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UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
GCE Advanced Subsidiary Level and GCE Advanced Level
9701 CHEMISTRY
9701/11
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the October/November 2011 question papers for most
IGCSE, GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
Page 2
www.maxpapers.com
Syllabus
9701
Question
Number
Key
Question
Number
Key
1
2
B
C
21
22
A
A
3
4
5
D
C
B
23
24
25
D
A
C
6
7
C
C
26
27
D
D
8
9
10
A
D
D
28
29
30
C
D
C
11
12
A
C
31
32
B
D
13
14
15
A
B
B
33
34
35
B
A
B
16
17
B
C
36
37
A
B
18
19
20
C
A
C
38
39
40
B
D
C
Paper
11
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UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
GCE Advanced Subsidiary Level and GCE Advanced Level
9701 CHEMISTRY
9701/12
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the October/November 2011 question papers for most
IGCSE, GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
Page 2
www.maxpapers.com
Syllabus
9701
Question
Number
Key
Question
Number
Key
1
2
A
A
21
22
C
D
3
4
5
D
C
C
23
24
25
A
B
B
6
7
B
D
26
27
A
A
8
9
10
C
D
A
28
29
30
B
D
A/B*
11
12
C
B
31
32
A
C
13
14
15
C
C
D
33
34
35
A
D
B
16
17
B
C
36
37
D
D
18
19
20
D
C
C
38
39
40
B
C
A
Paper
12
*This question contained some ambiguity. As a result, in this exceptional circumstance, answers A and B were both
credited.
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UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
GCE Advanced Subsidiary Level and GCE Advanced Level
9701 CHEMISTRY
9701/13
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the October/November 2011 question papers for most
IGCSE, GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
Page 2
www.maxpapers.com
Syllabus
9701
Question
Number
Key
Question
Number
Key
1
2
C
D
21
22
D
A
3
4
5
B
B
C
23
24
25
A
A
C
6
7
C
C
26
27
C
D
8
9
10
D
A
A
28
29
30
D
C
D
11
12
C
D
31
32
B
B
13
14
15
A
B
B
33
34
35
B
D
A
16
17
C
B
36
37
A
C
18
19
20
C
A
C
38
39
40
D
B
B
Paper
13
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UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
GCE Advanced Subsidiary Level and GCE Advanced Level
9701 CHEMISTRY
9701/21
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the October/November 2011 question papers for most
IGCSE, GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
www.maxpapers.com
Page 2
1
Syllabus
9701
Paper
21
(1)
(1)
(1)
(1)
(1)
(1)
[6]
(1)
[1]
(1)
= 59.89
allow 59.9 or 60
(ii) C2H4O2
(1)
(1)
[3]
(d) CH3CO2H
(1)
HCO2CH3
(1)
[2]
(1)
[1]
(e) the only products of the reaction are the two oxides H2O and CO2 and copper
[Total: 13]
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Page 3
Syllabus
9701
Paper
21
(1)
(1)
[2]
(1)
(1)
(1)
[3]
(1)
(1)
(ii) S and P
for S one 3p orbital has paired electrons and
for P 3p sub-shell is singly filled
(1)
(1)
[4]
Na
Mg
Al
Si
conductivity
high
high
moderate
low
low
melting point
low
high
high
low
low
(1)
(1)
(1)
(1)
(1)
[5]
(1)
[1]
[Total: 15]
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Page 4
3
Syllabus
9701
Paper
21
(1)
(1)
[2]
(1)
(1)
(1)
(1)
[4]
(1)
(1)
(1)
[3]
(2)
[2]
[Total: 11]
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Page 5
4
Syllabus
9701
Paper
21
(a)
CH3CH2CH=CH2
H2O(g)
H3PO4
MnO4 /H+
hot, concentrated
catalyst
CH3CH2CH2CH2OH
MnO4 /H+
cold, dilute
CH3CH2CO2H
or
CH3CH2CH(OH)CH3
U
T
CH3CH2CH(OH)CH2OH
Cr2O72 /H+
heat under reflux
CH3CH2COCO2H
W
correct T
correct U
correct V
correct > CO group in W
correct CO2H group in W
(1)
(1)
(1)
(1)
(1)
[5]
www.maxpapers.com
Page 6
Syllabus
9701
Paper
21
(b) T + U
or
correct structures
correctly displayed ester group
(1)
(1)
[2]
[Total: 7]
5
(a) (i) 1
2
primary
alcohol not hydroxyl
(1)
(1)
(1)
(ii)
test 1
reagent
Na
PCl3/PCl5/PBr3
RCO2H/H+
observation
gas/H2/effervescence/
fizzing
HCl/HBr
steamy fumes
fruity smell
reagent
Tollens reagent
Fehlings reagent
2,4-dinitrophenylhydrazine
observation
Ag mirror/silver/
black ppt
brick-red ppt
red ppt
orange/red/yellow
ppt/solid
test 2
(4)
[7]
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Page 7
Syllabus
9701
Paper
21
(b) (i)
(1)
(ii)
(1)
5
(c)
starting
compound
first
reagent
intermediate
X
A/1
HOCH2CHO
PCl3
PCl5
SOCl2
etc.
ClCH2CHO
A/2
HOCH2CHO
HBr
P/Br2
etc.
BrCH2CHO
route
[2]
B/1
HOCH2CHO
PCl3
PCl5
SOCl2
etc.
