H$moS> Z.

Series OSR/1/C

Code No.

amob Z.

56/1/2

narjmWu H$moS >H$mo Cma-nwpVH$m Ho$ _wI-n

>na Ad` {bIo &

Roll No.

Candidates must write the Code on the

title page of the answer-book.

H$n`m OmM H$a b| {H$ Bg Z-n _o _w{V n> 12 h &

Z-n _| Xm{hZo hmW H$s Amoa {XE JE H$moS >Z~a H$mo N>m Cma-nwpVH$m Ho$ _wI-n> na
{bI| &
H$n`m OmM H$a b| {H$ Bg Z-n _| >30 Z h &
H$n`m Z H$m Cma {bIZm ew$ H$aZo go nhbo, Z H$m H$_mH$ Ad` {bI| &
Bg Z-n H$mo nT>Zo Ho$ {bE 15 {_ZQ >H$m g_` {X`m J`m h & Z-n H$m {dVaU nydm
_| 10.15 ~Oo {H$`m OmEJm & 10.15 ~Oo go 10.30 ~Oo VH$ N>m Ho$db Z-n H$mo nT>|Jo
Ama Bg Ad{Y Ho$ XmamZ do Cma-nwpVH$m na H$moB Cma Zht {bI|Jo &

Please check that this question paper contains 12 printed pages.

Code number given on the right hand side of the question paper should be
written on the title page of the answer-book by the candidate.
Please check that this question paper contains 30 questions.
Please write down the Serial Number of the question before
attempting it.
15 minutes time has been allotted to read this question paper. The question
paper will be distributed at 10.15 a.m. From 10.15 a.m. to 10.30 a.m., the
students will read the question paper only and will not write any answer on
the answer-book during this period.

agm`Z {dkmZ (gmpVH$)

CHEMISTRY (Theory)

{ZYm[aV g_` : 3 KQ>o

A{YH$V_ AH$ : 70

Time allowed : 3 hours

56/1/2

Maximum Marks : 70
1

P.T.O.

gm_m` {ZX}e :
(i)

g^r Z A{Zdm` h &

(ii)

Z-g`m 1 go 8 VH$ A{V bKw-Cmar` Z h & `oH$ Z Ho$ {bE 1 AH$ h &

(iii)

Z-g`m 9 go 18 VH$ bKw-Cmar` Z h & `oH$ Z Ho$ {bE 2 AH$ h &

(iv)

Z-g`m 19 go 27 VH$ ^r bKw-Cmar` Z h & `oH$ Z Ho$ {bE 3 AH$ h &

(v)

Z-g`m 28 go 30 VH$ XrK-Cmar` Z h & `oH$ Z Ho$ {bE 5 AH$ h &

(vi)

Amd`H$VmZwgma bmJ Q>o~bm| H$m `moJ H$a| & H$Hw$boQ>am| Ho$ Cn`moJ H$s AZw_{V Zht h &

General Instructions :
(i)

All questions are compulsory.

(ii)

Questions number 1 to 8 are very short-answer questions and carry

1 mark each.

(iii)

Questions number 9 to 18 are short-answer questions and carry 2 marks

each.

(iv)

Questions number 19 to 27 are also short-answer questions and carry

3 marks each.

(v)

Questions number 28 to 30 are long-answer questions and carry 5 marks

each.

(vi)

Use Log Tables, if necessary. Use of calculators is not allowed.

1.

NaCl

{H$g H$ma H$m Q>mB{H$`mo_rQ>r Xmof XemVm h

What type of stoichiometric defect is shown by NaCl ?

2.

B_eZ (emulsions) H$mo n[a^m{fV H$s{OE &

Define Emulsions.
3.

XeF4 H$s

gaMZm Amao{IV H$s{OE &

Draw the structure of XeF4.

56/1/2

4.

Eobw{_{Z`_ Ho$ {ZH$fU _| {dew Eobw{_Zm

AXm H$s OmVr h ?

(Al2O3)

m H$aZo _|

CO2

mam `m ^y{_H$m
1

What role is played by CO2 in getting pure alumina (Al2O3) in the

extraction of aluminium ?
5.

2-~mo_monoQ>oZ

H$s gaMZm Amao{IV H$s{OE &

Draw the structure of 2-bromopentane.

