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771
S. Usa, K. Udayakumar
High voltage division, College of Engineering, Anna University
Guindy, Chennai 600 025
Tamil Nadu, India
ABSTRACT
In this paper, theoretical correlation amongst various electrical characteristics of a
housing / weather shed material is attempted. Also, a correlation relating tensile
strength (a mechanical property) to insulation characteristics is proposed. The
housing material used, is made of polymeric blends (Silicone/EPDM) with and
without fillers (silica and alumina trihydrate).The proposed correlation is obtained
through Dimensional Analysis technique. An attempt is also made to provide
qualitative interpretations for these relationships, based on the fundamental
physical quantities. Multivariate regression analysis of experimental values of the
dependent and independent variables, that figure in these correlations is carried
out. It yielded almost the same values for the exponents as those in the correlations
developed using dimensional analysis. This confirmed similar quantitative and
qualitative influences of various insulation parameters on tracking resistance and
tensile strength, as predicted by the dimensional analysis approach.
Index Terms - Insulators, polymeric housing, weather shed material, silicone
rubber, EPDM, insulation characteristics, dimensional analysis, matrix analysis,
multivariate regression, tracking resistance, tensile strength, fillers, ATH, silica.
1 INTRODUCTION
POLYMERIC housing materials are being accepted
increasingly for use in outdoor insulators. It is difficult to
evaluate life expectancy of polymeric insulators. The
tremendous growth is due to their advantages over the
traditional ceramic and glass insulators [1].
Manuscript received on 28 August 2007, in final form 12 December 2007.
772
R. R. Prabu et al.: Theoretical Correlations amongst Electrical and Mechanical Characteristics of Polymeric Housing Materials
3 RESULTS
The experimental data of various insulator properties for
the silicone/EPDM blend housing material are given in
Table 1 and the experimental data for 1:1 silicone: EPDM
blend with various levels of silica and alumina trihydrate (in
PHR) are given in Tables 2 and 3.
All the tests are carried out as per the IEC/ASTM
standards. In general, 5 samples are tested per blend
composition per test per property. Occasionally, 7 samples
are also tested, to rule out the experimental errors.
Various levels of silica filler are added to the silicone and
EPDM composite (in 1:1 weight ratio). The levels of filler
added are in parts per hundred parts of rubber (PHR).This is
shown along with the measured parameters and results in
Table 2.
Various levels of alumina trihydrate (ATH) filler are
added to the silicone and EPDM composite (in 1:1 weight
ratio). The levels of filler added are in parts per hundred
parts of rubber (PHR).This is shown along with the
experimentally determined parameters and their results in
Table 3.
773
Silicone:
EPDM
(weight ratio)
Tracking
Res. (TR)
(minute)
Vol. Res.
(VR) Ohmm
Surf. Res.
(SR)
Ohm
Arc Res.
(AR)
(second)
Dielec. Str.
(DES)
kV/mm
CTI
(Volt)
Tens. Str.
(TS) N/mm2
0:100
10:90
30:70
50:50
70:30
90:10
100:0
086
095
108
116
123
129
138
8.00 e12
2.00 e13
3.00 e13
4.70 e13
8.00 e13
1.30 e14
6.29 e14
5.65 e13
1.30 e14
1.80 e14
2.60 e14
5.00 e14
7.80 e14
3.10 e15
182
246
308
363
382
427
600
20.00
24.27
25.92
27.56
31.95
33.26
36.08
415
435
452
475
495
505
520
4.257
2.971
2.733
2.332
1.936
1.490
0.500
CTI
(Volt)
Tens.Str.
(TS) N/mm2
475
495
501
505
530
509
536
512
515
517
518
521
518
2.332
3.700
4.970
6.420
6.320
6.100
6.050
6.037
5.985
5.865
5.814
5.758
5.650
Table 2. Experimental Data For 50:50 Silicone:EPDM Blend With Silica Filler.
Silica filler in
PHR
Tracking
Res. (TR)
(minute)
0
116
10
127
20
135
30
146
30 (wst)
218
40
163
40 (wst)
235
50
175
60
193
70
205
80
213
90
222
100
228
wst with silane treatment
Vol. Res.
(VR) Ohmm
4.70e13
4.10e13
3.58e13
3.18e13
3.20e13
3.10e13
3.28e13
3.05e13
2.99e13
2.95e13
2.90e13
2.87e13
2.85e13
Surf. Res.
(SR)
Ohm
2.60e14
2.65e14
2.68e14
2.73e14
3.40e14
2.78e14
3.46e14
2.82e14
2.86e14
2.90e14
2.93e14
2.95e14
2.97e14
Arc Res.
