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Test - 6_Code - C_(Paper - II) (Answers & Hints)

All India Aakash Test Series for JEE (Advanced)-2015

All India Aakash Test Series for JEE (Advanced)-2015


Click here for Code-D Solution

Test Date : 01-02-2015

TEST - 6 (Paper-II) - Code-C

ANSWERS

PHYSICS

CHEMISTRY

MATHEMATICS

1.

(B)

21.

(C)

41.

(B)

2.

(B)

22.

(C)

42.

(B)

3.

(C)

23.

(B)

43.

(A)

4.

(B)

24.

(C)

44.

(C)

5.

(B)

25.

(B)

45.

(A)

6.

(D)

26.

(C)

46.

(B)

7.

(D)

27.

(A, B, C, D)

47.

(A, B, C, D)

8.

(B, D)

28.

(A, B, C, D)

48.

(A, C, D)

9.

(A, B, D)

29.

(A, B)

49.

(A, C)

10.

(C, D)

30.

(B, D)

50.

(A, C)

11.

(A, D)

31.

(A, C)

51.

(C, D)

12.

(D)

32.

(C)

52.

(A)

13.

(A)

33.

(C)

53.

(D)

14.

(B)

34.

(C)

54.

(A)

15.

(C)

35.

(A)

55.

(B)

16.

(A)

36.

(C)

56.

(B)

17.

(A)

37.

(B)

57.

(D)

18.

(6)

38.

(6)

58.

(2)

19.

(4)

39.

(5)

59.

(4)

20.

(3)

40.

(4)

60.

(9)

1/7

All India Aakash Test Series for JEE (Advanced)-2015

Test - 6_Code - C_(Paper - II) (Answers & Hints)

ANSWERS & HINTS


PART - I (PHYSICS)
1.

Answer (B)

2.

Answer (B)

3.

Answer (C)

13. Answer (A)

qEr

1
mv 2
2

(i)

2qEr
m

N2 N1 FE
r(1 cos) = x

...(i)

rsin = y

...(ii)

qB y 2
x

Momentum =

2 x

Answer (B)

5.

Answer (B)

(ii)

mv 2
FB 0
r

(iii)

2 qB 2 r
9 m

14. Answer (B)

From (i) & (ii)

4.

mv 2
r

N2 FB FE N1

i = 0.5 Wb
f = 2 Wb
= 1.5 Wb
15. Answer (C)
16. Answer (A)

6.

r dB
F = eE = e
2 dt

17. Answer (A)

Answer (D)

18. Answer (6)


When i is max V2C = V3C

At = 0
z=

Common potential =

i=0

C1V1 C2V2
C1 C2

7.

Answer (D)

8.

Answer (B, D)

7
3C V0 2C V0
2
=
3C 2C

9.

Answer (A, B, D)

= 2V0

10. Answer (C, D)

11. Answer (A, D)

19. Answer (4)

q
vBl
C

i = avBl

mg ilB = ma
mg avl2B2 = ma
a

mg
(m vl 2B 2 )

12. Answer (D)


2/7

1
(3C ) 4V02 6CV02
2

constant

q
vBl
C

(i)

i
aBl
C

(ii)

Now, kx ilB = ma

(iii)

kx CaB2l2 = ma

[Given]

Test - 6_Code - C_(Paper - II) (Answers & Hints)

kx = (CB2l2 + m)a

20. Answer (3)

a 2 2
x
CB l m
T 2

Time =

All India Aakash Test Series for JEE (Advanced)-2015

0
i

cos30 cos 60
B = 12
4 l 3
2

m B 2 l 2C
k

T
4

B=

0
i 3
l

3 1

PART - II (CHEMISTRY)
21. Answer (C)

Kh

From I to II to III it is a clockwise movement hence,

configuration at C is R.

Kw
Ka

Here Ka is the ionization constant of parent acid and

III

II

O
O

is the weakest acid so, its Kh is

OH

OH

From I to II to III it is a anticlockwise movement


hence, configuration at C* is S.
26. Answer (C)

highest.