6.

gH$_U Vd n[adVZr` AmgrH$aU AdWmE `m| XemVo h

Why do transition elements show variable oxidation states ?

7.

CH3 NH2

Ama

(CH3)3N

_| go, {H$g EH$ H$m dWZmH$ A{YH$ h

Out of CH3 NH2 and (CH3)3N, which one has higher boiling point ?
8.

{ZZ{b{IV `m{JH$ H$m

IUPAC

Zm_ {b{IE

Write the IUPAC name of the following compound :

9.

EH$ {db`Z H$s _mobaVm Ama _mobbVm _| AVa n> H$s{OE & {db`Z H$s _mobbVm _mZ
H$mo _mobaVm _mZ _| h_ H$go n[ad{VV H$a gH$Vo h ?

Differentiate between molarity and molality of a solution. How can we

change molality value of a solution into molarity value ?
10.

(b)

EH$ A{^{H$`m, A + B CnmX, Ho$ {bE doJ {Z`_, Rate = k[A]1 [B]2 go
{X`m J`m h & A{^{H$`m H$s H$mo{Q> `m h ?
W_ H$mo{Q> A{^{H$`m Ho$ {bE doJ {Z`VmH$ k H$s BH$mB {b{IE &

(a)

For a reaction, A + B Product, the rate law is given by,

(a)

Rate = k[A]1 [B]2. What is the order of the reaction ?

(b)
56/1/2

Write the unit of rate constant k for the first order reaction.
3

P.T.O.

11.

{ZZ H$_m| Ho$ nrN>o Omo {gmV {Z{hV hmoVo h CZH$m dUZ H$s{OE
(i)
A`H$m| Ho$ gmU _| PmJ bdZ H$_
(ii)
YmVwAm| H$m dmn mdWm n[aH$aU

Describe underlying principles of the following processes :

12.

(i)

Froth floatation process of concentration of ores

(ii)

Vapour phase refining of metals

{ZZ `m{JH$m| H$s gaMZmE Amao{IV H$s{OE

(i)

H2SO3

(ii)

N2O5

Draw the structures of the following compounds :

13.

(i)

H2SO3

(ii)

N2O5

{ZZ{b{IV `oH$ AdbmoH$Z Ho$ {bE Cn`w$ H$maU {b{IE

(i)

gH$_U YmVwE (Zn, Cd Ama Hg H$mo N>moS>H$a) R>mog (H$R>moa) Ama C JbZmH$
Ama dWZmH$ dmbr hmoVr h &

(ii)

gH$_U YmVwAm| H$s W_ loUr _| Am`ZZ EWpn`m (W_ Ama {Vr`) A{Z`{_V
$n go n[ad{VV hmoVr h &
AWdm

bWoZm`S> gHw$MZ `m h ? bWoZm`S> gHw$MZ H$m EH$ n[aUm_ Xr{OE &

Assign a reason for each of the following observations :
(i)

The transition metals (with the exception of Zn, Cd and Hg) are
hard and have high melting and boiling points.

(ii)

The ionisation enthalpies (first and second) in the first series of the
transition elements are found to vary irregularly.
OR

What is lanthanoid contraction ? Write a consequence of lanthanoid

contraction.
56/1/2

14.

{ZZ _| go `oH$ Ho$ {bE H$maU {b{IE :

(i)
gH$_U Vd AZwMw~H$s` JwU {XImVo h &
(ii)
Co2+ gabVm go ~b {bJS> H$s CnpW{V _| AmgrH$V hmo OmVm h &

Assign reason for each of the following :

15.

(i)

Transition elements exhibit paramagnetic behaviour.

(ii)

Co2+ is easily oxidised in the presence of a strong ligand.

byH$mog H$s CZ A{^{H$`mAm| H$m {ddaU Xr{OE {Oh| BgH$s Iwbr mIbm gaMZmAm| mam
Zht g_Pm`m Om gH$Vm h &

Enumerate the reactions of glucose which cannot be explained by its open

chain structures.
16.

{ZZ{b{IV A{^{H$`mAm| Ho$ g_rH$aU {b{IE

(i)
{d{b`gZ BWa gbofU
(ii)
H$mo~o A{^{H$`m

Write the equations involved in the following reactions :

17.