(AR)
(second)
363
370
376
379
395
382
400
386
390
394
397
401
408
Dielec. Str.
(DES)
kV/mm
27.56
30.60
33.50
35.70
35.90
33.30
34.10
32.50
32.00
31.50
31.40
31.00
30.50
Table 3. Experimental Data For 50:50 Silicone:EPDM Blend With ATH Filler.
ATH filler in
PHR
Tracking
Res. (TR)
(minute)
0
116
10
149
20
155
30
164
30 (wst)
220
40
181
40 (wst)
238
50
193
60
211
70
223
80
232
90
240
100
246
wst with silane treatment
Vol. Res.
(VR) Ohmm
Surf. Res.
(SR) Ohm
Arc Res.
(AR)
(second)
Dielec. Str.
(DES)
kV/mm
CTI
(Volt)
Tens.Str.
(TS) N/mm2
4.70e13
3.85e13
3.45e13
3.18e13
3.36e13
3.10e13
3.31e13
3.05e13
2.99e13
2.96e13
2.90e13
2.87e13
2.85e13
2.60e14
2.68e14
2.71e14
2.74e14
2.78e14
2.78e14
3.60e14
2.82e14
2.86e14
2.89e14
2.94e14
2.98e14
3.02e14
363
384
391
395
400
400
412
404
408
412
417
420
424
27.56
30.92
34.80
36.90
37.20
35.10
35.50
33.20
32.50
32.10
31.60
31.30
30.80
475
482
495
515
540
527
546
532
544
556
No Failure
No Failure
No Failure
2.332
3.500
5.050
6.350
6.200
5.825
5.780
5.406
5.387
5.258
5.165
5.080
4.980
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R. R. Prabu et al.: Theoretical Correlations amongst Electrical and Mechanical Characteristics of Polymeric Housing Materials
1
2
1
2
T 1 -2
-2
-2
-1
-2
Q 00
-2
-1
-2
-1
(2)
Here an, bn, cn, and dn are the power indexes of the
repeated variables. The dimensionless expression for 1 and
2 are:
1 D1 [M L2 T-2 Q-1]a1 [M L T-2 Q-1]b1 [M L2 T-1 Q-2]c1
[ M L3 T-2 Q-2]d1 [T]
= [M0 L0 T0 Q0]
(3)
2 D2 [M L2 T-2 Q-1]a2 [M L T-2 Q-1]b2 [M L2 T-1 Q-2]c2
(4)
[ M L3 T-2 Q-2]d2 [M L-1 T-2] = [M0 L0 T0 Q0]
Equating the powers of fundamental units M, L, T, and Q
on both sides of the above two expressions would lead to
homogeneous linear algebraic equations. The solutions of
those linear algebraic equations would give the values of the
power indexes using which one can construct the
mathematical relationship for Tracking Resistance (TR) and
Tensile Strength (TS) using the repeated variables.
Using equation (1), an expression for Tracking Resistance
(TR) can be written as
1 D1 [M] a1+b1+c1+d1
a -b -2c -2d
= [M]0
1 1 1 1
=0
(8)
= -1
a1 + b1 + c1 + d1 = 0
a2 + b2 + c2 + d2
775
2a -2b -c -2d -2
2 2 2 2
(7)
6 MULTIVARIATE REGRESSION
ANALYSIS
In order to make sure whether the relationship arrived at
using the DA approach is the best possible equation for
predicting TR, the multivariate regression is done on the
entire set of experimental data obtained with and without
fillers and with and without tri ethoxy vinyl silane treatment
involving the above mentioned variables. Here, the TR is
the dependent variable (Y). CTI, DES, SR, AR and VR are
the independent variables (X1, X2, X3, X4, X5)
respectively.
While carrying out the dimensional analysis, the
exponents of the independent variables in that equation are
arrived at purely by adjusting the dimensions on either side
of the equation. The multivariate regression gives the
exponent values for the independent variables and also the
value of the constants. Multivariate regression is trying to
correlate or fit the entire set of independent variable data
obtained with and without fillers and with tri ethoxy vinyl
silane treatment (X1, X2, X3, X4 and X5) to the dependent
variable (Y) and this gives rise to the exponent values.
