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O-DICHLOROBENZENE
CAUTIONARY RESPONSE INFORMATION
Common Synonyms
1,2-Dichlorobenzene
ortho-Dichlorobenzene
Dowtherm e
Liquid
Colorless
4. FIRE HAZARDS
Pleasant odor
Sinks in water.
Fire
Exposure
Combustible
POISONOUS GASES ARE PRODUCED IN FIRE.
Wear goggles and self-contained breathing apparatus.
Extinguish with water, dry chemical, foam, or carbon dioxide.
Cool exposed containers with water.
CALL FOR MEDICAL AID.
LIQUID
Irritating to skin and eyes.
Harmful if swallowed.
Remove contaminated clothing and shoes.
Flush affected areas with plenty of water.
IF IN EYES, hold eyelids open and flush with plenty of water.
IF SWALLOWED and victim is CONSCIOUS, have victim drink water
or milk and have victim induce vomiting.
IF SWALLOWED and victim is UNCONSCIOUS OR HAVING
CONVULSIONS, do nothing except keep victim warm.
Water
Pollution
2. CHEMICAL DESIGNATIONS
2.1 CG Compatibility Group: 36; Halogenated
hydrocarbon
2.2 Formula: o-C6H4Cl2
2.3 IMO/UN Designation: 6.1/1591
2.4 DOT ID No.: 1591
2.5 CAS Registry No.: 95-50-1
2.6 NAERG Guide No.: 152
2.7 Standard Industrial Trade Classification:
51139
3. HEALTH HAZARDS
3.1 Personal Protective Equipment: Organic vapor-acid gas respirator; neoprene or vinyl gloves;
chemical safety spectacles, face shield, rubber footwear, apron, protective clothing.
3.2 Symptoms Following Exposure: Chronic inhalation of mist or vapors may result in damage to lungs,
liver, and kidneys. Acute vapor exposure can cause symptoms ranging from coughing to central
nervous system depression and transient anesthesia. Irritating to skin, eyes, and mucous
membranes. May cause dermatitis.
3.3 Treatment of Exposure: INHALATION: remove victim to fresh air, keep him quiet and warm, and call
a physician promptly. INGESTION: no known antidote; treat symptomatically; induce vomiting and
get medical attention promptly. EYES AND SKIN: flush with plenty of water; get medical attention
for eyes; remove contaminated clothing and wash before reuse.
3.4 TLV-TWA: 25 ppm
3.5 TLV-STEL: 50 ppm
3.6 TLV-Ceiling: Not listed.
3.7 Toxicity by Ingestion: Grade 2; LD50 = 0.5 to 5 g/kg
3.8 Toxicity by Inhalation: Currently not available.
3.9 Chronic Toxicity: Causes kidney and liver damage in rats. Effects unknownin humans.
3.10 Vapor (Gas) Irritant Characteristics: Vapors cause moderate irritation such that personnel will find
high concentrations unpleasant. The effect is temporary.
3.11 Liquid or Solid Characteristics: Minimum hazard. If spilled on clothing and allowed to remain, may
cause smarting and reddening of the skin.
3.12 Odor Threshold: 4.0 ppm; 50 ppm
3.13 IDLH Value: 200 ppm
3.14 OSHA PEL-TWA: Not listed.
3.15 OSHA PEL-STEL: Not listed.
3.16 OSHA PEL-Ceiling: 50 ppm
3.17 EPA AEGL: Not listed
7. SHIPPING INFORMATION
8. HAZARD CLASSIFICATIONS
8.1 49 CFR Category: Keep Away From Food
8.2 49 CFR Class: 6.1
8.3 49 CFR Package Group: III
8.4 Marine Pollutant: Yes
8.5 NFPA Hazard Classification:
Category
Classification
Health Hazard (Blue)..........
2
Flammability (Red).............
2
Instability (Yellow).............
5. CHEMICAL REACTIVITY
5.1 Reactivity with Water: No reaction
5.2 Reactivity with Common Materials: No
reaction
5.3 Stability During Transport: Stable
5.4 Neutralizing Agents for Acids and
Caustics: Not pertinent
5.5 Polymerization: Not pertinent
5.6 Inhibitor of Polymerization: Not pertinent
6. WATER POLLUTION
JUNE 1999
DBO
O-DICHLOROBENZENE
9.20
SATURATED LIQUID DENSITY
Temperature
(degrees F)
81.799
81.770
81.730
81.700
81.660
81.629
81.589
81.559
81.520
81.490
81.450
81.419
81.389
81.349
81.320
81.280
81.250
81.209
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
77
40
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190
200
210
9.25
SATURATED VAPOR PRESSURE
9.24
SOLUBILITY IN WATER
Temperature
(degrees F)
Temperature
(degrees F)
Temperature
(degrees F)
40
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190
200
210
9.23
LIQUID VISCOSITY
9.22
LIQUID THERMAL CONDUCTIVITY
9.21
LIQUID HEAT CAPACITY
0.009
0.013
0.018
0.025
0.035
0.048
0.064
0.086
0.114
0.150
0.195
0.252
0.322
0.409
0.515
0.644
0.801
0.988
Temperature
(degrees F)
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120
125
130
135
140
145
150
155
9.26
SATURATED VAPOR DENSITY
Temperature
(degrees F)
40
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190
200
210
0.00024
0.00034
0.00047
0.00065
0.00088
0.00118
0.00157
0.00207
0.00270
0.00348
0.00446
0.00565
0.00712
0.00889
0.01103
0.01358
0.01662
0.02022
Temperature
(degrees F)
32
34
36
38
40
42
44
46
48
50
52
54
56
58
60
62
64
66
Centipoise
1.041
1.021
1.001
0.982
0.964
0.945
0.928
0.911
0.894
0.878
0.862
0.846
0.831
0.817
0.802
0.788
0.775
0.762
9.27
IDEAL GAS HEAT CAPACITY
Temperature
(degrees F)
0
25
50
75
100
125
150
175
200
225
250
275
300
325
350
375
400
425
450
475
500
525
550
575
600
JUNE 1999