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EEAdvancedExam

QuesPaper1

Code-9

JEE-ADVANCE 2014

PHYSICS

JEE (MAIN)2014

25 MAY 2014

PART A # PHYSICS

1.

refractive index n1 = 1.4 is coated on the convex

spherical surface of radius R at one end of a long

solid glass cylinder of refractive index n2 = 1.5, as

shown in the figure. Rays of light parallel to the axis

of the cylinder traversing through the film from air to

glass get focused at distance f1 from the film, while

rays of light traversing from glass to air get focused

at distance f2 from the film. Then

n1

Air

2.

Q1

E1

Q2

E2

n2

(A) | f1 | = 3R

(B) | f1 | = 2.8R

(C) | f2 | = 2R

(D) | f2 | = 1.4R

resonance column and a tuning fork of frequency

244 s1. He is told that the air in the tube has been

replaced by another gas (assume that the column

remains filled with the gas). If the minimum height

at which resonance occurs is (0.350 0.005)m,

the gas in the tube is :(Useful information

E1

(A) E 1

2

E1 1

(B) E K

2

Q1 3

(C) Q K

2

C1 2 K

(D) C K

2

1/2

1/2

167RT = 640 J mole ;

1/2

1/2

140RT = 590 J mole . The molar masses M

in grams are given in the options. Take the values of

4.

10

for each gas as given there.)

M

dielectric constant K between its plates that covers

1/3 of the area of its plates, as shown in the figure.

The total capacitance of the capacitor is C while

that of the portion with dielectric in between is C1.

When the capcitor is charged, the plate are covered

by the dielecteric gets charge Q1, and the rest of

the area gets charge Q2. The electric field in the

dielectric is E1 and that in the other portion is E2.

Choose the correct option/options, ignoring edge

effects.

10

7

)

20 10

x-axis is fixed at x = 0. The speed of the waves in

the string is 100 ms1. The other end of the string is

vibrating in the y direction so that stationary waves

are set up in the string. The possible waveformr(s)

of these stationary waves is(are) :(A) y(t) A sin

x

0t

cos

6

3

10 3

)

28 5

x

100t

cos

3

3

10

9

)

32 16

5x

250 t

cos

6

3

5x

cos 250t

2

10 17

)

36 32

(1)

PHYSICS

Code-9

5.

At time t = 0, terminal A in the circuit shown in the

figure is connected to B by a key and an alternating

current I (t) = I0 cos (wt), with I0 1A = and w = 500 rad

s1 starts flowing in it with the initial direction shown

in the figure. At t

7.

7

, the key is switched from B

6w

total charge Q flows from the battery to charge the

capacitor fully. If C = 20F, R = 10 and the battery

is ideal with emf of 50V, identify the correct statement

(s) :-

JEE-ADVANCE 2014

In the figure, a ladder of mass m is shown leaning

against a wall. It is in static equilibrium making an

angle with the horizontal floor. The coefficient of

friction between the wall and the ladder is 1 and

that between the floor and the ladder is 2. The

normal reaction of the wall on the ladder is N1 and

that of the floor is N2. If the ladder is about to slip,

then :-

B D

2

C = 20 F

50 V

R = 10

mg

2

mg

2

mg

(C) 1 0 2 0 and N2 1

1 2

capacitor before t

7

is 1 103 C.

6w

(B) The current in the left part of the circuit just before

t

7

is clockwise.

6w

8.

in R is 10 A.

resistances R1, R2 and R3 are connected as shown

in the figure. The current in resistance R2 would be

zero if :-

(D) Q = 2 103 C.

6.

V1

R1

R2

1 and 2 are 1 and 2 and the number of fringes for

them within a distance y on one side of the central

V2

R3

(A) 2 > 1

(B) m1 > m2

(C) From the central maximum, 3rd maximum of 2

(A) V1 = V2 and R1 = R2 = R3

than 2

(2)

mg

2

2

(A) Q 4r0

(B) r0

13.

10.

L and diameter d. It takes 4 minutes to raise the

temperature of 0.5 kg water by 40 K. This heater is

replaced by a new heater having two wires of the

same material, each of length L and diameter 2d.

The way these wires are connected is given in the

options. How much time in minutes will it take to

raise the temperature of the same amount of water

by 40 K ?

JEE-ADVANCE 2014

Consider an ellipticaly shaped rail PQ in the vertical

plane with OP = 3 m and OQ = 4 m. A block of mass

1 kg is pulled along the rail from P to Q with a force

of 18 N, which is always parallel to line PQ (see the

figure given). Assuming on fritional losses, the kinetic

energy of the block when it reaches Q is (n10)

Joules. The value of n is (take acceleration due to

gravity = 10 ms2)

Q

4m

O

14.

(B) 2 if wires are in series

(C) 1 if wires are in series

A current. By connecting it to a 4990 W resistance, it

can be converted into a voltmeter or range 0 30 V.

If connected to

3m

2n

resistance, it becomes an

249

11.

mass 0.45 kg is free to rotate about its axis. Two

massless spring toy-guns, each carrying a steel ball

of mass 0.05 kg are attached to the platform at a

distance 0.25 m from the the centre on its either

sides along its diameter (see figure). Each gun

simkultaneously fires the ball horizontally and

perpendicular to the diameter in opposite directions.

