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Article history:
Received 9 June 2014
Accepted 4 September 2014
Available online 26 September 2014
Keywords:
Spray drying
Energy recovery
Exhaust gas recirculation
Mathematical model
Advanced ceramic materials
a b s t r a c t
Model simulations were employed to investigate the inuences of process parameters on the energy
recovery in spray drying process that partially recycle the exhaust drying gas. The energy efciency
and energy saving were studied for various values of recirculation ratios with respect to the temperature
and ow rate of the drying air, slurry feed rate and concentration of slurry in spray drying of advanced
ceramic materials. As a result, signicant gains in energy efciency and energy saving were obtained
for a spray drying system with high recirculation ratio of exhaust air. The high slurry feed rate and the
low slurry concentration, inlet drying air temperature and drying air ow rate enhanced the energy efciency of spray drying system. However, the high energy saving was obtained in spray dryers operating at
low slurry feed rate and high slurry concentration.
2014 Elsevier Ltd. All rights reserved.
1. Introduction
Spray drying is an efcient and versatile method used in various
industries for manufacturing particle agglomerates from the slurry
or liquid feed. In recent years, this method has been increasingly
employed for the preparation of high-value particles, such as
agglomerates of nanoparticles [1] or agglomerates of controlled
porous structure [2]. Lately, alumina-based ceramic composites
such as zirconia dispersed in alumina matrix have been developed
for orthopedic applications [3]. These composite materials were
utilized for the production of femoral heads due to their biocompatibility, good wettability, low friction, strong wear resistance,
high fracture toughness and high strength. The forming of ceramic
parts is currently carried out by dry pressing of agglomerated powder. This technique is the most economic one, but it requires a
powder of good owability [4]. Spray drying is frequently used
for manufacturing of particle agglomerates of superior owability.
A typical spray drying process consists of atomization of liquid
feed into a spray of ne droplets, contact of drying air with
droplets, drying of droplets with formation of solid particle
agglomerates and separation of solid product from exhaust gas
[5]. The spray drying process consumes a large amount of energy
for water evaporation. The specic heat consumption was reported
to be close to 4900 kilojoule per kilogram of evaporated water in
drying of skim milk in a pilot-scale multi-stage spray dryer [6].
Corresponding author.
E-mail address: golmanboris@gmail.com (B. Golman).
http://dx.doi.org/10.1016/j.enconman.2014.09.012
0196-8904/ 2014 Elsevier Ltd. All rights reserved.
642
Nomenclature
Cp
ES
h
m
Q
RR
T
W
X
Y
Greek symbols
gR
energy efciency (%)
k
latent heat of water (J kg1)
Subscripts
a
dry air
aa
atomizing air
crit
critical
d
dry base
da
drying air
dew
ea
fa
h
i
in
j
l
loss
ma
oa
out
p
ra
rec
ref
req
s
sl
v
va
dew point
exhaust air
feed air
wet base
ith stream
inlet
jth phase
liquid
loss
mixed air
ambient air
outlet
solid product
recirculated air
recovered
reference
required
solid
slurry
vapor
vent air
atomizing air are fed to the spray dryer through an atomizer, which
is positioned at the top of the chamber. The atomizing air is used to
generate droplets from the slurry. A drying air is supplied to the
top of the chamber co-currently with the feed stream. The solid
agglomerates formed during drying leave the dryer from the bottom part of the drying chamber together with the exhaust air.
Agglomerates are separated from the air using a cyclone and collected as a product. If necessary, the exhaust air is further cleaned
using a bag lter. The exhaust air is divided into a recirculated air
and a vent air streams according to a specied recirculation ratio.
Thereafter, the recirculated air is mixed with a feed air stream to
maintain the moisture content of the drying air entering the dryer
at the desired level. The humidity and temperatures of all streams
are constantly checked as the dew point temperature to avoid
moisture condensation. The mixed air is heated up to the specied
drying temperature, Tda,out, in an indirect red heater, which is
used in spray drying of advanced materials to prevent contamination of product powder with combustion byproducts.
2.1. Mathematical model
The mathematical model derived on the basis of overall heat
and mass balances in a well-mixed dryer was employed in the
present study to calculate the energy efciency indices for various
values of the process parameters.
The amount of heat supplied to or withdrawn from the spray
drying system in unit time with ith stream, Qi, is computed as a
product of the mass ow rate of that stream specied on a dry
basis, mi,d, and the specic enthalpy of stream dened per unit
mass of dry air or dry solids, hi.
