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1
FIITJEE
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AIITS-HCT-VIII (Paper-2)-PCM(S)-JEE(Advanced)/15
JEE(Advanced), 2015
ANSWERS, HINTS & SOLUTIONS
HALF COURSE TEST VIII
(Paper-2)
Q. No.
PHYSICS
CHEMISTRY
MATHEMATICCS
1.
2.
3.
4.
5.
A, C
A, B, C
6.
B, C
A, C, D
A, B, C
7.
A, B, C
A, B, C
A, C, D
8.
A, C
A, B, C
B, C
9.
B, C
A, B, C
A, D
1.
(A) (t)
(B) (q)
(C) (q)
(D) (p)
(A) (q, r, t)
(B) (p, r)
(C) (p, r, s, t)
(D) (p, r)
(A) (p, q, r, s)
(B) (q)
(C) (r)
(D) (p)
(A) (p, q, r, s, t)
(B) (p, q, r, s, t)
(C) (p, q, r, s, t)
(D) (r)
(A) (p, q)
(B) (p, q, s)
(C) (p, q, s)
(D) (q, r, s, t)
(A) (r)
(B) (s)
(C) (q)
(D) (p)
1.
2.
3.
4.
5.
6.
7.
8.
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website: www.fiitjee.com
2
Physics
PART I
SECTION A
1.
2.
4.
5.
6.
8K
= 4 0
m/2
GM e m GM e m GM e m
R
Re
3R e
Re e
2
GM e
GM e m
1
1
.
E 2 mv 02 m.
R
2
2
3R e
R e
2
(C)
E1
3.
K
, '
m
For vertical equilibrium

T = weight upthrust
L
3
T 2LA g (2L x)Ag Ag x

2
4
where is the density of water

for rotational equilibrium about O
L
2L x
(2L x)Ag L
cos Ag x L cos
2
2
x=L
T
uptrust
(2Lx)/2
O
weight
If v be the velocity at mean position in two cases then

1
1
m
mv 2 kA 12 and T1 T2 2
2
2
k
A1 = A 2
Buoyant forces on both the spheres will be same because volume of both the spheres is same
and weight of the hollow sphere is less. If A and a are the accelerations of solid and hollow
spheres respectively, then A > a.
P = (4r2)T4
dT 3T 4
R
dt s
SECTION C
1.
At point P slope is tan 150

d
1
tan 150
dT
3
PM
d
PM
Since
RT
dT
RT 2
3
3.
V2
4ms 2
R
Mg
Mg N = 10 N 1.
V2
4
R
N = 6 Newtons
4.
K
M
T 2
M
K
T1 2
M1M2
K(M1 M2 )
T2 2
M2
K
T2 2
M2
K
M1 M2 T2
M M2 1 M2
9 1
M1
M1
M1
T1
M2
8
M1
5
= 120
K = 2 / 3
V 180 36X
K
X=5
6.
While floating net force = zero

Increase in buoyancy force = increase in weight
V
g xg
2
V
x
2
7.
tan
8.
m
15.92 7.96 6
7
10 7.96 10 Newton
Mg
1 10
2m
N
N
Y
8 1011 2
3
2
7
3.14(10 m) 7.96 10 m
m
5
5ms
10t
Jeep
10t
Vrel
Vrel 5 1 4t 2
sin
5 1 4t
Vrel2
1
1 4t
25
5
(1 4t 2 )3 /2 (17)3/ 2
aN
10
2
t = 2 seconds.
R
gsin aN
10
1 4t 2
1 4t 2 17
4
Chemistry
PART II
SECTION A
3.
(i) use PV = nRT

w
PV = RT
m
(ii) due to hydrogen bonding aNH3 aCO2
(iii) mean free path ()
1
2
3
kT.
2
(iv) Average K.E per molecule =

5.
(A) Aniline does not undergo Fridel Craft reaction due to lone pair on N-atom which directly
attacks on AlCl3.
(B) formation of carbocation at bridge head position is not favoured.
(C) CHCl3 alc. KOH :CCl2 (dichlorocarbene)
Cl
Cl
C
: CCl2
Cl
Cl
(D) Three times protonation followed by ring expansion gives benzene.

6.
In the option (b), the H atom is linked to an sp2 hybridised C atom.
8.
r = K [A]m [B]n
on calculation, m = 2, n = 1 & K = 2.66 108 mol-2 l2 sec-1 at 300 K
so, K will be > 2.66 108 at 320 K.
Hence, (A, B, C)
SECTION C
The PV diagram for the given changes is as:
(P1, 300 K)
(P1, T2)
P (in atm)
1.
20
40
(P2, 300 K)
V1
V (in litres)
for isobaric process AB,
5
V1 V2
(from Charles law)

T1 T2
20
40
,
300 T2
T2 = 600 K
wt = wAB + wBC
Now, wAB = nRdT (Isobaric process)
= 2 2 (600 300) = 1200 cal.
wBC = for adiabatic process
w = n CV T
3
= 2
R (600 300)
2
= 1800 Cal
wT = 1200 1800 = 3000 Cal = 3 kcal.
2.
H2 O
Mg2 C3
Mg(OH)2 H3C
(i) Na
H
(ii) CH3 CH2 Cl
H3C
CH2
CH3
(A)
Ni/H2
H
C
C+ C
(Enantiomeric)
Cl
+
C
Cl / h
C
CH3
monochlorination
CH2
CH2
CH3
(B)
Cl
C
CH2
Cl
3.
30 ml of N/50 HCl = 30 ml of N/50 Mg(HCO3)2

