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2 Hazards identification
Classification of the substance or mixture:
GHS02 Flame
Flam. Aerosol 1 H222 Extremely flammable aerosol.
GHS08 Health hazard
Muta. 1B
Carc. 1B
Skin Irrit. 2
H315 Causes skin irritation.
Eye Irrit. 2A
H319 Causes serious eye irritation.
Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of international guidelines.
Warning! Pressurized container.
(Contd. on page 2)
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Classification system:
The classification was made according to the latest editions of international substances lists, and expanded upon
from company and literature data.
Risk phrases:
May cause cancer.
May cause heritable genetic damage.
Extremely flammable.
Also harmful by inhalation and in contact with skin.
Irritating to eyes and skin.
Safety phrases:
Keep locked up and out of the reach of children.
Keep container tightly closed and in a well-ventilated place.
Keep away from food, drink and animal feedingstuffs.
Keep away from sources of ignition - No smoking.
When using do not eat or drink.
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).
Avoid contact with eyes.
Take precautionary measures against static discharges.
Wear suitable protective clothing and gloves.
In case of insufficient ventilation, wear suitable respiratory equipment.
Special labelling of certain preparations:
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50C, i.e. electric lights.
Do not pierce or burn, even after use.
Do not spray on a naked flame or any incandescent material.
Classification in accordance with Directive 75/324/EEC: Extremely flammable
Hazard description:
WHMIS-symbols:
A - Compressed gas
B5 - Flammable aerosol
D2A - Very toxic material causing other toxic effects
Health = 2
Fire = 4
Reactivity = 0
3 Composition/information on ingredients
Chemical characterization: Mixtures
Description: Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
8052-41-3 Stoddard solvent
Flam. Liq. 3, H226;
Muta. 1B, H340; Carc. 1B, H350; Asp. Tox. 1, H304
25-30%
(Contd. on page 3)
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1330-20-7 xylene
Flam. Liq. 3, H226;
Acute Tox. 4, H312; Acute Tox. 4, H332; Skin Irrit. 2, H315
68476-85-7 Petroleum gases, liquefied
Flam. Gas 1, H220; Flam. Liq. 1, H224;
Muta. 1B, H340; Carc. 1B, H350; Press.
Gas, H280
67-63-0 propan-2-ol
Flam. Liq. 2, H225;
Eye Irrit. 2, H319; STOT SE 3, H336
67-64-1 acetone
Flam. Liq. 2, H225;
Eye Irrit. 2, H319; STOT SE 3, H336
78-93-3 butanone
Flam. Liq. 2, H225;
Eye Irrit. 2, H319; STOT SE 3, H336
100-41-4 ethylbenzene
Flam. Liq. 2, H225;
Acute Tox. 4, H332
108-65-6 2-methoxy-1-methylethyl acetate
Flam. Liq. 3, H226
Additional information: Exact concentrations are being withheld as trade secrets.
20-<25%
10-<25%
10-<15%
10%
3.0-7.0%
3-5%
1-<3%
5 Firefighting measures
Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water.
For safety reasons unsuitable extinguishing agents: Water with full jet
Special hazards arising from the substance or mixture: No further relevant information available.
Protective equipment: Mouth respiratory protective device.
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67-63-0 propan-2-ol
EL Short-term value: 400 ppm
Long-term value: 200 ppm
EV Short-term value: 400 ppm
Long-term value: 200 ppm
67-64-1 acetone
EL Short-term value: 500 ppm
Long-term value: 250 ppm
EV Short-term value: 750 ppm
Long-term value: 500 ppm
78-93-3 butanone
EL Short-term value: 100 ppm
Long-term value: 50 ppm
EV Short-term value: 885 mg/m, 300 ppm
Long-term value: 590 mg/m, 200 ppm
100-41-4 ethylbenzene
EL 20 ppm
IARC 2B
EV Short-term value: 540 mg/m, 125 ppm
Long-term value: 435 mg/m, 100 ppm
108-65-6 2-methoxy-1-methylethyl acetate
EL Short-term value: 75 ppm
Long-term value: 50 ppm
EV 270 mg/m, 50 ppm
Additional information: The lists that were valid during the creation were used as basis.
