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Front. Energy Power Eng.

China 2009, 3(1): 99–108


DOI 10.1007/s11708-009-0013-1

RESEARCH ARTICLE

Zhen HUANG, Xinqi QIAO, Wugao ZHANG, Junhua WU, Junjun ZHANG

Dimethyl ether as alternative fuel for CI engine and vehicle

© Higher Education Press and Springer-Verlag 2009

Abstract As a developing and the most populous will be a potential and promising fuel for more efficient and
country in the world, China faces major challenges in cleaner engine and vehicle [1–8].
energy supply and environmental protection. It is of great As a developing and the most populous country in the
importance to develop clean and alternative fuels for world, China faces major challenges of energy supply and
internal combustion engines. On the basis of researches on environmental protection. It is of great importance to
DME engine and vehicle at Shanghai Jiaotong University develop clean and alternative fuels for internal combustion
in the last twelve years, fuel injection, combustion, engines and vehicles. DME will be a solution for energy
performance and exhaust emissions of DME engine and security and environmental protection in China. In the last
DME vehicle are introduced in this paper. The results decade, research and development of DME engine and
indicate that DME engines can achieve high thermal vehicle was conducted actively in several universities in
efficiency and ultra low emissions, and will play a China [9–12].
significant role in meeting the energy demand while Researches have been conducted on DME as alternative
minimizing environmental impact in China. fuel for CI engine and vehicle, including DME fuel
injection system, spray and combustion, engine perfor-
Keywords dimethyl ether (DME), fuel injection, com- mance and emissions, engine reliability and DME-tolerant
bustion process, emission control, CI engine, vehicle seal material by the authors at Shanghai Jiaotong
University since 1996 [13–18]. Furthermore, a turbo-
charged 6114ZLQB DME engine and a DME city bus
1 Introduction were successfully developed. This paper introduces the
research results on DME fuel injection, combustion,
Dimethyl ether (DME), whose chemical formula is CH3–O– performance and exhaust emissions of DME engine and
CH3, is the simplest ether compound and has been known to DME vehicle.
be both non-toxic and environmentally benign. DME can be
made from a wide variety of resources including coal,
coalbed methane, natural gas and biomass etc. For engine 2 Fuel properties and experimental
use, DME has a high cetane number of approximately 55– apparatus
60, which makes DME ideal for use in a compression
ignition (CI) engine. The chemical structure of DME with its The properties of DME and diesel fuel are shown in
high oxygen content promises a smoke-free combustion. Table 1. It can be seen that the properties of DME are quite
DME is a relatively new alternative fuel for engine and different from those of diesel fuel. DME has high vapor
vehicle. Researches on DME as fuel were initiated in 1995. pressure and low boiling temperature, which is a gas fuel at
Denmark Technical University, Haldor Topsoe A/S, Navis- room temperature and atmospheric pressure. Its handling
tar, AVL, AMOCO etc. conducted extensive investigations characteristics are very similar to LPG, a widely used fuel
on CI engines fueled with DME. Results show that DME for spark ignition engines. The heat value of DME is
significantly lower than conventional diesel fuel. There-
Received September 16, 2008; accepted November 25, 2008 fore, the fuel supply and injection system, and the
combustion system of the engine should be redesigned or

Zhen HUANG ( ), Xinqi QIAO, Wugao ZHANG, Junhua WU, Junjun modified.
ZHANG In this study, experiments were conducted on a naturally
Key Laboratory of Power Machinery and Engineering, Ministry of
Education, Shanghai Jiao Tong University, Shanghai 200240, China aspirated direct injection (DI) CI 2135 diesel engine and a
E-mail: z-huang@sjtu.edu.cn D6114 turbocharged heavy-duty CI engine respectively.
100 Front. Energy Power Eng. China 2009, 3(1): 99–108

