21 p=p/RT = (1.2)(1.01 x 10°) (287)(300) p= 141 kg/m? v=lp=W14 71 mikkg 2.2 Mean kinetic energy of each atom = k Te} (1.38 x 107)(500) = 1035 x 107° F One kg-mole, which has a mass of 4 kg, has 6 02x 10% atoms Hence 1 kg has, 4 02x 10°) = 1.505 x 10% atoms Total internal energy = (energy per atom)(number of atoms) = (1035 x 10)(1.505 x 10°) =| 1 558 x 10°F ee (1716)(460 +59) ft P 23 == pea Volume of the room — = (20)(15)(8) = 2400 ft? Total mass in the room = (2400)(0.00237) = 5 688 slug Weight = (5.688)(32.2) 24 p= & PP 2116 slug, RT (1716)(460-10) i 0.00274. ft Since the volume of the room is the same, we can simply compare densities between the two problems‘Ap = 0.00274 - 0.00237 = 0 0037 Ap _ 0.00037 el ve 7 00237 * (100) = [15.6% increase % change = —? 2.5 First, calculate the density from the known mass and volume, p= 1500/900 = 1 67 Ib,/ft* In consistent units, p = 1 67/32 2 = 0.052 slug/ft? Also, T = 70F Hence, p= pRT = (0 $2)(1716)(530) p= 47290 Ib/fi? or p=47290/2116 =[ 22.3 atm| 2.6 p=pRT enp= énp + énR+ ent Differentiating with respect to time, 1p _ ide, Lat pdt pdt Tdt on, pao at pdt Td ap _ ppd, AT mn, —- =RI—+ pR— L rer 2 At the instant there is 1000 Ib,, of air in the tank, the density is P= 1000/900 = 1.11 tbat?p= 111/322 = 00345 slug/f® Also, in consistent units, is is given that T=50+ 460 =510R and that a. LF/min = 1R/min = 0 0167R/sec From the given pumping rate, and the fact that the volume of the tank is 900 f°, we also have dp _ 95 Ib, see ae toon Re = 0.000556 Ib,,/(ft*)(sec) dp _ 0.000556 dt 322 = 1.73 x 10* slug/(A*)(sec) ‘Thus, from equation (1) above, 2 =(1716)(510)(1.73 x 10%) + (0 0345)(1716)(0.0167) =151+0:99= 16.1 bi(f?Xsec) = 1 2116 10.0076 atm/sec. 2.7 Inconsistent units, T=-10 +273 = 263K Thus, p=piRT = (1 7x 10°V(287)(263 .225 kg/m?