After leaving the platform, the balls have horizontal

speed of 9 ms1 with respect th the ground. The

rotational speed of the platform in rad s1 after the

balls leave the platform is

15.

state i with internal energy Ui = 100 J to the final

state f along two different paths iaf and ibf, as

schematically shown in the figure. The work done

by the system along the paths af, ib and bf are W af

= 200 J, Wib = 50 J and W bf = 100 J respectively.

The heat supplied to the system along the path iaf,

ib and bf are Qiaf, Qib and Qbf reppectively. If the

internal energy of the system in the state b is Ub =

200 J and Qiaf = 500 J, the ratio Qbf/Qib is

p

12.

0.5 m is initially at rest on a horizontal fricitonless

surface. Three forces of equal magnitude F=0.5 N

are applied simultaneouly along the three sides of

an equiateral triangel XYZ with its vertices on the

perimeter of the disc (see figure). One second after

applying the force, the angular speed of the disc in

rad s1 is

F

X

16.

seen clearly in foggy conditions, a railways engineer

uses dimensional analysis and assumes that the

distance depends on the mass density r of the fog,

intensity (power/area) S of the light from the signal

and its frequency f. The engineer finds that d is

proportinal to S1/n. The value of n is

O

Y

F

F

(3)

PHYSICS

Code-9

9.

Let E1 (r), E2 (r) and E3 (r) be the respective electric

fields at a distance r from a point charge Q, an

inifinitely long wire with constant linear charge density

, and an infinite plane with uniform charge density

. If E1 (r0) = E2 (r.0) = E3 (r0) at a given distance r0,

then :-

PHYSICS

Code-9

17.

Airplanes A and B are flying constant velocity in the

same vertical plane at angle 30 and 60 with respect

to the horizontal respectively as shown in figure. The

19.

observer in A finds B at a distance of 500 m. This

observer sees B moving with a constant velocity

perpendicular to the line of motion of A. If at t = t0, A

just escapes being hit by B, t0 in seconds is

A

JEE-ADVANCE 2014

Two parallel wires in the plane of the paper are

distance X0 apart. A point charge is moving with

speed u between the wires in the same plane at a

distance X1 from one of the wires. When the wires

carry current of magnitude l in the same direction,

the radius of curvature of the path point charge is R1.

In contrast, if the currents l in the two wires have

directions opposite to each other, the radius of

X0

curvature of the path is R2. If X 3 , the value of

1

60

30

18.

R1

R 2 is

constant acceleration of 3 ms2 along + X direction

(see figure). The length of a chamber inside the rocker

is 4 m. A ball is thrown from the left end of the chamber

in + X direction with a speed of 0.3 ms1 relative to

the rocket. At the same time, another ball is thrown

in X direction with a speed of 0.2 ms1 from its right

end relative to the rocket. The time in seconds when

the two balls hit each other is

20.

a=2 ms

0.2 ms1

0.3 ms

4m

(4)

scale lies between 3.20102 m and 3.25102 m of

the main scale. The 20th divsion of the Vernier scale

exactly coincides with one of the main scale

divisions. When an additional load of 2 kg is applied

to the wire, the zero of the Vernier scale still lies

between 3.20102 m and 3.25102 m of the main

scale but now the 45th division of Vernier scale

coincides with one of the main scale divisions. The

length of the thin metallic wire is 2 m and its crosssectional area is 8107 m2. The least count of the

Vernier scale is 1.0105 m. the maximum percentage

error in the Youngs modulus of the wire is

Code-9

JEE-ADVANCE 2014

CHEMISTRY

JEE (MAIN)2014

25 MAY 2014

PART B # CHEMISTRY

21.

alcohols with molecular formula C4H10O is /are :(A) tert-butanol and 2-methylpropan-2-ol

(B) tert-butanol and 1, 1-dimethylethan-1-ol

(C) n-butanol and butan-1-ol

(D) isobutyl alcohol and2-methylpropan-1-ol

25.

species is /are :(A) Na and excess of NH3

(B) K and excess of O2

(C) Cu and dilute HNO3

(D) O2 and 2-ethylanthraquinol

22

under appropriate conditions is given below :-

26.

formed is/are :-

NH2

OH

acetic anhydride

X2

CH2Cl 2

NH2

C(CH 3)3

Z

H

N

be explained by :(A) the steric effect of the halogen

(B) the steric effect of the tert-butyl group

(C) the electronic effect of the phenolic group

(D) the electronic effect of the tert-butyl group

23.

CH3

O

(A)

+ CH3COOH

NH2

O

NH2

+ CH3COOH

internal pressure = P1 volume = V1 and absolute

temperature = T1 expands irreversibly against zero

external pressure, as shown in the diagram. The

final internal pressure, volume and absolute

temperature of the gas are P 2 , V 2 and T 2 ,

respectively. For this expansion, :-

H

N

(B)

O

H

N

(C)

Irreversible

CH3

CH3

Pext = 0

Pext = 0

Product (s)

+ H2O

H

N

CH3

O

P2,V2,T2

P1,V1,T1

(D)

Thermal insulation

(A) q = 0

(B) T2 = T1

(C) P2 V2 = P1V1

(D) P2V2 = P1V1

24.

The correct statement (s) for orthoboric acid is /are :(A) It behaves as a weak acid in water due to self

ionization.

