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RESEARCH ARTICLE
Zhen HUANG, Xinqi QIAO, Wugao ZHANG, Junhua WU, Junjun ZHANG
Abstract As a developing and the most populous will be a potential and promising fuel for more efficient and
country in the world, China faces major challenges in cleaner engine and vehicle [1–8].
energy supply and environmental protection. It is of great As a developing and the most populous country in the
importance to develop clean and alternative fuels for world, China faces major challenges of energy supply and
internal combustion engines. On the basis of researches on environmental protection. It is of great importance to
DME engine and vehicle at Shanghai Jiaotong University develop clean and alternative fuels for internal combustion
in the last twelve years, fuel injection, combustion, engines and vehicles. DME will be a solution for energy
performance and exhaust emissions of DME engine and security and environmental protection in China. In the last
DME vehicle are introduced in this paper. The results decade, research and development of DME engine and
indicate that DME engines can achieve high thermal vehicle was conducted actively in several universities in
efficiency and ultra low emissions, and will play a China [9–12].
significant role in meeting the energy demand while Researches have been conducted on DME as alternative
minimizing environmental impact in China. fuel for CI engine and vehicle, including DME fuel
injection system, spray and combustion, engine perfor-
Keywords dimethyl ether (DME), fuel injection, com- mance and emissions, engine reliability and DME-tolerant
bustion process, emission control, CI engine, vehicle seal material by the authors at Shanghai Jiaotong
University since 1996 [13–18]. Furthermore, a turbo-
charged 6114ZLQB DME engine and a DME city bus
1 Introduction were successfully developed. This paper introduces the
research results on DME fuel injection, combustion,
Dimethyl ether (DME), whose chemical formula is CH3–O– performance and exhaust emissions of DME engine and
CH3, is the simplest ether compound and has been known to DME vehicle.
be both non-toxic and environmentally benign. DME can be
made from a wide variety of resources including coal,
coalbed methane, natural gas and biomass etc. For engine 2 Fuel properties and experimental
use, DME has a high cetane number of approximately 55– apparatus
60, which makes DME ideal for use in a compression
ignition (CI) engine. The chemical structure of DME with its The properties of DME and diesel fuel are shown in
high oxygen content promises a smoke-free combustion. Table 1. It can be seen that the properties of DME are quite
DME is a relatively new alternative fuel for engine and different from those of diesel fuel. DME has high vapor
vehicle. Researches on DME as fuel were initiated in 1995. pressure and low boiling temperature, which is a gas fuel at
Denmark Technical University, Haldor Topsoe A/S, Navis- room temperature and atmospheric pressure. Its handling
tar, AVL, AMOCO etc. conducted extensive investigations characteristics are very similar to LPG, a widely used fuel
on CI engines fueled with DME. Results show that DME for spark ignition engines. The heat value of DME is
significantly lower than conventional diesel fuel. There-
Received September 16, 2008; accepted November 25, 2008 fore, the fuel supply and injection system, and the
combustion system of the engine should be redesigned or
✉
Zhen HUANG ( ), Xinqi QIAO, Wugao ZHANG, Junhua WU, Junjun modified.
ZHANG In this study, experiments were conducted on a naturally
Key Laboratory of Power Machinery and Engineering, Ministry of
Education, Shanghai Jiao Tong University, Shanghai 200240, China aspirated direct injection (DI) CI 2135 diesel engine and a
E-mail: z-huang@sjtu.edu.cn D6114 turbocharged heavy-duty CI engine respectively.
