Engineering Chemistry by P. N. Dave and S. G. Pillai

Scilab Textbook Companion for
Engineering Chemistry
by P. N. Dave and S. G. Pillai1
Created by
Vishwa Shah
Instrumentation and Control
Instrumentation Engineering
Institute of Technology, Nirma University
College Teacher
None
Cross-Checked by
Lavitha Pereira
July 17, 2014
1 Funded
by a grant from the National Mission on Education through ICT,

http://spoken-tutorial.org/NMEICT-Intro. This Textbook Companion and Scilab
codes written in it can be downloaded from the Textbook Companion Project
section at the website http://scilab.in
Book Description
Title: Engineering Chemistry
Author: P. N. Dave and S. G. Pillai
Publisher: Mahajan Publishing, Ahmedabad
Edition: 1
Year: 2011
ISBN: 978-93-81256-28-2
Scilab numbering policy used in this document and the relation to the
above book.
Exa Example (Solved example)
Eqn Equation (Particular equation of the above book)
AP Appendix to Example(Scilab Code that is an Appednix to a particular
Example of the above book)
For example, Exa 3.51 means solved example 3.51 of this book. Sec 2.3 means
a scilab code whose theory is explained in Section 2.3 of the book.
Contents
List of Scilab Codes
1 Water
2 Fuel
17
5 Lubricants and Greases
22
6 Electrochemical System
23
List of Scilab Codes

Exa
Exa
Exa
Exa
Exa
Exa
Exa
Exa
Exa
Exa
Exa
Exa
Exa
Exa
Exa
Exa
Exa
Exa
Exa
Exa
Exa
Exa
Exa
Exa
Exa
Exa
Exa
Exa
1.1
1.2
1.3
1.4
1.5
1.6
1.7
1.8
1.9
1.10
1.11
2.1
2.2
2.3
2.4
2.5
2.6
2.7
2.8
5.1
6.1
6.2
6.3
6.4
6.5
6.6
6.7
6.8
Calculating Hardness . . . . . . . .
Calculating Mass . . . . . . . . . . .
Calculating Lime and Soda . . . . .
Calculating Hardness and Lime Soda
Calculating Volume . . . . . . . . .
Calculating GCV and NCV . . . . .
Proximate Analysis . . . . . . . . .
Calculating percentage C and H . .
Calculating percentage S and N . . .
Calculating percentage S . . . . . .
Calculating VI . . . . . . . . . . . .
Calculating emf . . . . . . . . . . .
Calculating pH . . . . . . . . . . . .
Calculating pH . . . . . . . . . . . .
Calculating potential . . . . . . . . .
Calculating solubility . . . . . . . .
Calculating Ksp . . . . . . . . . . .
Calculating Kc . . . . . . . . . . . .
Calculating Kc . . . . . . . . . . . .
4
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
6
6
7
8
9
10
12
13
14
15
16
17
17
18
19
19
20
21
21
22
23
23
24
24
24
25
25
26
Exa
Exa
Exa
Exa
6.9
6.10
6.11
6.12
Calculating
Calculating
Calculating
Calculating
deltaG and Kc .
Kc . . . . . . . .
Ecell and Energy
Kc . . . . . . . .
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
26
27
27
28
Chapter 1
Water
Scilab code Exa 1.1 Calculating Hardness

1
2
3
4
5
6
7
8
9
// c a l c u l a t i n g h a r d n e s s
// Example 1 . 1
clc
clear
// 100gm o f CaCO3 = 136gm o f CaSO4
m =204 // mass o f t h e s u b s t a n c e
wt =136 // m o l e c u l a r mass
Eq =( m *100) / wt // E q u i v a l e n t s o f CaCO3
printf ( Thus E q u i v a l e n t s o f CaCO3 = %3 . 2 f mg/L o r
ppm , Eq )
Scilab code Exa 1.2 Calculating Mass

1 // c a l c u l a t i n g mass
2 // Example 1 . 2
3 clc
4 clear
5 wt =152 // m o l a r mass o f FeSo4 i n m o l e s
6 Eq =210.5 // e q u i v a l e n t s o f CaCO3 i n ppm