B/2
HOCH2CHO
HBr
P/Br2
etc.
second
reagent
K2Cr2O7/H+
KMnO4/H+
KMnO4/OH
Tollens' or
Fehling's
reagents
K2Cr2O7/H+
KMnO4/H+
KMnO4/OH
Tollens' or
Fehling's
reagents
ClCH2CHO
NH3
BrCH2CHO
NH3
intermediate
Y
third
reagent
final
compound
ClCH2CO2H
NH3
H2NCH2CO2H
BrCH2CO2H
NH3
H2NCH2CO2H
K2Cr2O7/H+
KMnO4/H+
KMnO4/OH
H2NCH2CHO
Tollens' or
Fehling's
reagents
K2Cr2O7/H+
KMnO4/H+
KMnO4/OH
H2NCH2CHO
Tollens' or
Fehling's
reagents
Tollens'
or
HOCH2CO2H
HOCH2CHO
Fehling's
reagents
KBr/conc.
H2SO4
BrCH2CO2H
NH3
mark
(1)
(1)
(1)
(1)
(1)
H2NCH2CO2H
H2NCH2CO2H
H2NCH2CO2H
[5]
[Total: 14]
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UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
GCE Advanced Subsidiary Level and GCE Advanced Level
9701 CHEMISTRY
9701/22
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the October/November 2011 question papers for most
IGCSE, GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
www.maxpapers.com
Page 2
1
Syllabus
9701
Paper
22
(1)
(1)
(1)
(1)
(1)
(1)
[6]
(1)
[1]
(1)
= 59.89
allow 59.9 or 60
(ii) C2H4O2
(1)
(1)
[3]
(d) CH3CO2H
(1)
HCO2CH3
(1)
[2]
(1)
[1]
(e) the only products of the reaction are the two oxides H2O and CO2 and copper
[Total: 13]
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Page 3
Syllabus
9701
Paper
22
(1)
(1)
[2]
(1)
(1)
(1)
[3]
(1)
(1)
(ii) S and P
for S one 3p orbital has paired electrons and
for P 3p sub-shell is singly filled
(1)
(1)
[4]
Na
Mg
Al
Si
conductivity
high
high
moderate
low
low
melting point
low
high
high
low
low
(1)
(1)
(1)
(1)
(1)
[5]
(1)
[1]
[Total: 15]
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Page 4
3
Syllabus
9701
Paper
22
(1)
(1)
[2]
(1)
(1)
(1)
(1)
[4]
(1)
(1)
(1)
[3]
(2)
[2]
[Total: 11]
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Page 5
4
Syllabus
9701
Paper
22
(a)
CH3CH2CH=CH2
H2O(g)
H3PO4
MnO4 /H+
hot, concentrated
catalyst
CH3CH2CH2CH2OH
MnO4 /H+
cold, dilute
CH3CH2CO2H
or
CH3CH2CH(OH)CH3
U
T
CH3CH2CH(OH)CH2OH
Cr2O72 /H+
heat under reflux
CH3CH2COCO2H
W
correct T
correct U
correct V
correct > CO group in W
correct CO2H group in W
(1)
(1)
(1)
(1)
(1)
[5]
www.maxpapers.com
Page 6
Syllabus
9701
Paper
22
(b) T + U
or
correct structures
correctly displayed ester group
(1)
(1)
[2]
[Total: 7]
5
(a) (i) 1
2
primary
alcohol not hydroxyl
(1)
(1)
(1)
(ii)
test 1
reagent
Na
PCl3/PCl5/PBr3
RCO2H/H+
observation
gas/H2/effervescence/
fizzing
HCl/HBr
steamy fumes
fruity smell
reagent
Tollens reagent
Fehlings reagent
2,4-dinitrophenylhydrazine
observation
Ag mirror/silver/
black ppt
brick-red ppt
red ppt
orange/red/yellow
ppt/solid
test 2
(4)
[7]
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Page 7
Syllabus
9701
Paper
22
(b) (i)
(1)
(ii)
(1)
5
(c)
starting
compound
first
reagent
intermediate
X
A/1
HOCH2CHO
PCl3
PCl5
SOCl2
etc.
ClCH2CHO
A/2
HOCH2CHO
HBr
P/Br2
etc.
BrCH2CHO
route
[2]
B/1
HOCH2CHO
PCl3
PCl5
SOCl2
etc.
B/2
HOCH2CHO
HBr
P/Br2
etc.
second
reagent
K2Cr2O7/H+
KMnO4/H+
KMnO4/OH
Tollens' or
Fehling's
reagents
K2Cr2O7/H+
KMnO4/H+
KMnO4/OH
Tollens' or
Fehling's
reagents
ClCH2CHO
NH3
BrCH2CHO
NH3
intermediate
Y
third
reagent
final
compound
ClCH2CO2H
NH3
H2NCH2CO2H
BrCH2CO2H
NH3
H2NCH2CO2H
K2Cr2O7/H+
KMnO4/H+
KMnO4/OH
H2NCH2CHO
Tollens' or
Fehling's
reagents
K2Cr2O7/H+
KMnO4/H+
KMnO4/OH
H2NCH2CHO
Tollens' or
Fehling's
reagents
Tollens'
or
HOCH2CO2H
HOCH2CHO
Fehling's
reagents
KBr/conc.
