EMR-87003 T-87003 Full - Reviewed

TM
SuperChems Report
Welcome to SuperChems Version 6.50mp -- September 20, 2012
Contents
RELIEF SYSTEM SUMMARY (System 1 of 1)
PART 1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
PART 2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
EQUIPMENT SUMMARY
T-87003 - PHENOLIC WATER TANK . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
RELIEF DEVICE SUMMARY

EMR-87003 - Mechanical Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
EMR-87003 - Piping Layout Table (EMR-87003 PIPING) . . . . . . . . . . . . . . . . . . . . 5
EMR-87003 - Relief Flow Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
OVERPRESSURE SCENARIO REPORT

EMR-87003 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
SCENARIOS AND CALCULATIONS

EMR-87003_T-87003-01A - FIRE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
EMR-87003_T-87003-09A.1 - INDIVIDUAL CONTROL VALVE OPEN-CLOSE . . . . . . .
11
13
EMR-87003_T-87003.cor
January 28, 2014
Relief System Summary (System 1 of 1)

Part 1
PROTECTIVE RELIEF DEVICES
TAG
DEVICE LOCATION
P&ID
EMR-87003
Top of Tank T-87003
E-93298-08
TAG
DESCRIPTION
P&ID
T-87003 - PHENOLIC WATER TANK
Phenolic Water Tank
E-93298-08
EQUIPMENT PROTECTED
The currently installed relief system is adequate

OVERPRESSURE SCENARIOS REQUIRING RELIEF
SCENARIO
KEY
01A
02A
03A
03B
04B
05A
06A
07A
08A
09A
10A
11A
12A
13A
14A
15A
15B
15C
18A
20A
22A
99A
EXTERNAL FIRE EXPOSURE

INCORRECT VALVE POSITION OR CLOSED OUTLETS
OVERFILLING
OUTBREATHING
INBREATHING
THERMAL EXPANSION, INCLUDING SOLAR HEATING
LOSS OF COOLING
LOSS OF HEATING
POWER FAILURE
INSTRUMENT FAILURE OR FAILURE OF AUTOMATIC CONTROLS
UTILITY FAILURE
ABNORMAL HEAT INPUT
ABNORMAL FLOW INPUT
EXCHANGER TUBE FAILURE
PROCESS INDUCED RUNAWAY REACTION
ACCUMULATION OF NON-CONDENSABLES
LOSS OF REFLUX - TOWER TOP
LOSS OF REFLUX - SIDE STREAM
MIXING OF HOT, REACTIVE, AND HIGHLY VOLATILE MATERIALS
ABSORBENT FLOW FAILURE
INTERNAL EXPLOSION OR DEFLAGRATION
OTHER
(C) iOiQ LLC.
SuperChems Expert v7.21mp (09-30-2013)
YES
NO
NA
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
KEY
01A
02A
03A
03B
04B
05A
06A
07A
08A
09A
10A
11A
12A
13A
14A
15A
15B
15C
18A
20A
22A
99A
Page 1 of 14
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January 28, 2014
Relief System Summary (System 1 of 1)

Part 2
RELIEF SYSTEM COMMENTS
Relief device: EMR-87003, vessel: T-87003 - PHENOLIC WATER TANK
1
EMR-87003 provides adequate overpressure protec on for all iden
Overpressure Scenario
PRD Tag
EMR-87003_T-87003-01A - EMR-87003
FIRE
EMR-87003_T-87003-09A. EMR-87003
1 - INDIVIDUAL CONTROL
VALVE OPEN-CLOSE
ed overpressure con ngencies a ec ng the EQUIPMENT (T-87003).
RELIEF SYSTEM CALCULATIONS SUMMARY

Vapor
Required
Device
Required
Quality
Relief Rate Capacity
Area
(in)
Actual
Area
(in)
Inlet P.
Loss
(% of Set P.)
Back P.
(% of Set P.)
(lb/h)
(lb/h)
1.00
3,511.26
7,265.76
7.1285
28.8902
NA
NA
1.00
896.36
5,828.88
1.3352
28.8902
NA
NA
An inherent 5% tolerance is incorporated in the inlet pressure drop and backpressure
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EQUIPMENT SUMMARY
Vessel Built Per
Vessel Shape
P&ID
API-650
Ver cal Cylindrical; User de ned heads
E-93298-08
MECHANICAL DATA
Design Pressure / MAWP

