sodium dichromate ( N a 2 C r 2 0 , , 2 H 2 0 )is much more soluble (about 70 g per
litre); for this reason, as well as the fact that it is much cheaper, the latter is usually preferred for the preparation of 'cleaning mixture'. From time to time it is advisable to filter the sodium dichromate-sulphuric acid mixture through a little glass wool placed in the apex of a glass funnel: small particles or sludge, which are often present and may block the tips of burettes, are thus removed. A more efficient cleaning liquid is a mixture of concentrated sulphuric acid and fuming nitric acid; this may be used if the vessel is very greasy and dirty, but must be handled with extreme caution. A very effective degreasing agent, which it is claimed is much quicker-acting than 'cleaning mixture' is obtained by dissolving 100 g of potassium hydroxide in 50mL of water, and after cooling, making up to 1 litre with industrial methylated spirit.6a
3.9 TEMPERATURE STANDARD
The capacity of a glass vessel varies with the temperature, and it is therefore necessary to define the temperature at which its capacity is intended to be correct: in the UK a temperature of 20 OC has been adopted. A subsidiary standard temperature of 27 OC is accepted by the British Standards Institution, for use in tropical climates where the ambient temperature is consistently above 20 OC.The US Bureau of Standards, Washington, in compliance with the view held by some chemists that 25 OC more nearly approximates to the average laboratory temperature in the United States, will calibrate glass volumetric apparatus marked either 20 OC or 25 OC. Taking the coefficient of cubical expansion of soda glass as about 0.000 030 and of borosilicate glass about 0.000010 per 1 OC,Part A of Table 3.1 gives the correction to be added when the sign is +, or subtracted when the sign is -, to or from the capacity of a 1000 mL flask correct at 20 OC in order to obtain the capacity at other temperatures. In the use of graduated glassware for measurement of the volume of liquids, the expansion of the liquid must also be taken into consideration if temperature corrections are to be made. Part B of Table 3.1 gives the corrections to be added or subtracted in order to obtain the volume occupied at 20 OC by a volume of water which at the tabulated temperature is contained in an accurate 1000 mL flask having a standard temperature of 20 OC.It will be seen that the allowance for the expansion of water is considerably greater than that for the expansion Table 3.1 Temperature corrections for a 1L graduated flask Temperature (OC)