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Product identity :
1530950890
Product type :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Field of application :
Ready-for-use mixture :
15300 = 15309 4 vol. / 95040 1 vol. 15302 = 15309 4 vol. / 95570 1 vol.
Identified uses :
Company details :
HEMPEL A/S
Lundtoftegrdsvej 91
DK-2800 Kgs. Lyngby
Denmark
Tel.: + 45 45 93 38 00
hempel@hempel.com
Date of issue :
8 October 2014
23 October 2013.
Mixture
R10
Xn; R20/21
Xi; R36/38
R43
N; R51/53
See Section 16 for the full text of the R-phrases declared above.
See Section 11 for more detailed information on health effects and symptoms.
2.2 Label elements
Hazard pictograms :
Signal word :
Danger
Hazard statements :
Precautionary statements :
General :
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If medical advice is needed, have product container or label at hand. Keep out of reach of children.
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1530950890
Avoid breathing vapors, spray or mists. Wear protective gloves/protective clothing/eye protection/face
protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
Response :
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor.
Storage :
Keep cool.
Disposal :
Dispose of contents and container in accordance with all local, regional, national and international
regulations.
Hazardous ingredients :
Not applicable.
Not applicable.
None known.
Product/ingredient name
Identifiers
%
67/548/EEC
EC: 500-033-5
CAS: *25068-38-6
xylene
n-butanol
>=20 - <25
ethylbenzene
trizinc bis(orthophosphate)
CAS: 100-41-4
Index: 601-023-00-4
REACH #: 01-2119485044-40 >=0.25 - <2.5
EC: 231-944-3
CAS: 7779-90-0
Index: 030-011-00-6
Classification
Regulation (EC) No.
1272/2008 [CLP]
Xi; R36/38
R43
Type
[1]
[1] [2]
[1]
[1] [2]
[1] [2]
[1]
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.
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In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth
to an unconscious person.
If breathing is irregular, drowsiness, loss of consciousness or cramps: Call 112 and give immediate
treatment (first aid).
Eye contact :
Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15
minutes, occasionally lifting the upper and lower eyelids. Seek immediate medical attention.
Inhalation :
Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Give nothing by
mouth. If unconscious, place in recovery position and get medical attention immediately.
Skin contact :
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use
recognized skin cleanser. Do NOT use solvents or thinners.
Ingestion :
If swallowed, seek medical advice immediately and show this container or label. Keep person warm
and at rest. Do not induce vomiting unless directed to do so by medical personnel. Lower the head so
that vomit will not re-enter the mouth and throat.
Protection of first-aiders :
No action shall be taken involving any personal risk or without suitable training. If it is suspected that
fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing
apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact :
Inhalation :
May give off gas, vapor or dust that is very irritating or corrosive to the respiratory system.
Skin contact :
Ingestion :
Over-exposure signs/symptoms
Eye contact :
Inhalation :
No specific data.
Skin contact :
Ingestion :
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician :
Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been
ingested or inhaled.
Specific treatments :
No specific treatment.
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Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may
burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard.
This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material
must be contained and prevented from being discharged to any waterway, sewer or drain.
Decomposition products may include the following materials: carbon oxides halogenated compounds
metal oxide/oxides
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Gloves must be worn for all work that may result in soiling. Apron/coveralls/protective clothing must be
worn when soiling is so great that regular work clothes do not adequately protect skin against contact
with the product. Safety eyewear should be used when there is a likelihood of exposure.
Hygiene measures :
Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking,
using lavatory, and at the end of day.
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Safety eyewear complying with an approved standard should be used when a risk assessment
indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is
possible, the following protection should be worn, unless the assessment indicates a higher degree of
protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face
respirator may be required instead.
Hand protection :
Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. The
quality of the chemical-resistant protective gloves must be chosen as a function of the specific
workplace concentrations and quantity of hazardous substances.
Since the actual work situation is unknown. Supplier of gloves should be contacted in order to find the
appropriate type. Below listed glove(s) should be regarded as generic advice:
Recommended: Silver Shield / 4H gloves, polyvinyl alcohol (PVA), Viton
Not recommended: nitrile rubber, neoprene rubber, butyl rubber, natural rubber (latex), polyvinyl
chloride (PVC)
Body protection :
Personal protective equipment for the body should be selected based on the task being performed and
the risks involved handling this product.
Wear suitable protective clothing. Always wear protective clothing when spraying.
Respiratory protection :
If working areas have insufficient ventilation: When the product is applied by means that will not
generate an aerosol such as, brush or roller wear half or totally covering mask equipped with gas filter
of type A, when grinding use particle filter of type P. When the product is applied by spraying and for
continuous or prolonged work always wear an air-fed respirator e.g. hood with supply of fresh or
compressed air or a full face, powered air purifying filter. Be sure to use an approved/certified
respirator or equivalent.
Liquid.
Odor :
Solvent-like
pH :
Flash point :
Evaporation rate :
Flammability :
Highly flammable in the presence of the following materials or conditions: open flames, sparks and
static discharge and heat.
Flammable in the presence of the following materials or conditions: oxidizing materials.
Slightly flammable in the presence of the following materials or conditions: reducing materials.
Vapor pressure :
Vapor density :
Relative density :
1.383 g/cm
Solubility(ies) :
Partially soluble in the following materials: cold water and hot water.