Design Vacuum
Maximum Opera ng Pressure
Straight Side Length
Inner Diameter
1.00 psig
-0.07 psig
0.00 psig
11.83
11.00
Design Temperature / MAWT

MDMT
Maximum Opera ng Temperature
Top Head Type
Bo om Head Type
250.00 F
-20.00 F
120.00 F
Conical
Flat
**VESSEL IS EXPOSED TO FIRE

Fire Flux
Dura on
Bo om Eleva on Above Where Liquids Can Pool
Vessel We ed Area
Addi onal User Speci ed We ed Area
API 2000 Mi ga on Factor
Frac on of Vessel Area Exposed to Fire
Top head and bo om head were removed from we ed area es mate
101.87
2.00
0.00
58,886.01
0.00
1
0.6823
BTU/hr/in
h
in
in
EQUIPMENT NOTES
Design Condi ons from P&ID (E-93298-08).
Dimensions from (E-93298-08).
Opera ng Condi ons from Process Flow Diagram (E-100456-00).
PROTECTIVE RELIEF DEVICES

TAG
LOCATION
P&ID
EMR-87003
Top of Tank T-87003
E-93298-08
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January 28, 2014

EMR-87003
Loca on
P&ID
Top of Tank T-87003

E-93298-08
RELIEF VALVE DATA
Manufacturer
Model
Type
Size
Flange Class
Code
Stamp Required?
Vapor Kd
Two Phase Kd
Liquid Kd
Protectoseal
7806H
Pressure vent
6x6
150 RF x 150 RF
Set Pressure
Ori ce Le er
Actual Ori ce Area
Design Ori ce Area
Blowdown
Associated Rupture Disk
Mul ple Relief Devices?
Discharge Loca on
Design Basis
Flow Area Basis
1.000
1.00 psig
28.890 in
28.890 in
7.00 %
No
No
Atmosphere
EXTERNAL FIRE EXPOSURE
Other
MATERIALS OF CONSTRUCTION
Body
Bonnet
Nozzle
Nozzle Ring
Disk or Seat
O-Ring
Guide
Guide Ring
Spring
Spring Coa ng
Disk Holder
Bellows
Spindle
Balanced Piston
Diaphragm
Retainer
Bol ng
So Goods
Gaskets
Comply with NACE MR 0175?
No
ACCESSORIES
Cap
Li ing Lever
Screwed
Plain
Test Gag
Vent with Bug Screen
Not Required
Not Required
PROTECTED EQUIPMENT
TAG
DESCRIPTION
PID
Phenolic Water Tank
E-93298-08
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EMR-87003
Loca on
P&ID
Top of Tank T-87003

E-93298-08
PIPING LAYOUT
EMR-87003 PIPING
Number of Segments
Number of Rupture Disks
Number of Relief Valves
1
0
1
Inlet
Segment Name
NPS
Schd.
Outlet
NPS
Length
Roughness
(
)
( )
Angle
Schd.
Fi ng Type
K1
Kinf
kd
No. of
Fi ngs
EMR-87003
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Page 5 of 14
EMR-87003_T-87003.cor
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EMR-87003
Loca on
P&ID
Top of Tank T-87003