7 m = wt * Eq /100 // Mass o f FeSO4 i n ppm
8 m1 = m /1000 // Mass o f FeSO4 r e q u i r e d p e r l i t e r
9 printf ( Thus t h e mass o f FeSO4 r e q u i r e d p e r
litre
is
%2 . 5 f g /L , m1 )

// Example 1 . 3
clc
clear
// For Ca (HCO3) 2 ,
q1 =10 // q u a n t i t y
wt1 =162 // m o l e c u l a r w e i g h t
M1 =100/ wt1 // m u l t i p l i c a t i o n f a c t o r
Eq1 = M1 * q1 //CaCO3 e q u i v a l e n t s i n mg/L
// For Mg(HCO3) 2 ,
q2 =8.5 // q u a n t i t y
// For CaSO4 ,
q3 =12 // q u a n t i t y
// For MgSO4 ,
q4 =14 // q u a n t i t y
Th = Eq1 + Eq2 // Temperory h a r d n e s s due t o Mg(HCO3) 2 and
Ca (HCO3) 2
26 Ph = Eq3 + Eq4 // Permanent h a r d n e s s due t o CaSO4 and
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
MgSO4
T = Th + Ph // T o t a l h a r d n e s s
printf ( Thus ( i ) i n mg/L Temporary h a r d n e s s = %2 . 2 f
, Th )
printf ( \n and permanent h a r d n e s s = %2 . 2 f , Ph )
printf ( \n and t o t a l h a r d n e s s = %2 . 2 f ,T )
printf ( \n\n ( i i ) i n ppm Temporary h a r d n e s s = %2 . 2 f ,
Th )
printf ( \n and permanent h a r d n e s s = %2 . 2 f , Ph )
printf ( \n and t o t a l h a r d n e s s = %2 . 2 f ,T )
ThC = Th *0.07 // t e m p e r o r y h a r d n e s s i n d e g r e e C l
PhC = Ph *0.07 // permanent h a r d n e s s i n d e g r e e C l
TC = T *0.07 // t o t a l h a r d n e s s i n d e g r e e C l
ThF = Th *0.1 // t e m p e r o r y h a r d n e s s i n d e g r e e F r
PhF = Ph *0.1 // permanent h a r d n e s s i n d e g r e e F r
TF = T *0.1 // t o t a l h a r d n e s s i n d e g r e e F r
printf ( \n\n ( i i i ) i n d e g r e e C l Temporary h a r d n e s s =
%2 . 4 f , ThC )
printf ( \n and permanent h a r d n e s s = %2 . 4 f , PhC )
printf ( \n and t o t a l h a r d n e s s = %2 . 4 f , TC )
printf ( \n\n ( i v ) i n d e g r e e F r Temporary h a r d n e s s = %2
. 4 f , ThF )
printf ( \n and permanent h a r d n e s s = %2 . 4 f , PhF )
printf ( \n and t o t a l h a r d n e s s = %2 . 4 f , TF )

1
2
3
4
5
6
7
8
// Example 1 . 4
clc
clear
q1 =40.5 // q u a n t i t y
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35

// For Mg(HCO3) 2 ,
q2 =46.5 // q u a n t i t y
// For MgSO4 ,
q3 =27.6 // q u a n t i t y
// For CaSO4 ,
q4 =32.1 // q u a n t i t y
// For CaCl2
q5 =22.45 // q u a n t i t y
Ca (HCO3) 2
Ph = Eq3 + Eq4 + Eq5 // Permanent h a r d n e s s due t o CaSO4 and
MgSO4 and CaCl2
T = Th + Ph // T o t a l h a r d n e s s
printf ( Thus i n Temporary h a r d n e s s = %2 . 2 f mg/L , Th )
printf ( \n and permanent h a r d n e s s = %2 . 2 f mg/L , Ph )
printf ( \n and t o t a l h a r d n e s s = %3 . 2 f mg/L ,T )