Molecule as per Newman projection is

22. Answer (C)


Nitro group stabilizes phenoxide ion formed and
steric inhibition of resonance of NO2 stop stablization
of phenoxide ion by resonance. So, p-nitrophenol is
most acidic.

CH3

23. Answer (B)


Bulky groups at equitorial positions brings most
stable conformer.
24. Answer (C)

H3C

Cis(1, 4) dimethylcyclohexane
is crystalizes as ionic solid by keeping
negative terminal at five membered ring and positive
terminal on seven membered ring in order to maintain
aromaticity.
25. Answer (B)

27. Answer (A, B, C, D)




HCl D2O 
 HOD DCl
In solution available electrophiles are H+ and D+. So,
probable products are
OD

II

III

OH
O
I

IV

OH

OD

OD
D

OD
D

28. Answer (A, B, C, D)

3/7

All India Aakash Test Series for JEE (Advanced)-2015


29. Answer (A, B)

Test - 6_Code - C_(Paper - II) (Answers & Hints)


Cold alk.

(R)

Claisen rearrangement mechanism is completely


concerted hence, no crossover product formation is
observed.

KMnO4

30. Answer (B, D)

HO

LiAlH4 is not able to reduce unconjugated

OH

OH

C .

OH

OH

31. Answer (A, C)

DBE = 1

In case of t-butylbenzene because of the stability of


NO 2 substitute t-butyl group.

, electrophile

OH

mCPBA

(S)

32. Answer (C)


33. Answer (C)

Basic strength of amines is also dependent on steric


hinderence of the group bonded to N and hydration.

O
DBE = 4

34. Answer (C)

Cl

Cl

D
NH2

H
O

37. Answer (B)

O
D
O

In aqueous medium down the group nucleophilicity


increases, across the period nucleophilicity
increases. Anions are better nucleophile than neutral
ones and nucleophilicity decreases as steric
hinderence increases.
38. Answer (6)

35. Answer (A)

Cl

Cl

Cl

Cl

36. Answer (C)

Cl

Cl

O
(P)

O
Cl

HO

Cl

(i) LiAlH4
(ii) H2O

Cl

Cl

OH

Cl
H

OH

HO

Cl

DBE = 2
O

(Q)

Cl

Six sterioisomers are formed.


C

39. Answer (5)

NaBH4

HO

H2O

(1), (3), (5), (7) and (9) show Walden inversion in SN2.
40. Answer (4)

OH

HO
DBE = 5

4/7

Hydrogen from phenolic group, COOH, SH and


O

NH

are removed from NaOH.

Test - 6_Code - C_(Paper - II) (Answers & Hints)

All India Aakash Test Series for JEE (Advanced)-2015

PART - III (MATHEMATICS)


41. Answer (B)

44. Answer (C)

Length of sub-normal = length of sub-tangent

If

dy
1
dx
dy
1 , equation of the tangent y 4 = x 3
dx

y x = 1, area of OAB =
If

1
1
1 1
2
2

= exlog(ex + 1) log(1 + ex) + x + C

45. Answer (A)

42. Answer (B)


v = x3 and the percent error in measuring edge =

dx
100 K
x

5
4

dv
100
v

The percent error in measuring volume =


dv
3x 2
dx

2 cos x dx
4

Put x

dv = 3x dx
2

eex 1dx

x
x
= e 1 log e 1 x C

1
49
y + x = 7, area = 7 7
2
2

x
x
= e log e 1

x
x
x
= e log e 1 log e 1 C

dy
1 , equation of the tangent is y 4 = x + 3
dx

Now,

e x e x

ex 1 dx

I e x log e x 1

dv 3 x 2dx 3dx

v
x
x3

dv
3dx
100
100 3K
v
x

Adding

t
4

2 cos t
et 1

2 cos( t )
et 1

43. Answer (A)

2I 2

x3

f(x) = (x 2)(x 3)
= (x 2)(x 3)

cos t 0 I = 0

x<3

Graph of f(x) is

46. Answer (B)


0x<1

y = [x + 1] = 1
1

So required area =

5
2

Clearly f(x) is increasing in , 3,


2

ydy

3
2 2
y
=
3
0

2
sq. unit
3

5/7

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47. Answer (A, B, C, D)
Here