Multivariate regression often leaves a residual dimension to
the constant. Thus, the constant arrived at using
multivariate regression is 'dimensional' in nature whereas
776
R. R. Prabu et al.: Theoretical Correlations amongst Electrical and Mechanical Characteristics of Polymeric Housing Materials
Exponent for
CTI (X1)
Exponent for
DES(X2)
Exponent for
SR (X3)
Exponent for
AR (X4)
Exponent for
VR (X5)
Value of
Constant (D1)
Dimensions of
Const. D1
Range of Errors
(AR)
Exponent for
DES (X1)
Exponent for AR
(X2)
Exponent for VR
(X3)
Value of
Constant (D2)
Dimensions of
Const. D2
Range of Errors
Dimensional
Analysis
+2
Multivariate
Regression
+2.017
+1
+0.747
-1
-0.966
412
460.37
NIL
M-0.051 L-0.119
T0.321 Q0.085
-12.88% to
8.53%
Dimensional
Analysis
+1
Multivariate
Regression
+0.884
-1
-0.674
7 PREDICTIONS OF TR AND TS
+1
+0.978
+1
+0.843
-1
-0.974
2,00,000
3344.2
NIL
-3.033% to
0.793%
The equation based on multivariate regression to predict
tracking resistance is:
0.843
-11.91% to
3.92%
Silicone
:EPDM
(Weight
Ratio)
measured
Tracking
Resis. (TR
in Minute)
0:100
10:90
30:70
50:50
70:30
90:10
100:0
86
95
108
116
123
129
138
Predicted
TR
based
on
DA
(minute)
88.91
95.53
107.42
115.37
123.3
129.67
142.06
Predicted TR
based on
Multivariate
Regression
(minute)
84.48
92.22
102.16
108.85
120.45
126.19
135.56
Silicone:
EPDM
(weight
ratio)
Measured
TS
(N/mm2)
Predicted TS
based on
DA
(N/mm2)
0:100
10:90
30:70
50:50
70:30
90:10
100:0
4.257
2.971
2.733
2.332
1.936
1.49
0.5
3.75
2.98
2.84
2.42
2.01
1.50
0.512
Predicted TS
based on
Multivariate
Regression
(N/mm2)
4.10
3.13
2.86
2.37
1.99
1.46
0.485
Silica
filler in
PHR
Measured
Tracking
Res. (TR)
(minute)
Predicted
TR based
on DA
(minute)
0
10
20
30
30 (wst)
40
40(wst)
50
60
70
80
90
100
116
127
135
146
218
163
235
175
193
205
213
222
228
115
129
140
153
206.53
175
221.08
187
200
212
221
231
241
Predicted TR
based on
Multivariate
Regression
(minute)
108.85
124.42
138.37
153.58
203.69
170.26
213.77
180.82
191.51
201.2
208.78
217.07
224.55
777
Silica
filler in
PHR
0
10
20
30
30 (wst)
40
40 (wst)
50
60
70
80
90
100
Measured.
Tensile
Strength
(TS)
(N/mm2)
2.332
3.7
4.97
6.42
6.32
6.1
6.05
6.037
5.985
5.865
5.814
5.758
5.65
Predicted
TS based
on DA
(N/mm2)
2.42
3.48
4.86
6.26
6.55
5.63
5.84
5.51
5.50
5.46
5.56
5.53
5.49
Predicted TS
based on
Multivariate
Regression
(N/mm2)
2.37
3.39
4.7
6.02
6.24
5.4
5.55
5.26
5.24
5.18
5.26
5.22
5.15
ATH
filler in
PHR
0
10
20
30
30(wst)
40
40(wst)
50
60
70
80
90
100
Measured
Tracking
resistance
(TR)
(minute)
116
149
155
164
220
181
238
193
211
223
232
240
246
Predicted
TR based
on DA
(minute)
115
139
146
158
201.61
180
229.73
200
218
232
-
Predicted TR
based on
Multivariate
Regression
(minute)
108.85
133.84
144.53
158.81
200.45
176.16
223.4
191.61
206.64
218.51
-
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R. R. Prabu et al.: Theoretical Correlations amongst Electrical and Mechanical Characteristics of Polymeric Housing Materials
Table 11. Measured and Predicted Values of Tensile Strength for 50:50
Silicone/EPDM Blend with Various Levels (in PHR) of Alumina
Trihydrate (ATH) Filler.
ATH
filler in
PHR
0
10
20
30
30(wst)
40
40(wst)
50
60
70
80
90
100
Measured
Tensile
Strength
(TS)
(N/mm2)
2.332
3.5
5.05
6.35
6.2
5.825
5.78
5.406
5.387
5.258
5.165
5.08
4.98
Predicted
TS based
on DA
(N/mm2)
2.42
3.93
5.65
6.97
6.79
6.55
6.46
6.02
5.94
5.91
5.92
5.91
5.81
Predicted TS
based on
Multivariate
Regression
(N/mm2)
2.37
3.78
5.41
6.64
6.46
6.21
6.1
5.68
5.59
5.54
5.53
5.51
5.40
8 QUALITATIVE INTERPRETATIONS
The equation (6) can be qualitatively interpreted based on
their units and dimensions as follows:
CTI / DES = V/ (V/m) = m i.e. length that withstands
tracking;
2.
