GUJCET TEST [FROM SEM-3]

Marks 40
time 1hr
{ for incorrect answer 0.25 % negative marking}
1. A mixture of ethyl iodide and n-propyl iodide is subjected to Wurtz reaction. Which of the following
compounds is not formed during the reaction?
a) Butane
b) Propane
c) Pentane
d) Hexane
2. Which of the following alkyl halides has the maximum density?
a) C2H5CI
b) C2H5Br
c) C2H5I
d) C2H5F
2
3. SN mechanism proceeds through the formation of
a) Carbonium ion
b) Transition state c) Free radical
d) Carbanion
4. The order of reactivity of various alkyl halides towards reaction is
a) 3o > 2o > 1o
b) 1o > 2o > 3o
c) 3o = 2o = 1o
d) 1o > 3o > 2o
5. Which of the following compounds is used as a refrigerant?
a) CCl4
b) CH2Cl2
c) CF4
d) CF2Cl
1
6. Which of the following is not true forSN reactions?
a) They occur through a single step concerted reaction
b) They are favoured by polar solvents
c) 3o alkyl halides generally react through this mechanism
d) Concentration of nucleophile does not affect the rate of such reactions
7. Arrange the following compounds in order of increasing dipole moment Toluene (I) m-dichlorobenzene
(II)
o-dichlorobenzene (III)
p-dichlorobenzene (IV)
a) I < IV < II < III
b) IV < I < II < III c) IV < I < III < II d) IV < II < I < III
8. The number of unit cells in 58.5 g of NaCl is
(1) 6 1020
(2) 3 1022
(3) 1.5 1023
(4) 0.5 1024
9. The number of basic crystal system is
(1)7
(2) 8
(3)
6
(4)
4
10. The arrangement of Cl ions in CsCl structure is
(1) h.c.p.
(2)simple cubic (3) f.c.c
(4) b.c.c.
11. The co-ordination number of a body-centred atom in cubic structure is
(1) 4
(2) 6
(3) 8
(4)
12
12. A substance AxBy crystallizes in an f.c.c. lattice in which atoms of A occupy each corner of the cube and
atoms of B occupy the centres of each face of the cube. Identify the correct composition of the substance
AxBy.
(1) AB3
(2) A4B3
(3) A3B
(4) Composition cannot be
specified
13. The average osmotic pressure of human blood is 7:8 bar at 370C . What is the concentration of an aqueous
NaCl solution that could be used in the blood stream ?
(a) 0.15 mol/L
(b) 0.30 mol/L (c) 0.60 mol/L
(d) 0.45 mol/L
14. A 5.25 % solution of a substance is isotonic with a 1.5 % solution of urea (molar mass = 60 g ) in the same
solvent. If the densities of both the solutions are assumed to be equal to 1.0 g , molar mass of substance will
be..................
(a) 210.0 g (b) 90.0
(c) 115.0 g (d) 105.0 g
15. A student has 100 mL of 0.1 M KCl solution. To make it 0.2 M he has to.
(a) evaporate 50 mL of the solution (b) add 0.01 mole of KCl
(c) both (a) and (b) can be used
(d) neither (a) nor (b) can be used
16. One molal solution of a complex of cobalt chloride with ammonia in water showed an elevation in boiling
point equal to 2.080C . Assuming that the complex is completely ionized in the solution, the complex is ( for
water = 0.52 k kg )

CO NH3 Cl2 Cl
CO NH3 Cl3
CO NH3 Cl Cl2
4
(d) none of these
6
5

(a)
(b)
(c)
17. At , the vapour pressure of pure liquid A is 520 mm Hg and that of pure liquid B is 1000 mm Hg. If a
mixture solution of A and B boils at 800C and 1 atm pressure then amount of A in the mixture is (1
atm = 760 mm Hg)
(a) 48 mol percent (b) 50 mol percent
(c) 52 mol percent (d) 34 mol percent
18. When electricity is passed through molten Al2O3+Na3AlF6 13.5g of Al are deposited. The number of
faradays passedare

(a) 1.5 (b) 3 (c) 15 (d) 0.15.