The specic enthalpies of slurry feed and solid product streams
are given by
where Cpj is the specic heat capacity of jth phase, Xi is the mass
fraction of water in the ith stream on a dry basis, Yi is the humidity
of ith stream, kref is the latent heat of water vaporization, Ti is the
643
Atomizing air
Drying air
Tda,out, Yda, mda,d
Taa,Yaa, maa,d
Heater
Tda,in
Slurry
Tsl, Xsl, msl,d
Mixed air
Tma, Yma, mma,d
Spray dryer
chamber
Feed air
Tfa, Yfa, mfa,d
M2
Recirculated air
Tra, Yra, mra,d
M1
Exhaust air
Product
Tp, Xp, mp,d
Vent air
Fig. 1. Schematic diagram of the spray drying system with exhaust air recirculation.
Table 1
The energy balances of the spray drying system.
Table 2
The mass balances of the spray drying system.
Description
Equation
Description
Overall balance
Heat inputs
Heat by slurry
feed
Heat by feed air
Heat by
atomizing air
Energy for
heating drying
air from Tda,in to
Tda,out
Total heat input
Heat outputs
Solid product
discharge
Vent air from
system
Unaccountable
losses
Total heat output
Balance around
splitting point
M1
Balance around
mixing point M2
Qin = Qout
(4)
(5)
(6)
(7)
(8)
Equation
Overall balances
Dry solids
msl,d = mp,d
Dry air
mfa,d + maa,d = mva,d
Moisture
msl,dXsl + mfa,dYfa + maa,dYaa = mp,dXp + mva,dYva
Balance around splitting point M1
Dry air
mea,d = mra,d + mva,d, mra,d = mea,d (RR/100)
Moisture
mea,dYea = mra,dYra + mva,dYva, Yea = Yva = Yra
Balance around mixing point M2
Dry air
mma,d = mra,d + mfa,d
Moisture
mda,dYma = mfa,dYfa + mra,dYra
(9)
(10)
(11)
Qloss
Qout = Qp + Qva + Qloss
mea,dhea = mra,dhra + mva,dhva, Tea = Tra = Tva
(12)
(13)
(14)
(15)
(16)
(17)
(18)
(19)
(20)
(21)
Table 3
Process variables ranges.
Independent process variables
Units
Low
limit
High
limit
Hold
value
C
m3/h
160
2500
300
3500
230
3000
kg/h
%
10
20
90
60
50
40
Y va
22
Y ma
mfa;d
mra;d
Y fa
Y va
mda;d
mda;d
23
644
Y da Y oa
msl;d RRX sl X p
;
mda;d 100 RR
24
Using Eqs. (2), (14), (18) and the relationships Tda.in = Tma, the
drying air temperature at the heater inlet is given as
RR
T da;in 100
mda;d Cpa T v a T fa 1 100
Cpv T v a Y v a T fa Y fa 1 100
RR
RR
RR
100 maa;d Cpa T v a T fa Cpv T v a Y v a T fa Y fa
25
60
60
50
50
40
40
30
R ,[%]
30
R ,[%]
20
20
10
10
0
280
260
240
T
220
da
, [ o 200
C]
180
160
10
20
30
60
50
40
, [kg
m sl
70
80
0
280
260
90
240
da
,[
220
C] 200
/h]
160
l
Ws
25
20
45
]
, [%
60
60
50
50
40
40
R ,[%]
30
30
20
20
10
10
0
3400
0
3400
3200
3000
da ,
[m 3 2800
/h]
2600
10
20
30
40
50
60
, [ kg
70
80
90
3200
3000
da ,
/h ]
m sl
[m 3 2800
/h ]
2600
35
30
25
20
45
40
, [%
Wsl
50
55
60
(d)
(c)
60
60
50
50
40
40
R ,[%]
40
60
(b)
(a)
R ,[%]
30
180
35
55
50
R ,[%]
30
30
20
20
10
10
0
25
0
3400
30
35
sl ,
40
[%
45
50
55
60
10
20
30
40
50
60
, [kg
sl
70
/h]
80
90
180
3200
200
3000
da ,
220
240
[m 3 2800
/h]
2600
280
300
(f)
(e)
260
o C]
,[
T da
160
645
70
Qin
Qin
60
50
50
60
Qda
40
30
Qfa
20
40
30
20
Qreq
10
10
0
150
0
170
190
210
230
250
270
290
310
80
100
70
Qin
60
50
Qda
50
40
30
20
Qin
60
Qfa
10
40
30
20
Qreq
10
0
2400
2600
2800
3000
3200
3400
3600
10
20
26
where gR is the energy efciency and Qreq is the energy required for
evaporation of specied amount of water, which is expressed as
Q req X sl X p msl;d k
50
60
70
simulation process and output results of simulation. The thermodynamic water properties were implemented using the empirical
correlations [12] as well as the more precise models based on
the IAPWS Industrial Formulation 1997 [13]. The moist air properties were calculated using the experimental-based correlations
[14,15]. The heat capacity of solid as a function of temperature
was evaluated by an empirical correlation [16].