100 Front. Energy Power Eng. China 2009, 3(1): 99–108
Table 1 Properties of DME and diesel fuel Table 2 Technical parameters of 2135 diesel engine and DME engine
property (unit or condition) DME diesel fuel DME engine diesel engine
chemical formula CH3–O–CH3 – borestroke/(mmmm) 135145
mole weight/g 46.07 170 compression ratio 16.5∶1
boiling point/°C – 24.9 180–360 –1
rated power/ kW, rated speed/(r$min ) 29.4, 1500
–3
liquid density/(g$cm ) 0.668 0.84 plunger diameter/mm 10 8
liquid viscosity/cP 0.15 4.4–5.4 nozzle number orifice diameter/(1mm) 40.55 40.35
low heat value/(MJ$kg–1) 28.43 42.5 nozzle opening pressure/MPa 15 18
ignition temperature/°C 235 250
cetane number 55–60 40–55
Table 3 Technical parameters of D6114 turbocharged diesel engine and
stoichiometric air/fuel ratio/(kg$kg–1) 9.0 14.6
DME engine
mass fraction of carbon 52.2 86
DME engine diesel engine
mass fraction of hydrogen 13.0 14
borestroke/(mmmm) 135145
mass fraction of oxygen 34.8 0
compression ratio 18∶1
–2 8 9
modulus of elasticity/(N$m ) 6.3710 1.48610
displacement/cm3 8270
rated power/ kW, rated speed/(r$min–1) 184.1, 2200
maximum torque/(N$m), speed/(r$min–1) 1000,1400
plunger diameter/mm 13,12 12
nozzle number orifice diameter/(1mm) 60.4 60.24
fuel delivery advance angle (CA BTDC)/(°) 9,12 9
nozzle opening pressure/MPa 16 21
diameter of high pressure pipe/mm 2.2 1.8
here, CO2 int, CO2 ambient, and CO2 ext indicate the CO2 between DME and diesel fuel. It can be seen that with the
concentration in air intake before the compressor, at decrease in engine load, both acoustics velocity of DME
ambient condition and in the exhaust gas, respectively. and diesel fuel are reduced. At 100%, 75% and 50% engine
The DME fuel consumption was measured by an load, the acoustics velocity of DME are 810 m/s, 675 m/s
electronic scale. The cylinder pressure was measured and 578.6 m/s respectively; while the acoustics velocity of
using a Kistler Model 6125A pressure transducer. The diesel fuel are 1227.3 m/s, 1157.1 m/s and 1094.5 m/s
charge output from this transducer was converted to an respectively. The acoustics velocity of DME is much lower
amplified voltage using a Kistler Model 5015 amplifier. than that of diesel fuel. Figure 5 further illustrates a
The 1440 pulses per rotation (four pulses per crank angle) comparison of variations of injection delay and ignition
from a shaft encoder on the engine crankshaft were used as delay between DME engine and diesel fuel engine. With
the data acquisition clocking pulses to acquire the cylinder the decrease in engine load, the injection delay increases.
pressure data. Based on measured cylinder pressure, the At 100%, 75% and 50% engine load, the injection delay
heat release rate (HRR) is calculated and analyzed. NOx, increases by 36.4%, 43.5% and 46.2% respectively in
CO, HC, and CO2 emissions were measured by an AVL comparison with that of diesel fuel. Differences in
CEB serials gas analyzer. Smoke emission was tested by a acoustics velocity and injection delay between DME and
fully-automated fqd-102A smoke meter and PM was diesel fuel mainly result from the relatively larger
measured by an AVL 472 Smart Sampler PC. compressibility of DME.
Furthermore, as shown in Fig. 5, at 100%, 75% and 50%
engine load, the ignition delay decreases by 23.1%,
3 Results and discussion 21.15% and 18.5%, compared with diesel fuel, which is
thought to be caused by a higher cetane number of DME.