(i)

Williamson ether synthesis

(ii)

Kolbes reaction

{ZZ{b{IV Zm| Ho$ Cma Xr{OE :

(i)
{dQ>m{_Z A Ama {dQ>m{_Z C h_mao {bE `m| A`md`H$ h
(ii)
`ypbAmogmBS> Ama `ypbAmoQ>mBS> _| `m AVa hmoVm h ?

2
?

Answer the following questions :

18.

(i)

Why are vitamin A and vitamin C essential for us ?

(ii)

What is the difference between a nucleoside and a nucleotide ?

{ZZ{b{IV n[adVZm| H$mo {H$g H$ma {H$`m Om gH$Vm h

(i)
monrZ go monoZ-2-Amb
(ii)
E{Wb bmoamBS> go EWmZb

How are the following conversions carried out ?

56/1/2

(i)

Propene to Propan-2-ol

(ii)

Ethyl chloride to Ethanal

5

P.T.O.

19.

EH$ A{^{H$`m _| hmBS>moOZ noamgmBS>, H2O2 (Obr`), H2O (l) Ama O2 (g) _|
AnK{Q>V hmoVm h & A{^{H$`m H2O2 _| W_ H$mo{Q> H$s h Ama doJ {Z`VmH$
k = 1.06 103 min1 h &
(i)

H2O2

(ii)

{VXe Ho$

Ho$ EH$ {VXe Ho$

85%

15%

H$mo AnK{Q>V hmoZo _| {H$VZm g_` bJoJm

H$mo AnK{Q>V hmoZo _| {H$VZm g_` bJoJm

Hydrogen peroxide, H2O2 (aq) decomposes to H2O (l) and O2 (g) in a

reaction that is first order in H2O2 and has a rate constant
k = 1.06 103 min1.

20.

(i)

How long will it take for 15% of a sample of H2O2 to decompose ?

(ii)

How long will it take for 85% of the sample to decompose ?

5 kg

Ob Ho$ gmW Hw$N> E{WbrZ bmBH$mb, HOCH2CH2OH, AmnH$s H$ma H$s erVbZ
Umbr _| S>mbm OmVm h & `{X Ob-bmBH$mb {db`Z H$m {h_mH$ 15.0C hmo, Vmo
{db`Z H$m dWZmH$ `m hmoJm ?
(Ob Ho$ {bE Kb = 0.52 K kg mol1 Ama Kf = 1.86 K kg mol1)

Some ethylene glycol, HOCH2CH2OH, is added to your cars cooling

system along with 5 kg of water. If the freezing point of water-glycol
solution is 15.0C, what is the boiling point of the solution ?
(Kb = 0.52 K kg mol1 and Kf = 1.86 K kg mol1 for water)
21.

H$mna H$m KZd 8.95 g cm3 h & BgHo$ {H$Q>b H$s \$bH$ Ho$pV KZr` gaMZm hmoVr
h & H$mna na_mUw H$s {`m `m h ?
(na_mUw `_mZ Cu = 63.5 g mol1, NA = 6.02 1023 mol1)

The density of copper is 8.95 g cm3. It has a face centred cubic structure.
What is the radius of copper atom ?
(Atomic mass Cu = 63.5 g mol1, NA = 6.02 1023 mol1)
22.

56/1/2

{ZZ nXm| H$s n[a^mfm Xr{OE

(i)
emofU
(ii)
{Q>S>b ^md
(iii) BboQ>mo\$moao{gg

Define the following terms :

23.

(i)

Sorption

(ii)

Tyndall effect

(iii)

Electrophoresis

{ZZ H$mo H$maU XoVo hE g_PmBE :

(i)
Eo{ZbrZ \$rS>ob-H$mQ>g A{^{H$`m Zht XoVm h &
(ii)
E{WbEo_rZ Ob _| KwbZerb h naVw Eo{ZbrZ Zht &
(iii) _o{WbEo_rZ Ho$ pKb H$m _mZ Eo{ZbrZ Ho$ pKb _mZ go H$_ h &

Account for the following :

(i)
Aniline does not give Friedel-Crafts reaction.
(ii)
Ethylamine is soluble in water whereas aniline is not .
(iii) pKb of methylamine is less than that of aniline.
24.