2.2. Study case
27
Qin is calculated by taking into account the reduction in energy consumption for heating of drying air Qda by Eq. (8).
The energy saving is dened as the ratio of energy recovered
from exhaust air to the energy supplied to the spray dryer without
heat recovery:
Q rec
100%
Q in;S1
40
Q req
100%
Q in
30
ES
60
70
gR
40
20
[oC]
28
The four process parameters were chosen as independent variables: drying air temperature at the inlet of spray dryer (Tda), volumetric ow rate of drying air on a wet basis (Vda), slurry feed rate
(msl) and water content of slurry (Wsl) on a wet basis. The ranges of
parameter values are shown in Table 3. The slurry feed rates were
selected on the basis of the small-scale industrial production rates
of advanced materials [17]. The range of variation of water content
was chosen based on the literature data [18] and our preliminary
experimental study on drying of aluminazirconia composite
slurry in a laboratory-scale spray dryer. Other independent parameters were kept constant; ambient air temperature at 30 C and relative humidity at 70%, the product water content at 3 wt% on a wet
basis. The recirculation ratio was xed at various levels starting
from 5% and up to 80%.
3. Results and discussion
3.1. Model validation
To prove that the developed model could be utilized for analysis
of energy recovery in low-volume industrial spray-dryer, the
646
60
60
50
50
40
40
R ,[%]
R ,[%]
30
30
20
20
10
10
160
180
200
220
240
0
3400
3200
3000
Vd
, [m 3 2800
/h]
2600
o C]
260
280
300
,[
a
Td
(a)
0
3400
3200
da
200
3000
, [m
h]
160
220
2800
3/
180
240
260
2600
280
300
T da
o C]
,[
(b)
Fig. 7. Effect of recirculation ratio on response surfaces of energy efciency: (a) RR = 20% and (b) RR = 80%.
647
80
80
60
ES, [%]
ES, [%]
60
40
40
20
20
0
280
260
240
da
220
50
200
,[ o
180
C]
40
30
160
70
60
g
, [k
80
55
90
280
45
260
40
240
/h]
35
220
,[o
C]
da
m sl
20
10
30
200
25
180
, [%
sl
20
160
(a)
(b)
80
80
60
60
ES, [%]
ES, [%]
60
50
40
20
40
20
0
3400
3200
3000
V
2800
da
, [m
3/
2600
h]
10
20
30
40
50
70
60
, [k
m sl
g/h
80
0
2600
90
2800
da
35
3000
, [m
25
20
40
3200
30
/h]
45
50
3400
55
Ws
l,
[%
60
(c)
(d)
80
80
60
40
ES, [%]
20
20
25
20
90
80
70
60
50
, [k
m sl
40
g/h]
10
3000
/h ]
20
30
280
260
, [m
45
W 40
sl , [ 35
%
30
]
3400
3200
50
2800
240
220
Tda , o
[ C]
(e)
200
2600
180
160
(f)
Fig. 8. 3D surface plots of energy saving for RR = 70%.
da
0
55
40
ES, [%]
60
200
170
Qin,s1
140
Qrec
110
80
Qin
50
150
170
190
230
250
270
290
310
200
170
Qin,s1
140
Qrec
110
80
Qin
50
2400
2600
2800
3000
3200
3400
3600
200
Qin,s1
Qin , Qin,s1 , Qrec [kJ/s]
170
140
Qrec
110
80
Qin
50
0
20
40
60
80
100
200
210
648
Qin,s1
170
140
Qrec
110
80
Qin
50
10
20
30
40
50
60
70
649
80
80
60
ES, [%]
ES, [%]
60
40
40
20
20
0
2600
2800
da
3000
, [m
3200
3
/h]
180
3400
300
280
260
240
220
o C]
,[
200
T da
160
(a)
0
2600
300
280
2800
260
V 3000
da , [
m 3 3200
/h]
3400
240
220
o
200
180
160
T da
,[
C]
(b)
Fig. 13. Effect of recirculation ratio on response surfaces of energy saving: (a) RR = 20% and (b) RR = 80%.