1 // c a l c u l a t i n g h a r d n e s s
2 // Example 1 . 5
3 clc
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
clear
q1 =12.5 // q u a n t i t y
// For CaCl2 ,
q2 =8.2 // q u a n t i t y
// For MgSO4 ,
q3 =2.6 // q u a n t i t y
Th = Eq1 // Temperory h a r d n e s s due t o Ca (HCO3) 2 i n ppm
Ph = Eq3 + Eq2 // Permanent h a r d n e s s due t o MgSO4 and
CaCl2 i n ppm
T = Th + Ph // T o t a l h a r d n e s s i n ppm
TF = T *0.1 // T o t a l h a r d n e s s i n d e g r e e F r
printf ( Thus i n ppm Temporary h a r d n e s s = %2 . 2 f ppm ,
Th )
printf ( \n and permanent h a r d n e s s = %2 . 2 f ppm , Ph )
printf ( \n i n d e g r e e F r t o t a l h a r d n e s s = %3 . 3 f , TF )
Scilab code Exa 1.6 Calculating Lime and Soda

1 // c a l c u l a t i n g l i m e and s o d a
2 // Example 1 . 6
3 clc
4 clear
5 // For Ca (HCO3) 2 ,
6 q1 =4.86 // q u a n t i t y
7 wt1 =162 // m o l e c u l a r w e i g h t
10
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
// For Mg(HCO3) 2 ,
q2 =7.3 // q u a n t i t y
// For CaSO4 ,
q3 =6.8 // q u a n t i t y
// For MgCl2 ,
q4 =5.7 // q u a n t i t y
// For MgSO4 ,
q5 =9 // q u a n t i t y
// SiO2 and NaCl n e g l e c t e d
V =25000 // Volume o f w a t e r i n l i t r e s
L =74*( Eq1 +(2* Eq2 ) + Eq4 + Eq5 ) /100 // l i m e r e q u i r e m e n t i n
mg/L
L1 = L * V /1000000 // Lime r e q u i r e d f o r s o f t e n i n g 2 5 0 0 0
l i t r e s i n kg
S =106*( Eq3 + Eq4 + Eq5 ) /100 // s o d a r e q u i r e m e n t i n mg/L
S1 = S * V /1000000 // s o d a r e q u i r e d f o r s o f t e n i n g 2 5 0 0 0
l i t r e s i n kg
printf ( Thus amount o f l i m e r e q u i r e d t o s o f t e n 2 5 0 0 0
l i t r e s o f w a t e r = %2 . 5 f kg \n , L1 )
printf ( and amount o f s o d a r e q u i r e d t o s o f t e n 2 5 0 0 0
l i t r e s o f w a t e r = %2 . 5 f kg \n , S1 )
11
Scilab code Exa 1.7 Calculating Hardness and Lime Soda

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
// c a l c u l a t i n g l i m e s o d a and h a r d n e s s
// Example 1 . 7
clc
clear
q1 =40.5 // q u a n t i t y
// For Mg(HCO3) 2 ,
q2 =36.5 // q u a n t i t y
// For MgSO4 ,
q3 =30 // q u a n t i t y
// For CaSO4 ,
q4 =34 // q u a n t i t y
// For CaCl2 ,
q5 =27.75 // q u a n t i t y
// NaCl n e g l e c t e d
L =(74*( Eq1 +(2* Eq2 ) + Eq3 ) /100) *( V /1000) // Lime r e q u i r e d
12
33
34
35
36
37
38
39
40
41
f o r s o f t e n i n g 20000 l i t r e s i n g
S =(106*( Eq3 + Eq4 + Eq5 ) /100) *( V /1000) // s o d a r e q u i r e d
f o r s o f t e n i n g 20000 l i t r e s i n g
L1 =(100* L ) /(84*1000) // Lime r e q u i r e d f o r 84% p u r i t y
i n kg
S1 =(100* S ) /(92*1000) // Soda r e q u i r e d f o r 92% p u r i t y
i n kg
Ca (HCO3) 2
Ph = Eq3 + Eq4 + Eq5 // Permanent h a r d n e s s due t o CaSO4 and
MgSO4and CaCL2
printf ( Thus amount o f l i m e ( 8 4 p e r c e n t p u r e ) r e q u i r e d
t o s o f t e n 2 0 0 0 0 l i t r e s o f w a t e r = %2 . 5 f kg \n , L1
)
printf ( and amount o f s o d a ( 9 2 p e r c e n t p u r e ) r e q u i r e d
t o s o f t e n 2 0 0 0 0 l i t r e s o f w a t e r = %2 . 5 f kg \n , S1 )
printf ( \ n A l s o Temporary h a r d n e s s = %2 . 2 f ppm , Th )
printf ( \n and permanent h a r d n e s s = %2 . 2 f ppm , Ph )