Table 1 Properties of DME and diesel fuel Table 2 Technical parameters of 2135 diesel engine and DME engine
property (unit or condition) DME diesel fuel DME engine diesel engine
chemical formula CH3–O–CH3 – borestroke/(mmmm) 135145
mole weight/g 46.07 170 compression ratio 16.5∶1
boiling point/°C – 24.9 180–360 –1
rated power/ kW, rated speed/(r$min ) 29.4, 1500
–3
liquid density/(g$cm ) 0.668 0.84 plunger diameter/mm 10 8
liquid viscosity/cP 0.15 4.4–5.4 nozzle number orifice diameter/(1mm) 40.55 40.35
low heat value/(MJ$kg–1) 28.43 42.5 nozzle opening pressure/MPa 15 18
ignition temperature/°C 235 250
cetane number 55–60 40–55
Table 3 Technical parameters of D6114 turbocharged diesel engine and
stoichiometric air/fuel ratio/(kg$kg–1) 9.0 14.6
DME engine
mass fraction of carbon 52.2 86
DME engine diesel engine
mass fraction of hydrogen 13.0 14
borestroke/(mmmm) 135145
mass fraction of oxygen 34.8 0
compression ratio 18∶1
–2 8 9
modulus of elasticity/(N$m ) 6.3710 1.48610
displacement/cm3 8270
rated power/ kW, rated speed/(r$min–1) 184.1, 2200
maximum torque/(N$m), speed/(r$min–1) 1000,1400
plunger diameter/mm 13,12 12
nozzle number orifice diameter/(1mm) 60.4 60.24
fuel delivery advance angle (CA BTDC)/(°) 9,12 9
nozzle opening pressure/MPa 16 21
diameter of high pressure pipe/mm 2.2 1.8

The effects of exhaust gas recirculation (EGR) and


oxidation catalyst converter (DOC) on exhaust emission
control were also investigated. The layout of EGR and
DOC are shown in Fig. 2. Exhaust gas after the turbine
flows through an EGR valve and an EGR cooler, and then
enters the intake pipe before the compressor. The DOC is
Fig. 1 Schematic of DME engine experimental system installed in the exhaust pipe to reduce HC and CO
emissions. The EGR rate can be obtained by the following
The DME engine experimental system is shown in Fig. 1 equation:
and engine specifications and modifications are illustrated
in Tables 2 and 3. The fuel supply system contains a CO2 int – CO2 ambient
EGR rate ¼ , (1)
pressurized fuel tank, appropriate pipelines and valve, and CO2 ext – CO2 ambient
a fuel supply pump, which is capable of delivering fuel to
the high pressure pump at a pressure of up to 1.5 MPa to
prevent cavitations and vapor choke within the fuel
pipeline and the fuel injection system. In the fuel return
pipeline, a cooler is used to decrease the temperature of
DME. To keep the output of the DME engine the same as
that of the diesel engine, it is necessary to increase the
injection rate and quantity. Therefore, the diameter and the
stroke of the plunger, and the nozzle diameter were
enlarged and the adjustment of nozzle opening pressure
was also made. A lubricant additive was added to improve
the lubrication of DME fuel, due to its low viscosity and
poor lubrication. Since conventional rubber materials are
not chemically compatible and will deteriorate after
exposure to DME whose resolvability is high, a DME-
tolerant seal material was developed and used on the DME
engine system. Fig. 2 Layout of EGR and DOC
Zhen HUANG et al. Dimethyl ether as alternative fuel 101

