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Metamorphic Facies
When a rock is metamorphosed by heat and pressure, there may be addition or loss of volatiles such as
H2O and CO2, but the overall bulk chemistry of the rock remains essentially the same. The changes
brought about about by metamorphism , therefore, are simply mineralogical and textural changes, rather
than an overall chemical change.
The mineralogy of a metamorphic rock, therefore, is determined by the P-T conditions to which it has
been subjected. By reproducing the P-T conditions under laboratory conditions and observing what
minerals crystallise, we can deduce the P-T conditions of rocks containing those minerals.
The P-T conditions that produce particular rock types and particular mineral assemblages are termed
metamorphic facies . The following diagram shows metamorphic facies in relation to Pressure and
Temperature. The relative locations and approximate pressures and temperatures should be known.
Key reactions between minerals mark the boundaries between individual metamorphic facies. For
example, the out going of chlorite marks the greenschist - amphibolite boundary:
chlorite + muscovite + quartz => cordierite + aluminosilicate + biotite + water
The outgoing of muscovite marks the amphibolite - granulite boundary:
Metamorphic Facies
Index Minerals
Because some minerals form within particular range of P-T conditions, their presence within a rock
gives an indication of the conditions that the rock was formed under. Using two or more such index
minerals, the conditions of formation are able to be progressively narrowed. The aluminosilicate
polymorphs, andalusite, sillimanite and kyanite, are good examples of index minerals, as they only form
during metamorphism (see Chernicoff, Fig. 7-19, pg. 195). Andalusite is the low pressure polymorph,
forming during low grade regional metamorphism or by contact metamorphism. If two aluminosilicates
occur within the one rock, then the conditions of formation are constrained to around the boundary
between the two stability regions. Note that the conditions may not be exactly on the boundary, as the
sluggishness of reactions means that minerals may still be found a little outside their stability field.
Metamorphic Zones
As rocks of the same chemical composition have different mineral assemblages, but rocks with the same
mineral assemblages represent similar metamorphic facies, then by selecting characteristic index
minerals, regions of similar metamorphic grade can be mapped in the field. The line that indicates where
these index minerals first appear is known as an isograd. The region between isograds is a
metamorphic zone. Thus the first appearance of biotite in a metamorphic rock defines the biotite
isograd, and the biotite zone continues until the in coming of the next highest index mineral. Note that
biotite may continue to occur in the higher metamorphic zones.
The concept of metamorphic zones was pioneered by a Scottish geologist, Barrows, in the Sottish
highlands, where the index minerals, in order of increasing metamorphic grade, are chlorite - biotite garnet - staurolite - kyanite - sillimanite. This characteristic metamorphic facies series is now known as
Barrovian series metamorphism. A similar zoning occurs in the northeast U.S. (see Chernicoff, Fig. 721, pg. 197).
Metamorphic Facies
Metamorphic Facies
retrograde metamorphism may take place (t4). The P-T-t path of such a tectonic history delineates an
anti-clockwise path on a P-T diagram, as shown below.
1.
Metasomatism
1. Metamorphic reactions discussed so far involve relatively fixed chemical compositions, apart
from devolatilisation and the release of water and carbon dioxide. This is because there is
relatively fluid in relation to the amount of rock, and the reactions take place slowly. The fluid
provides the pathway for the mobilisation of elements from one mineral to another, but not
enough to dissolve enough to noticeably change the rock composition.
Where fluid is abundant, however, ions can be removed in solution or precipitated from solution
and the rock composition changes. Such an alteration of the rock composition by the movement
of fluids is known as metasomatism
Peter.Whitehead
Updated 12/2/01