Test - 6_Code - C_(Paper - II) (Answers & Hints)


49. Answer (A, C)

dy y

dx a

y
a constant
Sub-tangent =
dy
dx


ex

dx
3
x2 1 2

( x 1) 2

dy
y y
Sub-normal = y
y
dx
a
a

This meets the x-axis at a point given by

x = x1 a

3
2

y
y1 1 [ x x1]
a

x2 1

2
x 1
x
ex

( x 2 1) 2
x2 1

y
Equation of tangent at (x1, y1) is y y1 1 ( x x1 )
a

x2 x 1 x
e dx

f ( x ) f ( x ) dx

x
e f ( x ) c

The curve meets the y-axis at (0, C)

c
dy

dx
a

(0, c )

dx
3
2

where f ( x )

ex
2

x 1

1
2

x 1

f(x) =

1
2

x 1

50. Answer (A, C)


Let f(x) =

Equation of normal y c

1
( x 0)
c
a

3 x3

Clearly f(x) is increasing in [1, 3]


The least value of function m = f(1) =

ax + cy = c2

& maximum value M = f(3) =


3

48. Answer (A, C, D)


Therefore, (3 1) 2

Graph of f(x)

3 13 2

3 33 30

3 x 2 dx (3 1) 30

So 4

3 x 3 dx 2 30

51. Answer (C, D)

Since the curve y ax 2 bx passes through the


point (1, 2)

When n is even

2=a+b

...(i)

By observation the curve also passes through (0, 0)


1
4

2a
b
8 16 8
A ax 2 bx dx 8
3
2

When n is odd

2a
b 1
3

Solving (i) & (ii) we get a = 3, b = 1


6/7

...(ii)

Test - 6_Code - C_(Paper - II) (Answers & Hints)

All India Aakash Test Series for JEE (Advanced)-2015

52. Answer (A)

56. Answer (B)

h(x) = f(x) a((f(x))2 + a(f(x))3)

57. Answer (D)

h(x) = f(x) 2a f(x) f(x) + 3a(f(x))2 f(x)

58. Answer (2)

h(x) = f(x) [3a[f(x)]2 2af(x) + 1]

I xf (2 x )dx , Put 2x = t

Now h(x) increases if f(x) increases and

3a(f(x)) 2af(x) + 1 > 0 x R


2

3a > 0 & 4a2 12a 0

dx

a > 0 & a [0, 3]

dt
2

a [0, 3]

So I

53. Answer (D)

1
tf (t )dt
4

h(x) is non-monotonic functions if


3a(f(x)) 2a f(x) + 1 changes sign for which D 0 or
4a2 12a 0
2

Apply by parts to solve the integral.


59. Answer (4)

a (, 0] [3, )
54. Answer (A)
Put 1 + x = t6
To get I 6

t3
dt
t 1

t 3 1 1
dt
t 1

= 6

2
= 6 t t 1
1

1
dt
t 1

6 x 8y

x2
x2

(1 t 2 )2t (1 t 2 )2t
8t
dx 2
dt
2 2
(1 t )

1 t 2

dt

...(i)

So
3a2 4b2 = 72

...(ii)

Solving (i) & (ii) we get a = 6


& b = 3

dt
dt
2

2
1 t 2
1 t

1 t
2 tan1 t C
1 t

a
2
b

Also (a, b) lies on the curve

t2
1 1 t 2
8t
4
dt
t

dt
=

2 1 t 2 (1 t 2 )2
1 t 2 1 t 2

dy
0
dx

3a
3
dy

2
dx (a,b ) 4b

1 t
x2 1

by C & D x 2

x 2 t2
1 t 2

Differentiating the curve we get

log

60. Answer (9)

55. Answer (B)

y3
8 4
A xdy (2y y )dy 42
4
3
3 3

0
0
0

= 2 1 x 2 3 1 x 3 6(1 x ) 6 6ln (1 x ) 6 1 c

2
Let t

Out of (6, 3) & (6, 3), (6, 3) is closer to line


where t

So a = 6 & b = 3

x2
x2

ba=9


7/7

Test - 6_Code - D_(Paper - II) (Answers & Hints)

All India Aakash Test Series for JEE (Advanced)-2015

All India Aakash Test Series for JEE (Advanced)-2015


Click here Code-C Solution

Test Date : 01-02-2015

TEST - 6 (Paper-II) - Code-D

ANSWERS

PHYSICS

CHEMISTRY

MATHEMATICS

1.