here, CO2 int, CO2 ambient, and CO2 ext indicate the CO2 between DME and diesel fuel. It can be seen that with the
concentration in air intake before the compressor, at decrease in engine load, both acoustics velocity of DME
ambient condition and in the exhaust gas, respectively. and diesel fuel are reduced. At 100%, 75% and 50% engine
The DME fuel consumption was measured by an load, the acoustics velocity of DME are 810 m/s, 675 m/s
electronic scale. The cylinder pressure was measured and 578.6 m/s respectively; while the acoustics velocity of
using a Kistler Model 6125A pressure transducer. The diesel fuel are 1227.3 m/s, 1157.1 m/s and 1094.5 m/s
charge output from this transducer was converted to an respectively. The acoustics velocity of DME is much lower
amplified voltage using a Kistler Model 5015 amplifier. than that of diesel fuel. Figure 5 further illustrates a
The 1440 pulses per rotation (four pulses per crank angle) comparison of variations of injection delay and ignition
from a shaft encoder on the engine crankshaft were used as delay between DME engine and diesel fuel engine. With
the data acquisition clocking pulses to acquire the cylinder the decrease in engine load, the injection delay increases.
pressure data. Based on measured cylinder pressure, the At 100%, 75% and 50% engine load, the injection delay
heat release rate (HRR) is calculated and analyzed. NOx, increases by 36.4%, 43.5% and 46.2% respectively in
CO, HC, and CO2 emissions were measured by an AVL comparison with that of diesel fuel. Differences in
CEB serials gas analyzer. Smoke emission was tested by a acoustics velocity and injection delay between DME and
fully-automated fqd-102A smoke meter and PM was diesel fuel mainly result from the relatively larger
measured by an AVL 472 Smart Sampler PC. compressibility of DME.
Furthermore, as shown in Fig. 5, at 100%, 75% and 50%
engine load, the ignition delay decreases by 23.1%,
3 Results and discussion 21.15% and 18.5%, compared with diesel fuel, which is
thought to be caused by a higher cetane number of DME.
3.1 DME fuel injection As a result, since the increment in injection delay of DME

The characteristics of DME fuel injection, including


pipeline pressure, needle lift, acoustics velocity, injection
delay and ignition delay were measured in a 2135 CI
engine. Figure 3 shows the comparison of fuel pipeline
pressures at pump side between DME and diesel fuel. It is
indicated that under conditions of the same fuel delivery
advance angle and load, the peak pipeline pressure and
pressure rise rate of DME are much lower than those of
diesel fuel. For instance, at full load, the peak pressures of
DME and diesel fuel are 36.4 MPa and 51.6 MPa
respectively, which is believed to be caused by the
relatively larger nozzle orifice, the lower nozzle opening
pressure and the larger compressibility of DME. With the
decrease in engine load, the pipeline pressure decreases
and its phase retards as in the case of DME.
Fig. 4 Comparison of acoustics velocity between DME and
Figure 4 shows the comparison of the acoustics velocity
diesel fuel

Fig. 3 Comparison of line pressure at nozzle side between DME Fig. 5 Variation of injection delay and ignition delay of DME in
and diesel fuel comparison with diesel fuel
102 Front. Energy Power Eng. China 2009, 3(1): 99–108

is larger than the reduction in ignition delay, it is found that different engine speeds. It can be seen that the peak value of
at the condition of the same fuel delivery advance angle, cylinder pressure and HRR of DME are lower than those of
the start of ignition timing of DME is retarded in diesel fuel and the phase of pressure and HRR rise are
comparison with diesel fuel. The retardation of ignition retarded in comparison with diesel fuel. At the condition of
timing of DME is more obvious as the engine load fuel delivery advance angle of 9° (CA BTDC), engine speed
decreases. of 800 r/min and full load, the maximum cylinder pressure is
8.2 MPa at 16° (CA ATDC) in the case of DME and
3.2 DME engine combustion and performance 10.1 MPa at 11° (CA ATDC) in the case of diesel fuel,
respectively, with a phase difference of 5° (CA). The
Engine combustion and performance fuelled with DME was maximum rate of pressure rise of DME is much lower than
further investigated in a D6114 turbocharged CI engine. that of diesel fuel. The same phenomena can be found at
Figure 6 shows the comparison of cylinder pressure, HRR, conditions of engine speeds of 1400 r/min and 2200 r/min,
accumulated heat release and rates of pressure rise between as shown in Fig. 6. The relatively low maximum cylinder
the DME engine and the diesel engine at full load and pressure, HRR and rate of pressure rise and phase