3.1 DME fuel injection As a result, since the increment in injection delay of DME
Fig. 3 Comparison of line pressure at nozzle side between DME Fig. 5 Variation of injection delay and ignition delay of DME in
and diesel fuel comparison with diesel fuel
102 Front. Energy Power Eng. China 2009, 3(1): 99–108
is larger than the reduction in ignition delay, it is found that different engine speeds. It can be seen that the peak value of
at the condition of the same fuel delivery advance angle, cylinder pressure and HRR of DME are lower than those of
the start of ignition timing of DME is retarded in diesel fuel and the phase of pressure and HRR rise are
comparison with diesel fuel. The retardation of ignition retarded in comparison with diesel fuel. At the condition of
timing of DME is more obvious as the engine load fuel delivery advance angle of 9° (CA BTDC), engine speed
decreases. of 800 r/min and full load, the maximum cylinder pressure is
8.2 MPa at 16° (CA ATDC) in the case of DME and
3.2 DME engine combustion and performance 10.1 MPa at 11° (CA ATDC) in the case of diesel fuel,
respectively, with a phase difference of 5° (CA). The
Engine combustion and performance fuelled with DME was maximum rate of pressure rise of DME is much lower than
further investigated in a D6114 turbocharged CI engine. that of diesel fuel. The same phenomena can be found at
Figure 6 shows the comparison of cylinder pressure, HRR, conditions of engine speeds of 1400 r/min and 2200 r/min,
accumulated heat release and rates of pressure rise between as shown in Fig. 6. The relatively low maximum cylinder
the DME engine and the diesel engine at full load and pressure, HRR and rate of pressure rise and phase
Fig. 6 Comparison of cylinder pressure, HRR, accumulated heat release and rates of pressure rise between DME engine and diesel engine
(for DME engine, plunger diameter = 12 mm, nozzle type: 60.40 mm)
(a) 800 r/min, pe = 0.87 MPa; (b) 1400 r/min, pe = 1.52 MPa; (c) 2200 r/min, pe= 1.21 MPa
Zhen HUANG et al. Dimethyl ether as alternative fuel 103
load. With the increase of engine load, the equivalent by 28.1%, in comparison with that of the diesel engine. At
BSFC of the DME engine tends to be higher than that of 2200 r/min, the NOx emission is reduced more signifi-
the diesel engine, especially at medium and high engine cantly for the DME engine. Reduction of NOx is mainly
load. Due to the lower heating value of DME, to keep the attributed to the physicochemical properties of DME. For
engine output the same as that of the diesel engine, about the DME engine, retardation of ignition timing due to
1.9 times as much as the diesel fuel volume should be longer fuel injection delay, shorter ignition delay due to
injected into the combustion chamber per cycle, which high cetane number and larger latent heat of DME lead to a
leads to prolonged injection duration and combustion decrease in cylinder pressure and local temperature which
duration at high engine speed, and results in the result in a reduction of NOx emission.
deterioration of fuel consumption of DME. The comparison of HC and CO emission between the
DME engine and the diesel engine under different engine
3.3 DME engine exhaust emissions loads at an engine speed of 1400 r/min and 2200 r/min is
shown in Figs. 10 and 11. HC emission of DME is
Figure 9 shows the comparison of NOx emission between significantly lower than that of diesel fuel at all test range
DME and diesel fuel under different engine loads and at of loads and speeds. Meanwhile, with the increase of
engine speeds of 1400 r/min and 2200 r/min. It is engine load, HC emission tends to decrease. It is supposed
illustrated that the DME engine exhibits substantial that the low boiling temperature and high vapor pressure of
reduction in NOx emission at all test range of loads and DME will promote fuel atomization, mixture formation
speeds. At the BMEP of 1.52 MPa and engine speed of and combustion which result in low HC emission.
1400 r/min, NOx emission of the DME engine is reduced CO emission of the DME engine is almost the same as
Fig. 9 Comparison of NOx emission between DME engine and diesel engine
(a) 1400 r/min; (b) 2200 r/min
that of the diesel engine at low engine load. It is interesting 3.4 Effects of EGR and DOC on emissions
to note that CO emission of the DME engine is higher than
that of the diesel engine at high and medium engine loads, In order to meet more stringent emission regulation, effects
with emission levels of 12010–6 to 22010–6. It is of exhaust gas recirculation (EGR) and oxidation catalyst
considered that rich burning of DME at high load results in converter (DOC) on exhaust emission were evaluated.
