Q.1.

In electronic transition which electron is not

exited first at lower energy state
(a) - electrons
(b) n- electrons
(c) -electrons
(d) All of the
Q.2.Which of the following compounds is/ are
transparent in the ultraviolet region.
(a) Ether (b) Water (c) CDCl3
(d) both a & b
Q.3. Given are the four statement about UV
[P] When two chromophoric groups are conjugated
as in 1,3 butadiene the - transition undergoes
a bathochromic shift of 15- 45 nm
[Q] Ethylene has absorption at 165 nm, while 1,3
butadiene has a more intense peak at 217 nm
[R]Greater the conjugation in a molecule, the
greater is the shift to longer wavelength
[S] Transparent solvent is not used in uv
Choose correct statement
(a)P and R are correct while Q and S are not
(b)Q and S are correct while P and R are not
(c) P,R and S are correct while Q is not incorrect
(d) P,Q, Rand S all four are incorrect
Q.4.Which of the following groups when
substituted in the benzene ring causes
bathochromic shift as well as more intensity of
absorption
(a) OH
(b) NH2
(c) NO2
(d) CHO
(e) All of these
Q.5.When the following groups
CH3, Cl, Br,CH3CH2 substituted in the benzene
ring cause the effect
(a)Auxochromic
(b)Bathochromic
(c)Chromophoric
(d) Hypsochromic (e) All
Q.6. Given are the four statement about UV
[P]The transition of polar bonds like carbonyls, but
not ethylenes are affected by solvent polarity
[Q]The - bonds undergo red shifts as solvent
polarity is increased
[R]The n- bonds undergo blue shifts as solvent
polarity is increased
[S] The - bonds undergo red shifts due to
unsaturation or double bond
Choose the incorrect combination of statement
(a)P and R are correct while Q and S are not
(b)Q and S are correct while P and R are not
(c) P,R and S are correct while Q is not
(d) P,Q, Rand S all four are incorrect
Q.7.Arrange the following solvent increasing
order of wavelength
[p] CH3CH2OH
[q] Water
[r] CH3F
[s]CH3I
(a) p<q>r<s
(b) p>q>r>s
(c) q<p<r<s
(d) q>p>r>s

Q.8.Assertion: Alkyl substitution of the parent

compound causes the absorption at
longer
wavelength.
Reason : The bathochromic shift accompanying
alkyl substitution results from hyper conjugation in
which electrons of the alkyl group are mobile and
interact with the chromophoric group
(a) [a] is true but [r] is false
(b) Both [a] and [r] are true and [r] is the correct
reason for [a]
(c) Both [a] and [r] are false
(d) Both [a] and [r] are true but [r] is NOT the correct
reason for [a]
Q.9. Assertion : Chloral hydrate ,CCl3CHO .H2O
shows an absorption maximum at max=290 nm in
hexane solvent but no such spectrum of the
compounds is shown in aqueous solution
Reason : The structure of the compound CCl3
CHO.H2O in hexane changes to CCl3 CH(OH)2 in
aqueous solution.
(a) [a] is true but [r] is false
(b)Both [a] and [r] are true and [r] is the correct
reason for [a]
(c) Both [a] and [r] are false
(d) Both [a] and [r] are true but [r] is NOT the correct
reason for [a]
Q.10. Assertion : X-rays are more energetic than
rays of visible light
Reason: Lower the frequency of radiation the
greater will be its energy
(a) [a] is true but [r] is false
(b)Both [a] and [r] are true and [r] is the correct
reason for [a]
(c) Both [a] and [r] are false
(d) Both [a] and [r] are true but [r] is NOT the correct
reason for [a
Q.11. match the following
Colour of solution
colour of filter used
as monochromator
(a) Orange
1. blue
(b) Red
2. Blue- green
(c) Green
3. Red-orange
(d) Blue green
4. Purple
(e) Blue
5. Yellow
(A) a-2, b-1 c-4, d-3, e-5
(B) a-1, b-2, c-4, d-5, e-3
(C) a-3, b-2, c-1, d- 5,e-4
(D) a-3, b-2, c-4, d-1,e-5
Q.12. match the following Colour of light
wavelength(Nm)
absorbed
(a) Orange
1. 500
(b) Red
2. 600
(c) Green
3. 475

(d) Blue green

4. 490
(e) Blue
5. 450
(A) a-2, b-1 c-4, d-3, e-5
(B) a-1, b-2, c-3, d-4, e-5
(C) a-3, b-2, c-1, d- 5,e-4
(D) a-5, b-4, c-3, d-2,e-1
Q.13.Match the following
Compounds
Bands
1. 1, 3 Butadiene
(a) R- band
2. Acrolein
(b)B-band
3. Benzene
(c) E-band
4. Naphthalene
(d) K- band
(A) a-2, b-1 c-4, d-3,
(B) d-1, a-2, b-3, c-4
(C) a-3, b-2, c-1, d- 4
(D) a-3, b-2, c-4, d-1,
Q.14.Match the following wave characters with
their respective units
1. Energy
(a) Hertz
2. Wave number
(b) Cycle per second
3. Frequency
(c) Millimicron
4. Wave length
(d) Cm-1
(e) ergs
(A)1-e,2-d,3-b-,4-c
(B)1-e,2-b,3-c,4-a
(C))1-a,2-c,3-b,4-e
(D)1-e,2-b,3-d,4-c
Q.15. Assertion : The superior structure spectrum
can be obtained using hexane or cychlohexane as
solvents
Reason: Less polar solvents have least interaction
with the absorbing molecules
(a) [a] is true but [r] is false
(b) Both [a] and [r] are true and [r] is NOT the
correct reason for [a]
(c) Both [a] and [r] are true
(d) Both [a] and [r] are true but [r] is the correct
reason for [a]
Q.16.Assertion : Free radicals and out of the
ordinary electron molecule is not absorb in visible
region
Reason :Loosely bound electron can undergo
transition even by absorbing radiation of lower
frequency or lower energy
(a) [a] is true but [r] is false
(b) Both [a] and [r] are true and [r] is NOT the
correct reason for [a]
(c) [a] is false but [r] is true
(d) Both [a] and [r] are true but [r] is the correct
reason for [a]
Q.17.Assertion : Aniline in neutral solution absorb
at max = 230nm,but in acid solution it absorbs at
203nm
Reason : Removal of conjugation shifts max to
shorter wavelength