1
2
3
4
5
6
7
8
9
10
11
12
13
14
// c a l c u l a t i n g l i m e and s o d a
// Example 1 . 8
clc
clear
// For raw w a t e r Ca+2 ,
q1 =240 // q u a n t i t y
// For Mg+2 ,
q2 =96 // q u a n t i t y
13
// For CO2 ,
q3 =44 // q u a n t i t y
// For HCO3,
q4 =732 // q u a n t i t y
// For FeSO4 . 7 H2O ,
q5 =278 // q u a n t i t y
L =(74*( Eq2 + Eq3 + Eq4 + Eq5 ) /100) *( V /1000000) // l i m e
r e q u i r e m e n t i n kg
32 S =(106*( Eq1 + Eq2 + Eq5 - Eq4 ) /100) *( V /1000000) // s o d a
33 printf ( Thus amount o f l i m e r e q u i r e d t o s o f t e n
2 5 0 0 0 0 l i t r e s o f w a t e r = %3 . 1 f kg \n ,L )
34 printf ( and amount o f s o d a r e q u i r e d t o s o f t e n 2 5 0 0 0 0
l i t r e s o f w a t e r = %3 . 1 f kg \n ,S )
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31

1
2
3
4
5
6
7
8
// c a l c u l a t i n g l i m e and s o d a
// Example 1 . 9
clc
clear
// For raw w a t e r Ca+2 ,
q1 =160 // q u a n t i t y
14

// For Mg+2 ,
q2 =96 // q u a n t i t y
// For CO2 ,
q3 =34 // q u a n t i t y
// For HCO3,
q4 =403 // q u a n t i t y
// For NaAlO2 ,
q5 =20 // q u a n t i t y
wt5 =82*2 // m o l e c u l a r w e i g h t
L =(74*( Eq2 + Eq3 + Eq4 - Eq5 ) /100) *( V /1000000) // l i m e
32 S =(106*( Eq1 + Eq2 - Eq4 ) /100) *( V /1000000) // s o d a
33 printf ( Thus amount o f l i m e r e q u i r e d t o s o f t e n
2 5 0 0 0 0 l i t r e s o f w a t e r = %3 . 1 f kg \n ,L )
34 printf ( and amount o f s o d a r e q u i r e d t o s o f t e n 2 5 0 0 0 0
l i t r e s o f w a t e r = %3 . 1 f kg \n ,S )
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
Scilab code Exa 1.10 Calculating Volume

1
2
// c a l c u l a t i n g volume
// Example 1 . 1 0
15
3
4
5
6
7
8
9
10
clc
clear
v =100 // Amount o f NaCl s o l u t i o n i n l i t r e s
m =120* v // Amount o f NaCl i n g
wt =58.5*2 // m o l e c u l a r mass o f NaCl
Eq = m *100/ wt // E q u i v a l e n t s o f CaCO3 i n g
h =500 // h a r d n e s s i n ppm
V = Eq *1000/ h // w a t e r r e q u i r e d t o s o f t e n t h e z e o l i t e
softner in l i t r e s
11 printf ( Thus t h e z e o l i t e s o f t n e r can s o f t e n %5 . 2 f L
o f Hard w a t e r ,V )

// Example 1 . 1 1
clc
clear
v =30 // Amount o f NaCl s o l u t i o n i n l i t r e s
m =15* v // Amount o f NaCl i n g
wt =58.5*2 // m o l e c u l a r mass o f NaCl
Eq = m *100/ wt // E q u i v a l e n t s o f CaCO3 i n g
V =1000 // w a t e r r e q u i r e d t o s o f t e n t h e z e o l i t e s o f t n e r
in l i t r e s
10 h = Eq *1000/ V // h a r d n e s s i n ppm
11 printf ( Thus t h e h a r d n e s s o f w a t e r = %3 . 2 f ppm ,h )
1
2
3
4
5
6
7
8
9
16
Chapter 2
Fuel
Scilab code Exa 2.1 Calculating GCV and NCV