Personal protective equipment
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves:
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
(Contd. on page 6)
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Eye protection:
Tightly sealed goggles
pH-value:
Not determined.
Change in condition
Melting point/Melting range:
Boiling point/Boiling range:
-95.3 C
> 56 C
Flash point:
Ignition temperature:
230 C
Decomposition temperature:
Not determined.
Auto igniting:
Danger of explosion:
Explosion limits
Lower:
Upper:
1.1 Vol %
13.0 Vol %
Vapor pressure at 20 C:
233 hPa
Density at 20 C:
Relative density:
Vapour density at 20 C:
Evaporation rate:
0.77 g/cm
Not determined.
4.6 (AIR=1)
Not applicable.
Not determined.
Not determined.
Solvent content:
Organic solvents:
58.3 %
(Contd. on page 7)
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Other information
VOC Content:
VOC %:
HAP Content
MIR Value
693.090 g/l
>99 %
154.020 g/l
2.472 g O/g
11 Toxicological information
Information on toxicological effects:
Acute toxicity
LD/LC50 values that are relevant for classification:
1330-20-7 xylene
Oral
LD50 4300 mg/kg (rat)
Dermal LD50 2000 mg/kg (rabbit)
Specific symptoms in biological assay: No further relevant information available.
Primary irritant effect
on the skin: Irritant to skin and mucous membranes.
on the eye: Irritating effect.
Sensitization: No sensitizing effects known.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Harmful
Irritant
Carcinogenic.
The product can cause inheritable damage.
Carcinogenic categories
IARC (International Agency for Research on Cancer)
1330-20-7 xylene
67-63-0 propan-2-ol
100-41-4 ethylbenzene
3
3
2B
12 Ecological information
Aquatic toxicity: No further relevant information available.
Persistence and degradability: No further relevant information available.
Behavior in environmental systems
Bioaccumulative potential: No further relevant information available.
Mobility in soil: No further relevant information available.
(Contd. on page 8)
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13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings
Recommendation:
Place in a sealed container and label as waste. Place in a safe area, and comply with all federal, state, provincial
and local regulations for disposal.
14 Transport information
UN-Number
DOT, TDG, IMDG, IATA
UN1950
AEROSOLS, flammable
1950 AEROSOLS
AEROSOLS
Class
Label
TDG (Transport dangerous goods):
2.1
2.1
TDG class:
Label
2 5F Gases
2.1
IMDG, IATA
Class
2.1
(Contd. on page 9)
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Label
2.1
Packing group
DOT, TDG, IMDG, IATA
Not Available
Environmental hazards:
Marine pollutant:
No
Warning: Gases
F-D,S-U
TDG
Remarks:
IMDG
Remarks:
IATA
Remarks:
UN "Model Regulation":
15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
1330-20-7 xylene
67-63-0 propan-2-ol
78-93-3 butanone
100-41-4 ethylbenzene
TSCA (Toxic Substances Control Act):
All ingredients are listed.
(Contd. on page 10)
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Proposition 65
Chemicals known to cause cancer:
100-41-4 ethylbenzene
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
EPA (Environmental Protection Agency):
1330-20-7 xylene
67-64-1 acetone
78-93-3 butanone
100-41-4 ethylbenzene
TLV (Threshold Limit Value established by ACGIH):
1330-20-7 xylene
67-63-0 propan-2-ol
67-64-1 acetone
100-41-4 ethylbenzene
I
I
1
D
A4
A4
A4
A3
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16 Other information
This MSDS format meets ANSI Z400.1-1998, OSHA 1910.1200 and WHMIS requirements. Kemper System
America, Inc. provides the information contained herein in good faith but makes no representation as to its
comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary
handling of the material by a properly trained person using this product. Product use and conditions of use are
beyond the control of Kemper System America, Inc. Warranty of materials is limited to test results of product
performance as detailed in certificates of compliance. Interpretation of test results is the responsibility of end-user.
No other warranties, expressed or implied, are made. Kemper System America, Inc is an ISO 9001:2008
registered company.
Department issuing MSDS: Product safety department
Contact: Stephen Nowicki
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
NFPA: National Fire Protection Association (USA)
WHMIS: Workplace Hazardous Materials Information System (Canada)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
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