(D)

21.

(C)

41.

(B)

2.

(B)

22.

(B)

42.

(A)

3.

(B)

23.

(C)

43.

(C)

4.

(C)

24.

(B)

44.

(A)

5.

(B)

25.

(C)

45.

(B)

6.

(B)

26.

(C)

46.

(B)

7.

(A, D)

27.

(A, C)

47.

(C, D)

8.

(C, D)

28.

(B, D)

48.

(A, C)

9.

(A, B, D)

29.

(A, B)

49.

(A, C)

10.

(B, D)

30.

(A, B, C, D)

50.

(A, C, D)

11.

(D)

31.

(A, B, C, D)

51.

(A, B, C, D)

12.

(B)

32.

(C)

52.

(A)

13.

(C)

33.

(A)

53.

(B)

14.

(D)

34.

(C)

54.

(A)

15.

(A)

35.

(C)

55.

(D)

16.

(A)

36.

(B)

56.

(D)

17.

(A)

37.

(C)

57.

(B)

18.

(3)

38.

(4)

58.

(9)

19.

(4)

39.

(5)

59.

(4)

20.

(6)

40.

(6)

60.

(2)

1/7

All India Aakash Test Series for JEE (Advanced)-2015

Test - 6_Code - D_(Paper - II) (Answers & Hints)

ANSWERS & HINTS


PART - I (PHYSICS)
1.

Answer (D)

13. Answer (C)

At = 0

14. Answer (D)

z=

15. Answer (A)

i=0
2.

qEr

Answer (B)
F = eE = e

3.

Answer (B)

4.

Answer (C)

r dB
2 dt

1
mv 2
2

(i)

2qEr
m

mv 2
r

(ii)

mv 2
FB 0
r

(iii)

N2 FB FE N1

N2 N1 FE

2 qB 2 r
9 m

16. Answer (A)


r(1 cos) = x

...(i)

rsin = y

...(ii)

17. Answer (A)


18. Answer (3)

From (i) & (ii)


Momentum =
5.

Answer (B)

6.

Answer (B)

7.

Answer (A, D)

qB y 2
x

2 x

B=

q
vBl
C

i = avBl

mg ilB = ma
mg avl2B2 = ma
a

mg
(m vl 2B 2 )

0
i

cos30 cos 60
B = 12
4 l 3
2

constant

0
i 3
l

3 1

19. Answer (4)


q
vBl
C

(i)

i
aBl
C

(ii)

Now, kx ilB = ma

8.

Answer (C, D)

kx CaB l = ma

9.

Answer (A, B, D)

kx = (CB2l2 + m)a

10. Answer (B, D)


11. Answer (D)

22

a 2 2
x
CB l m

12. Answer (B)


i = 0.5 Wb

T 2

f = 2 Wb
= 1.5 Wb
2/7

Time =

m B 2 l 2C
k

T
4

(iii)

[Given]

Test - 6_Code - D_(Paper - II) (Answers & Hints)

All India Aakash Test Series for JEE (Advanced)-2015

7
3C V0 2C V0
2
=
3C 2C

20. Answer (6)


When i is max V2C = V3C

= 2V0
C1V1 C2V2
Common potential =
C1 C2

1
(3C ) 4V02 6CV02
2

PART - II (CHEMISTRY)
21. Answer (C)

24. Answer (B)

Molecule as per Newman projection is

CH3

Bulky groups at equitorial positions brings most


stable conformer.

25. Answer (C)


Nitro group stabilizes phenoxide ion formed and
steric inhibition of resonance of NO2 stop stablization
of phenoxide ion by resonance. So, p-nitrophenol is
most acidic.