// c a l c u l a t i n g GCV and NCV
// Example 2 . 1
clc
clear
C =60 // p e r c e n t a g e o f Carbon i n c o a l
O =33 // p e r c e n t a g e o f Oxygen i n c o a l
H =6 // p e r c e n t a g e o f Hydrogen i n c o a l
S =0.5 // p e r c e n t a g e o f S u l p h u r i n c o a l
N =0.5 // p e r c e n t a g e o f N i t r o g e n i n c o a l
GCV =((8080* C ) +(34500*( H - O /8) ) +(2240* S ) ) /100 // g r o s s
c a l o r i f i c v a l u e i n k c a l / kg
11 NCV =( GCV -(0.09* H *587) ) // n e t c a l o r i f i c v a l u e i n k c a l /
kg
12 printf ( Thus t h e h i g h e r c a l o r i f i c v a l u e o f c o a l = %4
. 2 f k c a l / kg , GCV )
13 printf ( \n and t h e l o w e r c a l o r i f i c v a l u e o f c o a l =
%4 . 2 f k c a l / kg , NCV )
1
2
3
4
5
6
7
8
9
10

17

// Example 2 . 2
clc
clear
N =1 // p e r c e n t a g e o f N i t r o g e n i n c o a l
GCV =((8080* C ) +(34500*( H - O /8) ) +(2240* S ) ) /100 // g r o s s
kg
12 printf ( Thus t h e g r o s s c a l o r i f i c v a l u e o f c o a l = %4
. 2 f k c a l / kg , GCV )
13 printf ( \n and t h e n e t c a l o r i f i c v a l u e o f c o a l = %4
. 2 f k c a l / kg , NCV )
1
2
3
4
5
6
7
8
9
10

// Example 2 . 3
clc
clear
GCV =((8080* C ) +(34500*( H - O /8) ) +(2240* S ) ) /100 // g r o s s
kg
. 0 f k c a l / kg , GCV )
1
2
3
4
5
6
7
8
9
10
18
13
printf ( \n and t h e n e t c a l o r i f i c v a l u e o f c o a l = %4
. 0 f k c a l / kg , NCV )

// Example 2 . 4
clc
clear
O =8.4 // p e r c e n t a g e o f Oxygen i n c o a l
H =5.5 // p e r c e n t a g e o f Hydrogen i n c o a l
GCV =((8080* C ) +(34500*( H - O /8) ) +(2240* S ) ) /100 // g r o s s
kg
. 0 f k c a l / kg , GCV )
13 printf ( \n and t h e n e t c a l o r i f i c v a l u e o f c o a l = %4
. 0 f k c a l / kg , NCV )
1
2
3
4
5
6
7
8
9
10
Scilab code Exa 2.5 Proximate Analysis

1 // c a l c u l a t i n g p r o x i m a t e a n a l y s i s
2 // Example 2 . 5
3 clc
4 clear
5 m1 =1 // mass o f a i r d r i e d c o a l i n g
6 m2 =0.985 // mass o f d r y c o a l r e s i d u e
after heating for
1 hr i n g
7 m3 =0.8 // mass o f r e s i d u e a f t e r h e a t i n g f o r 7 min i n g
19
m4 =0.1 // mass o f l a s t r e s i d u e
Mm = m1 - m2 // mass o f m o i s t u r e i n c o a l s a m p l e i n g
Mv = m2 - m3 // mass o f v o l a t i l e m a t t e r i n g
Ma = m4 // mass o f a s h
%m = Mm *100 // p e r c e n t a g e m o i s t u r e
%v = Mv *100 // p e r c e n t a g e o f v o l a t i l e m a t t e r
%a = Ma *100 // p e r c e n t a g e o f a s h
%c =100 -( %m + %v + %a ) // p e r c e n t a g e o f f i x e d c a r b o n
printf ( Thus ( i ) p e r c e n t a g e o f m o i s t u r e = %2 . 1 f
p e r c e n t \n , %m )
17 printf ( ( i i ) p e r c e n t a g e o f v o l a t i l e m a t t e r = %2 . 1 f
p e r c e n t \n , %v )
18 printf ( ( i i i ) p e r c e n t a g e o f a s h = %2 . 0 f p e r c e n t \n , %a
)
19 printf ( ( i v ) p e r c e n t a g e o f f i x e d c a r b o n = %2 . 0 f
p e r c e n t \n , %c )
8
9
10
11
12
13
14
15
16
Scilab code Exa 2.6 Calculating percentage C and H

