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Centre
No.
Initial(s)
Paper Reference
Candidate
No.
6 2 4 3
0 2
Signature
Paper Reference(s)
6243/02
Edexcel GCE
Chemistry
Advanced Subsidiary
Unit Test 3B
Wednesday 8 June 2005 Morning
Time: 1 hour
Question Leave
Number Blank
1
2
3
4
Instructions to Candidates
In the boxes above, write your centre number, candidate number, your surname, initial(s) and
signature.
Answer ALL the questions in the spaces provided in this question paper.
You may use a calculator. Show all the steps in any calculations and state the units.
Advice to Candidates
You are reminded of the importance of clear English and careful presentation in your answers.
You will be assessed on your Quality of Written Communication in this paper.
Total
This publication may be reproduced only in accordance with
Edexcel Limited copyright policy.
2005 Edexcel Limited.
Printers Log. No.
N21450A
W850/R6243/57570 7/7/4/23,200
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Observation
Inference
NH+4 ions
K+ ions
(4)
(ii) Complete the inference statements in the table below.
Test
Observation
White precipitate is
formed which does
not dissolve in dilute
hydrochloric acid.
Inference
The precipitate is
.....................................................
Therefore the anion in D is
.....................................................
(2)
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(4)
Q1
(Total 10 marks)
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2.
use a measuring cylinder to transfer 50 cm3 of 1.0 mol dm3 aqueous copper(II)
sulphate into a polystyrene cup, firmly held in a 250 cm3 beaker
stir the solution with the thermometer and record the temperature to the nearest 0.5 C
at exactly 3.5 minutes, add the zinc powder to the aqueous copper(II) sulphate,
stirring continuously
record the temperature of the solution every minute from 4.0 to 9.0 minutes.
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
53.0
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(a) (i) Plot a graph of temperature against time on the grid below.
70.0
60.0
50.0
Temperature
/ C
40.0
30.0
20.0
0
0
10.0
1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0
Time / minutes
(2)
(ii) Use the graph to calculate the maximum temperature change, T. Show clearly
on the graph how you obtained your answer.
T = ................................................C
(2)
(iii) Give ONE reason why a series of temperature readings is obtained instead of just
the starting and maximum temperatures.
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(1)
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(1)
(ii) What assumption have you made about the solution in your calculation in (i)?
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(1)
(iii) Calculate the amount (moles) of copper(II) sulphate, CuSO4, in 50 cm3 of a
1.0 mol dm3 solution.
(1)
(iv) Calculate the enthalpy change for this reaction in kJ mol1.
(2)
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(c) Suggest TWO improvements that could be made to the experimental procedure.
Give a reason for each.
Improvement 1 ..............................................................................................................
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Reason ..........................................................................................................................
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Improvement 2 ..............................................................................................................
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Reason ..........................................................................................................................
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(4)
Q2
(Total 14 marks)
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3.
Boiling
temperature
/ C
Density
2-methylpropan-2-ol
83.0
0.79
2-chloro-2-methylpropane
51.0
0.84
water
100
1.00
/g cm3
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(c) After washing and drying the organic product, a student set up the following
apparatus for distillation. It contains three mistakes, which were identified by a
teacher before heating began.
Water
in
Water
out
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(2)
(ii) Calculate the percentage yield of 2-chloro-2-methylpropane in this experiment.
(1)
(e) Describe a chemical test that you would do to show that the final sample of
2-chloro-2-methylpropane did not contain any 2-methylpropan-2-ol.
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(2)
(Total 13 marks)
10
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4.
A student investigated the ease with which Group 2 metal carbonates thermally
decompose when heated with a Bunsen burner.
XCO3(s) XO(s) + CO2(g)
The student heated each carbonate separately in a test tube. The volume of gas collected
in a gas syringe was measured after two minutes.
Test tube
100 cm3 graduated
syringe
Heat
(a) Each test tube must be heated directly by a Bunsen flame in an identical manner.
Suggest how this can best be achieved.
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(2)
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(b) In each experiment, the student used the same number of moles of metal carbonate.
The mass of magnesium carbonate, MgCO3, heated was 0.21 g.
Calculate the mass of barium carbonate, BaCO3, that should be used for a valid
comparison.
(3)
(c) (i) Calculate the maximum volume of carbon dioxide that would be produced by the
complete decomposition of 0.21 g of magnesium carbonate.
[1 mol of gas occupies 24000 cm3 under the conditions of the experiment.]
(2)
(ii) The balance used to weigh the magnesium carbonate is accurate to 0.01 g.
Calculate the percentage error in the mass of the magnesium carbonate weighed.
(1)
12
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(d) The following results were obtained after heating each sample for two minutes.
Metal carbonate in the
test tube
None
MgCO3
20
CaCO3
13
SrCO3
11
BaCO3
Q4
(Total 13 marks)
TOTAL FOR PAPER: 50 MARKS
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