(a)

(b)

{ZZ `w_m| _o go H$mZ-gm `m{JH$ OH g_yh YmaH$ `m{JH$ Ho$ gmW

A{^{H$`m H$aZo _| A{YH$ VoOr go A{^{H$`m H$aoJm ?
(i)

CH3Br

(ii)

(CH3)3CCl

`m

SN2

CH3I

`m CH3Cl
{ZZ A{^{H$`mAm| Ho$ CnmX {b{IE

3
(a)

(b)

56/1/2

Which compound in each of the following pairs will react faster in

SN2 reaction with OH group ?
(i)

CH3Br or CH3I

(ii)

(CH3)3CCl or CH3Cl

Write the product of the following reactions :

P.T.O.

25.

{ZZ H$mbogm| _| go `oH$ H$m AmB.`y.nr.E.gr.

(i)

[Co(NH3)5Cl]Cl2

(ii)

K3[Fe(CN)6]

(iii)

[NiCl4]2

(IUPAC) Zm_

{b{IE

AWdm
{ZZ H$mbog Am`Zm| _| go `oH$ Ho$ H$m{eH$ g_md`{d`m| H$s gaMZmE Amao{IV
H$s{OE :
[Cr(C2O4)3]3, [PtCl2(en)2]2+, [Cr(NH3)2Cl2(en)]+
Write down the IUPAC name for each of the following complexes :
(i)

[Co(NH3)5Cl]Cl2

(ii)

K3[Fe(CN)6]

(iii)

[NiCl4]2
OR

Draw the structures of optical isomers of each of the following complex

ions :
[Cr(C2O4)3]3, [PtCl2(en)2]2+, [Cr(NH3)2Cl2(en)]+
26.

{ZZ{b{IV `m h ? `oH$ H$m EH$-EH$ CXmhaU Xr{OE &

(i)

_YwaH$mar H$_H$ (drQ>oqZJ EOoQ>)

(ii)

Im n[aajH$

(iii)

{VO{dH$

What are the following ? Give one example of each.

56/1/2

(i)

Sweetening agents

(ii)

Food preservatives

(iii)

Antibiotics
8

27.

{ZZ ~hbH$m| Ho$ EH$bH$m| Ho$ Zm_ Xr{OE

(i)
{ZAmorZ
(ii)
nm{bQ>mBarZ
(iii) nm{bmonrZ

Give names of the monomers of the following polymers :

28.

(i)

Neoprene

(ii)

Polystyrene

(iii)

Polypropene

(a)

EH$ {dwV-AnKQ>` Ho$ {db`Z Ho$ {bE MmbH$Vm Ama _moba MmbH$Vm nXm| H$mo
n[a^m{fV H$s{OE & Vmn_mZ ~XbZo Ho$ gmW CZHo$ n[adVZ na {Q>nUr H$s{OE &

(b)

EH$ MmbH$Vm gob H$m _m{nV {VamoY 100 ohm Wm & n[aH${bV H$s{OE
(i) {d{e> MmbH$Vm Ama (ii) {db`Z H$s _moba MmbH$Vm &
(KCl = 74.5 g mol1 Ama gob pWamH$ = 1.25 cm1)
AWdm

(a)

(b)

{ZZ{b{IV `oH$ _| {dwV-AnKQ>Z Ho$ CnmXm| H$s mJw{$ H$s{OE

(i)

b{Q>Z_ BboQ>moS>m| Ho$ gmW

AgNO3

H$m Obr` {db`Z &

(ii)

b{Q>Z_ BboQ>moS>m| Ho$ gmW

H2SO4

H$m Obr` {db`Z &

2, 3

500C na Al2O3 H$m AnM`Z

A{^{H$`m 2 Al2O3 4 Al + O2 Ho$
3
3
1
(F = 96500 C mol )

Cg `yZV_ {d^dmVa H$m AmH$bZ H$s{OE Omo

H$aZo Ho$ {bE Amd`H$ h & AnKQ>Z
{bE {JO D$Om n[adVZ h

960 kJ &

(a)

Define the terms conductivity and molar conductivity for the

solution of an electrolyte. Comment on their variation with
temperature.

(b)

The measured resistance of a conductance cell was 100 ohms.

Calculate (i) the specific conductance and (ii) the molar
conductance of the solution.
(KCl = 74.5 g mol1 and cell constant = 1.25 cm1)
OR

56/1/2

P.T.O.

(a)

29.

Predict the products of electrolysis in each of the following :

(i)

An aqueous solution of AgNO3 with platinum electrodes.