// c a l c u l a t i n g p e r c e n t a g e C and H
// Example 2 . 6
clc
clear
wt1 =2.75 // i n c r e a s e i n wt o f KOH t u b e i n gm
wt2 =0.45 // i n c r e a s e i n wt o f CaCl2 t u b e i n gm
wt =1 // w e i g h t o f c o a l s a m p l e i n gm
%c =( wt1 *12*100) /( wt *44) // p e r c e n t a g e o f c a r b o n
%h =( wt2 *2*100) /( wt *18) // p e r c e n t a g e o f h y d r o g e n
printf ( Thus ( i ) P e r c e n t a g e o f c a r b o n = %2 . 0 f p e r c e n t
, %c )
11 printf ( \n ( i i ) P e r c e n t a g e o f h y d r o g e n =%2 . 0 f p e r c e n t
, %h )
1
2
3
4
5
6
7
8
9
10
20
Scilab code Exa 2.7 Calculating percentage S and N

1 // c a l c u l a t i n g p e r c e n t a g e S and N
2 // Example 2 . 7
3 clc
4 clear
5 wt1 =2.6 // w e i g h t o f c o a l t a k e n f o r
6
7
8
9
10
11
12
13
quantitative
a n a l y s i s i n gm
wt =1.56 // w e i g h t o f c o a l s a m p l e t a k e n i n gm
v =50 -6.25 // volume o f H2SO4 u s e d
N =0.1 // n o r m a l i t y
m =0.1755 // wt o f BaSO4 ppt . o b t a i n e d
%n =( v * N *1.4) /( wt ) // p e r c e n t a g e o f n i t r o g e n
%su =( m *32*100) /( wt1 *233) // p e r c e n t a g e o f s u l p h u r
printf ( Thus ( i ) P e r c e n t a g e o f n i t r o g e n = %2 . 3 f
p e r c e n t , %n )
printf ( \n ( i i ) P e r c e n t a g e o f s u l p h u r =%2 . 3 f p e r c e n t ,
%su )
Scilab code Exa 2.8 Calculating percentage S

1 // c a l c u l a t i n g p e r c e n t a g e S
2 // Example 2 . 8
3 clc
4 clear
5 wt =0.5 // w e i g h t o f c o a l t a k e n f o r
quantitative
a n a l y s i s i n gm
6 m =0.05 // wt o f BaSO4 ppt . o b t a i n e d
7 %su =( m *32*100) /( wt *233) // p e r c e n t a g e o f s u l p h u r
8 printf ( Thus P e r c e n t a g e o f s u l p h u r =%2 . 3 f p e r c e n t ,
%su )
21
Chapter 5
Lubricants and Greases
Scilab code Exa 5.1 Calculating VI

1
2
3
4
5
6
7
8
9
// c a l c u l a t i n g VI
// Example 5 . 1
clc
clear
L =674 // v i s c o s i t y o f low v i s c o s i t y i n d e x o i l
H =314 // v i s c o s i t y o f h i g h v i s c o s i t y i n d e x o i l
U =464 // v i s c o s i t y o f t e s t o i l i n S
VI =( L - U ) *100/( L - H ) // v i s c o s i t y i n d e x
printf ( Thus VI o f t h e o i l s a m p l e u n d e r t e s t =%2 . 2 f
, VI )
22
Chapter 6
Electrochemical System
Scilab code Exa 6.1 Calculating emf

1
2
3
4
5
6
7
8
9
// c a l c u l a t i n g emf
// Example 6 . 1
clc
clear
Es =1.5273 // emf o f known c e l l i n V
Ns =90 // n u l l p o i n t o f known c e l l i n cm
Nu =60 // n u l l p o i n t o f unknown c e l l i n cm
Eu = Nu * Es / Ns // Emf o f c e l l
printf ( Thus t h e emf o f c e l l = %2 . 4 f V , Eu )
Scilab code Exa 6.2 Calculating pH