H2SO4
BrCH2CO2H
NH3
mark
(1)
(1)
(1)
(1)
(1)
H2NCH2CO2H
H2NCH2CO2H
H2NCH2CO2H
[5]
[Total: 14]
www.maxpapers.com
UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
GCE Advanced Subsidiary Level and GCE Advanced Level
9701 CHEMISTRY
9701/23
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the October/November 2011 question papers for most
IGCSE, GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
www.maxpapers.com
Page 2
1
Syllabus
9701
Paper
23
(1)
(1)
(1)
[2]
(1)
[2]
(3 1)
[3]
(c)
number of
isotopes
protons
neutrons
electrons
84
129
84
90
142
90
213
Po
232
Th
(1)
(1)
(1)
[3]
[Total: 10]
2
(1)
(1)
(1)
(1)
(1)
[5]
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Page 3
Syllabus
9701
Paper
23
(1)
(1)
(1)
(ii)
(1)
(iii)
(1)
(1)
(1)
[7]
[Total: 12]
(1)
(1)
(1)
(1)
(1)
(1)
[2]
www.maxpapers.com
Page 4
Syllabus
9701
(iii) He and Ne
both He and Ne have the highest nuclear charges in their Period
Paper
23
(1)
(1)
(1)
(1)
(1)
(1)
(1)
[8]
[3]
NaOH(aq)
NO REACTION
(1)
MgO(s)
2HCl(aq)
MgCl2 + H2O
(1)
Al2O3(s)
2NaOH(aq)
3H2O(l)
2NaAl(OH)4 or
Al2O3(s)
2NaOH(aq)
H2O(l)
2NaAlO2 + 2H2O or
Al2O3(s)
6NaOH(aq)
3H2O(l)
2Na3Al(OH)6
Al2O3(s)
6HCl(aq)
2AlCl3 + 3H2O or
Al2O3(s)
6HCl(aq)
Al2Cl6 + 3H2O
SO2(g)
NaOH(aq)
NaHSO3 or
SO2(g)
2NaOH(aq)
Na2SO3 + H2O
SO2(g)
HCl(aq)
NO REACTION
(1)
(1)
(1)
(1)
[6]
[Total: 19]
4
(1)
(ii)
(1)
[2]
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Page 5
Syllabus
9701
Paper
23
(1)
type of isomerism
cis-trans or geometrical
optical
(1 + 1)
[3]
(1)
(1)
(iii) CH2=CHCH=CH2
allow CH2=C=CHCH3
(d) (i) CH3CH2CH(OH)CH2CH3
(ii) steam
conc. H2SO4
(1)
[3]
(1)
(1 + 1)
(1)
[4]
[Total: 12]
5
(a) V is HCHO
(1)
(1)
(ii) W is HCO2CH3
(c) (i) X is HOCH2CH2CO2H
(ii) Y is HO2CCH2CO2H
(1)
[1]
[2]
(1)
(1)
[2]
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Page 6
Syllabus
9701
Paper
23
(d) (i) Z is
(1)
(ii) esterification or
dehydration or
elimination or
condensation
(1)
[2]
[Total: 7]
www.maxpapers.com
UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
GCE Advanced Subsidiary Level and GCE Advanced Level
9701 CHEMISTRY
9701/31
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the October/November 2011 question papers for most
IGCSE, GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
www.maxpapers.com
Page 2
Syllabus
9701
Paper
31
Question
Sections
Indicative material
PDO
Recording
ACE
Interpretation
II
MMO Quality
II
(a)
(b)
PDO Layout
Mark
[7]
1
[4]
intersect.
(c)
ACE
Interpretation
[1]
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Page 3
(d)
(e)
(f)
(g)
(h)
(i)
(j)
(k)
ACE
Conclusions
ACE
Interpretation
Syllabus
9701
Paper
31
II
II
25 2 = 0.05
1000
ACE
Interpretation
[2]
[2]
[1]
ACE
Interpretation
PDO Display
II
PDO Display
ACE
Interpretation
II
ACE
Conclusions
ACE
Improvements
ACE
Conclusions
[2]
[1]
[2]
II
[1]
[2]
[Total: 25]
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Page 4
Syllabus
9701
Paper
31
(a)
MMO
Decisions
(i)
PDO
Recording
(ii) II
MMO
Collection
III Bubbles/effervescence in FA 4.
(b)
MMO
Decisions
ACE
Conclusions
MMO
Collection
observations.
FA3 is a sulfite.
FA4 is a carbonate.
FA5 is a sulfate.
(or correct formulae)
(i)
[6]
1
[6]
observations.
(ii) Lead/Pb2+ provided correct observations with
FA 6 + NaOH and
FA 6 + FA 5 (sulfate).
(iii) I
[1]
[2]
[Total: 15]
www.maxpapers.com
UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
GCE Advanced Subsidiary Level and GCE Advanced Level
9701 CHEMISTRY
9701/33
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the October/November 2011 question papers for most
IGCSE, GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
www.maxpapers.com
Page 2
Syllabus
9701
Paper
33
Question
Sections
Indicative material
PDO
Recording
ACE
Interpretation
II
MMO Quality
II
(a)
(b)
PDO Layout
Mark
[7]
1
[4]
intersect.
(c)
ACE
Interpretation
[1]
www.maxpapers.com
Page 3
(d)
(e)
(f)
(g)
(h)
(i)
(j)
(k)
ACE
Conclusions
ACE
Interpretation
Syllabus
9701
Paper
33
II
II
25 2 = 0.05
1000
ACE
Interpretation
[2]
[2]
[1]
ACE
Interpretation
PDO Display
II
PDO Display
ACE
Interpretation
II
ACE
Conclusions
ACE
Improvements
ACE
Conclusions
[2]
[1]
[2]
II
[1]
[2]
[Total: 25]
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Page 4
Syllabus
9701
Paper
33
(a)
MMO
Decisions
(i)
PDO
Recording
(ii) II
MMO
Collection
III Bubbles/effervescence in FA 4.
(b)
MMO
Decisions
ACE
Conclusions
MMO
Collection
observations.
FA3 is a sulfite.
FA4 is a carbonate.
FA5 is a sulfate.
(or correct formulae)
(i)
[6]
1
[6]
observations.
(ii) Lead/Pb2+ provided correct observations with
FA 6 + NaOH and
FA 6 + FA 5 (sulfate).