Fig. 6 Comparison of cylinder pressure, HRR, accumulated heat release and rates of pressure rise between DME engine and diesel engine
(for DME engine, plunger diameter = 12 mm, nozzle type: 60.40 mm)
(a) 800 r/min, pe = 0.87 MPa; (b) 1400 r/min, pe = 1.52 MPa; (c) 2200 r/min, pe= 1.21 MPa
Zhen HUANG et al. Dimethyl ether as alternative fuel 103

retardation of DME is considered to result from the


relatively shorter ignition delay caused by higher cetane
number of DME and the later ignition timing caused by
relatively larger injection delay.
Moreover, it is worth noticing that although the ignition
timing of DME is retarded in comparison with diesel fuel,
the end of heat release of DME is almost the same as that of
diesel fuel. The combustion duration tends to be shorter
than that of diesel fuel, especially in the cases of engine
speed of 800 r/min and 1400 r/min. It is believed that the
high vapor pressure, the low boiling temperature and the
high oxygen content of DME lead to rapid fuel evaporation,
good fuel/air mixture formation and prompt combustion.
Figure 7 shows the comparison of engine torque and
power between DME and diesel fuel engine. It is found that
both the torque and the power of DME are greater than those
of diesel at all engine speeds, especially at lower engine
speed. The torque of the DME engine is increased by 29.1%
and 32.8% at the speed of 1000 r/min and 900 r/min,
respectively, in comparison with the diesel engine. Maxi-
mum output is usually determined by smoke limitation in
diesel engines. However, there is no smoke limitation in
DME engine due to its smoke-free combustion.

Fig. 7 Comparison of engine torque and power between DME


and diesel fuel engine

Fig. 8 Variation of BSFC with engine speed and load


Figure 8 shows the variation of brake specific fuel (a) Full load; (b) 1400 r/min; (c) 2200 r/min
consumption (BSFC) with engine speed and load. In order
to make a comparison of the BSFC between the DME full load, when engine speed is less than 1500 r/min, the
engine and the diesel engine, the fuel consumption of equivalent BSFC of DME is better than that of diesel fuel.
DME is converted to that of diesel fuel based on the low When engine speed is larger than 1500 r/min, the equivalent
heating value. The equivalent BSFC of DME fuel is BSFC of DME is poorer than that of diesel fuel, which
defined as indicates that at high engine speed, the fuel consumption will
hDME deteriorate due to the lower heating value of DME.
BSFC ¼ BSFEDME  , With an increase in engine load, both BSFC of DME and
hdiesel
diesel fuel are decreased. At the speed of 1400 r/min, the
where hDME and hdiesel are the lower heating values of DME equivalent BSFC of DME engine is lower than that of the
and diesel fuel respectively. It can be seen that for both fuels, diesel engine at all test loads, especially at low load. At the
the lowest BSFC is obtained in the range of speed where the speed of 2200 r/min, the equivalent BSFC of the DME
maximum torque is achieved. It is found that in the case of engine is almost the same as that of the diesel engine at low
104 Front. Energy Power Eng. China 2009, 3(1): 99–108