1 // c a l c u l a t i n g pH
2 // Example 6 . 2
3 clc
4 clear
5 // f o r q u i n h y d r o n e e l e c t r o d e
6 Ecell =0.284 // Emf o f c e l l i n V
23
7 pH =(0.6996 -0.2422 - Ecell ) /0.0591 //pH o f t h e s o l u t i o n

8 printf ( Thus t h e pH o f t h e s o l u t i o n = %2 . 3 f V , pH )
Scilab code Exa 6.3 Calculating pH

1 // c a l c u l a t i n g pH
2 // Example 6 . 3
3 clc
4 clear
5 // f o r h y d r o g e n e l e c t r o d e
6 Ecell =0.6734 // Emf o f c e l l i n V
7 pH =( Ecell -0.2422) /0.0591 //pH o f t h e s o l u t i o n
8 printf ( Thus t h e pH o f t h e s o l u t i o n = %2 . 3 f , pH )
Scilab code Exa 6.4 Calculating potential

1
2
3
4
5
6
7
8
9
10
11
// c a l c u l a t i n g p o t e n t i a l
// Example 6 . 4
clc
clear
Ag =1
Ksp =8.7*(10^ -17)
Agplus = sqrt ( Ksp )
X = Ag / Agplus
E1 =0.799 //E( Ag+/Ag )
E2 = E1 -(0.0591* log10 ( X ) )
printf ( Thus E( Ag+/Ag ) = %2 . 3 f V , E2 )
Scilab code Exa 6.5 Calculating solubility
24
1
2
3
4
5
6
7
8
9
10
11
// c a l c u l a t i n g s o l u b i l i t y
// Example 6 . 5
clc
clear
Ecell =0.169
AgC =0.01
C1 = AgC /(10^( Ecell /0.0591) )
S = C1 *143.5 // s o l u b i l i t y o f AgCl i n g /L
Ksp = C1 ^2 // s o l u b i l i t y p r o d u c t o f AgCl i n Mol 2/L2
printf ( Thus s o l u b i l i t y o f AgCl = %e g /L ,S )
printf ( \n and Ksp = %e Mol 2/L2 , Ksp )
Scilab code Exa 6.6 Calculating Ksp

// c a l c u l a t i n g Ksp
// Example 6 . 6
clc
clear
Ec =0.071
Ea =0.799
Ecell = Ec - Ea
Ksp =10^( Ecell /0.0591) // s o l u b i l i t y p r o d u c t o f AgCl i n
Mol 2/L2
9 printf ( Thus Ksp = %e Mol 2/L2 , Ksp )
1
2
3
4
5
6
7
8
Scilab code Exa 6.7 Calculating Kc

1 // c a l c u l a t i n g Kc
2 // Example 6 . 7
3 clc
4 clear
5 //E c e l l = 0 . 0 5 9 1 l o g K c / n
6 Eag =0.8
25
7 Ecu =0.34
8 Ecell = Eag - Ecu
9 n =2
10 Kc =10^( n * Ecell /0.059) // e q u i l i b r i u m c o n s t a n t
11 printf ( Thus t h e e q u i l i b r i u m c o n s t a n t f o r t h e
r e a c t i o n = %e , Kc )

2 // Example 6 . 8
3 clc
4 clear
5 //E c e l l = 0 . 0 5 9 1 l o g K c / n
6 Ecell =0.16
7 n =4
Scilab code Exa 6.9 Calculating deltaG and Kc

1
2
3
4
5
6
7
8
9
10
11
// c a l c u l a t i n g d e l t a G and Kc
// Example 6 . 9
clc
clear
Ecell =0.89 // i n V
n =6
F =96500 // i n 1/ mol
deltaG = - n * F * Ecell // i n C . V o r J
//Kc r e l a t e d t o d e l t a G
R =8.314 // i n J / molk
T =298 // i n K
26
12 Kc1 =10^( - deltaG /(2.303* R * T ) )

13 //Kc r e l a t e d t o E c e l l
14 Kc2 =10^(( n * F * Ecell ) /(2.303* R * T ) )
15 printf ( Thus ( i ) d e l t a G = %e , deltaG )
16 printf ( \n ( i i ) Kc i n r e l a t i o n w i t h d e l t a G = %e , Kc1 )
17 printf ( \n ( i i i ) Kc i n r e l a t i o n w i t h E c e l l = %e , Kc2 )