(a) [a] is true but [r] is false

(b) Both [a] and [r] are true and [r] is NOT the
correct reason for [a]
(c) [a] is false but [r] is true
(d) Both [a] and [r] are true and [r] is the correct
reason for [a]
Q.18.Assertion:Amines
absorb
at
higher
wavelength in comparison to alcohols
Reason : n- transition is not more probable in
amine than in alcohol
(a) [a] is true but [r] is false
(b)Both [a] and [r] are true and [r] is NOT the correct
reason for [a]
(c) [a] is false but [r] is true
(d) Both [a] and [r] are true and [r] is the correct
reason for [a]
Q.19.Assertion:Hydrogen bonding shifts the
absorption to shorterer wavelength
Reason : Non -bonding n-electrons present in
amines and alcohols form Hydrogen bonds with the
solvent molecules and greater energy will be needed
for the n- transition
(a) [a] is true but [r] is false
(b) Both [a] and [r] are true and [r] is NOT the
correct reason for [a]
(c) [a] is false but [r] is true
(d) Both [a] and [r] are true but [r] is the correct
reason for [a]
Q.20. Broad absorption band in UV spectra is due
to
(a) Electronic transition.
(b) Vibrational motion in bonds of atom
(c) Rational motion of molecules.
(d) Both a & c
Q.21. Given are the four statement about
absobance (A)
[P] A = log(I0/I) = Cl
[Q] Auxochrom is responsible for the absorption of
light in the uv visible reason while chromophore not
[R] Beers law states about path-length Lamberts
law states about concentration of solution.
[S] The concentration and amount of analyte can be
detected by the uv
Choose the correct combination of statement
(a)P and S are correct while Q and R are not
(b)Q and R are correct while P and S are not
(c)P is correct while Q,R and S are not
(d) P, Q, R and S all are correct
Q.22. Given are the four statement about UV
[P] modify the conjugation thus results in increase
in absorption maximum and shift toward shorter
wavelenth

[Q] Alkyl substitution on olefinic compounds results

in decrease in absorption maximum.
[R] If electro-negativity is increased thus results in
moves towards shorter wavelength
[S] Trans isomer shows absorption maximum
toward longer wavelength.
Choose the correct combination of statement
(a)P and Q are incorrect while R and S are not
(b)P and R are incorrect while Q and S are not
(c)P, R and S all are correct but Q is not
(d) P, Q, R and S all are correct
Q.23. Given are the four statement about UV
[P] n- is forbidden transition because it have the
Emax value greater than 100
[Q] Blue shift is due to decrease the intensity of
absorption maximum and red shift is due increase
in absorption maximum wavelength.
[R] max increases in hypochromic effect and
decreases in hyperchromic effects.
[S] B-band is found in benzenoid system of three
ethylenic bond.
Choose the correct combination of statement
(a) All are incorrect
(b) Q,S and R are incorrect while P is not
(c) R is incorrect while P, Q and S are not
(d) P is correct while Q, R and S are not
(e) All are correct
Q.24. Given are the four statement about UV
[P] Photovoltic cell detector have higher sensitivity
than photomultiplier tube
[Q] Position and intensity of absorption maximum
get shifted by changing the polarity of solvent.
[R] When increase the polarity of solvent -*and n* shifted towards longer wavelength while n-*
shifted toward shorter wavelength.
[S] n-* shifted toward longer wavelength due to
hydrogen bonding.
Choose the correct combination of statement
(a)P and S are correct while Q and R are not
(b)Q is correct while P,S and R are not (c)P, R and
Q all are correct but S is not
(d) P, Q, R and S all are correct
Q.25. Given are the four statement about UV
[P] -* transition required higher energy than -
[Q] -* normally found in unsaturated
hydrocarbon, n-* found in unsaturated alkyl
halids, -* fond in saturated hydrocarbon and n* normally fond in saturated carbonyl compounds.
[R] n-* is forbidden transition, and -*, -*, n-
transition are allowed transition.
[S] Vacuum ultra voilet range is approx 200-250
nm.(200 nm)
Choose the correct combination of statement

(a)Rand S are incorrect while P andQ are not

(b)P and Q are incorrect while R and S are not
(c)Q and P are incorrect while R and S are correct
(d) P, Q, R and S all are incorrect
Q.26. Match of the following IR region with their
respective wavenumber.
Region
Wave number
(A) Near IR
i) 1500-600cm-1
(B) Far IR
ii) 667-50cm-1
(c) Middle IR
iii) 12500-4000cm-1
(D) Finger print
iv) 4000-667cm-1
v) 1500-100cm-1
(a) a-iii (b) a-i
(c) a-ii
(d) a-iv
b-ii
b-iii
b-iv
b-i
c-i
c-ii
c-i
c-iii
d-i
d-iv
d-iii
d-ii
Q.27. The most important region for an organic
chemist to detect and measure
molecular vibrations in an IR-spectra
a) 2.5 to 15
b) 14.3 to 50
c) 0.7 to 2.5
d) 6 to 13
Q.28. Given are the four statement about The IR
absorption occurs when
[P] Vibrational frequency equals to IR frequency.
[Q] Processional frequency equals to IR frequency.
[R] Vibrational frequency equals to processional
frequency.
[S] Vibrational frequency is not equals to IR
frequency.
(a)P and Q are correct while R and S are not
(b)Q and S are correct while P and R are not
(c)Q,S and R all are incorrect while P is not
(d) P, Q, R and S all are correct
Q.29.principal changes in the vibrational energy
of a molecules depends on the following
[P] Masses of the atoms presents in the mole.
[Q] Strength of the bonds.
[R] Arrangement of the atoms with in the molecule.
[S] Length of the bonds
Choose correct statement
(a)P and Q are correct while R and S are not
(b) P, Q, R and S all are incorrect
(c)P,Q and R all are correct while S is not
(d) P, Q, R and S all are correct
Q.30.In which of the following the bond angle
remain constant and the bond length remain
constant during the vibration
Choose irrespectively
[P] stretching and bending
[Q] Bending and stretching
[R] Symmetric , Asymmetric stretching and
rocking,Twisting bending