load. With the increase of engine load, the equivalent by 28.1%, in comparison with that of the diesel engine. At
BSFC of the DME engine tends to be higher than that of 2200 r/min, the NOx emission is reduced more signifi-
the diesel engine, especially at medium and high engine cantly for the DME engine. Reduction of NOx is mainly
load. Due to the lower heating value of DME, to keep the attributed to the physicochemical properties of DME. For
engine output the same as that of the diesel engine, about the DME engine, retardation of ignition timing due to
1.9 times as much as the diesel fuel volume should be longer fuel injection delay, shorter ignition delay due to
injected into the combustion chamber per cycle, which high cetane number and larger latent heat of DME lead to a
leads to prolonged injection duration and combustion decrease in cylinder pressure and local temperature which
duration at high engine speed, and results in the result in a reduction of NOx emission.
deterioration of fuel consumption of DME. The comparison of HC and CO emission between the
DME engine and the diesel engine under different engine
3.3 DME engine exhaust emissions loads at an engine speed of 1400 r/min and 2200 r/min is
shown in Figs. 10 and 11. HC emission of DME is
Figure 9 shows the comparison of NOx emission between significantly lower than that of diesel fuel at all test range
DME and diesel fuel under different engine loads and at of loads and speeds. Meanwhile, with the increase of
engine speeds of 1400 r/min and 2200 r/min. It is engine load, HC emission tends to decrease. It is supposed
illustrated that the DME engine exhibits substantial that the low boiling temperature and high vapor pressure of
reduction in NOx emission at all test range of loads and DME will promote fuel atomization, mixture formation
speeds. At the BMEP of 1.52 MPa and engine speed of and combustion which result in low HC emission.
1400 r/min, NOx emission of the DME engine is reduced CO emission of the DME engine is almost the same as

Fig. 9 Comparison of NOx emission between DME engine and diesel engine
(a) 1400 r/min; (b) 2200 r/min

Fig. 10 Comparison of HC emission between DME engine and diesel engine


(a) 1400 r/min; (b) 2200 r/min
Zhen HUANG et al. Dimethyl ether as alternative fuel 105

Fig. 11 Comparison of CO emission between DME engine and diesel engine


(a)1400 r/min; (b) 2200 r/min

that of the diesel engine at low engine load. It is interesting 3.4 Effects of EGR and DOC on emissions
to note that CO emission of the DME engine is higher than
that of the diesel engine at high and medium engine loads, In order to meet more stringent emission regulation, effects
with emission levels of 12010–6 to 22010–6. It is of exhaust gas recirculation (EGR) and oxidation catalyst
considered that rich burning of DME at high load results in converter (DOC) on exhaust emission were evaluated.
an increase of CO. However, further study is necessary to Figure 14(a) shows the effect of EGR rate on NOx emission
verify this possible mechanism. under different engine loads at the speed of 1400 r/min. It
The comparison of smoke emission between the DME is indicated that substantial reduction in NOx emission
engine and the diesel engine under different loads at an without smoke is obtained by means of EGR. With the
engine speed of 1400 r/min and 2200 r/min is indicated in increase of EGR rate, NOx emission is decreased
Fig. 12. DME presents almost zero emission of smoke at remarkably. In the case of BMEP of 1.52 MPa and 10%
all test engine loads and speeds. High oxygen content and EGR rate, the NOx is reduced by 51.8%. In the case of
absence of C–C bonds in the molecular structure of DME BMEP of 0.76 MPa and 25% EGR rate, the NOx is reduced
promises a smoke-free combustion. by 67.8%. With EGR, reduction of local temperature and
Figure 13 shows the results of ESC emission test of the oxygen concentration within the cylinder results in the
DME engine. Thirteen modes of ESC tests were suppression of NOx formation. EGR has influence on
conducted. The results show that without common rail engine fuel consumption, as shown in Fig. 14(b). At low
injection system, EGR and after-treatment system, NOx, load, the BSFC of the DME engine is improved with EGR.
HC, CO and PM emissions of the DME engine are 19.7%, At medium load, with the increase of EGR rate, the BSFC
80.5%, 62.5% and 50% below Euro III respectively. The first decreases, then increases when EGR rate is larger than
requirements for EURO III are satisfied with the DME 15%. At full load, when EGR rate is larger than 10%, the
engine with in-line fuel pump. The baseline diesel engine BSFC tends to deteriorate. It appears that there is no loss in
can only narrowly meet Europe II. fuel consumption for test EGR rate in the case of BMEP of