(B) Acidity of its aqueous solution increases upon

addition of ethylene glycol.

(C) It has a three dimensional structure due to

hydrogen bonding.

(D) It is a weak electrolyte in water.

27.

(5)

In a galvanic cell, the salt bridge :(A) does not participate chemically in the cell

reaction.

(B) stops the diffusion of ions from one electrode to

another.

(C) is ncessary for the occurrence of the cell

reaction.

(D) ensures mixing of the two electrolytic solutions.

CHEMISTRY

Code-9

28.

Upon heating with Cu2S, the reagents(s) that give

copper metal is/are :(A) CuFeS2

(B) CuO

(C) Cu2O

(D) CuSO4

29.

30.

31.

32.

33.

phenomena :(A) Ice floats in water.

(B) Higher Lewis basicity of primary amines than

tertiary amines in aqueous solutions.

(C) Formic acid is more acidic than acetic acid.

(D) Dimerisation of acetic acid in benzene.

For the reaction :

The correct statement (s) in the balanced equation

is /are :

(A) Stoichiometric coefficient of HSO4 is 6.

(B) Iodide is oxidized.

(C) Sulphur is reduced.

(D) H2O is one of the products.

A list of species having the formula XZ4 is given below.

2+

2

XeF4, SF4, SiF4, BF4 , BrF4 , [Cu(NH3)4] , [FeCl4]

2

2

,[CoCl4] and [PtCl4] .

Defining shape on the basis of the location of X and

Z atoms, the total number of species having a square

planar shape is

34.

35.

stereoisomers of MW = 100. All these isomers are

idependently reacted with NaBH 4 (NOTE :

stereoisomers are also reacted separately). The total

number of ketones that give a racemic product(s) is

/are.

36.

MX 2 dissociates into M

and X ions in an

aqueous solution, with a degree of dissociation

() of 0.5. The ratio of the observed depression of

freezing point of the aqueous solution to the value

of the depression of freezing point in the absence

.

of ionic dissociation is

37.

quantum numbers n = 4, |ml| = 1 and ms = 1/2 is .

38.

1

dissolved in a solvent having density of 0.4 g ml .

Assuming no change in volume upon dissolution,

the molality of a 3.2 molar solution is.

39.

and the value of Boltzamann constant is

23

1

1.380 10 J K , then the number of significant

digits in the calculated value of the universal gas

constant is.

40.

amino acids obtained by complete acidic hydrolysis

of the peptide shown below is

non-zero dipole moment for the following compound

is (are) :-

Acidified K2Cr2O7, alkaline KMnO4, CuSO4, H2O2, Cl2,

O3, FeCl3, HNO3 and Na2S2O3.

The total number of reagents that can oxidise aqueous

iodide to iodine is :

(6)

JEE-ADVANCE 2014

Among PbS, CuS, HgS, Mns, Ag2 S, NiS, Cos, Bi2S3

and SnS2, the total number of BLACK coloured

sulphides is.

2+

23

Code-9

JEE-ADVANCE 2014

MATHS

JEE (MAIN)2014

25 MAY 2014

PART C # MATHS

41.

Let f: , R be given by

2 2

f(x) : (log (sec x + tan x))3.

Then

(A) f(x) is an odd function

(B) f(x) is a one-one function

(C) f(x) is an onto function

(D) f(x) is an even function

42.

f(x) = x5 5x + a

Then

(A) f(x) has three real roots if a > 4

(B) f(x) has only one real root if a > 4

(C) f(x) has three real roots if a < 4

(D) f(x) has three real roots if 4 < a < 4

43.

Let f: (0 ) R be given by

x

f(x) =

1

x

1

t

t

46.

orthogonal to the circles (x 1)2 + y2 = 16 and x2 +

y2 = 1 . Then:(A) radius of S is 8

(B) radius of S is 7

(C) centre of S is (7 , 1)(D) centre of S is ( 8, 1)

47.

entries. Then M is invertible if:(A) the first column of M is the transpose of the

second row of M

(B) the second row of M is the transpose of the first

column of M

(C) M is a diagonal matrix with nonzero entries in

the main diagonal

(D) the product of entries in the main diagonal of M

is not the square of an integer

48.

dt

1

(B) f(x) is monotonically decreasing on (0, 1)

y and z x , then:-

1

= 0, for all x (0, )

x

(C) f(x) + f

(A) b (b. z) (z x)

(C) a.b (a.y)(b.z)

44.

45.

f,g: [0,1] R such that max

{f(x) : x [0,1]} = max {g(x): x [0,1]},

the correct statement(s) is (are):(A) (f(c))2 + 3f(c) = (g(c))2 + 3g(c) for some c [0,1]

(B) (f(c))2 + f(c) = (g(c))2 + 3g(c) for some c [0, 1]

(C) (f(c))2 + 3f(c) = (g(c))2 + g(c) for some c [0,1]

(D) (f(c))2 = (g(c))2 for some c [0,1]

49.