[S] rocking,Twisting bending and Symmetric ,

Asymmetric stretching
(a)P and Q are correct while R and S are not
(b)Q and S are correct while P and R are not
(c)Q,S and R all are incorrect while P is not
(d) P, Q, R and S all are correct
Q.31. Given are the four statement about The IR
[P]The vibrational frequency or wave number
depends on Bond length, Reduced mass Velocity of
radiation
[Q] principle of ir is absorption of ir radiation
[R] IR determined the functional group
[S] IR determined the molecular formula Which of
the following statements are correct
(a)P,S and Q all are correct while R is not
(b)Q,R and S all are correct while P is not
(c)P,Q and R all are correct while S is not
(d) P, Q, R and S all are incorrect
Q.32.The O-H streching absorbs at high
frequency than C-C streching is due to
[P] Lower reduced mass of O-H than C-C
[Q] Lower redused mass of C-C than O-H
[R] Decrease in bond strength of O-H than C-C
[S] ] Decrease in bond energy of O-H than C-C
(a)P and Q are correct while R and S are not
(b)Q and S are incorrect while R is not
(c)Q ,R and S all are incorrect while P is not
(d) P, Q, R and S all are correct
Q.33. Given are the four statement about The IR.
[P] The theoretical fundamental bands for the
linear molecular is 3n-5.
[Q] The number of vibration degree of freedom in
benzene is 30.
[R] The theoretical fundamental bands for the
nonlinear molecular is 3n-6
[S] IR considered to the transition of electron.
(a)P and Q are correct while R and S are not
(b)Q and S are correct while P and R are not
(c)P,Q and R all are correct while S is not
(d) P, Q, R and S all are correct
Q.34.What is the right option in the following for
IR spectra
[P] 1-chloro ethanol wave number is higher than
methane.
[Q]1-chloro ethanol wave number is lower than
methane.
[R] Methane wave number is equal to 1-chloro
ethanol.
[S] Methane wave number is not equal to 1-chloro
ethanol
(a) P and Q are incorrect while R is not
(b)R and Q are incorrect while S is not
(c) P and S are incorrect while Q is not

(d) P, Q, R and S all are incorrect

Q.35. Fermi-resonance occurs in ir spectra when
[P] Energy of overtone more than fundamental
mode
[Q]Energy of fundamental mode than overtone
[R] Energy of overtone coincides with the
fundamental mode.
[S]Energy of overtone less than fundamental mode
(a) P and Q are incorrect while R is not
(b)R and Q are incorrect while S is not
(c) P and S are incorrect while Q is not
(d) P, Q, R and S all are incorrect
Q.36.Match the following compounds with respect
to their wave number.
Compounds
wave number
(P) Formaldehyde
(i) 1725cm-1
(Q) Acetone
(ii) 1735cm-1
(R) Anhydride
(iii) 1760cm-1
(S) Ester
(iv) 1715cm-1
a) P-iii
b)P-i
c) P-ii
d) P-iv
Q-ii
Q-iv
Q-iv
Q-i
R-iv
R-iii
R-i
R-iii
S-i
S-ii
S-iii
S-ii
Q.37. Given are the four statement about The IR
[P ]The electronic effect influence the vibrational
frequencies in IR are Inductive effect,
Mesomeric,Field effect.
[Q] When the compound is para substituted, the
wave number of absoption in IR region is decided
by Inductive effect and Mesomeric effect.
[R] The interferometer and movable mirror is not
present in FT-IR spectrometer.
[S] Generally monochromator is not used in IR.
(a)P and Q are correct while R and S are not
(b)Q and S are correct while P and R are not
(c)P,Q and R all are correct while S is not
(d) P, Q, R and S all are correct
Q.38. Given are the four statement about
sampling of solid inThe IR
[P] In Mull technique for IR analysis the
substances used for the sampling is Nujol and Nujol
in combination
[Q] solid ,liquid and gas sample can be prepared in
IR for sampling
[R] The solid sample prepared by pressed pellet
technique or KBr plate
[S] Solid run in solution and solid film techniques
used for liquid sampling
Choose correct combination of statement
(a)P and Q are correct while R and S are not
(b)Q and S are correct while P and R are not
(c)P,Q and R all are correct while S is not
(d) P, Q, R and S all are correct

Q.39. Match the following

Vibration
P. O-H stretching
1. 3500-3300cm-1
Q. C=O vibration
2. 1280-1000 cm-1
R. N-H vibration
3. 3700-3350 cm-1
S. C-O vibration
4. 1950-1640 cm-1
a) P-3 b) P-4 c) P-2
d) P-2
Q-4 Q-1 Q-4
Q-3
R-1 R-2
R-1
R-1
S-2 S-3
S-3
S-4
Q.40.Gas cell which is used for sampling of gases
in IR is made up of
a. KBr or NaBr
b. KCl or NaCl
c. Both a & b
d. None
Q.41. Given are the four statement about infrared
[P] The interferometer is the construction of
traditional infrared spectrophotometers
[Q] Possible representations for IR spectra. % T vs
Wave number and Absorption vs Wave number
[R] Inductive effect is considered when the
compound is meta substituted
[S] Composition of prism is/are Nacl, KBr ,CsBr
(a)P and Q are correct while R and S are not
(b)Q and S are correct while P and R are not
(c)P,Q and R all are correct while S is not
(d) P, Q, R and S all are correct
Q.42. Given are the four statement about infrared
[P] Fundamental vibration of H2S molecules is 6
[Q] The compounds which have Zero dipole
moment are infra-red inactive
[R] Translational vibration of linear molecules is
two while three for nonlinear molecules
[S] Rotational vibration of linear molecules is two
while three for nonlinear molecules. Choose the
correct combination of statement
(a) P and R are incorrect while Q and S are not
(b)Q and S are incorrect while P and R are not
(c)P,Qand R all three are incorrect while S is not
(d) P, Q, R and S all are incorrect
Q.43. Given are the four statement about infra red
[P] Overtone band is having the stretching wave
number is 1667-2000 cm-1
[Q] The wave number of finger print region is 1500400 cm-1 and The wave number of functional group
region is 4000-1500 cm-1 .
[R] Carbon carbon double bond in benzene shows
stretching at 1600-1475 cm-1 .
[S] N-H stretching in amine occur at approx 32003400 cm-1
Choose the correct combination of statement
(a)P and Q are correct while R and S are not

