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Dr. D. Mandal
References.
[1] Mandal D., Sathiyamoorthy D., Vinjamur M., Experimental Measurement of Effective
Thermal Conductivity of Packed Lithium-Titanate Pebble Bed, Fusion Eng. Des, 87, 6776, 2012.
[2] Mandal D., Sathiyamoorthy D., Vinjamur M., Hydrodynamics of Beds of Small Particles in
the Voids of Coarse Particles, Powder Technol., 235, 256262, 2013.
[3] Mandal D., Sathiyamoorthy D., Vinjamur M., Void fraction and effective thermal
conductivity of binary particulate bed, Fusion Eng. Des, 88, 216-225, 2013.
[4] Mandal D., Sathiyamoorthy D., Vinjamur M., Experimental Investigation of Heat Transfer
in Gas-Solid Packed Fluidized Bed, Powder Technol., 246, 252268, 2013.
10 April 2014
10-4-2014
HT IN PB
The ratio of the thermal conductivity of pebble to that of gas i.e., ks/kg
(b)
The structure of the pebble matrix, void fraction and its distribution and the extent of
the continuity of the solid phase are important.
(c)
Whether pebbles are coated with other materials or not. The contact resistance
between the non-consolidated pebbles, i.e., the solid surface oxidation and other
coatings are important.
(d)
The ratio of the mean free path of gas molecules and the average linear pore
dimension (i.e., the Knudsen number) also affect the conductivity.
HT IN PB
HT IN PFB
r
qz|z+z
qr|r+r
qz|z
qr
|r
pfb + P + f = 1
Bed is heated at a constant bed wall temperature ( Tw )
Gas flows at constant superficial gas velocity ( u ),
o
Temperature gradient will exist along the radial as well as in the axial direction.
Effective thermal conductivity of this packed fluidized bed may be determined from
steady state energy balance.
One concentric annulus elemental volume of inner radius r , outer radius r + r and
height (as shown in Figure 1) inside the bed has been considered for the development
of the model to estimate effective thermal conductivity ( k eff, pfb ) .
The following assumptions have been made in the derivation of energy balance
equation within the elemental volume.
10-4-2014
3-8-2012
HT IN PB HT IN PFB
2/8
Mass flux of gas and fluidized particles across the boundary of the elemental volume is
negligible.
Packing pebbles in the elemental volume are considered as an integrated mass and the
contact resistance among the pebbles due the surface roughness is negligible.
The gas velocity ( u ) and the velocity of the fluidized particle in the interstices within
the elemental volume are the same.
At steady state heat is neither generated nor accumulated in the elemental volume.
10-4-2014
HT IN PFB
q r , i = 2 (r + r ) z q r |r + r
(1)
The rate of thermal energy leaving along the radial direction at is . Then we can
estimate using Equation 2.
q r , o = 2 r z q r |r + r
(2)
The rate of thermal energy entering along the axial direction by conduction at is ,
which can be estimated using Equation 3.
q z , i = 2 rr q z |z
(3)
HT IN PFB
q r , o = 2 r z q r |r + r
(4)
The rate of thermal energy entering with the flowing gas along the axial direction at z ,
( q g , i ) can be estimated using Equation 5.
q g , i = (2 rr u g pfb ) c p (Tg Ti ) |z
(5)
The rate of thermal energy entering along with the fluidizing particles along the axial
direction at
( q ) can be estimated using Equation 6.
f ,i
q f , i = (2 rr u f f ) c pf (T Ti ) | z
(6)
Similarly, the rate of thermal energy entering along the axial direction through the
packing pebbles at z ( q ) can be estimated using Equation 7.
P, i
q P, i =
10-4-2014
({(r + r ) 2 r 2 } z P P ) c p , P (T Ti ) |z
4
HT IN PFB
(7)
9
c p ,f , c
p, P
cp
and
q g ,o = (2 r ru pfb g ) c p (Tg Tg ,i ) |z + z
(8)
The rate of thermal energy out with the fluidized particles from the elemental volume
along the axial direction at z + z ,
q f ,o = (2 r r u g fp ) c p (Tg Tg ,i ) |z + z
(9)
Similarly, the rate of thermal energy out along the axial direction through the packing
pebbles at z + z,
10-4-2014
HT IN PFB
10
q p, o
= ({(r + r ) 2 r 2 } z P P ) c p , P (Tg Tg , i ) |z + z
4
(10)
The size ratios of particles to pebbles ranging from 0.0231-0.078 were used in the
present study.