an increase of CO. However, further study is necessary to Figure 14(a) shows the effect of EGR rate on NOx emission
verify this possible mechanism. under different engine loads at the speed of 1400 r/min. It
The comparison of smoke emission between the DME is indicated that substantial reduction in NOx emission
engine and the diesel engine under different loads at an without smoke is obtained by means of EGR. With the
engine speed of 1400 r/min and 2200 r/min is indicated in increase of EGR rate, NOx emission is decreased
Fig. 12. DME presents almost zero emission of smoke at remarkably. In the case of BMEP of 1.52 MPa and 10%
all test engine loads and speeds. High oxygen content and EGR rate, the NOx is reduced by 51.8%. In the case of
absence of C–C bonds in the molecular structure of DME BMEP of 0.76 MPa and 25% EGR rate, the NOx is reduced
promises a smoke-free combustion. by 67.8%. With EGR, reduction of local temperature and
Figure 13 shows the results of ESC emission test of the oxygen concentration within the cylinder results in the
DME engine. Thirteen modes of ESC tests were suppression of NOx formation. EGR has influence on
conducted. The results show that without common rail engine fuel consumption, as shown in Fig. 14(b). At low
injection system, EGR and after-treatment system, NOx, load, the BSFC of the DME engine is improved with EGR.
HC, CO and PM emissions of the DME engine are 19.7%, At medium load, with the increase of EGR rate, the BSFC
80.5%, 62.5% and 50% below Euro III respectively. The first decreases, then increases when EGR rate is larger than
requirements for EURO III are satisfied with the DME 15%. At full load, when EGR rate is larger than 10%, the
engine with in-line fuel pump. The baseline diesel engine BSFC tends to deteriorate. It appears that there is no loss in
can only narrowly meet Europe II. fuel consumption for test EGR rate in the case of BMEP of
Fig. 12 Comparison of smoke emission between DME engine and diesel engine
(a) 1400 r/min; (b) 2200 r/min
106 Front. Energy Power Eng. China 2009, 3(1): 99–108
structure of DME with its high oxygen content promises The performance of the DME city bus is tested
high EGR tolerance. according to the national vehicle standard. Table 4 shows
Figure 15 further shows the effect of DOC on HC and the test results. The noise of acceleration of the DME bus is
CO emissions of the DME engine at different engine load 80.6 dB(A), which is 2.3 dB(A) lower than that of the
at the speed of 1400 r/min. It is illustrated that HC and CO baseline diesel bus. The noise within the bus is 77.8 dB(A),
emissions is reduced significantly with an emission level of which is 2.5 dB(A) lower than that of the baseline diesel
less than 1010–6 by means of DOC. For instance, in the bus. The maximum speed (25–60 km/h) and the accelera-
case of BMEP of 0.378 MPa, HC and CO emissions are tion time satisfy the requirements of the national standard.
reduced by 87% and 92% respectively. As a result, it is The fuel consumption of the DME bus was measured
believed that DME engine with EGR and DOC will satisfy under a condition of constant vehicle speed of 50 km/h.
more stringent emission regulation. The equivalent fuel consumption is 17.78 L/100 km, which
is better than that of the baseline diesel bus.
3.5 Performance of DME city bus
On the basis of DME engine research, a dedicated DME 4 Conclusions
fuel supply, injection and combustion system were
developed. In 2005, the first DME city bus in China was 1) The injection delay of DME is longer than that of
successfully developed in cooperation with Shanghai Auto diesel fuel due to the lower acoustics velocity resulting
Industry and Shanghai Diesel Works. In 2007, ten DME from the higher compressibility of DME. The ignition
city buses were manufactured by Shanghai Auto Industry delay of DME is shorter than that of diesel fuel due to the
for demonstration and public use, as shown in Fig. 16. higher cetane number of DME. Since the increment in
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test item DME national standard 2. Paul K, Herwig O. Development of fuel injection equipment and
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