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28/1/2004
Course M6 Lecture 6
28/1/2004
Diffusion in polymers
6.1 Introduction
z
z
z
Course M6 Lecture 6
28/1/2004
Penetrant
Design goal
packaging
additives
gas separation
analytical chemistry
monomer removal
polymer electrolytes
drug implants
biosensors
gas, moisture
plasticizers, dyes
gases
ions
unreacted monomer
ions
pharmaceuticals
biomolecules
high barrier
high barrier
selectivity
high selectivity
low barrier
ionic conductivity
controlled release
high selectivity
Sorption isotherm
Course M6 Lecture 6
28/1/2004
Course M6 Lecture 6
28/1/2004
Course M6 Lecture 6
28/1/2004
J = A
dX
dx
J = D
dC
dx
C = kp
P = Dk = Diffusivity Solubility
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Course M6 Lecture 6
28/1/2004
6.10.1 Sorption
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z
ch = kp + ch bp/ (1 + bp)
cd
Henry
ch
Langmuir
ch
p
Course M6 Lecture 6
28/1/2004
6.10.2 Sorption
z
liquid
glass
Vexc
Tg
z
z
z
Temperature
dc
dJ
d 2c
=
= D 2
dt
dx
dx
z
D = D0 exp( Ed / RT )
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z
Course M6 Lecture 6
28/1/2004
D = RTAf exp( B / vf )
Course M6 Lecture 6
28/1/2004
D = 13 v(t )v(0) dt
z
(Green - Kubo)
(Einstein)
Q
=
t
6D
Qt / lc
transient
state
steady
state
l2
=
6D
Course M6 Lecture 6
28/1/2004
Mt
4
=
M
Dt
l2
t1/2
10
Course M6 Lecture 6
28/1/2004
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Course M6 Lecture 6
28/1/2004
10
5
0
-5
0
10
15
20
25
x ()
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Course M6 Lecture 6
28/1/2004
M ean-Squared-Displacement (2)
100
200
300
400
Time (ps)
Summary of M6 Part 1
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Course M6 Lecture 6
28/1/2004
Summary of M6 Part 1
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