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Lubricating Oils
Sanjeev Kashikar
AETS India & Middle East
Crude Oils
Refining Process
API Groups
Synthetics
Base Oil Properties
Additives
Oil Applications
Molykote Oils
Crude Oils
Process of making hydro-carbon base oils begins with Crude
Oil
Crude compositions vary
Paraffinic
Naphthenic
Mixed Paraffinic and Naphthenic
Paraffins
Paraffins/Branched Paraffins are Wax like
Aromatics
Undesired Components
High volatility
High toxicity
Low load carrying capacity
Aromatics
Oil Refining
Process
Naphta and light Gas
Residuum
Hydroprocessing
Vacuum Distillation
Crude
Oil
Atmospheric Distillation
Kerosene
Hydrocracking
Hydrotreating
Solvent Refining
Acid Refining
Residuum (Asphalt)
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Hydrofinisher
Catalytic Dewaxer
Hydrocracker
Vacuum Destillation
Neutral
Oils
Crude
Oil
Atmospheric Distillation
Vacuum Distillation
Hydroprocessing
Hydrocracking
Hydrotreating
Solvent Refining
Acid Refining
Residuum (Asphalt)
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Benefits of Molykote MO
Feature
Benefit
Good Lubricity
Low Volatility
(no change in viscosity)
No Heavy Metals
Low Toxicity
Long Lasting
10
Synthetic Oils
Production starts with synthetic base stocks often
produced from petroleum-based building blocks.
Man-made to have controlled molecular
structure with predictable properties.
Polyalphaolefin
Diester
Polyolester
Polyglycol
Silicone
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Polyalphaolefines - PAO
Produced from raw material derived from crude oil and
polymerised to obtain different viscosities
Similar to mineral oils and thus compatible
Contains no S, P, Wax or Metals
High Viscosity Index (>> 100, typically >135)
Very Low Pour Point (< -30 C)
RCHCH2CH H
Excellent shear resistance
CH3
R
n
Excellent hydrolytic stability
Good oxidation and thermal stability
Low volatility
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Diester - DE
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Polyolester - POE
Even higher thermal and oxidation resistance
than DE
Better seal compatibility than DE
Higher VI
Low volatility
Hydrolytic stability
Only lower viscosity grades
No H1 grades available
O
ROCCH2CCH2COR
CH2
COOR
14
Polyglycols - PAG
High VI: >>100, typically >150
Available water soluble and water insoluble types
Low volatility; forms no deposits at high
temperatures
Biodegradable
Good lubricity
Poor performance at low temperatures
Not compatible with MO
High cost - 6-8 times more than MO
RO-CH2-CH2OH
n
RO-CH-CH2OH
CH3
15
Silicones
High compressibility
Oxidation products are abrasive (SiO2)
Low surface tension
(does not form adherent lubricating films)
Poor AW properties
Poor additive response
CH3
CH3
H3CSi-OSi-CH3
CH3
n CH3
16
Polyalfaolefin
C5
C10
C15
C20
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25-35% aromatics
13-15,000 ppm sulfur
150 ppm water
500-750 ppm water
bearing wear occurs
1500 ppm water
cloudy oil appearance
90%+ saturated
hydrocarbon molecules
Nil aromatics
saturated hydrocarbon
molecules
<10 ppm sulfur
150 ppm water
Water remains low over
oil life
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Benefit
Oxidation Stability
Thermal Stability
High VI
Lower Friction
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20
Possible Disadvantages
High Cost
Seal Compatibility
Hydrolytic Stability
Mixability
21
TEMPERATURE
ADDITIVE
ACCEPTANCE
RANGE (C)
VISCOSITY
INDEX
PLASTIC/RUBBER
COMPATIBILITY
BALLPARK
PRICING ($/LB)
Mineral
-35150
Excellent
Fair
Fair
<5
PAG
-45175
Excellent
Good
Good
<5
PAO
-60200
Good
Good
Very Good
5 - 10
Ester
-45200
Good
Good
Fair
10 - 20
Silicone
-75200
Poor
Excellent
Very Good
10 - 20
Fluorosilicone
-40250
Poor
Very Good
Excellent
50 - 75
PFPE
-60300
Poor
Fair
Excellent
75 - ?
22
Viscosity
Viscosity Index
Pour Point
Cloud Point
Freeze Point (Melt Point)
Flash Point
Fire Point
Color
Demulsibility
23
Viscosity
24
Kinematic viscosity
is measured based on the time required for
a given amount of fluid to flow through
a certified capillary while the pressure head
is allowed to drop
Units: Stokes (CGS Unit)
1 cSt = 10-2 cm2/s = 10-6 m2/s = 1 mm2/s
Units: Saybold Universal Seconds (SUS)
Time in seconds for 60 milliliters of oil to flow
through a standard orifice at a given temperature.