(iii) I
[1]
[2]
[Total: 15]
www.maxpapers.com
UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
GCE Advanced Subsidiary Level and GCE Advanced Level
9701 CHEMISTRY
9701/34
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the October/November 2011 question papers for most
IGCSE, GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
www.maxpapers.com
Page 2
Syllabus
9701
Paper
34
Question
Sections
Indicative material
MMO
Collection
PDO
Collection
II
ACE
Interpretation
MMO Quality
(a)
Mark
(b)
PDO Display
II
IV
[8]
[4]
www.maxpapers.com
Page 3
(c)
ACE
Interpretation
(i)
(ii) II
Syllabus
9701
V
(v) VI
1
1
(e)
Paper
34
ACE
Interpretation
ACE
Improvements
ACE
Interpretation
(i)
[7]
[2]
II
PDO Display
Decisions
1
[4]
[Total: 25]
* e.g.
1st mark
2nd mark
www.maxpapers.com
Page 4
Syllabus
9701
Paper
34
(a)
PDO
Recording
(i)
MMO
Collection
II
Solution
FB 3
III FB 4
IV FB 5
H2SO4
Pb(NO3)2
white ppt
FB 3
yellow ppt
FB 4
FB 5
white ppt
ACE
Conclusions
MMO
Decisions
Collection
II
ACE
Conclusions
(b)
(i)
MMO
Collection
1
[6]
1
1
III FB 5 bromide/Br from cream ppt (or offwhite ppt insol or partially soluble in NH3)
(ii) II
[3]
(i) FB 6 is a catalyst
Allow O2 formed or H2O2 decomposes if
glowing splint test correct.
1
[6]
[Total: 15]
www.maxpapers.com
UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
GCE Advanced Subsidiary Level and GCE Advanced Level
9701 CHEMISTRY
9701/35
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the October/November 2011 question papers for most
IGCSE, GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
www.maxpapers.com
Page 2
Syllabus
9701
Paper
35
Question
Sections
Indicative material
PDO Layout
Recording
II
(a)
Mark
0.5C.
(Must have at least one at 0.5C.)
MMO
Decisions
(b)
[5]
ACE
Interpretation
PDO Display
MMO Quality
II
1
1
1
1
[6]
www.maxpapers.com
Page 3
(c)
(d)
(e)
(f)
(g)
(h)
PDO Layout
(i)
Syllabus
9701
Paper
35
ACE
Interpretation
PDO Display
ACE
Conclusions
ACE
Interpretation
(i)
Same volume FA 2.
ACE
Interpretation
ACE
Improvements
ACE
Improvements
[4]
[2]
[2]
[1]
[1]
[3]
[Total: 24]
www.maxpapers.com
Page 4
Syllabus
9701
Paper
35
(a)
MMO
Decisions
(i)
PDO Layout
(ii) II
MMO
Collection
effervescence or effervescence.
MMO
Collection
FA 3 + FA 4 white ppt.
II
1
[4]
(iii).
(c)
MMO
Collection
[2]
www.maxpapers.com
Page 5
(d)
ACE
Conclusions
Syllabus
9701
Paper
35
SO32 (1).
Evidence: formation SO2 in (a) or (b) (1).
(e)
MMO
Decisions
[4]
1
[1]
[Total: 16]
www.maxpapers.com
UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
GCE Advanced Subsidiary Level and GCE Advanced Level
9701 CHEMISTRY
9701/36
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the October/November 2011 question papers for most
IGCSE, GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
www.maxpapers.com
Page 2
Syllabus
9701
Paper
36
Question
Sections
Indicative material
PDO Layout
PDO
Recording
MMO Decision
MMO
Collection
(a)
(b)
(c)
[3]
[2]
ACE
Interpretation
PDO
Recording
PDO Display
(i)
(ii)
(d)
Mark
[2]
[2]
www.maxpapers.com
Page 3
(e)
PDO Layout
Syllabus
9701
Paper
36
II
ACE
Conclusion
ACE
Improvement
MMO Decision
ACE
Interpretation
ACE
Conclusion
MMO Quality
(f)
(g)
(h)
[8]
[3]
[2]
[1]
www.maxpapers.com
Page 4
(i)
ACE
Interpretation
Syllabus
9701
Paper
36
[2]
[Total: 25]
(a)
MMO Decision
(i)
MMO
Collection
(c)
MMO
Collection
PDO
Recording
[4]
FB 6 + FB 4 effervescence/bubbling.
FB 4 no change scores 1.
[3]
[4]
www.maxpapers.com
Page 5
(d)
ACE
Conclusions
Syllabus
9701
Paper
36
Evidence: yellow ppt and white ppt with NaOH or NH3 (1)
2
3+
or Pb
2+
[4]
[Total: 15]
www.maxpapers.com
UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
GCE Advanced Level
9701 CHEMISTRY
9701/41
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the October/November 2011 question papers for most
IGCSE, GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
www.maxpapers.com
Page 2
1
Syllabus
9701
Paper
41
(a) (i) either burn or shine light/uv on mixture of H2 + Cl2 but NOT heat
[1]
[2]
Cl-Cl = 244
H-Cl = 431
= 182 kJ mol
Br-Br = 193
[2]
H-Br = 366
= 103 kJ mol
[2]
(iv) H-Br bond is weaker than the H-Cl bond allow converse.
