J, Dimos D 1998 Inuence of rheology on the deposition behavior of ceramic pastes in direct fabrication systems. In: Bourell D L, 11 Rapid Prototyping Beamen J J, Marcus H L, Crawford R H, Barlow J W (eds.) Proc. SFF Symp. Austin, TX, Vol. 9, p. 391 Klosterman D, Charto R, Osborne N, Graves G 1997a Automated fabrication of monolithic and ceramic matrix composites via laminated object manufacturing (LOM). In: Bourell D L, Beamen J J, Marcus H L, Crawford R H, Barlow J W (eds.) Proc. SFF Symp. Austin, TX, Vol. 8, p. 537 Klosterman D, Charto R, Osborne N, Graves G, Lightman A 1997b Pre-LOM, LOM, and post-LOM processes for the fabrication of SiC and SiC\SiC components. In: Bourell D L, Beamen J J, Marcus H L, Crawford R H, Barlow J W (eds.) Proc. SFF Symp. Austin, TX, Vol. 8, p. 247 Klosterman D, Charto R, Priore B, Osborne N, Graves G, Lightman A, Han G, Pak S, Weaver J 1996 Functional ceramic components via laminated object manufacturing. In: Bourell D L, Beamen J J, Marcus H L, Crawford R H, Barlow J W (eds.) Proc. SFF Symp. Austin, TX, Vol. 7, p. 356 Kupp D M, Eifert H, Greul M, Kunstner M 1997 Rapid prototyping of functional metal and ceramic components by the multiphase jet solidication (MJS) process. In: Bourell D L, Beamen J J, Marcus H L, Crawford R H, Barlow J W (eds.) Proc. SFF Symp. Austin, TX, Vol. 8, p. 203 Lakshminarayan U, Marcus H L 1991 Microstructural and mechanical properties of Al # O $ \P # O & and Al # O $ \B # O $ com- posites fabricated by selective laser sintering. In: Bourell D L, Beamen J J, Marcus H L, Crawford R H, Barlow J W (eds.) Proc. SFF Symp. Austin, TX, Vol. 2, p. 205 Lakshminarayan U, Ogrydiziak S, Marcus H L 1990 Selective laser sintering of ceramic materials. In: Bourell D L, Beamen J J, Marcus H L, Crawford R H, BarlowJ W(eds.) Proc. SFF Symp. Austin, TX, Vol. 1, p. 16 Liu Z E, Wei P, Kernan B, Heuer A H, Cawley J D 1996 Metal and ceramic components made by CAM-LEM technology. In: Bourell D L, Beamen J J, Marcus H L, Crawford R H, BarlowJ W(eds.) Proc. SFF Symp. Austin, TX, Vol. 7, p. 377 Liu Z, N Suppakarn, Cawley J D 1999 Coated feedstock for fabrication of ceramic parts by CAM-LEM. In: Bourell D L, Beamen J J, Marcus H L, Crawford R H, Barlow J W (eds.) Proc. SFF Symp. Austin, TX, Vol.10, p. 393 Lous G M, Cornejo I A, McNulty T F, Safari A, Danforth S C 2000 Fabrication of piezoelectric ceramic\polymer composite transducers using fused deposition of ceramics. J. Am. Ceram Soc. 83, 124 Manriquez-Frayre J A, Bourell D L1990 Selective laser sintering of binary metallic powder. In: Bourell D L, Beamen J J, Marcus H L, Crawford R H, Barlow J W (eds.) Proc. SFF Symp. Austin, TX, Vol. 1, p. 99 McIntosh J J, Danforth S CJamalabad V R1997 Shrinkage and deformationincomponents manufacturedby fused deposition of ceramics. In: Bourell D L, Beamen J J, Marcus H L, Crawford R H, Barlow J W (eds.) Proc. SFF Symp. Austin, TX, Vol. 8,p. 159 Nutt K 1991 Selective laser sintering as a rapid prototyping and manufacturing technique. In: Bourell D L, Beamen J J, Marcus H L, Crawford R H, Barlow J W (eds.) Proc. SFF Symp. Austin, TX, Vol. 2, p. 131 Pope M J, PattersonC L, Zimbeck W, Fehrenbacher M 1997 Laminated object manufacturing of Si $ N % with enhanced properties. In: Bourell D L, Beamen J J, Marcus H L, Crawford R H, Barlow J W (eds.) Proc. SFF Symp. Austin, TX, Vol. 8, p. 529 Prinz F B, Weiss L E 1998. Naal Research Reiews, ONR, Vol. L, Three, p. 19 Sachs E et al. 1995. US