Normally, solid has much higher thermal conductivity than that of the
gas. So, the amount of thermal energy in and out through the packing pebbles as
shown in Equations 7 and 10 respectively may be assumed to be equal. From
Equations 1-10 and taking the limits r 0 and z 0 the energy balance equation
can be written as,
T
1 (rq r ) q z
u o ( g c p pfb + f c f f ) g = 0
r r
z
z
(11)
q r = k e ,r
and
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dT
dr
HT IN PFB
(12)
11
q z = k e ,z
where,
qr
and
qz
dT
dz
(13)
T
k e ,r T
2T
2T
+ r 2 + k e ,z 2 = u o ( g c p pfb + fpc p,f fp )
z
r r
r
z
(14)
Equation 14 can be further simplified to Equation 15 as the second term on the left
hand side is negligible, since the temperature gradient along the axial direction is less
compared to that along the radial direction, moreover, the value of its second
derivative may be very negligible.
k e, r
10-4-2014
1 T 2 T
T
(
)
=
u
g p pfb
fp p , f fp
2
r
r
z
HT IN PFB
(15)
12
k e, r
T
u (g c p pfb + fpc p, f fp )
z
=
1 T 2T
+ 2
r r r
(16)
Equation 16 is similar to the equation used by Bunnell et al. [2] and Mandal et al. [3] in
the determination of effective thermal conductivity of packed bed under similar
conditions, except the second part within the brackets in the numerator of the right
hand side, which is due the contribution of conductive heat transfer by the fluidized
particles in the packed fluidized bed.
[2 ] G. Bunnell, H. B. Irvin, R. W. Olson, J.M. Smith, Effective Thermal Conductivities in Gas-Solid Systems, I. &
E. C., 1949, 9, 1977-1982.
[3] D. Mandal, D. Sathiyamoorthy, M. Vinjamur, Experimental Measurement of Effective Thermal Conductivity of
Packed Lithium-Titanate Pebble Bed, Fusion Eng. Des, 2012, 87, 67-76.
10-4-2014
HT IN PFB
13
HT IN PFB
14
EXPERIMENTAL SET-UP
SS
Cyclone
Separator
DPTs
Instrumentation cables
Transmitters
Oil
filter
Dew
Point
Ana.
PRV
P8
P7
P6
P5
P4
PP33
P2
P1
Test
Secti
on
T18 T19
T20T21
T14 T15
T16T17
T10 T11
T12T14
T6 T7 T8T9
T2 T3 T4T5
T1
Flow
Meter
Computer
Compressor
Air-drying
Primary
unit
receiver
Secondary
Air-receiver
Instrumentation cables
Control Panel
Indication Panel
HT IN PFB
ID,
Pebble size
1, 3, 5, 7 and 10 mm
2.4
k = 2.72-1.05x10-3 T- 7.5x10-5T2
s
ks [ W / m K ]
2.7
2.1
1.8
1.5
1.2
200oC
400oC
600oC
300
450
600
750
900
T [ K]
0.07 m/s
0.14 m/s
0.21 m/s
0.28 m/s
10-4-2014
HT IN PFB
16
1.1
PB
1.0
Li2TiO3
Tw=200 C
DP=10
G=0.163kg/m s
were determined.