E-93298-08
DESIGN BASIS
Scenario
EMR-87003_T-87003-01A - FIRE
Required Flow Rate
3,511.26 lb/h
System Capacity
7,265.76 lb/h
Inlet Pressure Drop
NA
Relief Pressure
1.20 psig
Relief Temperature
215.39 F
Fluid
DEFAULT
Fluid Phase
VAPOR
Mass Percent Vapor at PRD Inlet
100.00 %
Viscosity at Relief Temperature
Vap = 0.012 cP
Vapor Compressibility Factor
Z,v = 0.991
Speci c Heat Ra o
Cp/Cv = 1.325
Required Area
Device Actual Area
Total Backpressure
Backpressure Correc on Factor
Percent Overpressure
PRD Outlet Temperature
Vapor MW / Liquid Speci c Gravity
Liquid Latent Heat of Vaporiza on
Isentropic Expansion Coe cient
Maximum Reac on Force(in / out)
Exit Mach Number
7.1285
28.8902
NA
1.00
20.00
202.39
Mw, v = 18.015
971.76
K,v = 1.323
/ 458.23
0.35
in
in
%
F
BTU/lb
lbf
NON-DESIGN SIZING
Scenario
EMR-87003_T-87003-09A.1 - INDIVIDUAL CONTROL VALVE OPEN-CLOSE
Required Flow Rate
896.36 lb/h Required Area
System Capacity
5,828.88 lb/h Device Actual Area
Inlet Pressure Drop
NA
Total Backpressure
Relief Pressure
1.10 psig Backpressure Correc on Factor
Relief Temperature
80.00 F
Percent Overpressure
Fluid
NITROGEN
PRD Outlet Temperature
Fluid Phase
VAPOR
Vapor MW / Liquid Speci c Gravity
Mass Percent Vapor at PRD Inlet
100.00 %
Liquid Latent Heat of Vaporiza on
Viscosity at Relief Temperature
Vap = 0.018 cP
Isentropic Expansion Coe cient
Vapor Compressibility Factor
Z,v = 1.000
Maximum Reac on Force(in / out)
Speci c Heat Ra o
Cp/Cv = 1.400
Exit Mach Number
(C) iOiQ LLC.
1.3352 in
28.8902 in
NA
1.00
10.00 %
69.00 F
Mw, v = 28.014
NA
K,v = 1.401
/ 443.20 lbf
0.32
Page 6 of 14
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January 28, 2014
OVERPRESSURE SCENARIO REPORT

EMR-87003
Overpressure Scenario Applicability
EMR-87003_T-87003-01A - FIRE
Applicable
Fire exposure may result in overpressure due to vaporiza on of residing liquid. Note that the equipment is located in a re zone and is within the re
exposure height of 30 feet.
EMR-87003_T-87003-02A.1 - MANUAL VALVE OPERATION OPEN-CLOSE
Applicable
*** VAPOR ***

Source: [Line 2"-1BC1P-N-0047-0.0"-N from Nitrogen Header on P&ID E-93298-08]:
Blocked vapor outlet may result in overpressure. The upstream pressure is limited to 235 PSIG maximum normal opera ng pressure in the Nitrogen
header, which is greater than the design pressure of T-87003 (1.0 psig). See 09A.1-FV-8686 fail open for calcula ons.
The vapor outlet may become blocked in due to any number of events, including the following:
1. Inadvertent closure of the manual valve on the vapor outlet line (6"-1SA0G-AV-3006-0.0"-N) on P&ID E-93305-07.
*** LIQUID ***

Source: [Line 2"-1SA0G-DM-0058-1.5"-FET from P-87919 & P-87920, Demin Water Pumps on P&ID E-93334-08]:
Over lling may result in overpressure. The upstream pressure is limited to the discharge pressure of the upstream PUMP (P-87919 & P-87920 on
P&ID E-93334-08; 125 psig) which is greater than the design pressure of V-87003 (1.0 psig). The ow rate of DM through the control valve, LV-8687B
and its Bypass Valve, is the unknown and is the largest feed ow to T-87003.
According to the tank datasheet, the maximum feed rate to T-87003 is 1680 gal/h. It will take less than 15 mins to over ll the tank. Over lling is
considered a credible overpressure con ngency.
Refer to Gooseneck-87003 for calcula ons.
Source: [Line 1"-1SA0G-PHE-2173-1.5"-EC from E-87020 on P&ID E-93231-04]:

Over lling may result in overpressure. The upstream pressure is limited to 1.7 psig by the maximum normal opera ng pressure in the jet condensate
header, which is greater than the design pressure of T-87003 (1.0 psig). The ow rate of this line is 0.1 GPM and is unlikely to cause over lling.


Source: [Line 2"-1SA0G-HC-5083-1.5"-EC from E-87514 on P&ID E-93282-05]:

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January 28, 2014
Source: [Line 2"-1SA0G-HC-3087-1.5"-EC from E-87309 on P&ID E-93248-05]:

The liquid outlet may become blocked in due to any number of events, including the following:
1. Inadvertent closure of the manual valve on the outlet line (LINE 2"-1SA0G-PHE-0053-0.0"-N)
2. Shut-down of the downstream pump (P-87045 & P-87046; PID E-93298-08)
EMR-87003_T-87003-02A.2 - REMOTE BLOCKED OUTLET DUE TO CHECK VALVE FAILURE
Not Applicable
[2" TYPE bypass valve around LV-8687B on line 2"-1SA0G-DM-0058-1.5"-FET from P-87919 & P-87920 Demin Water Pumps; P&ID E-93334-08]:
Normal opera ng pressure upstream of the listed valve is 125 psig according to the control valve data sheet for OPERATIONS, which is greater than
the design pressure of T-87003 (1.0 psig); therefore, inadvertently opening the listed valve may result in overpressure and over lling.
[1.5" check valve on line 1.5"-1SA0G-PHE-0057-1.5"-FET from P-87045 & P-87046 to V-87204; P&ID E-93234-16]: Normal opera ng pressure
downstream of the listed check valve is 13.5 psig according to H&MB which is greater than the design pressure of upstream T-87003 (1.0 psig);
therefore, latent failure of the check valve followed by shut-down of P-87045 & P-87046 may result in overpressure due to back ow. There is at least
one block valve upstream or downstream of the check valve, refer to scenario: T-87003_STORAGE TANK-02A.1 - MANUAL VALVE OPERATION OPENCLOSE
[1.5" check valve on line 1.5"-1SA0G-PHE-0056-1.5"-FET from P-87045 & P-87046 to V-87205; P&ID E-93235-15]: Normal opera ng pressure
downstream of the listed check valve is 7.5 psig according to H&MB which is greater than the design pressure of upstream T-87003 (1.0 psig);
therefore, latent failure of the check valve followed by shut-down of P-87045 & P-87046 may result in overpressure due to back ow. There is at least
one block valve upstream or downstream of the check valve, refer to scenario: T-87003_STORAGE TANK-02A.1 - MANUAL VALVE OPERATION OPENCLOSE
[1.5" check valve on line 1.5"-1SA0G-PHE-0056-1.5"-FET from P-87045 & P-87046 to T-87000; P&ID E-93294-16]: Normal opera ng pressure
downstream of the listed check valve is 0.0 psig according to H&MB which is less than the design pressure of upstream T-87003 (1.0 psig); therefore,
latent failure of the check valve followed by shut-down of P-87045 & P-87046 WILL NOT result in overpressure due to back ow. There is at least one
block valve upstream or downstream of the check valve, refer to scenario: T-87003_STORAGE TANK-02A.1 - MANUAL VALVE OPERATION OPEN-CLOSE
EMR-87003_T-87003-02A.3 - REMOTE IMPROPER VALVE SEQUENCING
Not Applicable
RVVB-87003 discharges into to the atmosphere and improper valve sequencing would have no e ect on RVVB-87003.
EMR-87003_T-87003-03A - REMOTE INEFFECTIVE OPERATOR INTERVENTION
Not Applicable
No credit for operator interven on was applied to any of the listed scenarios.
EMR-87003_T-87003-04A - OUTBREATHING
Applicable
Outbreathing may result in overpressure due to the in ow of liquid to the tank T-87003 or due to expansion and vaporiza on of the liquid inventory
(FLUID) caused by an increase in ambient condi ons.
The following feeds to T-87003 are:
1"-1SA0G-PHE-2173-1.5"-EC from E-87020 on P&ID E-93231-04 is only 0.1 GPM (0.0134 CFM) which is unlikely to require Outbreathing as line
3"-1SA0G-AV-0042-0.0"-N is open to E-87006 on P&ID E-93305-07.
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2"-1SA0G-HC-5083-1.5"-EC from E-87514 on P&ID E-93282-05 is only 0.8 GPM (0.11 CFM) which is unlikely to require Outbreathing as line 3"-1SA0GAV-0042-0.0"-N is open to E-87006 on P&ID E-93305-07.
2"-1SA0G-HC-3087-1.5"-EC from E-87309 on P&ID E-93248-05 is only 0.2 GPM (0.027 CFM) which is unlikely to require Outbreathing as line
2"-1SA0G-DM-0058-1.5"-FET from P-87919 & P-87920 on P&ID E-93334-08 is of UNKNOWN FLOW RATE which is likely to require Outbreathing. THE
FLOW RATE FROM THE DM HEADER MUST BE ESTIMATED
Refer to RVVB-87003 Scenario-04B for calcula ons.
EMR-87003_T-87003-04B - VACUUM CREDIBLE INBREATHING
Applicable
Inbreathing as a result of the contrac on or condensa on of vapors caused by a decrease in ambient temperature or as a result of the ou low of
FLUID from the tank (TAG) may result in underpressure.
Inbreathing will be caused by pumpout of liquids by P-87045 & P-87046 at rates of possibly 50 GPM according to PI&D informa on.
EMR-87003 DOES NOT PROTECT T-87003 from Inbreathing. See Scenario 04B for RVVB-87003 calcula ons pertaining to Inbreathing.
EMR-87003_T-87003-05A - THERMAL EXPANSION RELIEF
Not Applicable
The equipment does not operate liquid-full during this mode of opera on; therefore, thermal expansion is not expected to result in overpressure.
EMR-87003_T-87003-06A.1 - GENERAL COOLING WATER FAILURE