(ASTM Designation D88-56.)
25
Kinematic Viscosity
Glass Capillary Tube Viscometer
T1
T2
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Viscosity grades
Any of a number of systems which characterize lubricants
according to viscosity for particular applications, such as:
Industrial Oils
(ISO VG)
(AGMA)
Gear Oils
(SAE Crankcase)
(SAE Gear)
and others
28
Viscosity Classifications
29
Typical Range
of Molykote
Industrial Oils
30
Viscosity Index
1000
Viscosity [cSt]
L-0115
L-0115FG
L-0122
L-0122FG
L-0132
L-0146
L-0146FG
L-0168
100
10
20
30
40
50
60
70
80
90
100
110
120
Temperature [C]
31
Pour Point
The Pour Point- the lowest
temperature an oil or distillate fuel is
observed to flow, when cooled under
conditions prescribed by test method
ASTM D 97.
The Pour Point is 3C (5F) above the
temperature at which the oil in a test
vessel shows no movement when the
container is held horizontally for five
seconds.
In other words, the lowest temperature
a fluid pours from a container
one indication of low temperature
capability
32
Cloud Point
Temperature when fluid begins to crystallize
due to freezing
33
Flash Point
The Flash Point (Cleveland Open Cup)
is the temperature to which a combustible
liquid must be heated so that the released
vapor will burn for no more than 5 seconds
when ignited under specified conditions
In other words, the lowest temperature at
which the fluids vapors will ignite and burn
for at no more than five seconds
34
Fire Point
The Fire Point (Clevelend Open Cup)
is the temperature to which a combustible
liquid must be heated so that the released
vapor will burn continuously when ignited
under specified conditions
In other words, the lowest temperature at
which the fluids vapors will ignite and continue
to burn for at least five seconds
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Color
Color Scale of new lubricant is defined by ASTM
D1500
Determined by content of aromatics, sulfur, additives,
dyes, impurities
In-service lubricants change of the color may
indicate:
Oxidation acid forming from sulfur compounds
Thermal degradation air bubbles implosion, high
surface T
Contamination mixing of lubs, solid particles,
chemical process
37
Oil/Water Demulsibility
Demulsibility how fast is the ability of the oil to separate the
water
Test ASTM D1401 and D2711
Conventional
Mineral Oil
Oil phase
(< 500 ppm H2O)
Water phase
Mixing
5 min.
Oil phase
(> 1,000 ppm H2O)
Emulsion
Water phase
Molykote
Mineral Oil
Mixing
5 min.
~ 54 C
(130 F)
Oil phase
(< 500 ppm H2O)
Water phase
Oil phase
(< 500 ppm H2O)
Water phase
Additives
Anti-Oxidants
Demulsifier
Detergent/Dispersants
VI Improver
Pour Point Depressants
EP Additives
AW Additives
Tackifier
Corrosion/Rust Inhibitor
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Role of Additives
Additives
Purpose
How it works
Compounds used
Extreme Pressure
(EP)
Sulfur-phosphorous
compounds or solid
dispersions like Borate or
MoS2
Antiwear (AW)
Zinc dialkyldithiophosphate
(ZDDP),
Tricresylphosphate (TCP)
Corrosion Inhibitors
Reduce rust
formation on iron
surfaces
Additive is metallophilic
and hydrophobic. Coats
metal surfaces and rejects
moisture.
Anti-Oxidants and
Oxidation Inhibitors
Additive oxidizes in
preference to the oil by
seeking out free radicals
and peroxides.