(b)P Q and S are correct while R is not

(c)P, R and S are correct while Q is not
(d)P, Q and S all are correct while R is not incorrect
Q.44.Wavelength
of
radiation
is
10.0
wavenumber corresponding to.in( cm-1)
(a) 2000 (b) 1000 (c) 10000 (d) 100
Q.45. Given are the four statement about
instrumentation of infra red
[P] Nichrome wire can not be used as ir radiation
source
[Q] Grating monochromator is made up of alumina
while prism monochromator is made up of metal
halide Nacl,KBr
[R] Globar bendedom is used as radiation source
and it is made up sintered silicon carbide.
[S] Nernst glower cell is used as detector and it is
made up of rare earth particles
Choose the correct combination of statement
(a)R and S are incorrect while P and Q are not
(b)S and R are incorrect while Q and R are not
(c)Q, R and S are incorrect while P is not
(d) P, Q, R and S all are incorrect
(c)Q, R and S all are correct but P is not
(d) P, Q, R and S all are correct
Q.46. The no. of vibrational degree of freedom in
CO2 is
(a) 2
(b) 4
(c) 6
(d) 8
Q.47. The no. of vibrational degree of freedom in
TNT (tri nitro toluene) is
(a)52
(b) 51
(c) 6o
(d) 58
Q.48. Given are the four statement about infrared
[P] +I effects results stretching occur at lower wave
number.
[Q] Order of wave number is correct in given
compounds on the basis of conjugation effect
>

>

[R] Order of wave number is correct in given

following compound on the basis of ring size
O

O
>

>

>

[S] The different peak observed in ir spectrum

shows the different type of molecular vibration
Choose the correct combination of statement
(a)P and Q are correct while R and S are not
(b)Q and S are correct while P and R are not
(c)P, Q and R all are correct while S is not
(d) P, Q, R and S all are correct

Q.49.Assertion:-Vibrational spectra appear as

bands rather than as lines although the absorption
is quantized
Reason:- A single vibrational energy is
accompanied by a number of rotational
energy charges.
(a) is
true but [r] is false
(b)Both [a] and [r] are true and [r] is the correct
reason for [a]
(c) Both [a] and [r] are false
(d) Both [a] and [r] are true but [r] is not the correct
reason for [a]
Q.50. Given are the four statement about sample
preparationof solid for Infra-red
[P] Solid film technique mainly used for non
amorphous solid.
[Q] mull technique is for the preparation of solid
sample. In this technique window plate is made up
of KBr for moisture free sample but when moisture
is present in sample then window plate is made up
of calcium fluoride.
[R] In solid run in solution technique the must be
dissolved in non aqueous solvent
[S]Greatest response detector in infra-red is
Pyroelectric detector because it provides high
sensitivity for ir radiation.
Choose the correct combination of statement
(a)P and Q are correct while R and S are not
(b)Q and S are correct while P and R are not
Q.51. Assertion :-Phototubes are not generally used
as detectors in the infrared Reasons:-The photons
in this region lack the energy to use photoemission
of electrons
(a) is true but [r] is false
(b)Both [a] and [r] are true and [r] is the correct
reason for [a]
(c) Both [a] and [r] are false
(d) Both [a] and [r] are true but [r] is not the correct
reason for [a]
Q.52.Assertion:-Carbon disulphide can not be used
as a solvent for primary and secondary amines.
Reason :- The CS2 reacts with these amines and
form new substances
(a) is true but [r] is false
(b)Both [a] and [r] are true and [r] is the correct
reason for [a]
(c) Both [a] and [r] are false
(d) Both [a] and [r] are true but [r] is not the correct
reason for [a]
Q.53. Assertion :- Symmetrical stretching of C=C
bond in CH2=CH2 is IR inactive

Reason :- The symmetrical stretching of C = C bond

in CH2 = CH2, molecule with a centre of symmetry
will not produces a change in the dipole moment
(a) is true but [r] is false
(b)Both [a] and [r] are true and [r] is the correct
reason for [a]
(c) Both [a] and [r] are false
(d) Both [a] and [r] are true but [r] is not the correct
reason for [a]
Q.54. Assertion : - Ignoring the bending vibrations
the O-H stretching frequency in acetic acid is at
higher frequency than the C-H stretching
frequency.
Reason :-O-H bond strength is higher than C-H
bond.
(a) is true but [r] is false
(b)Both [a] and [r] are true and [r] is the correct
reason for [a]
(c) Both [a] and [r] are false
(d) Both [a] and [r] are true but [r] is not the correct
reason for [a]
Q.55. Assertion :-The symmetrical stretching
vibration in linear triatomic CO2 molecule O-C-O
is inactive in IR
Reason :- It produces change in the dipole moment
of the molecule .
(a) is true but [r] is false
(b)Both [a] and [r] are true and [r] is the correct
reason for [a]
(c) Both [a] and [r] are false
(d) Both [a] and [r] are true but [r] is not the
Q.56. Given are the four statement about
stretching of alcohol
[P] OH Stretching in alcohol is greater than -OH
of phenol
[Q] Pure alcohol shows stretching at 3600-3660 cm1
while impure alcohol shows stretching at 34003450 cm-1
[R] C-O stretching of 10alcohol is at 1050 cm-1
[S] Free OH give sharp peak while hydrogen
bonded OH gives broad peak peak.
Choose the correct combination of statement
(a)P and Q are correct while R and S are not
(b)Q and S are correct while P and R are not
(c)P,Q and R all are correct while S is not
(d) P, Q, R and S all are correct
Q.57. The no. of vibrational degree of freedom in
PABA (paraamino benzoic acid) is
a) 47
(b) 45
(c) 60
(d)48
Q.58. Given are the four statement about inrfared