H3C

26. Answer (C)

Cis(1, 4) dimethylcyclohexane

Kh

22. Answer (B)

II

Kw
Ka

Here Ka is the ionization constant of parent acid and

III

OH
O
I

OH

is the weakest acid so, its Kh is

IV

From I to II to III it is a clockwise movement hence,

configuration at C is R.

H
III

OH

highest.
27. Answer (A, C)

II

OH

From I to II to III it is a anticlockwise movement


hence, configuration at C* is S.
23. Answer (C)

In case of t-butylbenzene because of the stability of


, electrophile

NO 2 substitute t-butyl group.

28. Answer (B, D)


LiAlH4 is not able to reduce unconjugated

C .

29. Answer (A, B)


is crystalizes as ionic solid by keeping
negative terminal at five membered ring and positive
terminal on seven membered ring in order to maintain
aromaticity.

Claisen rearrangement mechanism is completely


concerted hence, no crossover product formation is
observed.
30. Answer (A, B, C, D)
3/7

All India Aakash Test Series for JEE (Advanced)-2015

Test - 6_Code - D_(Paper - II) (Answers & Hints)

31. Answer (A, B, C, D)

OD
H

HO

In solution available electrophiles are H+ and D+. So,


probable products are
OD

OH



HCl D2O 
 HOD DCl

DBE = 5

OD

Cold alk.

(R)

KMnO4

OD
D

HO

OH

OH

OH

32. Answer (C)

Cl

D
NH

H
O

OH

OH

Cl

DBE = 1

mCPBA

(S)

D
O

33. Answer (A)

O
DBE = 4

34. Answer (C)


35. Answer (C)
Basic strength of amines is also dependent on steric
hinderence of the group bonded to N and hydration.

38. Answer (4)


Hydrogen from phenolic group, COOH, SH and
O

36. Answer (B)


In aqueous medium down the group nucleophilicity
increases, across the period nucleophilicity
increases. Anions are better nucleophile than neutral
ones and nucleophilicity decreases as steric
hinderence increases.
37. Answer (C)

O
(P)

O
C

NH

are removed from NaOH.

39. Answer (5)


(1), (3), (5), (7) and (9) show Walden inversion in SN2.
40. Answer (6)

O
Cl

HO

(i) LiAlH4

Cl

Cl

Cl

Cl

Cl

Cl

(ii) H2O

Cl

OH
OH

HO

Cl
H

Cl

H
Cl

DBE = 2
O

(Q)

4/7

HO

H
Cl

NaBH4
H2O

Cl

Six sterioisomers are formed.

Test - 6_Code - D_(Paper - II) (Answers & Hints)

All India Aakash Test Series for JEE (Advanced)-2015

PART - III (MATHEMATICS)


41. Answer (B)

44. Answer (A)

0x<1

x3

f(x) = (x 2)(x 3)
= (x 2)(x 3)

y = [x + 1] = 1

Graph of f(x) is

So required area =

x<3

ydy

3
2 2
y
=
3
0
=

2
sq. unit
3

2 cos x dx
4

Put x

v = x3 and the percent error in measuring edge =

dx
100 K
x

t
4

The percent error in measuring volume =


Now,

2 cos( t )

dv = 3x2dx

et 1

Adding

2I 2

cos t 0 I = 0

dv 3 x 2dx 3dx

v
x
x3

dv
3dx
100
100 3K
v
x

46. Answer (B)

43. Answer (C)

Length of sub-normal = length of sub-tangent

e x e x

ex 1 dx

I e x log e x 1

dy
1
dx

eex 1dx

If

x
x
x
= e log e 1 log e 1 C

y x = 1, area of OAB =

= exlog(ex + 1) log(1 + ex) + x + C

If

x
x
= e log e 1

dv
100
v

dv
3x 2
dx

et 1

45. Answer (B)

2 cos t

5
2

Clearly f(x) is increasing in , 3,


2

42. Answer (A)


5
4

x
x
= e 1 log e 1 x C

dy
1 , equation of the tangent y 4 = x 3
dx

1
1
1 1
2
2

dy
1 , equation of the tangent is y 4 = x + 3
dx

y + x = 7, area =

1
49
77
2
2

5/7

All India Aakash Test Series for JEE (Advanced)-2015


47. Answer (C, D)

Test - 6_Code - D_(Paper - II) (Answers & Hints)