(ii)

An aqueous solution of H2SO4 with platinum electrodes.

(b)

Estimate the minimum potential difference needed to reduce Al2O3

at 500C. The Gibbs energy change for the decomposition reaction
2
4
Al2O3
Al + O2 is 960 kJ. (F = 96500 C mol1)
3
3

(a)

{ZZ H$m dUZ H$s{OE :

(i)
EoS>mob gKZZ
(ii) H${Omamo A{^{H$`m

(b)

{ZZ `w_m| _| AVa H$aZo Ho$ {bE amgm`{ZH$ OmM H$m dUZ H$s{OE
(i)
EWZb Ama monZb
(ii) ~oOpS>hmBS> Ama EogrQ>mo\$sZmoZ
(iii) monoZ-2-AmoZ Ama monoZ-3-AmoZ
AWdm

56/1/2

(a)

{ZZ `m{JH$m| H$s gaMZmE Amao{IV H$s{OE

(i)
4-bmoamonoQ>oZ-2-AmoZ
(ii) `yQ>-2-BZ-1-Ab

(b)

{ZZ{b{IV _| CnmX {b{IE

(a)

Describe :

(i)

Aldol condensation

(ii)

Cannizzaro reaction
10

2, 3

(b)

Describe a chemical test to distinguish between

(i)

Ethanal and Propanal

(ii)
(iii)

Benzaldehyde and Acetophenone

Propan-2-one and Propan-3-one
OR

(a)

Draw the structures of the following compounds :

(i)
(ii)

30.

4-chloropentan-2-one
But-2-en-1-al

(b)

Write the product(s) in the following :

(a)

{ZZ amgm`{ZH$ g_rH$aUm| H$mo nyam H$s{OE

(b)

(i)

P4 + NaOH + H2O

(ii)

XeF4 + O2F2

{ZZ pW{V`m| H$mo Amn H$go C{MV R>hamEJo :

(i)
BZ `m{JH$m| _| Abr` gm_` {ZZ H$_ _| ~T>Vm h

PH3 < H2S < HCl

(ii)

bmoarZ Ho$ AmgmoAbm| H$s AmgrH$maH$ j_Vm H$m H$_ {ZZ h

HClO4 < HClO3 < HClO2 < HClO

(iii)

2, 3

dmn AdWm _| g\$a AZwMw~H$s` `dhma X{eV H$aVm h &

AWdm

(a)

56/1/2

dr.Eg.B.nr.Ama. (VSEPR) {gmV H$m Cn`moJ H$aVo hE {ZZ H$s g^m{dV

gaMZmAm| H$s mJw{$ H$s{OE :
(i)

N2O3

(ii)

BrF3
11

P.T.O.

(b)

nXmWm] Ho$ {ZZ g_yhm| H$mo `oH$ g_yh Ho$ AmJo {XE JE JwUY_ Ho$ H$_ _|
`dpWV H$s{OE :
(i)
NH3, PH3, AsH3, SbH3 ~T>Vo hE dWZmH$ _mZm| Ho$ H$_ _|
(ii) O, S, Se, Te G$Um_H$ {M Ho$ gmW BboQ>mZ bpY EWnr Ho$ ~T>Vo
H$_ _|
(iii) F2, Cl2, Br2, I2 Am~Y {d`moOZ EWnr Ho$ ~T>Vo H$_ _|

(a)

Complete the following chemical equations :

(b)

(i)

P4 + NaOH + H2O

(ii)

XeF4 + O2F2

How would you account for the following situations ?

(i)

The acidic strength of these compounds increases in the

following order :
PH3 < H2S < HCl

(ii)

The oxidising power of oxoacids of chlorine follows the order :

HClO4 < HClO3 < HClO2 < HClO

(iii)

In vapour state sulphur exhibits paramagnetic behaviour.

OR

(a)

(b)

56/1/2

Using VSEPR theory predict the probable structures of the

following :
(i)

N2O3

(ii)

BrF3

Arrange the following groups of substances in the order of the

property indicated against each group :
(i)

NH3, PH3, AsH3, SbH3 increasing order of boiling points.

(ii)

O, S, Se, Te increasing order of electron gain enthalpy with

negative sign.

(iii)

F2, Cl2, Br2, I2 increasing order of bond dissociation

enthalpy.

12