[P] CHCl3,CCl4, are not good solvent for ir but

water is good solvent because it absorbed several
reason of ir spectra.
[Q] Asymmetric coupling vibration is at lower wave
number as compare to symmetric coupling
vibration.
[R] When overtone vibration coupled with
fundamental band is called Fermiresonance
[S] Bolometer and thermister detector is used in ir.
Choose the correct combination of statement
(a)P is incorrect while Q, R and S are not
(b) Q and R are correct while P and S are not
(c) Q and S are correct while P and R are not
(d) P, Q, R and S all are correct
Q.59.Given are the four statement about NMR
[P]All solvents are used to record NMR spectra
CDCl3 ,DMSOd6 ,(CDS3) CO2
[Q]The CDCl3 solvent is most frequently used in
NMR Spectroscopy
[R]The CHCl3 is not used in NMR Spectroscopy is
[S]The value of chemical shift is expressed in ppm
(a)Q and R are incorrect while P and S are not
(b)Q and S are incorrect while P and R are not
(c)P,Q and R all three are incorrect while S is not
(d) P, Q, R and S all are correct
Q.60.Given are the four statement about NMR
[P]The and have the relation is =10 - [Q]The
minimum radio frequency 60 megacycle/sec from
source which fall on sample
[R]Gyromagnetic ratio is expressed as 2 / hI
[S]chemical shift value three directional
(a)Q and R are incorrect while P and S are not
(b)Q,R and S are incorrect while P is not
(c)P,Q and R all three are correct while S is not
(d) P, Q, R and S all are correct
Q.61. Match the following
Compounds
number of signle
1. Methanol
(A) 1
2. Acetone
(B) 2
3. Ethyl alcohol
(C) 3
4. carbon tetra chloride
(D) 0
(a)1-B,2-A,3-C,4-D
(b) 1-D,2A,3-C,4-B
(c) 1-B,2-A,3-D,4-C
(d) 1-B,2-A,3-C,4-D
Q.62.Given are the four statement about NMR
[P] 1H1 nuclei shows NMR spectrum
32
S nuclei does not show NMR spectrum
[Q] 16
[R] Compound is nmr active when it have odd
atomic mass and atomic number

[S] Compound is nmr active when it have spin

quantum number zero
(a)Q and R are incorrect while P and S are not
(b)Q,R and S are correct while P is not
(c)P,Q and R all are correct while S is not
(d) P, Q, R and S all are correct
Q.63.Assertion: TMS is not used as a reference in
NMR spectroscopy.
Reason: It gives a single strong well defined
absorption peak in NMR
Spectrum.
(a) is true but [r] is false
(b)Both [a] and [r] are true and [r] is the correct
reason for [a]
(c) Both [a] and [r] are false
(d) Both [a] and [r] are true but [r] is not the correct
reason for [a]
Q.64.Assertion: Toluene does not show splitting of
NMR signals.
Reason:In C6H5 CH3, the three methyl protons,
which are equivalent to each other are separated
from the five aromatic protons by two
carbon
atoms.
(a) is true but [r] is false
(b)Both [a] and [r] are true and [r] is the correct
reason for [a]
(c) Both [a] and [r] are false
(d) Both [a] and [r] are true but [r] is not the correct
reason for [a]
Q.65.Assertion:
The value of chemical
environment shift depends on the
chemical
Environment of the proton.
Reason: Chemical environment of the proton is the
source of variations in Shielding electrons.
(a) is true but [r] is false
(b)Both [a] and [r] are true and [r] is the correct
reason for [a]
(c) Both [a] and [r] are false
(d) Both [a] and [r] are true but [r] is not the correct
reason for [a]
Q.66.Assertion:Spin Spin coupling to an observed
proton attached to an oxygen or nitrogen atom,
i.e. a proton of a OH or -NH2 group
Reason : Such protons are relatively acidic and as a
result these protons Rapidly interchange between
molecules.
(a) is true but [r] is false
(b)Both [a] and [r] are true and [r] is the correct
reason for [a]
(c) Both [a] and [r] are false
(d) Both [a] and [r] are true but [r] is not the correct
reason for [a]

Q.67.Assertion:The CH3 protons in CH3CCl

experience less deshielding in comparison to CH3
protons in CH3 Cl.
Reason:As the distance of the protons from the
electronegative atoms Increases, the deshielding
effect due to it decreases.
(a) is true but [r] is false
(b)Both [a] and [r] are true and [r] is the correct
reason for [a]
(c) Both [a] and [r] are false
(d) Both [a] and [r] are true but [r] is not the correct
reason for [a]
Q.68.Assertion: Attachment of electronegative atom
or group to the carbo bearing the proton causes a
downward shift (higher values of )
Reason: The electronegative atom or group attracts
electrons toward Itself. As a result, the electron
density round the nearby proton decreases causing
deshielding.
Because of deshielding, smaller
values of applied field will be required to bring the
proton to resonance
(a) is true but [r] is false
(b)Both [a] and [r] are true and [r] is the correct
reason for [a]
(c) Both [a] and [r] are false
(d) Both [a] and [r] are true but [r] is not the correct
reason for [a]
Q.69.Assertion:The deshielding of proton attached
to different halide groups is in Order. H3C F >
H3C Cl > H3C Br > H3C I
Reason: High is the electronegativity of the atom,
greater is the deshielding caused to proton.
(a) is true but [r] is false
(b)Both [a] and [r] are true and [r] is the correct
reason for [a]
(c) Both [a] and [r] are false
(d) Both [a] and [r] are true but [r] is not the correct
reason for [a]
Q.70.Which of the following nuclei have spin
1
quantum number I as odd integral multiple of
2
1
3
i.e.
,
, etc.
2
2
19
23
Na
(a) 1735 Cl
(b) 11
(c)
All of
9 F (d)
these
Q.71. Given are the four statement about NMR
[P] 12 H , 147 N , 105 B nuclei have I = 1, 2, 3 etc.
[Q]In the case of halides, the electrons Provides
largest shielding effect order is
F <Cl <Br < I
[R] Ethyl chloride is expected to show 3 signals

[s]The electronegativity of a nucleus is reduced the

proton shift up field and proton is called shielded
proton
(a)Q and R are incorrect while P and S are not
(b)Q,R and S are correct while P is
not
(c)P,Q and S all are correct while R is not
(d) P, Q, R and S all are correct
Q.72. Given are the four statement about NMR
[P] Greater is the deshielding of protons, lower will
be the value of .
[Q] Greater is the shielding of protons, greater will
be value of .
[R] The and scale are related as = 10 - .
[S]Deshielding known as Upfield/ lower chemical
shift value/high magnetic field
(a)Q and R are incorrect while P and S are not
(b)P,Q and S are incorrect while R is not
(c)P,Q and R all are incorrect while S is not
(d) P, Q, R and S all are correct
Q.73. Given are the four statement about NMR
[P]An anisotropic effect does not cause deshielding
in the Alkynes
[Q]Alkene, aldehyde, benzene are cause anisotropic
deshielding effect
[R]Benzene have both shielding and deshielding
anisotropic effect.
[S] In benzene ring above and below the proton
cause up field and inplane proton cause downfield.
(a)Q and R are incorrect while P and S are not
(b)Q and S are incorrect while P and R are not
(c)P,Q and R all three are incorrect while S is not
(d) P, Q, R and S all are correct
Q.74.Read the following statements
[P] Enantiotropic protons can not be distinguished
by NMR spectroscopy
[Q]The non-equivalent protons are called
accidentally equivalent when these absorb at the
same chemical shift.
[R]The protons with the same chemical shift do not
split each other.
[S] When a proton is substituted by D (Duterium) at
achiral center of any carbon do not give chiral
center called homotropic proton
(a)Q and R are incorrect while P and S are not
(b)Q and S are incorrect while P and R are not
(c)P,Q and R all three are incorrect while S is not
(d) P, Q, R and S all are correct
Q.75.How many types of protons are present in
the Ccompound
CH3CH2COO
H
C

||
C

(a) Ha (b) Hb (c) Hc (d) All

H

Q.81.which of the following structure proton

show higher down field in 1HNMR

COOCH2CH3

CH2

(a) 2 (b) 6

(c) 4

(d) 5

CH2
CH2

Br

Q.76.How many types of hydrogens are present in

the compound.