[1]
[8]
[1]
[2]
(iii) The overall reaction is endothermic or no strong bonds/only weak bonds are
formed or high Eact
(c) (i) homolytic fission is the breaking of a bond to form (two) radicals/neutral species/
odd-electron species
(ii) CH2Cl
the C-Br bond is the weakest or needs least energy to break/breaks most easily
(d)
Cl
Cl
Cl
Cl
Cl
Cl
Cl
[1]
[4]
[1]
[1]
[1]
[3]
Cl
4 structures: [2]
2 or 3 structures: [1]
Correct chiral atom identified
[1]
[3]
[Total: 18]
www.maxpapers.com
Page 3
2
Syllabus
9701
Paper
41
[1]
[1]
[1]
[1]
[1]
[1]
[6]
(b)
[CH3CHO]
/mol dm 3
[CH3OH]
/mol dm 3
[H+]
/mol dm
at start
0.20
0.10
at equilibrium
(0.20 x)
at equilibrium
0.175
[acetal A]
/mol dm 3
[H2O]
/mol dm
0.05
0.00
0.00
(0.10 2x)
0.05
0.05
0.05
0.025
0.025
3 x [1]
4 x [1]
[1]
[1]
[1]
[max 9]
[Total: 15]
www.maxpapers.com
Page 4
Syllabus
9701
Paper
41
dxy
energy
[1]
O
O
[1]
[1]
[7]
[1]
(iii)
[1]
[1]
[1]
O
Fe
O
O
O
O
[2]
[2]
[max 5]
[Total: 14]
www.maxpapers.com
Page 5
Syllabus
9701
Paper
41
[1]
(ii)
most basic
ethylamine
least basic
ammonia
phenylamine
[1]
[1]
[1]
[4]
[1]
[1]
[1]
[1]
[1]
[5]
[1]
(ii)
reaction
reagent(s)
Step 1
NaNO2 + HCl
or HNO2 [1]
Step 2
H2O / aq
Step 3
HNO3
NB HNO3(aq) OK for both
conditions
T < 10C
heat/boil/T > 10
dilute
[1]
(both) [1]
(both) [1]
[4]
[5]
[Total: 14]
www.maxpapers.com
Page 6
5
Syllabus
9701
Paper
41
(b)
4 [1]
[4]
O
CO2H
O
2 [1]
[2]
(c) isomers of C
OH
OH
cis
trans
[1]
[1]
[1]
[3]
[Total: 9]
www.maxpapers.com
Page 7
Syllabus
9701
Paper
41
[1]
[1]
[2]
[1]
[1]
type of bonding
HNCH(CH2CH2CH2CH2NH2)CO
HNCH(CH2CH2CO2H)CO
HNCH(CH3)CO
HNCH(CH3)CO
HNCH(CH2SH)CO
HNCH(CH2SH)CO
Disulfide bonds
HNCH(CH2OH)CO
HNCH(CH2CO2H)CO
Hydrogen bonds
[4]
[Total: 10]
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Page 8
7
Syllabus
9701
Paper
41
(a) Sketch and label the apparatus used to carry out electrophoresis e.g
Marks: power supply / electrolyte + filter paper / buffer / acid mixture central
(c) (i) They have insufficient electron density / only one electron
(ii) Sulfur
because it has the greatest atomic number / number of electrons
4 [1]
[4]
[1]
[1]
[1]
[1]
[1]
[1]
(max 3)
[max 3]
[1]
[1]
[1]
[3]
[Total: 10]
www.maxpapers.com
Page 9
8
Syllabus
9701
Paper
41
(a)
traditional material
Paper/cardboard/wood/leaves
hessian/hemp/jute
steel/aluminium
PVC in packaging
Cotton/wool/linen
Terylene in fabrics
Glass/china/porcelain/earthenware
metal/leather
Polycarbonate bottle
3 2 marks, 2 1 mark
[2]
(b) Reasons: Plastics/polymers pollute the environment for a long time do not decompose/
biodegrade quickly
[1]
They are mainly produced from oil
[1]
Produce toxic gases on burning
[1]
max two
Strategy 1: Recycle polymer waste / use renewable resources
Strategy 2: Develop biodegradable polymers
(c) PVC
Combustion would produce HCl / dioxins as a pollutant
or
nylon/acrylic
Combustion would produce HCN
[1]
[1]
[max 3]
[1]
[1]
[1]
[1]
[2]
[1]
[1]
[1]
[3]
[Total: 10]
www.maxpapers.com
UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
GCE Advanced Level
9701 CHEMISTRY
9701/42
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the October/November 2011 question papers for most
IGCSE, GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
www.maxpapers.com
Page 2
1
Syllabus
9701
Paper
42
(a) (i) either burn or shine light/uv on mixture of H2 + Cl2 but NOT heat
[1]
[2]
Cl-Cl = 244
H-Cl = 431
= 182 kJ mol
Br-Br = 193
[2]
H-Br = 366
= 103 kJ mol
[2]
(iv) H-Br bond is weaker than the H-Cl bond allow converse.