Patent No. 5, 387, 380 Sachs E et al. 1998a. US Patent No. 5, 807, 437 Sachs E, Allen S, Cima M, Xu X, Banos J, Serdy J, Brancazio D, Guo H 1998b. Naal Research Reiews, ONR, Vol. L, Three, p. 9 Sachs E, Allen S, Hadjiloucas C, Yoo J, Cima M 1999 Low shrinkage metal skeletons by three-dimensional printing. In: Bourell D L, Beamen J J, Marcus H L, Crawford R H, Barlow J W (eds.) Proc. SFF Symp. Austin, TX, Vol. 10, p. 411 Sachs E, Cima M, Williams P, Brancazio D, Cornie J 1992 Three-dimensional printing; rapid tooling and prototypes directly from a CAD model. J. Eng. Ind. 114, 481 Safari A et al. 1998. US Patent No. 5, 818, 149 Steidle C, Klosterman D, Osborne N, Graves G, Charto R 1997 Automated fabrication of nonresorbable bone implants using laminated object manufacturing (LOM). In: Bourell D L, Beamen J J, Marcus H L, Crawford R H, Barlow J W (eds.) Proc. SFF Symp. Austin, TX, Vol. 8, p. 248 Stratasys, Inc. Homepage, http:\\www.stratasys.com Subramanian P K, Zhong G, Marcus H L 1992 Selective laser sintering and reaction sintering of ceramic composites. In: Bourell D L, Beamen J J, Marcus H L, Crawford R H, Barlow J W (eds.) Proc. SFF Symp. Austin, TX, Vol. 3, p. 63 Subramanian P K, Zhong G, Vail N K, Barlow J W, Marcus H L 1993 Selective laser sintering of Al # O $ . In: Bourell D L, Beamen J J, Marcus H L, Crawford R H, Barlow J W (eds.) Proc. SFF Symp. Austin, TX, Vol. 4, p. 350 Vail N K, Barlow J W 1991 Eect of polymer coating as intermediate binder on sintering of ceramic parts. In: Bourell D L, Beamen J J, Marcus H L, Crawford R H, Barlow J W (eds.) Proc. SFF Symp. Austin, TX, Vol. 2, p. 195 Vasinonta A, Beuth J, Grith M 1999 Process maps for laser deposition of thin-walled structures. In: Bourell D L, Beamen J J, Marcus H L, Crawford R H, BarlowJ W(eds.) Proc. SFF Symp. Austin, TX, Vol. 10, p. 383 Venkataraman N 2000 The Process-property-performance Rela- tionships of Feedstock Materials Used for Fused Deposition of Ceramics (FDC). PhD Thesis, Rutgers University Venkataraman N, Rangarajan S, Matthewson M J, Harper B, Safari A, Danforth S C, Wu G, Langrana N, Yardimci A, Guceri S 1999 Material property-process relationships in fused deposition of ceramics (FDC) and metals (FDMet). In: Proc. Symp. Innoatie Processing and Synth. of Ceramics, American Ceramic Society Ventura S, Narang S 1998. Naal Research Reiews, ONR, Vol. L, Three, p. 44 Wu G, Langrana N A, Rangarajan S, McCuiston R, Sadanji R, Danforth S, Safari A 1999 Fabrication of metal components using FDMet: fused deposition of metals. In: Bourell D L, Beamen J J, Marcus H L, Crawford R H, Barlow J W (eds.) Proc. SFF Symp. Austin, TX, Vol. 10, p. 775 Yan X, Gu P 1996 Computer-aided Design. 28, 4, Elsevier, Amsterdam, p. 307 Yardimci M A 1999. PhD Thesis, University of Illinois at Chicago A. Safari, S. C. Danforth, M. Allahverdi, and N. Venkataraman 12 Rapid Prototyping Copyright '2001 Elsevier Science Ltd. All rights reserved. No part of this publication may be reproduced, stored in any retrieval system or transmitted in any form or by any means: electronic, electrostatic, magnetic tape, mechanical, photocopying, recording or otherwise, without permission in writing from the publishers. Encyclopedia of Materials: Science and Technology ISBN: 0-08-0431526 pp. 79918003 13
3D PRINTER USER GUIDE - A Complete Step by Step User Manual For Understanding The Fundamentals of 3D Printing, How To Maintain and Troubleshoot Common Difficulties