CH2CH3

Cl

Cl

(a)

(b)
H

Br

H
*

*
H

H
H

H
(a) 4 (b) 5
(c) 3
(d) 6
Q.77. Different number of signals present in NMR
spectra indicates
(a) Different protons present in different environment
(b) Different protons present in same environment
(c) Different number of proton environment
(d) Both a and b
(e) All
Q.78. Given are the four statement about is
coupled coupling condition for proton.
The proton with each other when they are
(a)Chemically
equivalent
and
magnetically
nonequivalent proton
(b)Chemically nonequivalent and magnetically
nonequivalent proton
(c)Chemically nonequivalent and magnetically
equivalent proton
(d)Chemically nonequivalent and magnetically
equivalent proton
(e) both a &b
Q.79.In the given structure which one of the
labeled proton show upfield and down field
Irrespectively
Cl H Hb Ha
Hd

Br

H Hc I
(a) Hd and Hc
(c)Hc and Hd

Ha

(b) Hb and Hc
(d) Hd and Hb

Q.80.Which of the following proton shows up field

CH3
Ha

Br

Hb

Hc
NO2

(c)
(d)
Q.82. Which of the following labeling proton have
high chemical shift value and splitting into triplet
Cl

Hc Hb Ha

Cl

Cl
Hd Hc NO2Ha

(a) Hd (b) Hc
(c) Hb (d) Ha
Q.83.In the given compound labeled proton Ha
show splitting and intensity ratio of multiplates is
respectively.
H

H
Hb

Ha
H

H
Hb
H

Ha
H

(a) Triplet, 1:2:1

(b)doublet, 1:1
(c) quartet, 1:3:3:1
(d) Singlet 1
Q.84.In the given compound labeled proton Hc
show splitting
Hc Hb Ha

Hc

Cl

Cl Hb Ha
(a) Doublet
(b) Triplet
(c) Quatret
(d) singlet
Q.85. Given are the four statement about NMR
[P] For water soluble samples 2,2dimethyl-2silapentane-5-sulfonate is used as references
standard in nuclear magnetic resonance
[Q]300 mega hertz frequency is required for the
magnetic field of 7.05 tesla.
[R] Energy difference is created between two
magnetic energy level when very strong magnetic
field is applied.

[S] When precessional frequency is equal to radio

wave frequency than proton nmr signal is obtained.
Choose the correct combination of statement
(a)Q and R are incorrect while P and S are not
(b)Q and S are incorrect while P and R are not
(c)P,Q and R all three are incorrect while S is not
(d) P, Q, R and S all are correct
Q.86. Given are the four statement about NMR
[P] Alkyl effect increase the electron density
around proton cause deshield the proton signal goes
to upfield.
[Q]Natural abundance and gyromagnetic ratio is
high for carbon-13 NMR than proton NMR.
[R] Micro wave frequency is applied for flipping of
proton and radio wave frequency is used for
generating the NMR signal on recorder
[s] Reference compound is used in NMR instrument
is Trimethylsilane (TMS)
(a)P and Q are incorrect while R and S are not
(b)Q and S are incorrect while P and R are not
(c)P,Q and R all are incorrect while S is not
(d) P, Q, R and S all are incorrect
Q.87. Given are the four statement about NMR
[P] -spin state is +1/2
[Q] -spin state is higher in energy
[R] -spin state is lower in energy
[S] -spin state is -1/2
(a)P and Q are incorrect while R and S are not
(b)P and S are incorrect while Q and R are not
(c)P,Q and R all three are incorrect while S is not
(d) P, Q, R and S all are correct
Q.88. Given are the four statement about Mass
[P] Positive charged particle in the plane of
magnetic field shows clockwise rotation
[Q] Reason for the presence of circular path in
dempster mass spectrometer the Positive ions rotates
clockwise in the plane of magnetic field
[R] Application of vaccum in mass analyzer is to
Produce collision between positive ions.
[S] The vacuum region is not present in time of
flight mass analyzer.
Choose correct statement
(a)P and Q are correct while R and S are not
(b)Q and S are correct while P and R are not
(c) Q ,R and S are correct while P is not
(d) P ,R and S are correct while Q and is not
Q.89. Given are the four statement about Mass
[P] The Parent ion abundance is not more in the
Aromatic compounds
[Q] The broad peak is observed in Para amino
anisole when is analyzed by double beam mass
spectrometer. The broad peak is due to Metastable
ion

[R] The broad peaks are generated in para amino

anisole is due to presence of Second field free
region.
[S] The Position of broad peak of para amino
anisole in mass spectra is (m/z) 94.8
Choose correct statement
(a) P and Q are correct while R and S are not
incorrect
(b)Q and S are correct while P and R are not
(c) Q ,R and S are correct while P is not
(d) P ,R and S are correct while Q and is not
Q.90. Given are the four statement about Mass
[P] MC Lafferty rearranged ions are not observed
in the aldehydes, ketones, unsaturated compounds
and Amines.
[Q] MC Lafferty rearrangement involve the
migration of hydrogen atom followed by the
cleavage of a bond
[R] MC Lafferty rearrangement proceed through a
statically hindered six membered transition state.
[S] MC Lafferty rearrangement involve the
migration of hydrogen atom followed by the
cleavage of a bond
Choose correct statement
(a)S and Q are correct while R and P are not
(b)Q and R are correct while P and S are not
(c) Q ,R and S are correct while P is not
(d) P ,R and S are correct while Q and is not
Q.91. Given are the four statement about Mass
[P] The positively charged ions produced in the ion
chamber are accelerated by applying Accelerated
potential.
[Q] The pressure of ion chamber is more than 10-6
torr.
[R] In the ion chamber only cation is form.
[s] Molecular ion is fragmented at higher electron
beam energy (70 ev)
Choose correct statement
(a)Q and R are correct while P and S are not
(b)P and S are correct while Q and R are not
(c) Q ,R and S are correct while P is not
(d) P ,R and S are correct while Q and is not
Q.92. Given are the four statement about Mass
[P]The position of meta stable peak is equal to
m1/m2
[Q] When daughter ion m1+ occurs after the source
exists and before arrival at collector, then m1+ is
called Meta stable ion.
[R] The ions, which are separated by the analyzer
are detected and measured by Photographically
[S] By the mass spectrometer the cations are not
detected.only free radical are detected Choose
correct statement