(B) a (a. y) (y z)

(D) a (a. y) (z y)

g : R R be defined as

if x a,

0

x

g(x) f(t)dt if a x b,

a

b

f(t)dt

if x b.

a

NM. Further, if M N2 and M2 = N4 , then:(A) determinant of (M2 + MN2) is 0

(B) there is a 3 3 non-zero matrix U such that (M2

+ MN2) U is the zero matrix

(C) Determinant of (M2 + MN2) 1

(D) for a 3 3 matrix U , if (M2 + MN2) U equals the

zero matrix then U is the zero matrix

(B) g(x) is differentiable on R

(C) g(x) is continuous but not differentiable at b

(D) g(x) is continuous and differentiable at either a

or b but not both

(7)

MATHS

Code-9

50.

From a point P (), perpendicular PQ and PR

are drawn respectively on the lines y = x, z = 1 and

y = x , z = 1, If P is such that QPR is a right

angle then the possible value(s) of is (are):(A)

(B) 1

(C) 1

JEE-ADVANCE 2014

56.

(D) 2

of

3 d

4x

(1 x 2 )5 dx is.

The value of 0

2

dx

52.

53.

57.

f(x) = |x| + 1 and g(x) = x2 + 1 . Define h: R R by:max {f(x),g(x)} if x 0,

h(x) =

min {f(x),g(x)} If x 0.

The number of points at which h(x) is not differentiable is.

Let n be an integer. Take n distinct points on a

circle and join each pair of points by a line segment.

Colour the line segment joining every pair of adjacent

points by blue and the rest by red. If the number of

red and blue line segments are equal, then the value

of n is.

54.

(y x5)2 = x(1 + x2)2 at the point (1, 3) is:-

55.

such that the angle between every pair of them is

. If a b b c pa qb rc , where p, q and r

3

p2 2q2 r 2

are scalars, then the value of

is:q2

b

is an

a

the arithmetic mean of a,b,c is b + 2, then the value

51.

a2 a 14

is:a 1

x). The number of points x [0, 4] satisfying the

equation

f(x) =

58.

10 x

is:10

1 x

ax sin(x 1) a 1

which lim

x 1

x sin(x 1) 1

1

is:4

59.

distances of the point P from the lines x y = 0 and

x + y = 0 respectively. The area of the region R

consisting of all points P lying in the first quadrant of

the plane and satisfying 2 d1 (P) + d2(P) 4, is:-

60.

n1 + n2 + n3 + n4 + n5 = 20. Then the number of such

distinct arrangements (n1,n2, n3,n4,n5) is:-

(8)

J

EEAdvancedExam

QuesPaper2

Code-4

JEE-ADVANCE 2014

PHYSICS

JEE (MAIN)2014

25 MAY 2014

PART A # PHYSICS

1.

2.

4.

wavelengths 248 nm and 310 nm. The maximum

speeds of the photoelectrons corresponding to these

wavelengths are u1 and u2, respectively. If the ratio

u1 :u2 = 2 : 1 and hc = 1240 eV nm, the work function

of the metal is nearly :(A) 3.7 eV

(B) 3.2 eV

(C) 2.8 eV

(D) 2.5 eV

If Cu is the wavelength of K X-ray line of copper

(atomic number 29) and Mo wavelength of the K

X-ray line of molybdenum (atomic number 42), then

the ratio Cu / Mo is close to :(A) 1.99

(B) 2.14

(C) 0.50

(D) 0.48

1

(radius of Earth) has

10

the same mass density as Earth. Scientists dig a

R

well of depth

on it and lower a wire of the same

5

length and of linear mass density 103 kgm1 into it.

If the wire is not touching anywhere, the force

applied at the top of the wire by a person holding it

in place is (take th radius of Earth = 6 106 m and

the acceleration due to gravity on Earth is

10 ms2):(A) 96 N

(B) 108 N

(C) 120 N

(D) 150 N

5.

A planet of radius R

6.

bead, is bent in the form of quarter of a circle. The

wire is fixed vertically on ground as shown in the

figure. The bead is released from near the top of the

wire and it slides along the wire without friction. As

the bead moves from A to B, the force it applies on

the wire is :A

incident on a spherical black body kept in

surrounding of temperature 300 K. Take

Stefan-Boltzmann constant = 5.7 108 Wm2

K4 and assume that the energy exchange with the

sorrounding is only through radiation. The final

steady state temperature of the black body is close

to :(A) 330 K

(B) 660 K

(C) 990 K

(D) 1550 K

90

(B) always radially inwards.

(C) radially outwards initially and radially inwards later.

(D) radially inwards initially and radially outwards later.

galvanometer shows a null point when the jockey is

pressed at 40.0 cm using a standard resistance of

90 , as shown in the figure. The least count of the

scale in the metre bridge is 1 mm. The unknown

resistance is :-

7.

cone with an apex angle so that its two ends

have cross sections of different radii. When dipped

in water vertically, water rises in it to a height h,

where the radius of its cross section is b. If the

surface tension of water is S, its density is p, and

its contact angle with glass is , the value of h will

be (g is the acceleration due to gravity) :-

40.0 CM

h

(A) 60 0.15

(C) 60 0.25

(D) 135 0.23

2S

(A) bpg cos( )

2S

(C) bpg cos( / 2)

(1)

2S

(B) bpg cos( )

2S

(D) bpg cos( / 2)

PHYSICS

Code-4

8.

Charges Q, 2Q and 4Q are uniformly distributed in

three dielectric solid spheres 1, 2 and 3 of radii R/2,

R and 2R respectively, as shown in figure. If

magnitudes of the electric fields at point P at a

distance R from the centre of spheres 1, 2 and 3 are

E1, E2 and E3 respectively, then :-

P

R

2Q

10.