19. The electrode potential of an electrode is
(a) the potential applied to the electrode
(b) the ionisation potential ofthe material of the electrode
(c) the tendency of the electrode to lose or gain electrons when it is in contact with its ions.
(d) the potential energy of the electrons in an electrode.
20. During charging of a lead storage battery, the reaction taking place at anode.
(a) Pb2+ +
PbSO4 (b) Pb2+ + 2e
-Pb
(c) Pb

Pb2++ 2e

(d)

+2e

21. In a galvanic all, a salt bridge is used to

(a) complete the circuit
(b) reduce electric resistance in cell
(c) attain equilibrium
(d) carry salts for electrons occurring in
cell
22. The time in hours required for a current of 3 ampere to decompose electrolytically 18gm of H2O is
(A) 9 (B) 18(C) 36 (D) 54
23. By how much will the potential of a copper electrode change if the solution CuSO4 in which it is immersed
is diluted to 10 times at 298K?(2 mark)
a. increases by 30mV
b. Decreases by 30mV
c. Increases by 60mV
d. Decreases by 60mV
24. An acidic solution of Cu+2 salt containing 0.4 g of Cu+2 is electrolysed until all the copper is deposited. The
electrolysis is continued for seven more minute with the volume of solution kept at 100 ml and the current
at 1.2 amp. Calculate the volume of gases evolved at STP during the entire electrolysis
O =99.79 ml, H 2 =48.45 ml
O =87.91ml, H 2 =58.48 ml
a) 2
b) 2
O =99.79 ml, H 2 =58.48 ml
O =100 ml, H 2 =50 ml
c) 2
d) 2
25. The process of concentrating Ag and Au ores is based upon their solubility in.................
(a) NH3
(b)HNO3 (c)HCl
(d)KCN
26. In which of the following minerals, aluminium is not present ?
(a) Cryolite
(b) Mica
(c) Fledspar
(d) Fluorspar
27. Which of the following metals is sometimes found native in nature ?
(a) Aluminium
(b) copper
(c) Iron
(d) Magnesium
500 K

1675 K

TiI 4 Ti 2 I 2
28. Which method of purification is represented by the equations. Ti 2 I 2
( Impure)
( Pure)
(a) Cupellation

(b) Poling

(c) Van Arkel

(d) Zone refining

29. In the equation 4M 8 CN 2H 2O O2 4 M CN 2 4 OH , , the metal M is

30.
31.
32.
33.

34.

35.

(a) copper (b) iron

(c) Gold (d) zinc
Which of the following metals is leached by cyanide process ?
(a) Ag
(b)Na (c)Al
(d) Cu
Blister copper is...............
(a) Impure
(b) alloy
(c) Pure
(d) copper having 5% impurity
Which of the following is not an ore of Al ?
(a) Anglesite (b) Mica (c) Beryl
(d) Orthoclase
Sulphur does not exist as molecule because
a) it is less electronegative
b) It is not able to constitute bond
c) it has ability to exhibit catenation
d) of tendency to show variable oxidation state
Which of the following statements regarding sulphur is not true?
a) Rhombic sulphur is stable at room temperature
b) Monoclinic sulphur is stable at room
temperature
c) Both rhombic and monoclinic sulphur are soluble in
d) Both rhombic and monoclinic sulphur have a puckered -ring structure of eight sulphur atoms
For H3PO3 and H3PO4 , the correct choice is
a) H3PO3 is diabasic and reducing b) H3PO3 is dibasic and nonreducing
c) H3PO4 is tribasic and reducing
d) H3PO4 is tribasic and nonreducing

36. One mole of calcium phosphide on reaction with excess of water gives
a) One mole of phosphine
b) Two moles of phosphoric acid
c) Two moles of phosphine
d) One mole of phosphorus oxide
37. Hydroboration oxidation reaction of propylene yields
a)propanaone
b)propan-1-ol c)propan-2-ol
d)propanol
38. Acetone on reaction with Grignard reagent gives
a)Acetaldehyde
b)-alcohol
c)Acetic acid
d)-alcohol
39. Lucas reagent
a) Conc. HNO3 + anhydrous MgCl2
b) dil. HCl + anhydrous ZnCl2
c) Conc. HNO3 + anhydrous ZnCl2 d) Conc. HCl + anhydrous ZnCl2
40. Compound A reacts with Na metal to give B. A also reacts with PCl5 to give C. B and C reacts with each
other to give dimethyl ether. Then A, B and C respectively are
a) CH3OH, CH3ONa, CH3COCl
b) CH3OH, CH4, CH3Cl
c) CH3OH, CH3ONa, CH3Cl
d) CH3Cl, CH4, CH3OH