(a)P and Q are correct while R and S are not

(b) P, Q and S are correct while S is not
(c) Q ,R and S are correct while P is not
(d) P ,R and S are correct while Q is not
Q.93. Given are the four statement about Mass
[P] The 20 ev energy is required for removing one
electron from the neutral molecule
[Q] The 70 ev energy of bombarding electrons
which are capable to producing ions in a mass
spectrophotometer.
[R] The pressure of ion collector is 10-10 tork
[S] The current flow in ion collector is 10-8-10-10
ampere
Choose correct statement
(a)P and Q are correct while R and S are not
(b)Q and S are correct while P and R are not
(c) all are in correct
(d) All are correct
Q.94.Given are the four statement about Mass
[P] Intensity of the base peak is 99.99%
[Q] The largest peak in a mass spectrum is called
parent peak.
[R] Molecular ion peak is known as Parent peak.
[S] The largest height peak is molecular ion peak
Choose correct statement
(a)P and Q are correct while R and S are not
(b)Q and S are correct while P and R are not
(c) Q ,R and S are incorrect while P is not
(d) P ,R and S are incorrect while R is not
Q.95. Given are the four statement about Mass
[P] Molecules are bombarded by energetic electron
beam and broken up into the many fragment.
[Q] Unsaturated six member rings can undergo a
Retro Diels-Alder fragmentation.
[R] Retro Diels-Alder fragmentation of six
membered compound to produced radical cation of
Diene and a neutral alkene.
[S] Hemolytic and heterotypic cleavage is a type of
fragmentation modes.
Choose correct statement
(a)P and Q are correct while R and S are not
(b)Q and S are correct while P and R are not
(c) Q ,R and S are correct while P is not
(d) P ,R and S are correct while Q is correct
Q.96. Assertion : In mass spectrometer the sample
vapour is generally introduced at low pressure of
about 10-5-10-6 torr
Reason: In order to
minimize the number of collisions between ions and
unionized molecules, a low pressure is necessary
(a) is true but [r] is false
(b)Both [a] and [r] are true and [r] is the correct
reason for [a]
(c) Both [a] and [r] are false

(d) Both [a] and [r] are true but [r] is not the correct
reason for [a]
Q.97. Assertion : The molecular ion is the most
important in the mass spectrum of a compound and
odd electron ions are generally more significant
than even electron ions of similar mass or
abundance
Reason : Odd electron ions generally formed via a
rearrangement reaction which may be typical of a
particular category of compounds
(a) is true but [r] is false
(b)Both [a] and [r] are true and [r] is the correct
reason for [a]
(c) Both [a] and [r] are false
(d) Both [a] and [r] are true but [r] is not the correct
reason for [a]
Q.98.Assertion : Ions of high mass generally give
more useful information than those of lower mass
Reason : Ions of high mass are likely to have been
formed via a simple rational fragmentation
(a) is true but [r] is false
(b)Both [a] and [r] are true and [r] is the correct
reason for [a]
(c) Both [a] and [r] are false
(d) Both [a] and [r] are true but [r] is not the correct
reason for [a]
Q.99.Assertion: In the case of molecular ions
derived from n-alkanes, an extensive decomposition
takes place to give a series of fragment ions,
separated by 14 mass units but a branched chain
alkane shows enhanced bond fission adjacent to the
branching point
Reason : This is due to increased stability of 2 and
3carbonium ions than 1 carbonium ion formed by
n- alkanes
(a) is true but [r] is false
(b)Both [a] and [r] are true and [r] is the correct
reason for [a]
(c) Both [a] and [r] are false
(d) Both [a] and [r] are true but [r] is not the correct
reason for [a]
Q.100. Assertion : Most peaks found in the mass
spectra of organic compounds possess an odd m/e
value
Reason : Because
peaks are formed by the loss of an add molecular
weight free radical fragment.
(a) is true but [r] is false
(b)Both [a] and [r] are true and [r] is the correct
reason for [a]
(c) Both [a] and [r] are false
(d) Both [a] and [r] are true but [r] is not the correct
reason for [a]

Q.101 .Assertion : The compounds contain a

hydrogen atom at the position gamma to the
carboxyl group show a relatively intense peak
with an even m/e value
Reason : Due to Mc lafferty rearrangement
fragmentation accompanied by loss of a neutral
molecule
(a) is true but [r] is false
(b)Both [a] and [r] are true and [r] is the correct
reason for [a]
(c) Both [a] and [r] are false
(d) Both [a] and [r] are true but [r] is not the correct
reason for [a]
Q.102. Assertion : In general,the molecular ion is
stabilized by the presence of -electron systems.
Reason: -electron
systems
more easily
accommodate a loss of one electron
(a) is true but [r] is false
(b)Both [a] and [r] are true and [r] is the correct
reason for [a]
(c) Both [a] and [r] are false
(d) Both [a] and [r] are true but [r] is not the correct
reason for [a]
Q.103.Assertion : Majority of mass spectral
application involve positive ions only
Reason: Bombardment of molecules by energetic
electrons usually produce more negatives ions than
positive ions
(a) is true but [r] is false
(b)Both [a] and [r] are true and [r] is the correct
reason for [a]
(c) Both [a] and [r] are false
(d) Both [a] and [r] are true but [r] is not the correct
reason for [a]
Q.104. Assertion : Majority of mass spectra are run
with a 70 ev beam
Reason : 70 ev beam is energetic enough to break
any bonds likely to be present therefore, each
compound yields a characteristic series of
fragments, called the fragmentation pattern.
(a) is true but [r] is false
(b)Both [a] and [r] are true and [r] is the correct
reason for [a]
(c) Both [a] and [r] are true
(d) Both [a] and [r] are false
Q.105.Assertion: The mass spectrum of 1- hexanol
gives a base peak at m/e=56
Reason : The peak is obtained from the elimination
of H2O and CH2-CH2
from the molecular ion
of 1- hexanol
(a) is true but [r] is false
(b)Both [a] and [r] are true and [r] is the correct
reason for [a]