JEE-ADVANCE 2014

A point source S is placed at the bottom of a

transparent block of height 10 mm and refractive

index 2.72. It is immersed in a lower refractive index

liquid as shown in the figure. It is found that the light

emerging from the block to the liquid forms a circular

bright spot of diameter 11.54 mm on the top of the

block. The refractive index of the liquid is :-

4Q

Liquid

Block

R

S

R/2

Sphere 1

Sphere 2

(C) E2 > E1 > E3

9.

2R

Sphere 3

(A) 1.21

(B) 1.30

(C) 1.36

(D) 1.42

The figure shows a circular loop of radius a with two

long parallel wires (numbered 1 and 2) all in the plane

of the paper. The distance of each wire from the centre

of the loop is d. The loop and the wires are carrying

the same current I. The current in the loop is in the

counter clockwise direction if seen from above.

(D) E3 > E2 > E1

surface. It bounces back to its original position after

hitting the surface. The force on the ball during the

collision is proportional to the length of compression

of the ball. Which one of the following sketches

describes the variation of its kinetic energy K with

time t most appropriately ? The figures are only

illustrative and not to the scale.

Wire 1

d

a

Wire 2

(A)

t

11.

found that the net magnetic field on the axis of the

loop is zero at a height h above the loop. In that

case

(1) current in wire 1 and wire 2 is the direction PQ

and RS, respectively and h a

(2) current in wire 1 and wire 2 is the direction PQ

and SR, respectively and h a

(3) current in wire 1 and wire 2 is the direction PQ

and SR, respectively and h 1.2 a

(4) current in wire 1 and 2 is the direction PQ and

RS, respectively and h 1.2 a

12.

diameter parallel to the wires by 30 from the position

shown in the figure. If the currents in the wires are in

the opposite directions, the torque on the loop at its

new position will be (assume that the net field due to

the wires is constant over the loop) :-

(B)

t

(C)

t

K

(D)

t

(1)

(3)

(2)

0I2a2

d

30I2a 2

d

(2)

(4)

0I2a2

2d

30I2a 2

2d

Code-4

JEE-ADVANCE 2014

16.

for a given pistion speed the rate (volume per unit time)

at which the liquid is sprayed will be proportional to

17.

3

5

R, CP = R, and those for

2

2

5

7

R, CP = R.

2

2

P.

Q.

13.

14.

does not move. When equilibrium is achieved, the

final temperature of the gases will be

(A) 550 K

(B) 525 K

(C) 513 K

(D) 490 K

Now consider the partition to be free to move without

friction so that the pressure of gases in both

compartments is the same. Then total work done by

the gases till the time they achieve equilibrium will

be :(A) 250 R

(B) 200 R

(C) 100 R

(D) 100 R

A spray gun is shown in the figure where a piston pushes air

out of a nozzle. A thin tube of uniform cross section is

connected to the nozzle. The other end of the tube is in a

small liquid container. As the piston pushes air through the

nozzle, the liquid from the container rises into the nozzle

and is sprayed out. For the spray gun shown, the radii of the

piston and the nozzle are 20 mm and 1 mm respectively. The

upper end of the container is open to the atmosphere.

R.

S.

18.

(A)

(B)

(C)

(D)

small hole at the lower end of its side. When the lift

is at rest, the water jet coming out of the hole hits

the floor of the lift at a distance d of 1.2 m from the

person. In the following, state of the lifts motion is

given in List I and the distance where the water jet

hits the floor of the lift is given in List II. Match the

statements from List I with those in List II and select

the correct using the code given below the lists.

List I

List II

Lift is accelerating

1.

d = 1.2 m

vertically up.

Lift is accelerating

2.

d > 1.2 m

vertically down with

an acceleration less

than the gravitational

acceleration.

Lift is moving vertically 3.

d < 1.2 m

up with constant speed.

Lift is falling freely.

4.

No water leaks out

of the jar

Code

(A) P-2, Q-3, R-2, S-4 (B) P-2, Q-3, R-1, S-4

(C) P-1, Q-1, R-1, S-4 (D) P-2, Q-3, R-1, S-1

Four charges Q1, Q2, Q3 and Q4 of same magnitude

are fixed along the x axis at x = 2a, a, +a and 2a

respectively. A positive charge q is placed on the

positive y axis at a distance b > 0. Four options of

the signs of these charges are given in List I. The

direction of the forces on the charge q is given in List

II. Match List II. Match List I with List II and select the

correct answer using the code given below ths lists.

q(0, b)

Q2

Q1

(2a, 0) (a, 0)

P.

Q.

R.

S.

15.

comes out of the nozzle with a speed of

(A) 0.1 ms1

(B) 1 ms1

1

(C) 2 ms

(D) 8 ms1

(3)

List I

Q1, Q2, Q3, Q4 all

positive

Q1, Q2, positiver; Q3, Q4

negative

Q1, Q4 positive; Q2 Q3

negative

Q1, Q3 positive; Q2 Q4

negative

Code

(A) P-3, Q-1, R-4, S-2

(C) P-3, Q-1, R-2, S-4

Q3

Q4

(+a, 0) (+2, 0)

List II

1. +

2.