= 30 ml of N/50 CaCO3 = 100 ml of tap water
E N V
mass of CaCO3 in 100 ml tap water =
1000
50 30
=
0.03 g
50 1000
Hardness = 300 ppm
X=3
4.
diglyme
NaBH4 I2
B 2H6 H2 2NaI
solution
Cl2
B 2H6 2NH3 B2H6 .2NH3

B3N3H6
B3N3H4 Cl2
adduct
dichloro derivatives
So, dichloro derivatives of (Y) = 4
6
Mathematics
PART III
SECTION A
1.
Let the equation of the line L be y 2 = m(x 8), m < 0

2
P 8 , 0 , Q = (0, 2 8m)
m
2
OP + OQ = 8 2 8m 18
m
2.
Let centre C = (a, 0)

COP = 45
OP = 2 2 CP
OC = 4
The point on the circle with greatest abscissa is B
= OB = 4 2 2
3.
y = mx 2am am3, y = mx + 2b +
O
P
(2, 2)
b
m2
b
2am am3 0
m2
am5 + 2am3 + 2bm2 + b = 0
Maximum 5 normal
For common normal, 2b
4.
Equation of tangent y mx a 2m2 b 2

Equation of a perpendicular from centre (0, 0) on the tangent is y
1
x
m
x
x2
Required locus y x a2 2 b2
y
y
5.
Pair of tangents SS = T2
2 a2 1
2 h2 ab
=
ab
a2 2
tan < 0
tan
2 a2 1
a2 2
a 2, 1 1, 2
6.
2s(2s 2a) = xbc

4s s a
A
x
= 4cos2
bc
2
x (0, 4)
7.
x + x + 1 = ax + 1 and 1 x + x + 1 1
a<1
7
8.
cos4 sin4 = cos2 sin2 = cos 2

2
2
(2b) 4b = (4) 4 2
b = 1, 2
9.
Put x = 1
2 12
(2 + 3c + c ) = 0 (as the sum of coefficients vanishes)
2
c + 3c + 2 = 0
c = 1, 2
SECTION B
1.
2.
1
(A) Can take any value except , 3
3
A B C sec A sec B sec C
(C) Centroid of ABC is
,
3
3
sec A secB sec C

A BC
sec
3
3
sec A sec B sec C

2 Least value of sec A = 6
3
2sin 20 cos 20
(D)
4
1
sin20 cos 20
2
C
y = sec x
B
A
R = 15
1
18 24
r
= 2
=6
18 24 30
s
2
Circum-centre = (9, 12), orthocentre = (0, 0), in-centre = (6, 6), centroid = (6, 8)
SECTION C
1.
x2 + y2 12x 2y + 28 = 0
C = (6, 1), r = 3
|z0 + 5 i|min = 8
2.
|z 1| + |z 2| + |z 3| |3z 6| = 3|z 2| = 3|2ei 2| = 12
3.
k=2
n n 1
29
2
10
n(2a + n 1) = 2
Which is only possible for n = 1
a = 512
na
8
11!
6! 5!
Teachers are at remaining places in 12P3 ways
11!
12 P3
5! 6!
4.
6 boys and 5 girls in
5.
b ac
b3 abc
b3 4
b 41/3
[b] = 1
6.
6 cot = cot( ) + cot( + ) =
sin2
sin sin
3cos
2sin cos
sin
cot 2 cos 2
4 sin2 = 6 sin2
2 sin2
3
sin2
7.
x=y=z=1
2x + 3y + 4z = 9
8.
2zz 2 | z 3 || z 3 | 82
|z + 3| + |z 3| = 10
|z|max = 5

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For vertical equilibrium

T 2LA g (2L x)Ag Ag x

where is the density of water

If v be the velocity at mean position in two cases then

At point P slope is tan 150

While floating net force = zero

(i) use PV = nRT

(iv) Average K.E per molecule =

(D) Three times protonation followed by ring expansion gives benzene.

In the option (b), the H atom is linked to an sp2 hybridised C atom.

for isobaric process AB,

(from Charles law)

30 ml of N/50 HCl = 30 ml of N/50 Mg(HCO3)2

B 2H6 2NH3 B2H6 .2NH3

So, dichloro derivatives of (Y) = 4

Let the equation of the line L be y 2 = m(x 8), m < 0

Let centre C = (a, 0)

For common normal, 2b

Equation of tangent y mx a 2m2 b 2

2s(2s 2a) = xbc

cos4 sin4 = cos2 sin2 = cos 2

sec A secB sec C

sec A sec B sec C

|z 1| + |z 2| + |z 3| |3z 6| = 3|z 2| = 3|2ei 2| = 12

6 boys and 5 girls in

6 cot = cot( ) + cot( + ) =

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