No sources of externally supplied cooling were iden
EMR-87003_T-87003-06A.2 - PARTIAL COOLING WATER FAILURE

Not Applicable
ed for considera on.
EMR-87003_T-87003-06A.3 - INDIVIDUAL COOLING WATER FAILURE

Not Applicable
Not Applicable
EMR-87003_T-87003-08A - GENERAL POWER FAILURE
Not Applicable
In the event of a power failure, power will be lost to the following equipment:
* EQUIPMENT (P-87045 & P-87046 on P&ID E-93298-08), resul ng in inability to pump out T-87003. Feed lines to T-87003 y gravity ow and will
con nue, possibly leading to over lling T-87003. See Scenario 02A for calcula ons of over lling.
EMR-87003_T-87003-08B - INDIVIDUAL POWER FAILURE
Not Applicable
EMR-87003_T-87003-08C - PARTIAL POWER FAILURE
Not Applicable
Applicable
[PV-8686 (FAIL SAFE CLOSED) on line 2"-1BC1P-N-0047-0.0"-N from Ni rogen Header; P&ID E-93298-08]: Normal opera ng pressure upstream of
the listed control valve is 235 psig according to OPERATIONS which is greater than the design pressure of T-87003 (1.0 psig); therefore, failure open of
the listed control valve may result in overpressure.
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January 28, 2014
[LV-8687A (FAIL SAFE CLOSED) on line 2"-1SA0G-DM-0058-1.5"-FET from P-87919 & P-87920; P&ID E-93334-08]: Normal opera ng pressure
upstream of the listed control valve is 125 psig according to / OPERATIONS which is greater than the design pressure of T-87003 (1.0 psig); therefore
failure open of the listed control valve may result in overpressure. Refer to scenario 02A and 03A for considera on of failure of control valve leading
to over lling.
The over lling will be protected by the Gooseneck. See gooseneck T-87003 for calcula ons.
EMR-87003_T-87003-09A.1 - INDIVIDUAL CONTROL VALVE OPEN-CLOSE REQUIRED RELIEF RATE
Applicable
[PV-8686 (FAIL SAFE CLOSED) on line 2"-1BC1P-N-0047-0.0"-N from Ni rogen Header; P&ID E-93298-08]: Normal opera ng pressure upstream of
the listed control valve is 235 psig according to OPERATIONS which is greater than the design pressure of T-87003 (1.0 psig); therefore, failure open of
the listed control valve may result in overpressure.
[LV-8687A (FAIL SAFE CLOSED) on line 2"-1SA0G-DM-0058-1.5"-FET from P-87919 & P-87920; P&ID E-93334-08]: Normal opera ng pressure
upstream of the listed control valve is 125 psig according to / OPERATIONS which is greater than the design pressure of T-87003 (1.0 psig); therefore
failure open of the listed control valve may result in overpressure. Refer to scenario 02A and 03A for considera on of failure of control valve leading
to over lling.
EMR-87003_T-87003-09A.2 - REMOTE_ BOTH CONTROL VALVE AND BYPASS WIDE OPEN
Applicable
LV-8687B (FAIL SAFE CLOSED) on line 2"-1SA0G-DM-0058-1.5"-FET from P-87919 & P-87920; P&ID E-93334-08: The listed control valve has a 2"
bypass valve. Consider failure open of bypass with control valve in normal opera on.
EMR-87003_T-87003-10D - GENERAL INSTRUMENT FAILURE

No u lity failure situa ons were iden
ed that adversely a ect the analyzed process system during this mode of opera on.
EMR-87003_T-87003-10E - STEAM FAILURE