50. Answer (A, C, D)

Since the curve y


point (1, 2)

1
2
ax

Graph of f(x)

bx passes through the

2=a+b

...(i)

By observation the curve also passes through (0, 0)


1

2a
b
2

8 16 8
A ax bx dx 8
3
2

2a
b 1
3

When n is even

...(ii)

Solving (i) & (ii) we get a = 3, b = 1


48. Answer (A, C)
Let f(x) =

3 x3

When n is odd

Clearly f(x) is increasing in [1, 3]


The least value of function m = f(1) =
& maximum value M = f(3) =
3

Therefore, (3 1) 2

3 13 2

3 33 30

3 x 2 dx (3 1) 30

51. Answer (A, B, C, D)


Here

dy y

dx a

So 4

Sub-tangent =

3 x dx 2 30

y
a constant
dy
dx

49. Answer (A, C)


I

x2 x 1 x
e dx

x2 1

3
2


ex

dx
3
x2 1 2

( x 1) 2

dy
y y2
y
dx
a
a

Equation of tangent at (x1, y1) is y y1

2
x 1
x
ex

( x 2 1) 2
x2 1

f ( x ) f ( x ) dx

x
e f ( x ) c

6/7

Sub-normal = y

dx
3
2

where f ( x )

ex
x2 1

This meets the x-axis at a point given by


y1

y1
[ x x1]
a

x = x1 a
The curve meets the y-axis at (0, C)

c
dy

dx (0, c ) a

1
2

x 1

f(x) =

Equation of normal y c
1
2

x 1

ax + cy = c2

1
( x 0)
c
a

y1
( x x1 )
a

Test - 6_Code - D_(Paper - II) (Answers & Hints)

All India Aakash Test Series for JEE (Advanced)-2015

52. Answer (A)

56. Answer (D)

Put 1 + x = t6
To get I 6

57. Answer (B)

t3
dt
t 1

t 3 1 1
dt
t 1

= 6

58. Answer (9)


Differentiating the curve we get

2
= 6 t t 1
1
2

6 x 8y

1
dt
t 1

1
3

= 2 1 x 3 1 x 6(1

3a
3
dy

2
dx (a,b ) 4b

1
6
x)

6ln (1

1
6
x)

1 c

53. Answer (B)


2
Let t

dy
0
dx

a
2
b

...(i)

Also (a, b) lies on the curve

x2
x2

So
3a2 4b2 = 72

1 t 2
x2 1

by C & D x 2

2
x2 t
1 t 2

Solving (i) & (ii) we get a = 6


& b = 3

(1 t 2 )2t (1 t 2 )2t
8t
dx 2
dt
2 2
(1 t )

1 t 2

Out of (6, 3) & (6, 3), (6, 3) is closer to line

dt

So a = 6 & b = 3
ba=9

t2
1 1 t 2
8t
4
dt

t
dt

2 1 t 2 (1 t 2 )2
1 t 2 1 t 2

...(ii)

59. Answer (4)

dt
dt
2

1 t 2 1 t 2

log

1 t
2 tan1 t C
1 t

where t

x2
x2

54. Answer (A)


2

y3
8 4
A xdy (2y y )dy 42
4
3
3 3

0
0
0

h(x) = f(x) a((f(x))2 + a(f(x))3)

h(x) = f(x) 2a f(x) f(x) + 3a(f(x))2 f(x)


h(x) = f(x) [3a[f(x)]2 2af(x) + 1]

60. Answer (2)

Now h(x) increases if f(x) increases and

3a(f(x))2 2af(x) + 1 > 0 x R

I xf (2 x )dx , Put 2x = t

3a > 0 & 4a2 12a 0

a > 0 & a [0, 3]


a [0, 3]

dx

55. Answer (D)

dt
2
2

h(x) is non-monotonic functions if

So I

3a(f(x))2 2a f(x) + 1 changes sign for which D 0 or


4a2 12a 0

1
tf (t )dt
4

a (, 0] [3, )

Apply by parts to solve the integral.


7/7

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