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TO THE EDITOR
oi
.. ..-
tt
7.825 t L
Z 7.815
4155
7.410
7.405
CHLOROPHYLL A
;
i
7.400
ff---------7,100
I
c
z
w
a
Q
2n
7.090
a
7,470
, , , , , , , , , , , , ,
CHLOROPHYLL B
I2
15
18
21
24
27
30 33
36
7.080
39 4 2
TI M E ( s e c )
(1)'
(2)
PHOTOCHEMISTRY
SECTION
ENERGETICS
BRANCH
SPACEPHYSICS
LABORATORY
L. G. HANSCOM
FIELD
BEDFORD,
MASSACHUSETTS 01730
K E N N E T P.
H QUINLAN
EIJI FUJIMORI
RECEIVED
AUGUST14, 1967
CHLH'(CHLH*)
+ Q +CHL. + Q . - + H +
(3)
COMMUNICATIONS
TO THE EDITOR
4156
Scheme I
Si
I
I
Si
I &Si
I
4Si-+A1
H
f
+ 3H20
--.f
3 Si-0-H
H-0-Si
Si
+ Al(0H)a
Si
I1
V
Si
Si
O
3Si-O-Al
I I
&Si
iAI(OH):, + 3%-0-Al-0-Si
II
I
I
Si
Si
e
f
+ HzO
Al(OH)2@
I11
structure I11 may react with one or two additional
protons t o yield Al(OH)2+and A13+. Studies to be reported later show that cationic aluminum has an average charge of 1.5, indicating the presence of both Al(OH)z+ and A1(OH)2+.
Thermogravimetric studies of the stable material suggest that it contains no chemical water in its final form.
Therefore, the four hydroxyl groups in structure I1 are
probably lost as water, resulting in some type of
Si-0-Si bonding. The nature of these sites is not
presently known, but the pronounced contraction of
the unit-cell dimensions of this material, relative to
sodium and hydrogen zeolite Y, is probably related to
the formation of the aluminum-deficient sites. Water
derived from these sites and from the proposed hydroxylated aluminum cations is available for hydrolysis
of additional Brpinsted acid sites. Details of our
investigation will be reported later.
MOBILRESEARCH
AND
GEORQE
T. KERB
DEVELOPMENT
CORPORATION
CENTRAL
RESEARCH
DIVISION
LABORATORY
PRINCETON,
NEWJERSEY 08540
RECEIVED
JUNE23, 1967