No hea ng failure situa ons were iden
Not Applicable
Not Applicable
ed that adversely a ect the analyzed process system during this mode of opera on.
EMR-87003_T-87003-12B - REMOTE VAPOR BREAKTHROUGH
Not Applicable
There are no situa ons of remote vapor breakthrough.
EMR-87003_T-87003-13A - REMOTE - HEAT EXCHANGER TUBE RUPTURE

No heat exchangers tube failure situa ons were iden
Not Applicable
ed that adversely a ect the analyzed relief system during this mode of opera on.
EMR-87003_T-87003-14A - REACTIVE HAZARDS
Not Applicable
There are no apparent reac ve hazards which may result in an overpressure.
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EMR-87003_T-87003.cor
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EMR-87003
Calcula on Method(s)
EMR-87003_T-87003-01A - FIRE
GAS/VAPOR RELIEF UNDER FIRE/USER HEATING USING CCPS/API 520; PIPES CONTAINING VAPOR
SCENARIO APPLICABILITY
Fire exposure may result in overpressure due to vaporiza on of residing liquid. Note that the equipment is located in a re zone and is within the re
exposure height of 30 feet.
GAS/VAPOR RELIEF UNDER FIRE/USER HEATING USING CCPS/API 520 COMMENTS

The Vapor Relief Under Fire or External Hea ng Using CCPS and API 520 model is used to quan fy th e required ow area in the event of an external
re.
The Hea ng Load and relief requirement are based on the re ux calcula ons as described in the equipment notes.
The Ini al Vessel Liquid Temperature is the normal opera ng temperature based on vessel speci ca on sheet.
The Hea ng Load is calculated based on the re ux as described above.
The Set Pressure is the set pressure of the tank vent(EMR-87003; 1 psig).
The back pressure is 0 psig since the vent relieves to atmosphere.
The Discharge Coe cient is the discharge coe cient for the relief device (0.978).
The liquid inventory (water) is based on the Equipment Data Sheet, with uid proper es obtained f rom SuperChems.
GAS/VAPOR RELIEF UNDER FIRE/USER HEATING USING CCPS/API 520 INFORMATION

Inputs
Hea ng rate
Set pressure
Back pressure
Percent overpressure
Discharge coe cient
3,414,445.51
1.00
0.00
20.00
0.978
BTU/hr
psig
psig
%
Outputs
Temperature at maximum pressure
Compressibility factor
Density
Heat of vaporiza on
Average Molecular Weight
Speci c Volume Correc on Factor
Correc on factor vapor density
Correc on factor liquid density
Back pressure correc on factor (Kb)
Flow is cri cal (choked)
Evapora on/relief rate
Volumetric ow rate
Required relief device ori ce area
216.06
0.99
0.01
971.76
18.02
1.00
0.01
7.97
1.00
No
3,511.26
72,727.13
7.129
Ini al Vessel Liquid Inventory Data

Component
Chemical Formula
WATER
H2O
Mass Frac on
1.0000
Mole Frac on
1.0000
F
lb/gal
BTU/lb
lb/gal
lb/gal
lb/h
SCFH
in
Molecular Weight
18.02
RELIEF CAPACITY COMMENTS - EMR-87003 PIPING

The Pipes Containing Vapor model is used to quan fy the relief system performance in the event of external re scenario .
The Inlet Pressure is the relief pressure based on the design pressure of the tank plus 20% allowable accumula on.
The Inlet Temperature is the relief temperature calculated in scenario EMR-87003-STORAGE TANK-T-87003-01A-FIRE.
The backpressure (Surroundings/Back Pressure) is 0 psig since the vent relieves to atmosphere.
Relief system piping (EMR-87003 piping layout) is based on a vent set on tank directly and relieves to atmosphere directly.
(C) iOiQ LLC.
Page 11 of 14
EMR-87003_T-87003.cor
January 28, 2014
The uid composion is water with uid proper es obtained from SuperChems.
RELIEF CAPACITY - EMR-87003 PIPING

Relief Condi ons:
Temperature
Pressure
Superimposed backpressure
215.39 F
1.20 psig
0.00 psig
Exit Condi ons:

Exit Temperature
Exit Pressure
Exit Mach Number
Pressure at device inlet
Backpressure
Vapor Mass Flow Rate
Volumetric Flow Rate
Relief Device Flow Area
202.39
0.00
0.35
0.00
0.00
7,265.76
150,488.59
28.8902
Vibra on Risk Analysis (IEC Acous c E ciency Used)

Segment #, Type, Name
D/t
001, Pressure Relief Valve (ori ce), EMR-87003
Maximum SPL
dB
21.66
Limit SPL
dB
138.04
172.93
F
psig
psig
psig
lb/h
SCFH
in
SPL Di erence Vibra on Risk?

dB
-34.89
Not Likely
Sound Power Level Pro le

IEC acous c e ciency used
Max SPL, dB
SPL Limit, dB
180
Sound Power Lever, dB
160
140
120
100
80
0
0.001
0.002
0.003
0.004
0.005
0.006
Axis Distance,
RELIEF STREAM DATA

Component
Chemical Formula
WATER
H2O
(C) iOiQ LLC.
Mass Frac on
1.0000
Mole Frac on
1.0000
Molecular Weight
18.02
Page 12 of 14
EMR-87003_T-87003.cor
January 28, 2014

EMR-87003
Calcula on Method(s)

IDEAL NOZZLE; PIPES CONTAINING VAPOR
SCENARIO APPLICABILITY
[PV-8686 (FAIL SAFE CLOSED) on line 2"-1BC1P-N-0047-0.0"-N from Ni rogen Header; P&ID E-93298-08]: Normal opera ng pressure upstream of the
listed control valve is 235 psig according to OPERATIONS which is greater than the design pressure of T-87003 (1.0 psig); therefore, failure open of the
listed control valve may result in overpressure.
[LV-8687A (FAIL SAFE CLOSED) on line 2"-1SA0G-DM-0058-1.5"-FET from P-87919 & P-87920; P&ID E-93334-08]: Normal opera ng pressure upstream
of the listed control valve is 125 psig according to / OPERATIONS which is greater than the design pressure of T-87003 (1.0 psig); therefore failure
open of the listed control valve may result in overpressure. Refer to scenario 02A and 03A for considera on of failure of control valve leading to
over lling.
IDEAL NOZZLE COMMENTS

The Ideal Nozzle model is used to quan fy the required ow area in the event of control valve PV-8686 wide open.
The relief temperature (nozzle inlet Temperature) is based on the normal opera ng temperature.
The relief pressure (nozzle inlet Pressure) is the design pressure of the tank plus 10% allowable accumula on.
The backpressure (Surroundings/Back Pressure) is 0 psig because the relief device discharges to atmosphere.
The relief requirement (Mass Flow Rate) is based on the required relief rate calcula on when PV-8686 wide open.
The Discharge Coe cient is 0.8 since the relief device is an emergency vent.
The uid composi on is nitrogen, with uid proper es obtained from SuperChems.
IDEAL NOZZLE INFORMATION

Input:
Ini al Phase
Temperature
Pressure
Superimposed Backpressure
Mass Flow Rate
Discharge coe cient, Kd
VAPOR
80.00
1.10
0.00
896.36
1.000
F
psig
psig
lb/h
Outputs:
Final Phase
Required Flow Area
VAPOR
1.335 in
RELIEF CAPACITY COMMENTS - EMR-87003 PIPING

The Pipes Containing Vapor model is used to quan fy the capacity of the relief vent in the event of control valve PV-8685 wide open.
The inlet temperature (nozzle inlet Temperature) is based on the normal opera ng temperature.
The inlet pressure (nozzle inlet Pressure) is the relief pressure of the emergency vent.
The backpressure (Surroundings/Back Pressure) is 0 psig since the vent discharges to atmosphere.
The uid composi on is nitrogen, with uid proper es obtained from SuperChems.
RELIEF CAPACITY - EMR-87003 PIPING

Relief Condi ons:
Temperature
Pressure
Superimposed backpressure
80.00 F
1.10 psig
0.00 psig
Exit Condi ons:

Exit Temperature
(C) iOiQ LLC.
69.00 F
Page 13 of 14
EMR-87003_T-87003.cor
January 28, 2014
Exit Pressure
Exit Mach Number
Pressure at device inlet
Backpressure
Vapor Mass Flow Rate
Volumetric Flow Rate
Relief Device Flow Area
0.00
0.32
0.00
0.00
5,828.88
78,914.94
28.8902
Vibra on Risk Analysis (IEC Acous c E ciency Used)