Hindered Phenols,
Zinc dithiophosphates,
Aromatic Amines
40
Other Types
Additives
Bulk
Surface
Microbial
Interfacial
Chemical
Fungicide
Demulsifier
Antioxidant
Biocide
Dispersant
Detergent
Foam Inhibitor
Antistatic
Rheological
Pour Point
Depressant
VI Improver
EP/AW
Corrosion/Rust
Friction modifier
Metal deactivator
Tackifier
41
Additive
Package
Gear Oils
L-11XXFG
L-21XX
R&O, AW
R&O, EP
Compressor Oils
Vacuum Pump
Oils
L-12XX
L-12XXFG
L-X6XX
R&O
Hydraulic Oils
Multi-Purpose Oils
L-X3XX
L-X3XXFG
L-05XXFG
R&O
AW
Chain Oils
L-X4XXFG
L-15XX
CI
R&O:
AW:
EP:
T:
PPD:
CI:
42
Molykote Nomenclature
Molykote Hydraulic Oils
Molykote Air Compressor Oils
Molykote Vacuum Pump Oils
Molykote Ammonia compressor Oils
Molykote Special Purpose Oils
Molykote Gear Oils
Molykote Chain Oils
43
Load
Environment
Temperature
Speed
44
Molykote Nomenclature
L = Liquid
Molykote L-X X XX FG
L-X000 Base Oil
0 MO
1 PAO/or Blend
2 PAO
3 PAG
4 Esters
e.g. L-1246FG
PAO Base Ol
Compressor Oil
ISO VG 46
Complies with NSF H1
L-0X00 Application
1 Gear
2 Compressor
3 Hydraulic
4 Chain
5 Multi-purpose
6 Special purpose, Pumps
FG = Food Grade
(Comply with
NSF H1)
45
46
Hydraulic Applications
Fluid used to transmit
power via pressure
developed by pump
Hydraulic Oils require
Rust & Oxidation
Additives
Viscosity is dictated
by the pump type
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49
Viscosity Increase, %
Discharge 220-230F
Ambient 120-130F
Pressure 100 PSIG
120
R&O
Turbine
Diester
MO
Molykote
PAO L-1246
PAO-1
PAO-2
100
ATF
80
60
Oil oxidative
failure
40
20
0
0
250
500
750 1000 1250 1500 1750 2000 2250 2500 2750 3000
Time
50
Helical-Lobed (Screw)
Straight-Lobed (Blowers)
Rotary-Lobe
Vane
Liquid Piston
Centrifugal
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Reciprocating Compressors
L-4610 Primary Recommendation
ISO 100 blend of diester and hydro cracked mineral oil with
R&O + AW Add Pac
Why diester? Valve deposits and recompression
Limitation on temperature, pressure: Not much over 275F, <
145 psi
56
Vacuum Pumps
L-1668FG Synthetic Blend Vacuum Pump Oil
H-1 ISO 68 MO/ PAO Blend With R&O Add Pac
Can Be Used In Compressors Too
Cousin to L-1240FG
58
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Molykote L-1232FG
Molykote L-1246FG
Molykote L-1668FG
Molykote L-1232
Molykote L-1246
Molykote L-1268
Molykote L-1210
Molykote L-4611
Superior AO additive
Extra long service life
> 8,000 h @ 90C for H2
> 4,000 h @ 90C for H1
conventional mineral oils cost less, but
useful lifetime ranges from 500-1500 hr
Synthetic base oils (PAO)
Extremely low water emulsification
Can be used in Vacuum Pump applications
Suitable for rough vacuums (760 torr 1
torr) and medium vacuum application
(down to 10-3 torr)
60
61
Gear Applications
62
Gear Types
Spur
Bevel
Helical
Worm
Hypoid
63
Gear Oils
Synthetic PAOs
ISO 150, 220, 320, 460, 680
FG in all viscosities except 320 and 680
L-1115, L-1115FG, L-1122, L-1122FG, L-1132, L1146, L-1146FG, L-1168
Synthetic Extreme Pressure (EP)
ISO 100, 150, 220, 320, 460, 680
L-2110, L2115, L-2122, L-2132, L-2146, L-2168
64
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66
Chain Applications
Pin and Roller
lubrication required
Boundary,
Hydrodynamic & EHL
depending on speed
& load
67
Chain Oils
L-1468FG Freezer Chain Oil
ISO 68 PAO
Very Low Pour Point
Not Just For Freezers- PAO Can Hack Elevated Temps
Too
68
Chain Oils
L-1428 High Temp Chain Oil
Low viscosity of base oil allows good penetration into chain links
POE based
70
Molykote L-0460FG
Multipurpose MO
Molykote L-1428
POE
High temperature applications
Does not form carbon residue
as petroleum products
+
Low viscosity of base oil allows
good penetration into chain links
Unique tackifier additive
promotes adherence to metal
without thickening oil
Do not emulsify with water
71
Molykote S-1501
Molykote S-1502
Molykote S-1503
Molykote CO 220
72
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Multi-Purpose Oils
L-0532FG, L-0568, L-0510FG, L-0510
All MO Products Suitable For Many Applications Including
Compressors
All Contain R&O + AW Additive Packages
Suitable For Hydraulics, But Should Only Be Used In Lightly
Loaded Gears
L-0532FG
Primary Air-Line Lube Recommendation
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www.molykote.com
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THANK YOU
The information provided in this presentation does not constitute a contractual commitment by Dow Corning. While Dow Corning
does its best to assure that information contained in this presentation is accurate and fully up-to-date, Dow Corning does not
guarantee or warranty the accuracy or completeness of information provided in this presentation. Dow Corning reserves the right
to make improvements, corrections and/or changes to this presentation in the future.
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