0.9
0.8
0.7
z/H=0.894, PB
0.6
bed
0.5
z/H=0.591, PB
0.4
0.3
Z/H=0.288, PB
0.2
z/H=0.045, PB
0.1
0.0
0.0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1.0
ke,r
10-4-2014
G c pg
=
2T
+
locations
Tg
1 T
r r
Two-dimensional homogeneous
HT IN PFB
DP=1mm
keff pb [W/mK]
200oC
at 400oC at 600oC
0.893
0.859
0.642
0.954
0.896
0.725
1.229
1.035
0.913
1.261
1.225
1.214
DP=3mm
G
keff pb [W/mK]
2
[kg/m -s] 200oC
400oC
0.162
0.961 0.903
0.326
1.525 1.229
0.493
1.846 1.629
0.663
1.933 1.902
G
2
[kg/m -s]
0.162
0.326
0.493
0.663
10-4-2014
600oC
0.759
1.181
1.356
1.667
DP=5mm
keff pb [W/mK]
200oC
at 400oC at 600oC
1.280
1.263
1.108
1.765
1.617
1.421
1.862
1.738
1.679
1.961
1.989
1.982
HT IN PFB
1.3
Li2TiO3: Dp=1.0 mm
2.2
1.2
Keff increases
0.9
0.8
1.7
with increase
1.9
1.8
0C
40
o
in G
20
0 Co
C
200
[ W m-1 K-1 ]
C
400
1.0
2.0
keffpb
2.1
1.1
keffpb [ Wm-1K-1 ]
Li2TiO3: DP=10mm
1.6
0.7
1.4
0.1
0.6
0.1
0.2
0.3
0.4
0.5
-2
0.6
0.3
0.7
0.4
0.5
-2
0.6
0.7
-1
G [Kg m S ]
2.3
2.2
Li2TiO3: DP= 7 mm
2.1
0.2
-1
G [Kg m S ]
2.2
2.0
Li2TiO3 DP=10 mm
Keff increases
2.1
1.9
keffpb [Wm-1K-1 ]
2.0
1.8
1.7
1.6
20
0 Co
C
600
1.5
C
600
1.5
with increase
1.9
1.8
0C
20
o
0C
20
o
0C
60
o
1.7
C
400
o
0C
60
1.4
1.3
1.6
1.5
in Rep
1.2
1.4
1.1
40
60
80
100
120
140
160
180
200
220
240
260
50
150
200
250
Rep [-]
Rep [-]
10-4-2014
100
HT IN PFB
19
Keffpb [ W m-1K-1 ]
1.6
DP = 10 mm
1.4
DP = 7mm
V = 5m3/hr
G=0.162 Kgm-2s-1
DP = 5 mm
1.2
keff , pb
increase in
1.0
decreases with
Tw
DP = 3 mm
0.8
D =
P
1 mm
0.6
200
300
400
500
600
T [ C]
2.2
increase with
DP
5mm ( = 0.459)
3mm ( = 0.441),
1mm ( = 0.483),
7mm ( = 0.447) Tw: 200oC
7mm
2.0
3mm
1.8
keffpb [ W / m K ]
keff , pb
1.6
1.4
1.2
1mm
5mm
1.0
0.8
4
10
12
14
16
18
20
22
10-4-2014
HT IN PFB
20
keff , pb
depends on
Re p and Tw
2.4
keffpb [ W / m K ]
Correlation is proposed to
estimate
2.8
keff , pb
2.0
1.6
1.2
0.8
ka ,T
keff , pb
ka ,T
0.2 Tw
= 18 Re p
Ta
T
= 15 Re0p.2 w
Ta
0.14
for Re p < 15
Re p =
10-4-2014
100
150
200
250
2.2
2.0
0.44
for Re p 15
50
Rep [-]
keff , pb
1.8
1.6
1.4
1.2
1.0
0.8
(1 pb )
0.6
0.6
0.8
1.0
1.2
1.4
1.6
1.8
2.0
2.2
HT IN PFB
21
uo/umfpf=1
Xfi =20%
1.1
Tw=200oC
DP=10mm
dp/DP=0.0231
z/H=0.894, PFB
1.0
z/H=0.591 PFB
0.9
0.8
z/H=0.045, PFB
z/H=0.288, PFB
Packed fluidized
bed
T / Tw [-]
0.7
z/H=0.894, PB
0.6
0.5
z/H=0.591, PB
0.4
0.3
Z/H=0.288, PB
z/H=0.045, PB
0.2
0.1
Packed bed
PB-PACKED BED
0.0
0.0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1.0
r/R [-]
HT IN PFB
22
TEMPERATURE PROFILES
1.2
uo/umfpf=1
Xfi =20%
1.1
Tw=200oC
DP=10mm
dp/DP=0.0231
Temperatures
z/H=0.894, PFB
1.0
z/H=0.591 PFB
0.9
0.8
fluidized
z/H=0.045, PFB
z/H=0.288, PFB
T / Tw [-]
0.7
were
higher
than
the
z/H=0.894, PB
0.6
bed
0.5