Segment #, Type, Name
D/t
001, Pressure Relief Valve (ori ce), EMR-87003
Maximum SPL
dB
21.66
Limit SPL
dB
133.75
172.93
psig
psig
psig
lb/h
SCFH
in
SPL Di erence Vibra on Risk?

dB
-39.18
Not Likely
Sound Power Level Pro le

IEC acous c e ciency used
Max SPL, dB
SPL Limit, dB
180
Sound Power Lever, dB
160
140
120
100
80
60
0
0.001
0.002
0.003
0.004
0.005
0.006
Axis Distance,
RELIEF STREAM DATA

Component
Chemical Formula
NITROGEN
N2
(C) iOiQ LLC.
Mass Frac on
1.0000
Mole Frac on
1.0000
Molecular Weight
28.01
Page 14 of 14

EMR-87003 T-87003 Full - Reviewed

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EMR-87003 T-87003 Full - Reviewed

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Welcome to SuperChems Version 6.50mp -- September 20, 2012

RELIEF DEVICE SUMMARY

OVERPRESSURE SCENARIO REPORT

SCENARIOS AND CALCULATIONS

January 28, 2014

Relief System Summary (System 1 of 1)

Top of Tank T-87003

T-87003 - PHENOLIC WATER TANK

Phenolic Water Tank

The currently installed relief system is adequate

EXTERNAL FIRE EXPOSURE

(C) iOiQ LLC.

SuperChems Expert v7.21mp (09-30-2013)

January 28, 2014

Relief System Summary (System 1 of 1)

EMR-87003 provides adequate overpressure protec on for all iden

ed overpressure con ngencies a ec ng the EQUIPMENT (T-87003).

RELIEF SYSTEM CALCULATIONS SUMMARY

An inherent 5% tolerance is incorporated in the inlet pressure drop and backpressure

(C) iOiQ LLC.

SuperChems Expert v7.21mp (09-30-2013)

January 28, 2014

Design Pressure / MAWP

Design Temperature / MAWT

**VESSEL IS EXPOSED TO FIRE

PROTECTIVE RELIEF DEVICES

Top of Tank T-87003

(C) iOiQ LLC.

SuperChems Expert v7.21mp (09-30-2013)

January 28, 2014

RELIEF DEVICE SUMMARY

Top of Tank T-87003

T-87003 - PHENOLIC WATER TANK

Phenolic Water Tank

(C) iOiQ LLC.

SuperChems Expert v7.21mp (09-30-2013)

January 28, 2014

RELIEF DEVICE SUMMARY

Top of Tank T-87003

(C) iOiQ LLC.

SuperChems Expert v7.21mp (09-30-2013)

January 28, 2014

RELIEF DEVICE SUMMARY

Top of Tank T-87003

(C) iOiQ LLC.

SuperChems Expert v7.21mp (09-30-2013)

January 28, 2014

OVERPRESSURE SCENARIO REPORT

EMR-87003_T-87003-02A.1 - MANUAL VALVE OPERATION OPEN-CLOSE

*** VAPOR ***

*** LIQUID ***

Source: [Line 1"-1SA0G-PHE-2173-1.5"-EC from E-87020 on P&ID E-93231-04]:

Source: [Line 2"-1SA0G-PHE-4021-1.5"-EC from E-87415 on P&ID E-93257-05]:

Source: [Line 2"-1SA0G-PHE-4169-1.5"-EC from E-87416 on P&ID E-93267-05]:

Source: [Line 2"-1SA0G-HC-5083-1.5"-EC from E-87514 on P&ID E-93282-05]:

(C) iOiQ LLC.

SuperChems Expert v7.21mp (09-30-2013)

January 28, 2014

Source: [Line 2"-1SA0G-HC-3087-1.5"-EC from E-87309 on P&ID E-93248-05]:

EMR-87003_T-87003-02A.2 - REMOTE BLOCKED OUTLET DUE TO CHECK VALVE FAILURE

EMR-87003_T-87003-02A.3 - REMOTE IMPROPER VALVE SEQUENCING

EMR-87003_T-87003-03A - REMOTE INEFFECTIVE OPERATOR INTERVENTION

(C) iOiQ LLC.

* VAPOR *

* LIQUID *