[1]
[8]
[1]
[2]
(iii) The overall reaction is endothermic or no strong bonds/only weak bonds are
formed or high Eact
(c) (i) homolytic fission is the breaking of a bond to form (two) radicals/neutral species/
odd-electron species
(ii) CH2Cl
the C-Br bond is the weakest or needs least energy to break/breaks most easily
(d)
Cl
Cl
Cl
Cl
Cl
Cl
Cl
[1]
[4]
[1]
[1]
[1]
[3]
Cl
4 structures: [2]
2 or 3 structures: [1]
Correct chiral atom identified
[1]
[3]
[Total: 18]
www.maxpapers.com
Page 3
2
Syllabus
9701
Paper
42
[1]
[1]
[1]
[1]
[1]
[1]
[6]
(b)
[CH3CHO]
/mol dm 3
[CH3OH]
/mol dm 3
[H+]
/mol dm
at start
0.20
0.10
at equilibrium
(0.20 x)
at equilibrium
0.175
[acetal A]
/mol dm 3
[H2O]
/mol dm
0.05
0.00
0.00
(0.10 2x)
0.05
0.05
0.05
0.025
0.025
3 x [1]
4 x [1]
[1]
[1]
[1]
[max 9]
[Total: 15]
www.maxpapers.com
Page 4
Syllabus
9701
Paper
42
dxy
energy
[1]
O
O
[1]
[1]
[7]
[1]
(iii)
[1]
[1]
[1]
O
Fe
O
O
O
O
[2]
[2]
[max 5]
[Total: 14]
www.maxpapers.com
Page 5
Syllabus
9701
Paper
42
[1]
(ii)
most basic
ethylamine
least basic
ammonia
phenylamine
[1]
[1]
[1]
[4]
[1]
[1]
[1]
[1]
[1]
[5]
[1]
(ii)
reaction
reagent(s)
Step 1
NaNO2 + HCl
or HNO2 [1]
Step 2
H2O / aq
Step 3
HNO3
NB HNO3(aq) OK for both
conditions
T < 10C
heat/boil/T > 10
dilute
[1]
(both) [1]
(both) [1]
[4]
[5]
[Total: 14]
www.maxpapers.com
Page 6
5
Syllabus
9701
Paper
42
(b)
4 [1]
[4]
O
CO2H
O
2 [1]
[2]
(c) isomers of C
OH
OH
cis
trans
[1]
[1]
[1]
[3]
[Total: 9]
www.maxpapers.com
Page 7
Syllabus
9701
Paper
42
[1]
[1]
[2]
[1]
[1]
type of bonding
HNCH(CH2CH2CH2CH2NH2)CO
HNCH(CH2CH2CO2H)CO
HNCH(CH3)CO
HNCH(CH3)CO
HNCH(CH2SH)CO
HNCH(CH2SH)CO
Disulfide bonds
HNCH(CH2OH)CO
HNCH(CH2CO2H)CO
Hydrogen bonds
[4]
[Total: 10]
www.maxpapers.com
Page 8
7
Syllabus
9701
Paper
42
(a) Sketch and label the apparatus used to carry out electrophoresis e.g
Marks: power supply / electrolyte + filter paper / buffer / acid mixture central
(c) (i) They have insufficient electron density / only one electron
(ii) Sulfur
because it has the greatest atomic number / number of electrons
4 [1]
[4]
[1]
[1]
[1]
[1]
[1]
[1]
(max 3)
[max 3]
[1]
[1]
[1]
[3]
[Total: 10]
www.maxpapers.com
Page 9
8
Syllabus
9701
Paper
42
(a)
traditional material
Paper/cardboard/wood/leaves
hessian/hemp/jute
steel/aluminium
PVC in packaging
Cotton/wool/linen
Terylene in fabrics
Glass/china/porcelain/earthenware
metal/leather
Polycarbonate bottle
3 2 marks, 2 1 mark
[2]
(b) Reasons: Plastics/polymers pollute the environment for a long time do not decompose/
biodegrade quickly
[1]
They are mainly produced from oil
[1]
Produce toxic gases on burning
[1]
max two
Strategy 1: Recycle polymer waste / use renewable resources
Strategy 2: Develop biodegradable polymers
(c) PVC
Combustion would produce HCl / dioxins as a pollutant
or
nylon/acrylic
Combustion would produce HCN
[1]
[1]
[max 3]
[1]
[1]
[1]
[1]
[2]
[1]
[1]
[1]
[3]
[Total: 10]
www.maxpapers.com
UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
GCE Advanced Level
9701 CHEMISTRY
9701/43
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the October/November 2011 question papers for most
IGCSE, GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
www.maxpapers.com
Page 2
1
(a) Cr3+:
Mn2+:
Syllabus
9701
Paper
43
[1]
[1]
[2]
[1]
[1]
[4]
[1]
[1]
[1]
(ii) No effect, because H+ does not appear in the overall equation or its effect on the
MnO2/Mn2+ change is cancelled out by its effect on the SO2/SO42 change
[1]
[4]
(d) (i) MnO2 + 4H+ + Sn2+ Mn2+ + 2H2O + Sn4+
(ii) n(MnO4 ) = 0.02 18.1/1000 = 3.62 10 4 mol
n(Sn2+) = 3.62 10 4 5/2 = 9.05 10 4 mol
n(Sn2+) that reacted with MnO2 = (20 9.05) 10 4 = 1.095 10 3 mol
reaction is 1:1, so this is also n(MnO2)
mass of MnO2 = 1.095 10 3 (54.9+16+16) = 0.0952 g
95% 96%; 2 or more s.f.
[1]
[1]
[1]
[1]
[1]
[1]
[6]
[Total: 16]
www.maxpapers.com
Page 3
2
Syllabus
9701
Paper
43
(a) (i) A molecule/ion/species with a lone pair (of electrons) or electron pair donor...
.... that bonds to a metal ion/transition element....
[1]
[1]
[2]
(b) (i) straight line from (0, 0.01) to point at (350, 0.0028) with all points on the line
[1]
[1]
[1]
3
[1]
(v) N.B. the chosen mechanism must be consistent with the rate equation in (iii). Thus:
either if rate = k[Cr(CO)6]
mechanism B is consistent
[1]
because its the only mechanism that does NOT involve PR3 in its slow/rate-determining
step or only Cr(CO)6 is involved in slow step or [PR3] does not affect the rate
[1]
or
if rate = k[Cr(CO)6][PR3], then
mechanism A or C or D is consistent
because both reactants are involved in slow step
[1]
[1]
[9]
[Total: 11]
www.maxpapers.com
Page 4
3
Syllabus
9701
Paper
43
[1]
(ii) C6H5CH2CHO
[1]
[2]
O
N
H
[1]
[1]
Allow peptide bond shown in full (C=O) in a dipeptide ala-ala for 1 mark
H2N
O
N
H
OH
O
[3]
(c) (i) HCl or H2SO4 or NaOH or H+ or OH reagents
+ heat and H2O/aq (allow H3O+).