z/H=0.591, PB
0.4
0.3
Z/H=0.288, PB
Voids
z/H=0.045, PB
0.2
0.1
0.0
0.0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1.0
higher
r/R [-]
1.1
uo/umfpf =2
1.0
Xfi =20%
Tw=200oC
DP=10mm
dp/DP=0.0231
z/H=0.894, PFB
0.9
z/H=0.591 PFB
0.8
z/H=0.288, PFB
T / Tw [-]
0.7
z/H=0.045, PFB
0.6
z/H=0.894, PB
0.5
0.4
z/H=0.591, PB
0.3
Z/H=0.288, PB
0.2
temperature,
z/H=0.045, PB
0.1
0.0
0.0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1.0
r/R [-]
10-4-2014
HT IN PFB
23
Li2TiO3
Xfi=20%
dp/DP=0.0231
DP=10mm
2.1
2.0
1.9
1.8
1.7
0
20
600oC
C
400
1.6
1.5
1.4
1.3
1.2
1.0
1.5
2.0
2.5
3.0
3.5
4.0
uo / umfpf [-]
2.4
uo > 3umf , pf
2.3
2.2
[-]
2.0
keffpfb / keffpb
2.1
1.9
200 C
C
400
1.8
1.7
600oC
1.6
1.5
1.4 Li TiO
2
3
1.3
1.0
Xfi=40%
1.5
dp/DP=0.0231
2.0
2.5
DP=10mm
3.0
3.5
4.0
uo / umfpf [-]
10-4-2014
HT IN PFB
24
2.6
Xfi=60 %
dp/ DP=0.02
DP=10mm
2.5
2.4
keff , pfb
in
2.3
increases increase
uo / umf , pf
2.2
o
200 C
2.1
2.0
C
400
1.9
keff , pfb
keff , pfb
increases with
keff , pfb
is maximum at
is maximum at
uo / umf , pf 3
C
600
1.8
1.7
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
1.0
Li2TiO3
1.5
2.0
2.5
uo / umfpf [-]
dp/DP=0.04275
Xfi=60%
3.5
4.0
X fi
DP=10mm
X fi = 60 %
200 C
o
C
400
C
600
keff , pfb
1.5
2.0
2.5
uo / umfpf [-]
10-4-2014
3.0
3.0
3.5
4.0
enhancement of
HT IN PFB
Tw
the
keff , pfb
25
uo / umfpf =1
DP =10 mm
dp / DP = 0.0231
1.7
uo / umfpf = 1
1.9
DP =10 mm
dp / DP = 0.04275
1.6
1.5
1.7
keffpfb [ W m-1K-1]
keffpfb [Wm-1K-1]
1.8
1.6
1.5
1.4
o
1.3
C
200
1.2
400 C
600 oC
1.3
1.2
1.1
1.1
1.0
1.4
20
30
40
50
60
70
uo / umfpf = 3
dp / DP = 0.0231
2.0
DP =10 mm
50
60
70
80
Xfi [ % ]
uo / umfpf = 3
dp / DP = 0.04275
DP =10 mm
1.8
200oC
keffpfb [ Wm-1K-1 ]
keffpfb [Wm-1K-1]
40
1.9
1.8
600 oC
1.6
1.5
1.4
400oC
1.7
1.6
1.5
1.4
200 C
1.3
1.2
1.2
400 C
1.1
20
30
40
50
60
70
80
1.0
Xfi [%]
10-4-2014
30
2.1
1.9
1.3
400 C
20
2.1
1.7
600oC
1.0
80
Xfi [%]
2.0
200 C
20
600 C
30
40
50
60
70
80
Xfi [%]
HT IN PFB
26
keffpfb / keffpb
[-]
Li2TiO3
Xfi=40%
dp/DP=0.04275
DP=10mm
Tw
200 C
400 C
o
600 C
1.0
1.5
2.0
2.5
3.0
3.5
4.0
u / umfpf [-]
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
Li2TiO3
Xfi=60%
dp/DP=0.04275
DP=10mm
200 C
o
C
400
operating conditions
C
600
1.0
1.5
2.0
2.5
3.0
3.5
4.0
uo / umfpf [-]
10-4-2014
HT IN PFB
27
OPTIMUM PARAMETERS
keff , pfb
10-4-2014
dp
uo
umf , pf
HT IN PFB
28
keff , pfb
depends on, X fi
d p / DP and Tw
x
1.2
=
y
2.2
keff , pfb
2.0
1.8
.8x
y=0
1.6
1.4
1.2
Particle size:
231m
428 m
550m
780m
1.0
0.8
0.6
0.6
1.0
1.4
1.6
1.8
2.0
2.2
2.4
ks
0.15 0.33 DP
2
Pe
(1 pfb ) + 7.7 x10 X f
=
dp
kg
kg
d puo g c pg
(1 pfb )
Pe =
Peclet Number kg
10-4-2014
1.2
-1 -1
keff , pfb
0.8
HT IN PFB
1.1
29
THE END
10-4-2014
HT IN PFB
29