3.
(A)
779
TS* Q = V2 * ;
(B)
TS = (V2 * ) / Q;
The units on both sides of above equation are,
N/m2 = (Volt)2 * (1/Ohm) * (sec/m3)
This can be rearranged as,
N/m2 = (Volt/m)2 * (1/Ohm.m) * (sec)
In terms of the electrical properties of an insulator that are
considered in this work, it is expressed as,
TS = (DES)2*(1/VR)*(AR) = (DES)2 * (AR/VR)
9 SUMMARY
1.
780
R. R. Prabu et al.: Theoretical Correlations amongst Electrical and Mechanical Characteristics of Polymeric Housing Materials
2.
3.
4.
5.
6.
7.
APPENDIX A
A.1 PREPARATION OF BLENDS
Passing through the rollers for three minutes softens
EPDM rubber initially and then silicone rubber is mixed.
The mixing of EPDM and silicone rubber is carried out for
twelve minutes. Di cumyl peroxide is mixed at the final
stage of mixing.
The blends of silicone and EPDM containing various
proportions of component polymers are prepared in a
laboratory model two roll mixing mill at a temperature of
353 K. Dicumyl Peroxide is mixed during the mill mixing
as a curing agent to all the blends at 2.5 parts per hundred
parts of rubber (phr).
A.2 VULCANIZATION
The vulcanization of the blends is carried out in a
hydraulically operated press at 443 K for 10 minutes. The
vulcanized samples are post cured at 423 K for 2 hours in an
air circulated oven. Test specimens are punched out from
the compression moulded sheets.
A.3 BLEND COMPOSITION
Various compositions of silicone rubber and EPDM
blends prepared are given as follows
First EPDM rubber is blended with silicone rubber in a
complementary mixture of 0, 10, 30, 50, 70, 90, and 100
percent by weight. 2.5 phr of di-cumyl peroxide is added as
the curing agent. With the above set of mixtures, it becomes
possible to analyze the performance characteristics of
silicone rubber alone, EPDM rubber alone and a mixture of
silicone and EPDM in various ratios.
APPENDIX B
B.1 CHARACTERIZATION
In this section, the test conditions and procedure for the
important electrical and mechanical insulation characteristics of
a polymeric insulator are described.
B.2 TRACKING RESISTANCE
A partially conducting part of localized deterioration on
the surface of the insulating material is called a 'track. The
process that produces track as a result of action of electrical
discharges on or close to insulation surface is called
'tracking'. 'Tracking resistance' is the quantitative expression
of the voltage and time required to develop tracking under
specified conditions. Tracking resistance was assessed as
per IEC-60587 standards.
Tracking resistance is determined as per IEC-60587. The
distance between the top and bottom electrode is adjusted to
be equal to 50 mm and 4.5 kV is applied. Ammonium
chloride solution of 0.1 % concentration is used as
contaminant at a flow rate of 0.6 ml / min, which is
controlled by using a peristaltic pump. The conductivity of
the contaminant is 2500 S/cm. The conductivity is
measured using Lutron CD 4302. Time to failure due to
tracking is noted.
B.3 VOLUME RESISTIVITY AND SURFACE
RESISTIVITY
The volume and surface resistivity of the samples are
measured as per ASTM D257 (IEC 60093) Standards. The
voltage applied is 500 V (DC) for 60 seconds at room
temperature. The diameter and thickness of the specimen are
100 mm and 3 mm respectively. Million meg-Ohm meter is
used to measure volume and surface resistivity
781
ACKNOWLEDGEMENT
The authors wish to express their gratitude to the
Management of B.S.A Crescent Engineering College, Mr
Abdul Qadir A. Rahman Buhari, Correspondent, Dr.V.M.
Periasamy, Principal, Dean(s) and Director, for their support
and encouragement.
Special encomiums are due to the faculty, department of
High Voltage Engineering, College of Engineering, Guindy,
Anna University, Chennai-25.
REFERENCES
[1]
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R. R. Prabu et al.: Theoretical Correlations amongst Electrical and Mechanical Characteristics of Polymeric Housing Materials
Dr. S. Usa received the B.E, M.E., and Ph.D., degrees in electrical
engineering from College of Engineering, Anna University in 1986, 1989
and 1995, respectively. From 1992 to 2000, she worked as Lecturer and
since 2000 as Assistant Professor at the College of Engineering, Anna
University. Her research interests include electromagnetic field
computation and high voltage engineering. She is a member of IEE, UK.