3.

+y

4.

(D) P-4, Q-2, R-1, S-3

PHYSICS

In the figure a container is shown to have a movable

(without friction) piston on top. The container and the piston

are all made of perfectly insulating material allowing no heat

transfer between outside and inside the container. The

container is divided into two compartments by a rigid partition

made of a thermally conducting material that allows show

transfer of heat. The lower compartment of the container is

filled with 2 moles of an ideal monatomic gas at 700 K and

the upper compartment is filled with 2 moles of an ideal

diatomic gas at 400 K. The heat capacities per mole of an

PHYSICS

Code-4

19.

Four combinations of two thin lenses are given in

List I. The radius of curvature of all curved surfaces

is r and the refractive index of all the lenses is 1.5.

Match lens combinations in List I with their focal

length in List II and select the correct answer using

the code given below the lists.

List I

List II

P.

1.

2r

Q.

2.

r/2

20.

JEE-ADVANCE 2014

A block of mass m1 = 1 kg another mass m2 = 2 kg,

are placed together (see figure) on an inclined plane

with angle of inclination . Various values of are

given in List I. The coefficient of friction between the

block m1 and the plane is always zero. The coefficient

of static and dynamic friction between the block m2

and the plane are equal to = 0.3. In List II expressions

for the friction on block m2 are given. Match the correct

expression of the friction in List II with the angles given

in List I. and choose the correct option. The

acceleration due to gravity is denoted by g.

[Useful information : tan (5.5) 0.1 ; tan (11.5)

0.2 ; tan (16.5) 0.3 ]

m1

m2

R.

3.

S.

4.

Code

(A) P-1, Q-2, R-3, S-4

(C) P-4, Q-1, R-2, S-3

(D) P-2, Q-1, R-3, S-4

P.

Q.

R.

S.

(4)

List I

= 5

= 10

= 15

= 20

Code

(A) P-1, Q-1, R-1, S-3

(C) P-2, Q-2, R-2, S-4

List II

1.

m2g sin

2.

(m1+m2) g sin

3.

m2g cos

4.

(m1+m2) g cos

(B) P-2, Q-2, R-2, S-3

(D) P-2, Q-2, R-3, S-3

Code-4

JEE-ADVANCE 2014

Chemistry

JEE (MAIN)2014

25 MAY 2014

PART B # CHEMISTRY

21.

27.

(B) acidic solution of -naphthol

(C) neutral solution of -naphthol

(D) alkaline solution of -naphthol

22.

(A)

(B)

(C)

(D)

disappearance of M increass by a factor of 8 upon

doubling the concentration of M. The order of the

reaction with respect to M is :-

23.

(A) 4

(B) 3

(C) 2

(D) 1

28.

NH2OH respectively, is acting as a :(A) reducing agent, oxidising agent

(B) reducing agent ,reducing agent

(C) oxidising agent, oxidising agent

(D) oxidising agent, reducing agent

29.

when :-

H2O(l) H2O(g)

at T = 100C and 1 atmosphere pressure , the

correct choice is :(A) Ssystem > 0 and Ssurroundings > 0

(B) Ssystem > 0 and Ssurroundings < 0

(C) Ssystem < 0 and Ssurroundings > 0

(D) Ssystem < 0 and Ssurroundings < 0

24.

be divided into three distinct classes as shown in

the figure.

(I)

and

(II)

(B) one phenyl group is replaced by a paramethoxyphenyl group.

(C) two phenyl groups are replaced by two paramethoxyphenyl groups.

(D) no structural change is made to X.

and

(III)

The correct order of their boiling point is :-

25.

30.

released as products in the final step of the reaction

scheme shown below is :-

26.

(A) Be2

(B) B2

(C) C2

(D) N2

white phosphorous is :(A) PCl3

(B) SO2Cl2

(C) SCl2

(D) POCl3

(A) 0

(C) 2

(5)

(B) 1

(D) 3

Code-4

Chemistry

X and Y are two volatile liquids with molar weights

of 10 g mol1 and 40 g mol1 respectively. Two cotton

plugs, one soaked in X and the other soaked in Y,

are simultaneously placed at the ends of a tube of

length L = 24 cm, as shown in the figure. The tube

is filled with an inert gas at 1 atmosphere pressure

and a temperatur of 300 K. Vapours of X and Y react

to form a product which is first observed at a distance

d cm from the plug soaked in X. Take X and Y to

have equal molecular diameters and assume ideal

behaviour for the inert gas and the two vapours.

31.

estimated from Grahams law, is :(A) 8

(B) 12

(C) 16

(D) 20

32.

than the estimate obtained using Grahams law. This

is due to:(A) larger mean free path for X as compared to that

of Y.

(B) larger mean free path for Y as compared to that

of X.

(C) Increased collision frequency of Y with the inert

gas as compared to that of X with the inert gas.

(D) Increased collision frequency of X with the inert

gas as compared to that of Y with the inert gas.

34.

An aqueous solution of metal ion M1 reacts

separately with reagents Q and and R in excess to

given tetrahedral and square planar complexes,

respectively. An aqueous solution of another metal

ion M2 always from tetrahedral complexes with these

reagents. Aqueous solution of M2 on reaction with

reagent S givesn whiite precipitate which dissolves

in excess of S gives white precipitate which dissolves

in excess of S. The reactions are summarized in the

shceme given below.