(c) Both [a] and [r] are false

(d) Both [a] and [r] are true but [r] is not the correct
reason for [a]
Q.106. Assertion: Base peak provide better results
for peak division
Reason: Because the base peak have 100%
abundance and largest height
(a) is true but [r] is false
(b)Both [a] and [r] are true and [r] is the correct
reason for [a]
(c) Both [a] and [r] are false
(d) Both [a] and [r] are true but [r] is not the correct
reason for [a]
Q.107. Which is the correct order of decreasing
stability of the molecular ion peak
(a) Aromatics> Ketones> Carboxylicacid> Alcohols
(b) Aromatics> Carboxylic acids> Alcohols>
Ketones
(c)
Aromatics> Alcohols> Ketones> Carboxylic acid
(d) Ketones> Aromatics> Alcohols> Carboxylic
Q.108. Given all are following statement about the
alcohol
[P] Alcohols usually have a very weak or non
existent molecular ion peak
[Q]They usually give a strong peak at M-18
[R] In alcohols, cleavage of C-C bond next to an
oxygen is very common
[S] Primary alcohols always have a strong peak at
mass 31
Choose correct statement
(a)P and Q are correct while R and S are not
(b)Q and S are correct while P and R are not
(c) All are incorrect
(d) All are correct
Q.109. Given are the four statement about Mass
[P] The molecular ion is not give very useful
information about the identity of an organic
compound
[Q] Fragmentation is the break up process of the
molecular ion into smaller ions called fragment ions
[R] Fragmentation pattern is not give further
information about the structure of the compound
[S] Base peak have 100% abundance
Choose correct statement
(a)P and Q are correct while R and S are not
(b)Q and S are correct while P and R are not
(c) Q ,R and S are correct while P is not
(d) P ,R and S are correct while Q and is not
Q.110.Calculate the hydrogen deficiency index
(H.D.I) For the aniline (C6H5NH2)
(a) 4
(b) 6
(c) 7
(d) 8
Q.111.Calculate the hydrogen deficiency index
(H.D.I) For the Benzene (C6H6)

(a) 4
(b) 6
(c) 7
(d) 8
Q.112.Calculate the hydrogen deficiency index
(H.D.I) For the (CCl3CHO)
(a) 1
(b) 1.5
(c) 2
(d) 2.5
Q.113.Calculate the hydrogen deficiency index
(H.D.I) For the (C9H14ONH2)
(a) 2.5
(b) 2
(c) 4
(d) 3
Q.114. Given are the four statement about Mass
[P] Nicotinic and piconilic derivatives are not used
as matrix in MALDI.
[Q] Knudsen cell is used as detector.
[R] The function of magnetic field is to deflected the
ion on the basis of mass
[S] EI one is most common ionization method
Choose the correct statement
(a)P and Q are correct while R and S are not
(b)R and S are correct while P and Q are not
(c)P, Q and R all are correct while S is not
(d) P, Q, R and S all are correct
Q.115. Given are the four statement about Mass
[P] Mass utilize for molecular weight determination
[Q] Quadrupole contains quadrant of four parallel
circular tungsten rod is used as mass analyzer and
it separates uranium isotopes.
[R] Mass provide functional group information
better than ir
[S] Omegatron is ion collector.
Choose the correct statement
(a)P and Q are correct while R and S are not
(b)Q and S are correct while P and R are not
(c)P,Q and R all are correct while S is not
(d) P, Q, R and S all are correct
Q.116. Given are the four statement about Mass
spectroscopy
[P] Unsaturation index five means one benzene ring
and one double bond
[Q] When 15 group element (N, P, As, Sb, Bi) is
added in the compound than HDI is decreases by 1.
[R] In mass the graph plot b/w m/e vs relative
abundance
[S] Unsaturation index one means one double bond
Choose the correct combination of statement
(a)P and Q are correct while R and S are not
(b)Q and S are correct while P and R are not
(c) Q ,R and S are correct while P is not
(d) P ,R and S are correct while Q and is not
Q.117.Diffusion current is the difference between
(a)Limiting current & residual current
(b)Limiting current & kinetic current
(c)Limiting current & Migration current
(d)Migration current & kinetic current

Q.118.Assertion (A) :
Before
measuring
a
polarogram, Nitrogen gas is bubbled through the
solution in a polarographic cell.
Reason (R) : Oxygen is polarographically active
(a) is true but [r] is false
(b)Both [a] and [r] are true and [r] is the correct
reason for [a]
(c) Both [a] and [r] are false
(d) Both [a] and [r] are true but [r] is not the correct
reason for [a]
Q.119. The main disadvantage of DME is
(a)Hg is toxic in biological studies.
(b)Surface area of drop is never constant
(c)Diffusion current is not constant
(d)Variation in applied voltage changes surface
tension of the mercury
Q.120.Which type of molecules analyzed by
polarimetry
(a) Optical active compound
(b) Optical inactive compound
(c) Optical active and optical inactive compound
compound
(d) Only c
Q.121.Magnetude of the rotation of light is depend
upon
[P] Nature of the substances
[Q] Concentrations of solution
[R] Nature of solvent
[S] Wavelength of light used
Choose the correct statement
(a)P and Q are correct while R and S are not
(b)R and S are correct while P and Q are not
(c)P, Q and R all are correct while S is not
(d) P, Q, R and S all are correct
Q.122.In amperometry reference electrode is
generally
(a) DME
(b)Calomel electrode
(c) H electrode
(d) Glass electrode
Q.123 The dead stop end point method is used in
(a) Polarimetry
(b) Amperometry
(c) Polarography (d) Glass electrode
Q.124.E 1 / 2 ( Half wave potential ) potential help in
(a)Qualitative analysis
(b) Quantitative analysis
(c) Structural elucidation (d) Both a and b
Q. 125. max is

(a) 313 nm (b) 325nm (c) 345 nm

(d) 351 nm