2 // Example 6 . 1 0
3 clc
4 clear
5 //E c e l l = 0 . 0 5 9 1 l o g K c / n
6 Ecell = -0.8277
7 n =1
Scilab code Exa 6.11 Calculating Ecell and Energy

1
2
3
4
5
6
7
8
9
10
11
// c a l c u l a t i n g E c e l l and e n e r g y
// Example 6 . 1 1
clc
clear
Ec =0.4
Ea = -0.87
Ecell = Ec - Ea
F =96500
Wmax =(2* F * Ecell ) /1000
printf ( Thus ( i ) E c e l l = %2 . 2 f V , Ecell )
printf ( \n ( i i )Wmax= %3 . 0 f kJ , Wmax )
27

1
2
3
4
5
6
7
8
9
10
11
// c a l c u l a t i n g Kc
// Example 6 . 1 2
clc
clear
//E c e l l = 0 . 0 5 9 1 l o g K c / n
Ec =0.77
Ea =0.54
Ecell = Ec - Ea
n =2
Kc =10^( n * Ecell /0.059) // e q u i l i b r i u m c o n s t a n t
printf ( Thus t h e e q u i l i b r i u m c o n s t a n t f o r t h e
28

Engineering Chemistry by P. N. Dave and S. G. Pillai

Загружено:

Сведения о документе

Авторское право

Доступные форматы

Поделиться этим документом

Поделиться или встроить документ

Параметры публикации

Этот документ был вам полезен?

Это неприемлемый материал?

Авторское право:

Доступные форматы

Engineering Chemistry by P. N. Dave and S. G. Pillai

Загружено:

Авторское право:

Доступные форматы

Scilab Textbook Companion for

by a grant from the National Mission on Education through ICT,

5 Lubricants and Greases

List of Scilab Codes

Scilab code Exa 1.1 Calculating Hardness

Scilab code Exa 1.2 Calculating Mass

6 Eq =210.5 // e q u i v a l e n t s o f CaCO3 i n ppm

Scilab code Exa 1.3 Calculating Hardness

Scilab code Exa 1.4 Calculating Hardness

Eq1 = M1 * q1 //CaCO3 e q u i v a l e n t s i n mg/L

Scilab code Exa 1.5 Calculating Hardness

Scilab code Exa 1.6 Calculating Lime and Soda

Scilab code Exa 1.7 Calculating Hardness and Lime Soda

Scilab code Exa 1.8 Calculating Lime and Soda

Scilab code Exa 1.9 Calculating Lime and Soda

Eq1 = M1 * q1 //CaCO3 e q u i v a l e n t s i n mg/L

Scilab code Exa 1.10 Calculating Volume

Scilab code Exa 1.11 Calculating Hardness

Scilab code Exa 2.1 Calculating GCV and NCV

Scilab code Exa 2.2 Calculating GCV and NCV

// c a l c u l a t i n g GCV and NCV

Scilab code Exa 2.3 Calculating GCV and NCV

Scilab code Exa 2.4 Calculating GCV and NCV

Scilab code Exa 2.5 Proximate Analysis

after heating for

Scilab code Exa 2.6 Calculating percentage C and H

Scilab code Exa 2.7 Calculating percentage S and N

Scilab code Exa 2.8 Calculating percentage S

Scilab code Exa 5.1 Calculating VI

Scilab code Exa 6.1 Calculating emf

Scilab code Exa 6.2 Calculating pH

7 pH =(0.6996 -0.2422 - Ecell ) /0.0591 //pH o f t h e s o l u t i o n

Scilab code Exa 6.3 Calculating pH

Scilab code Exa 6.4 Calculating potential

Scilab code Exa 6.5 Calculating solubility

Scilab code Exa 6.6 Calculating Ksp

Scilab code Exa 6.7 Calculating Kc

Scilab code Exa 6.8 Calculating Kc

Scilab code Exa 6.9 Calculating deltaG and Kc

12 Kc1 =10^( - deltaG /(2.303* R * T ) )

Scilab code Exa 6.10 Calculating Kc

Scilab code Exa 6.11 Calculating Ecell and Energy

Scilab code Exa 6.12 Calculating Kc

Вам также может понравиться