Fig. 12 Comparison of smoke emission between DME engine and diesel engine
(a) 1400 r/min; (b) 2200 r/min
106 Front. Energy Power Eng. China 2009, 3(1): 99–108

duration will be prolonged due to the relatively low air/fuel


ratio within the cylinder, which will lead to deterioration of
fuel consumption.
The effect of EGR rate on HC and CO emissions under
different engine loads at the speed of 1400 r/min is shown
in Figs. 14(c) and (d). With the increase of EGR rate, HC
emission increases slightly. At all test EGR rates, HC
emission is maintained at a low level. It is worth noticing
that EGR has a great influence on CO emission. With the
increase of EGR rate, CO emission increases. Especially
when EGR rate is over a certain value and the engine runs
at medium and high load, CO emission increases
considerably. It is indicated that CO emission increases
dramatically when EGR rate is larger than 12% in the case
Fig. 13 Results of ESC emission test of DME engine
of BMEP of 1.52 MPa, 22% in the case of BMEP of
0.76 MPa and 35% in the case of BMEP of 0.38 MPa.
0.38 MPa, when EGR rate is less than 25% in the case of Deterioration of CO emission is considered to be attributed
BMEP of 0.76 MPa, and EGR rate is less than 10% in the to reduction in local air/fuel ratio and temperature with the
case of BMEP of 1.52 MPa. It is believed that at low load, introduction of exhaust gas. However, HC and CO
combustion will be promoted due to the introduction of emissions can be readily reduced by an oxidation catalyst
exhaust gas; therefore, fuel consumption is improved. At converter. In this work, effect of EGR on smoke is also
high load, combustion will be suppressed and combustion investigated. The result indicates that the chemical

Fig. 14 Effect of EGR rate on exhaust emission of DEM engine


(a) NOx emission; (b) fuel consumption; (c) HC emission; (d) CO emission
Zhen HUANG et al. Dimethyl ether as alternative fuel 107

structure of DME with its high oxygen content promises The performance of the DME city bus is tested
high EGR tolerance. according to the national vehicle standard. Table 4 shows
Figure 15 further shows the effect of DOC on HC and the test results. The noise of acceleration of the DME bus is
CO emissions of the DME engine at different engine load 80.6 dB(A), which is 2.3 dB(A) lower than that of the
at the speed of 1400 r/min. It is illustrated that HC and CO baseline diesel bus. The noise within the bus is 77.8 dB(A),
emissions is reduced significantly with an emission level of which is 2.5 dB(A) lower than that of the baseline diesel
less than 1010–6 by means of DOC. For instance, in the bus. The maximum speed (25–60 km/h) and the accelera-
case of BMEP of 0.378 MPa, HC and CO emissions are tion time satisfy the requirements of the national standard.
reduced by 87% and 92% respectively. As a result, it is The fuel consumption of the DME bus was measured
believed that DME engine with EGR and DOC will satisfy under a condition of constant vehicle speed of 50 km/h.
more stringent emission regulation. The equivalent fuel consumption is 17.78 L/100 km, which
is better than that of the baseline diesel bus.
3.5 Performance of DME city bus
On the basis of DME engine research, a dedicated DME 4 Conclusions
fuel supply, injection and combustion system were
developed. In 2005, the first DME city bus in China was 1) The injection delay of DME is longer than that of
successfully developed in cooperation with Shanghai Auto diesel fuel due to the lower acoustics velocity resulting
Industry and Shanghai Diesel Works. In 2007, ten DME from the higher compressibility of DME. The ignition
city buses were manufactured by Shanghai Auto Industry delay of DME is shorter than that of diesel fuel due to the
for demonstration and public use, as shown in Fig. 16. higher cetane number of DME. Since the increment in

Fig. 15 Effect of DOC on HC and CO emissions


(a) HC emission; (b) CO emission

Fig. 16 DME city bus developed by the project


(a) First DME city bus in China; (b) Shanghai DME city bus demonstration
108 Front. Energy Power Eng. China 2009, 3(1): 99–108

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noise outside bus 80.6 dB(A) satisfy
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2 noise inside bus 77.8 dB(A) ≤79 dB(A)
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4 maximum speed 83.2 km/h ≥80 km/h neat dimethyl ether. SAE Paper no. 950064, 1995
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