35.

M1, Q and R, respectively are:(A) Zn2+, KCN and HCl (B) Ni2+, HCl and KCN

(C) Cd2+ , KCN and HCl (D) Co2+ , HCl and KCN

36.

(C) K2CrO4

37.

Schemes 1 and 2 describe sequential transformation

of alkynes M and N. Consider only the major

products formed in each step for both the schemes.

33.

(B)

an appropriate pair of characteristics from List - II

and select the correct answer using the code given

below the lists.:{en = H2NCH2CH2NH2; atomic numbers ; Ti = 22;

Cr = 24; Co = 27; Pt = 78}

List -I

List -II

P. [Cr(NH3)4Cl2]Cl

1. Paramagnetic and

exhibits ionisation

isomerism

Q. [ [Ti(H2O)5Cl](NO3)2 2. Diamagnetic and exhibits

cis- trans isomerism

R. [Pt(en) (NH3) Cl]NO3 3. Paramagnetic and

exhibits cis- trans

isomerism

S.[Co(NH3)4(NO3)2]NO3 4. Diamagnetic and exhibits

ionisation isomerism

(A)

(B)

(C)

(D)

(B) Na2HPO4

(D) KOH

Code :

CH CH O

(C)

JEE-ADVANCE 2014

The correct statement with respect to product Y is :(A) It gives a positive Tollens test and is a functional

isomer of X.

(B) It gives a positive Tollens test and is a geometrical

isomer of X.

(C) It gives a positive iodoform test and is a functional

isomer of X.

(D) It gives a positive iodoform test and is a

geometrical isomer of X.

(D)

H

(6)

P

4

3

2

1

Q

2

1

1

3

R

3

4

3

4

S

1

2

4

2

P.

1. p d antibonding

Q.

2. d d bonding

R.

3. p d bonding

S.

4. d d antibonding

39.

JEE-ADVANCE 2014

Different possible thermal decomposition pathways

for perosysters are shown below, match each

opathway from List with an appropriate structure from

List II and select the correct answer using the code

given below the lists.:List-I

List - II

(P)

Pathway P

(1)

(Q) Pathway Q

(2)

(R)

Pathway R

(3)

(S)

Pathway S

(4)

Code :

(A)

(B)

(C)

(D)

40.

P

2

4

2

4

Q

1

3

3

1

R

3

1

1

3

S

4

2

4

2

Match the four starting materials (P,Q,R,S) given in List-I with the corresponding reaction schemes (I,II,III,IV)

provided in List-II and select the correct answer using the code below the lists.

List-I

List-II

P. H

H

1. Scheme-I

? (iii) SOCl2 (iv) NH3

C7H6N2O3

OH

Q.

2. Scheme-II

OH

(i) Sn/HCl (ii)CH3COCl(iii) conc. H2SO4

? (iv) HNO3(v) dil. H2SO4. Heat (vi) HO

C6H6N2O3

NO2

R.

3. Scheme-III

(i) Red hot iron, 873 K (ii) fuming HNO3, H2SO4, heat

(iii) H2S. NH3 (iv) NaNO2, H2SO4 (v) hydrolysis

C6H5NO3

NO2

S.

4. Scheme-IV

CH3

(i) Conc. H2SO4, 60C

? (ii) conc. HNO3, conc. H2SO4 (iii) dil. H2SO4, heat

Code :

(A)

(B)

(C)

(D)

P

1

3

3

4

Q

4

1

4

1

R

2

4

2

3

S

3

2

1

2

(7)

C6H5NO4

Chemistry

Code-4

38.

Match the orbital overlap figure shown in List-I with

the describption given in List-II and select the correct

answer using the code given below the lists:List-I

List-II

Code-4

JEE-ADVANCE 2014

PHYSICS

JEE (MAIN)2014

25 MAY 2014

PART C # MATHS

41.

of the same two sides is y. If x2 c2 = y, where c is

the third side of the triangle, then the ratio of the inradius to the circum-radius of the triangle is:(A)

(C)

42.

43.

44.

45.

3y

2x(x c)

3y

4x(x c)

(B)

(D)

46.

x2

f(x) =

3y

2c(x c)

3y

4c(x c)

47.

3

2

f(0) = 0, Then

f(x) dx is:-

48.

(A)

3

2

(B)

3

4

(C)

6

4

(D)

6

2

sin x + 2sin 2x sin 3x = 3 has:(A) infinitely many solutions

(B) three solutions

(C) one soltuion

(D) no solution

probability, that the number of boys ahead of every

girl is at least one more than the number of girls

ahead of her, is:-

49.

4

1

(B)

3

(D)

dy

xy

x 4 2x

equation

in (1, 1) satisfying

dx x 2 1

1 x2

1,2,3,4,5,6 and cards are to be placed in envelopes

so that each envelope contains exactly one card

and no card is placed in the envelope bearing the

same number and moreover the card numbered 1

is always placed in envelope numbered 2. Then the

number of ways it can be done is:(A) 264

(B) 265

(C) 53

(D) 67

2

3

t )dt

For x [0, 2], If F(x) = f(x) for all x (0, 2), then

F(2) equals:(A) e2 1

(B) e4 1

(C) e 1

(D) e4

has purely imaginary roots. Then the equation

p(p(x)) = 0 has :(A) only purely imaginary roots

(B) all real roots

(C) two real and two purely imaginary roots

(D) neither real nor purely imaginary roots

(C)

f(

0

the parabola y2 = 8x touch the circle at the points

P, Q and the parabola at the points R, S. Then the

area of the quadrilateral PQRS is :(A) 3

(B) 6

(C) 9

(D) 15

1

(A)

2

on [0,2] and is differentiable on (0,2) with f(0) = 1.