If T is quoted, 80 oC < T < 120 oC. NOT warm. conditions
(ii)
H2N
CO2H
[1]
[1]
CO2H
and
NH2
HO2C
(if a structural formula, it must have all H atoms) allow protonated or deprotonated
versions
[1] + [1]
[max 3]
www.maxpapers.com
Page 5
Syllabus
9701
Paper
43
[1]
(ii)
compound
H 2N
zwitterion
CO2H
H3N
CO2
OH
NH2CH3
NHCH3
HO
SO2
NH2
NH3
SO2
[3]
[4]
(e) (i) A buffer is a solution whose pH stays fairly constant or which maintains roughly the
same pH or which resists/minimises changes in pH
[1]
when small/moderate amounts of acid/H+ or alkali/OH are added
[1]
(ii) NH2CH(CH3)CO2H + H(Cl) +NH3CH(CH3)CO2H (+ Cl )
[1]
[1]
[1]
[1]
[1]
[7]
[Total: 19]
www.maxpapers.com
Page 6
Syllabus
9701
Paper
43
[1]
[1]
(b) (down the group) nitrates become more stable or require a higher temperature to
decompose
[1]
as size/radius of (cat)ion increases or charge density of ion decreases
[1]
so polarisation/distortion of anion/nitrate decreases
[1]
[3]
(c) (i) Li2CO3 Li2O + CO2
[1]
(ii) radius of Li ion/Li+ is less than that of Na ion/Na+ (or polarising power of M+ is greater) [1]
(iii) Brown/orange fumes/gas would be evolved or glowing splint relights
[1]
Since the nitrate is likely to be thermally unstable or decomposes (just like the
carbonate) or the balanced equation: 2LiNO3 Li2O + 2NO2 + O2
[1]
[4]
[Total: 8]
www.maxpapers.com
Page 7
5
Syllabus
9701
Paper
43
[1]
[1]
Cl2 2Cl
Cl + C2H6 C2H5 + HCl
C2H5 + Cl2 C2H5Cl + Cl
C2H5 + Cl C2H5Cl
or Cl + Cl Cl2 etc
[1]
[1]
[1]
[1]
all 3 names [1]
(iii)
structural formula of by-product
formed by
further substitution
CH3CH2CH2CH3
(termination of 2 ) C2H5
[3]
accept in the formed by column the formulae of radicals that will produce the
compound in the by-product column, or the reagents, e.g. C4H9 + Cl2 or C4H9 + Cl or
C4H10 + Cl2 (giving CH3CH2CH2CH2Cl).
do not allow anything more Clsubstituted than dichlorobutane.
N.B. C2H5Cl is the major product, not a by-product, so do not allow C2H5Cl.
(iv) J/K = 2.3 : 1 or 7:3 or 21:9
[2]
(reason: straightforward relative rate suggests 21:1, but there are 9 primary to 1 tertiary,
so divide this ratio by 9. 21/9 = 2.33)
allow [1] mark if J/K ratio is given as 21:1;
[10]
(c)
Cl
Cl
Cl
Cl
4 isomers 4 [1]
[1] + [1]
[max 5]
[Total: 16]
www.maxpapers.com
Page 8
6
Syllabus
9701
Paper
43
(a) (i) K, because it is the (only) one to contain nitrogen or its an amino acid
or because it contains CO2H or NH groups
(ii)
or
molecule: J,
molecule: L,
[1]
[1]
[2]
[1]
[1]
[1]
[3]
[1]
(ii) change in pH
increase in T (NOT decrease; T > 40 oC or too high are OK)
addition of heavy metal ions or specific, e.g. Hg2+, Ag+. Pb2+ etc.
any two bullet points [1] + [1]
change in pH disrupts ionic bonds
or metal ions disrupt ionic bonds
or metal ions disrupt SS bonds
or heating disrupts hydrogen bonds
any one [1]
This changes: the 3D structure or shape of the enzyme or the active site
[1]
[max 4]
[Total: 9]
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Page 9
7
Syllabus
9701
Paper
43
(a)
structural information
analytical technique
three-dimensional
arrangement of atoms and
bonds in a molecule
X-ray crystallography/diffraction
chemical environment of
protons in a molecule
Electrophoresis / chromatography /
mass spectrometry
[1] + [1] + [1]
[3]
0.2 100
= 3.08 hence 3 carbons
5.9 1.1
(ii) Bromine
[1]
[1]
(iii) One bromine is present as there is only an M+2 peak / no M+4 peak or the M and M+2
peaks are of similar height
[1]
(iv) NMR spectrum shows a single hydrogen split by many adjacent protons and 6 protons in
an identical chemical environment. This suggests...
two CH3 groups and a lone proton attached to the central carbon atom
[1]
Empirical formula of N is C3H7Br
[1]
Hence N is (CH3)2CHBr or
H
CH3
CH3
Br
[1]
[6]
[Total: 11]
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Page 10
8
Syllabus
9701
Paper
43
[1]
[1]
(iii) The gel coat stops it being broken down while passing through the upper part of the
digestive system/stomach
or the gel coat is stable to stomach acid.
[1]
[3]
(b) The drug is taken quickly/directly to the target
or more accurate dosing can be achieved
[1]
When the drug is taken by mouth it has to pass through the stomach/intestine wall to get into
the bloodstream. or some is digested/lost to the system
[1]
[2]
(c) (i) condensation (polymerisation)
(ii) hydrogen bonds or van der Waals
(iii) It would change the overall shape of the (drug) molecule
The fit into the active site would be less effective
(iv) Hydrolysis
[1]
[1]
[1] + [1]
[1]
[5]
[Total: 10]
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UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
GCE Advanced Level
9701 CHEMISTRY
9701/51
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the October/November 2011 question papers for most
IGCSE, GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
www.maxpapers.com
Page 2
Question
1
(a)
(b)
PLAN
Problem
Syllabus
9701
Paper
51
Indicative material
Mark
[1]
[1]
[1]
(i)
[1]
[1]
www.maxpapers.com
Page 3
(c)
Syllabus
9701
Paper
51
There are four different approaches, all of which share the first
five marking points.