Auto-ignition temperature :
Decomposition temperature :
Viscosity :
Explosive properties :
Highly explosive in the presence of the following materials or conditions: open flames, sparks and static
discharge and heat.
Oxidizing properties :
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Weighted average: 33 %
Water % by weight :
Weighted average: 0 %
VOC content :
459.2 g/l
438.6 g/l
TOC Content :
Solvent Gas :
n-butanol
solvent naphtha (petroleum), light
arom.
ethylbenzene
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Result
Species
Dose
Exposure
Rat
Rat
Rabbit
Rat
Rat
Rabbit
Rat
Rat
5000 ppm
6350 ppm
>2000 mg/kg
4300 mg/kg
24000 mg/m
3400 mg/kg
790 mg/kg
>5 mg/l
4 hours
4 hours
4 hours
4 hours
LD50 Dermal
LD50 Oral
LD50 Dermal
Rabbit
Rat
Rabbit
>2000 mg/kg
8400 mg/kg
>5000 mg/kg
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1530950890
Rat
3500 mg/kg
ATE value
Oral
Dermal
Inhalation (gases)
Inhalation (vapors)
12543.2 mg/kg
6560.8 mg/kg
29821.6 ppm
110.2 mg/l
Irritation/Corrosion
Product/ingredient name
Result
xylene
n-butanol
solvent naphtha (petroleum), light
arom.
ethylbenzene
Species
Score
Exposure
Rabbit
Rabbit
Rabbit
Rabbit
Rabbit
24 hours 5 milligrams
24 hours 500 milligrams
24 hours 2 milligrams
24 hours 20 milligrams
24 hours 100 microliters
Rabbit
Rabbit
Rabbit
24 hours 15 milligrams
-
Category
Route of exposure
n-butanol
Category 3
Not applicable.
Category 3
Not applicable.
Target organs
Respiratory tract irritation and Narcotic
effects
Respiratory tract irritation
Category
ethylbenzene
Category 2
Route of exposure
Target organs
Not determined
ears
Aspiration hazard
Product/ingredient name
Result
Contains middle molecular epoxy resin MMW 700-1200, 1,3-bis(12-hydroxyocta-decanamide-Nmethyle)benzene. May produce an allergic reaction.
Other information :
Result
Acute LC50 1.376 mg/l
Acute EC50 19 mg/l
Acute EC50 6.14 mg/l
Acute LC50 9.22 mg/l
ethylbenzene
trizinc bis(orthophosphate)
Species
Fish
Algae - Pseudokirchneriella subcapitata
(green algae)
Daphnia - Daphnia magna
Fish - Oncorhynchus mykiss (rainbow
trout)
Algae - Pseudokirchneriella subcapitata
Fish - Oncorhynchus mykiss
Exposure
96 hours
96 hours
48 hours
96 hours
96 hours
96 hours
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Test
Dose
Inoculum
Product/ingredient name
xylene
n-butanol
solvent naphtha (petroleum), light
arom.
ethylbenzene
Result
Photolysis
Biodegradability
Readily
Readily
Readily
Readily
LogPow
2.64 to 3.78
3.12
1
3.6
-
BCF
31
8.1 to 25.9
10 to 2500
60960
Potential
low
low
low
high
low
high
Mobility :
Not applicable.
vPvB :
Not applicable.
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ADR/RID
Class
14.1
UN no.
14.2
Proper shipping name
UN1263
PAINT
14.3
Transport hazard class(es)
3
14.4
PG*
III
14.5
Env* Additional information
Yes. The environmentally
hazardous substance mark
is not required when
transported in sizes of 5 L
or 5 kg.
Special provisions
640 (E)
Tunnel code
(D/E)
IMDG
Class
UN1263
III
IATA
Class
UN1263
PAINT
III
No.
The environmentally
hazardous substance mark
may appear if required by
other transportation
regulations.
Seveso category
P5c: Flammable liquids 2 and 3 not falling under P5a or P5b
E2: Hazardous to the aquatic environment - Chronic 2
C6: Flammable (R10)
C9ii: Toxic for the environment
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F - Highly flammable
Xn - Harmful
Xi - Irritant
N - Dangerous for the environment
H225
H226
H302 (oral)
H304
H312 (dermal)
H315
H317
H318
H319
H332 (inhalation)
H335 (Respiratory
tract irritation)
H335 and H336
(Respiratory tract
irritation and
Narcotic effects)
H373 (ears)
H400
H410
H411
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May cause respiratory irritation. May cause drowsiness and dizziness. (Respiratory
tract irritation and Narcotic effects)
May cause damage to organs through prolonged or repeated exposure. (ears)
Very toxic to aquatic life.
Very toxic to aquatic life with long lasting effects.
Toxic to aquatic life with long lasting effects.
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Justification
On basis of test data
Calculation method
Calculation method
Calculation method
Calculation method
Notice to reader
Indicates information that has changed from previously issued version.
The information contained in this safety data sheet is based on the present state of knowledge and EU and national legislation. It provides
guidance on health, safety and environmental aspects for handling the product in a safe way and should not be construed as any guarantee
of the technical preformance or suitability for particular applications.
It is always the duty of the user/employer to ascertain that the work is planned and carried out in accordance with the national regulations.
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