Let

3

4

(8)

log(1 2 )

(A)

(B)

(C)

(D)

0

log(1 2 )

0

log(1 2 )

0

log(1 2 )

0

2(eu e u )16 du

(eu e u )17 du

(eu e u )17 du

2(eu e u )16 du

Code-4

50.

Coefficient of x11 in the expansion of

(1 + x2)4 (1+ x3)7 (1 + x4)12 is:(A) 1051

(B) 1106

(C) 1113

(D) 1120

51.

1 h

0

29

105

57

(C)

105

(B)

55.

(A)

(C)

1

(D)

2

56.

9

(A)

105

10

(B)

105

11

(C)

105

7

(D)

105

54.

1

t

(C)

a(t 2 1)2

t3

(B)

(D) 0

and

f(x)dx = 1, is

2. 2

(B)

t 1

t

(D)

t2 1

t

R.

3x 2

2 (1 e x ) dx equals

3. 4

S.

21

1 x

1 cos 2x log

dx

1 x

2

equals

21

1 x

0 cos 2x log

dx

1 x

4. 0

the parabola meet at a point whose ordinate is:-

(t 2 1)2

(A)

2t 3

List-I

List-II

P. The number of polynomials f(x) with 1. 8

non-negative integer coefficients of

degree 2, satisfying f(0) = 0

(C)

(D)

(C) -

Let a,r,s,t be nonzero real numbers. Let P(at2, 2at),

Q,R(ar2,2at),Q, R(ar2, 2ar) and S(as2, 2as) be distinct points

on the parabola y2 = 4ax. Suppose that PQ is the focal chord

and lines QR and PK are parallel, where K is the point (2a, 0).

1

t

1

The value of g is:2

progression, is:-

(A)

(B) 2

53

105

57.

53.

(1 t)a 1 dt

1

The value of g is :2

(A)

52.

that the function g(a) is differentiable on (0,1).

a(t 2 1)2

(B)

2t 3

(D)

(A)

(B)

(C)

(D)

a(t 2 2)2

t3

(9)

P

3

2

3

2

Q

2

3

2

3

R

4

4

1

1

S

1

1

4

4

PHYSICS

Box 1 contains three cards bearing numbers 1,2,3;

box 2 contains five cards bearing numbers 1,2,3,4,5; and

box 3 contains seven cards bearing numbers 1,2,3,4,5,6,7.

A card is drawn from each of the boxes. Let xi be the number

on the card drawn from the ith box, i = 1,2,3.

JEE-ADVANCE 2014

Paragraph For Questions 55 and 56

Code-4

58.

JEE-ADVANCE 2014

List-I

List-II

1. 1

PHYSICS

x [1 , 1] , x

60.

3

.

2

1 2

d2 y(x)

dy(x)

x

Then y(x) (x 1)

2

dx equals

dx

of a regular polygon of n sides with its

position vectro of the point AK,

K = 1, 2, ...., n.

n1

n1

If k 1 ak ak 1 = k 1 ak .ak 1 ,

on the ellipse

3. 8

4. 9

1

1 = 1 2

tan1

tan1

tan x 2 is

2x 1

4x 1

(A)

(B)

(C)

(D)

59.

P

4

2

4

2

Q

3

4

3

4

R

2

3

1

1

S

1

1

2

3

Let f 1 : R R , f 2 : [0, ) R, f 3 :R R

and f4: R [0, ) be defined by

| x | if

f1(x) = x

if

e

x 0,

x 0;

f2(x) = x2;

sin x if

f3(x) =

if

x

x 0,

x0

and

if

f2 (f1(x))

f4(x) = f (f (x)) 1 if

2 1

List-I

P. f4 is

Q. f3 is

R. f2 0 f1 is

S. f2 is

P

(A) 3

(B) 1

(C) 3

(D) 1

Q

1

3

1

3

1.

2.

3.

4.

R

4

4

2

2

R.

x 0,

x 0.

List-II

onto but not one-one

neither continuous nor one-one

differentiable but not one-one

continuous and one-one

S

2

2

4

4

(10)

(A)

(B)

(C)

(D)

List-II

1. true

2. false

| 1 z1 | | 1 z 2 |....| 1 z9 |

equals

10

3. 1

2k

cos

equals

10

4. 2

x2 y2

1 is

6

3

then the value of h is

S. Nmber of positive solutions

satisfying the equation

List-I

P. For each zk there exists a zj

such that zk . zj = 1

Q. There exists a k {1,2,....,9} such

that z1. z = zk has no solution z in

the set of complex numbers.

S. 1

R. If the normal from the point P(h,1)

2k

2k

i sin

Let zk = cos

;k 1,2,....,9.

10

10

P

1

2

1

2

k 1

Q

2

1

2

1

R

4

3

3

4

S

3

4

4

3

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