Use 7 number labelled ticks and crosses for these points.
(i)
At least 5 experiments.
[1]
[1]
[1]
[1]
(v) stirs
[1]
Alternate 1
(vi) Heat mixture to dissolve all the solute.
[1]
[1]
OR Alternate 2
(vi) Heats mixture to a particular temperature.
(vii) Filters the solution (not cooled or decanted) and weighs
the residue.
OR Alternate 3
(vi) Heats mixture to a particular temperature.
(vii) filters the solution (not cooled or decanted) and evaporates
the filtrate and weighs solid.
OR Alternate 4
(vi) Heats mixture to dissolve the solute.
(vii) Records temperature at which the solute dissolves.
(d)
PLAN
Methods
[1]
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Page 4
(e)
Syllabus
9701
Paper
51
Total
Question
2
(a)
[15]
Sections
ACE
Data
Indicative material
Mark
[1]
[1]
[1]
ACE
Data
[1]
[1]
[1]
www.maxpapers.com
Page 5
(c)
Syllabus
9701
Paper
51
[1]
[1]
[1]
ACE
Evaluation
[1]
ACE
Data
[1]
[1]
ACE
Correct calculation. Any calculation that has slope above
Conclusions multiplied by 19 i.e. EA = slope 19. Or slope = EA/19.
Ignore units. Also accept that calculation subsequently divided
by 1000 i.e. about 19950 or 19.95. T is not in this calculation.
[1]
ACE
Increased K.E/energy/speed.
Conclusions
More collisions/unit time or more frequent collisions or more
chance of collisions or more energetic collisions or more
collisions exceeding activation energy or more successful
collisions or more effective collisions.
[1]
[1]
[15]
www.maxpapers.com
UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
GCE Advanced Level
9701 CHEMISTRY
9701/52
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the October/November 2011 question papers for most
IGCSE, GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
www.maxpapers.com
Page 2
Question
1
(a)
(b)
PLAN
Problem
Syllabus
9701
Paper
52
Indicative material
Mark
[1]
[1]
[1]
(i)
[1]
[1]
www.maxpapers.com
Page 3
(c)
Syllabus
9701
Paper
52
There are four different approaches, all of which share the first
five marking points.
Use 7 number labelled ticks and crosses for these points.
(i)
At least 5 experiments.
[1]
[1]
[1]
[1]
(v) stirs
[1]
Alternate 1
(vi) Heat mixture to dissolve all the solute.
[1]
[1]
OR Alternate 2
(vi) Heats mixture to a particular temperature.
(vii) Filters the solution (not cooled or decanted) and weighs
the residue.
OR Alternate 3
(vi) Heats mixture to a particular temperature.
(vii) filters the solution (not cooled or decanted) and evaporates
the filtrate and weighs solid.
OR Alternate 4
(vi) Heats mixture to dissolve the solute.
(vii) Records temperature at which the solute dissolves.
(d)
PLAN
Methods
[1]
www.maxpapers.com
Page 4
(e)
Syllabus
9701
Paper
52
Total
Question
2
(a)
[15]
Sections
ACE
Data
Indicative material
Mark
[1]
[1]
[1]
ACE
Data
[1]
[1]
[1]
www.maxpapers.com
Page 5
(c)
Syllabus
9701
Paper
52
[1]
[1]
[1]
ACE
Evaluation
[1]
ACE
Data
[1]
[1]
ACE
Correct calculation. Any calculation that has slope above
Conclusions multiplied by 19 i.e. EA = slope 19. Or slope = EA/19.
Ignore units. Also accept that calculation subsequently divided
by 1000 i.e. about 19950 or 19.95. T is not in this calculation.
[1]
ACE
Increased K.E/energy/speed.
Conclusions
More collisions/unit time or more frequent collisions or more
chance of collisions or more energetic collisions or more
collisions exceeding activation energy or more successful
collisions or more effective collisions.
[1]
[1]
[15]
www.maxpapers.com
UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
GCE Advanced Subsidiary Level and GCE Advanced Level
9701 CHEMISTRY
9701/53
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the October/November 2011 question papers for most
IGCSE, GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
www.maxpapers.com
Page 2
Question
1
(a)
(c)
(d)
PLAN
Problem
PLAN
Methods
PLAN
Methods
Paper
53
Indicative material
Mark
[1]
(i)
(b)
Syllabus
9701
[1]
[1]
(i)
[1]
[1]
(i)
Flush out the syringe with the gas under test at least once
before filling. Accept gas removal by vacuum pump.
[1]
(ii) Starts the descent of the piston above the start volume to
ensure constant speed. (Free movement, not pushed to
start mark.)
[1]
(iii) Uses the same volume for all the gasses or measures the
time between the same two volume marks. Alternatively,
candidates may record volume effused over a fixed time
for all gases. Table in 1(e) will change slightly in this case.
[1]
[1]
[1]
[1]
[1]
[1]
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Page 3
(e)
Syllabus
9701
Paper
53
Name /formulae of all the gases; correct Mrs; effusion time (or
effusion volume for alternative method); rate of effusion; with
relevant units. If an incorrect formula is given, ecf for Mr.
[2]
[15]
Question
Sections
Indicative material
ACE
Data
[1]
[1]
(a)
Mark
[1]
ACE
Data
[1]
[1]
ACE
Evaluation
[1]
[1]
[1]
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Page 4
(d)
Syllabus
9701
Paper
53
[1]
(f)
ACE
Data
[1]
[1]
ACE
Line is the ratio of oxygen to lead or vice versa.
Conclusions
Calculation to determine the formula, i.e. gives the ratio of
atoms commensurate with the answer in 2(e).
[1]
[1]
[1]
[15]