02-08-14 JR - IPLCO JEE-MAIN (2013) WTM-13 Q'PAPER

Sri Chaitanya IIT Academy., India.
A right Choice for the Real Aspirant

Central Office , Madhapur Hyderabad
Jr.IPLCO
Time : 3:00
JEE MAIN
WTM-13
Dt:02-08-14
Marks : 360
IMPORTANT INSTRUCTIONS:
1. There are three parts in the question paper A, B, C consisting of Physics,
Chemistry and Maths having 30 questions in each part of equal weightage.
Each question is allotted 4 (four) marks for each correct response.
2. Candidates will be awarded marks as stated above in instruction for correct
response of each question. 1/4 (one fourth) marks will be deducted for
indicating incorrect response of each question. No deduction from the total
score will be made if no response is indicated for an item in the answer sheet.
3. There is only one correct response for each question. Filling up more than one
response in each question will be treated as wrong response and marks for
wrong response will be deducted accordingly as per instruction
02-08-14_Jr.IPLCO_JEE-MAIN_WTM-13_SYLLABUS
Physics:
Centre of Mass & Conservation of linear Momentum(Excluding variable mass)(100%)
Chemistry:
Structure and Nomenclature : Hybridisation of carbon; Sigma and pi-bonds; Shapes of
simple organic molecules, Trivial and IUPAC names of Organic compounds,
Sri Chaitanya IIT Academy

02-08-14_Jr.IPLCO_(JEE-Main 2013) WTM-13
Nomenclature of Hydrocarbons, Nomenclauture of mono and bi-functional organic

compounds (Note to paper setter: No questions of aromatic compounds to be asked)
(100 %)
Mathematics:
types of functions ( one-one, onto,many-one, into, even and odd), inverse of a function
( excluding domain and range problems)
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Space for Rough Work
Page 2

PHYSICS
1. Two cylinders of lengths 10 cm and 20 cm and of same area of cross-section are joined end to
end. They are made of materials whose densities are in the ratio 2:1. Their common centre of
mass is at a distance of
a) 2.5 cm from the interface towards the longer rod
b) 2.5 cm from the interface towards the shorter rod
c) 5 cm from the interface towards the longer rod
d) 3.3 cm from the interface towards the shorter rod
2. If particles of masses m, 2m, 3m,..nm are placed at distances 1, 2, 3, .n metres from
the origin on the x-axis, the distance of centre of mass of the system of particles from the
origin in metres is
a)
2n 1
4
b)
2n 1
3
c)
4n 1
3
d)
n1
4
3. Three masses 8 kg, 4 kg and 4 kg are placed at (4, 1), (-2, 2) and (1, -3) respectively. If
r
r
r
they are acted upon by forces 16i , 6i and 14i newton respectively, the acceleration of the
centre of mass of the system is
a) 1.6 ms-2
b) 1.8 ms-2
c) 1.5 ms-2
d) 1.2 ms-2
4. The position of center of mass of a semi- circular uniform disk of mass m and radius R from
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its center is at
a)
4R
3
b)
3R
c)
3R
2
d)
R
2
5. A square plate of mass 4 kg and perimeter 8 m is placed such that its centre of mass lies at
the origin. If two particles each of mass 2 kg are placed at the intersecting points of the
square with positive x and positive y-axis, the angle made by the position vector of centre
of mass with y-axis is
a) 30o
b) 45o
c) 60o
d) Tan-12
6. A metal plate is as shown in the figure. The distance of centre of mass of the plate from O
is
a) 6.25 cm
b)5.25 cm
c) 4.85 cm
d) 7.25 cm
7. Three particles of masses 1 kg, 2 kg and 3 kg are situated at the three corners A, B and C of
an equilateral triangle ABC of side 1 m. The distance of their centre of mass from AB is
a) 1/
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b)
c)
/4 m
d) 3/4 m
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8. Starting from rest two bodies of masses 2 kg and 4 kg are moving with velocities 2 ms 1 and
v ms 1 towards each other due to mutual gravitational attraction. The velocity of their
centre of mass is
a) 5 ms 1
b) 6 ms 1
c) 8ms 1
d) zero
9. A hole of radius r/2 is cut from disc of radius r having mass m. The centre of mass of the
system will be
a) at the centre C
b) at distance r/3 from centre C away from the hole along the common diameter
c) at distance r/4 from centre C away from hole along the common diameter
d) at distance r/6 from centre C away from the hole along the diameter
10.Two bodies of masses m1 and m2 (m2< m1) are connected to the ends of a massless string
which passes over a massless fixed pulley. If the masses are allowed to move, the
acceleration of the centre of mass of the system is
(m1 m 2 )g
a) (m m )
1
2
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(m1 m 2 )g
b) (m m )
1
2
c)
(m1 m 2 ) 2 g
(m1 m 2 ) 2
d)
(m1 m 2 ) 2 g
(m1 m 2 ) 2
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11.
A uniform square sheet has a side of length 2R. A circular sheet of maximum
possible area is removed from one of the quadrants of the square sheet. The distance
of centre of mass of the remaining portion from the centre of the original sheet is
R
a) 16
12.
2R
b) (16 )
c)
R
2 (16 )
d)
R
2(16 )
A thin rod of length L is bent with its mid point as one vertex into the shape of a regular
hexagon. The shift in its centre of mass is
a) L / 4 3
13.
b) L / 2 3
c) L / 3 3
d) L / 6
Two twins each of mass m are on a horizontal floor at a distance d apart. A light rope is
held at its ends by them and they pull it each with a steady force of F. The time after
which they meet each other is
a)
14.
2md
F
b)
md
2F
c)
md
F
d)
F
md
Two particles of masses m1 and m2 (m1> m2) are separated by a distance d. The shift in
centre of mass when the two particles are interchanged is
(m1 m 2 )d
a) (m m )
1
2
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(m1 m 2 )d
b) (m m )
1
2
c) m
m1d
1 m2
d) m
m2d
1 m2
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15.
A man hangs from a rope attached to a hot-air balloon. The mass of the man is greater
than the mass of the balloon and its contents. The system is stationary in air. If the man
now climbs upto the balloon using the rope, the centre of mass of the man plus
balloon system will
a) remain stationary
b) move up
c) move down
d) first move up and then return to its initial position
16.
A boat of mass 80 kg is floating on still water. A dog of mass 20 kg on the boat is at a

distance of 10 m from the shore. The dog moves on the boat by a distance of 2 m
towards the shore. At what distance from the shore is the dog in the later case?
a) 11.6 m
b) 8.4 m
c) 9.6 m
d) 10.4 m
Qns(17to 19): Two blocks of masses m and 2m are attached to spring. The spring is
compressed by x0 and released on a smooth horizontal surface.
17.
The displacement of mass m at the time compression of the spring become x0 / 2 is

a)
18.
x0
3
b)
x0
2
c)
x0
4
d)
x0
6
The ratio of K.E. of blocks at the time compression become x0 / 2 is

a) 2 : 3
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b) 3 : 4
c) 2 : 1
d) 4 : 9
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19.
20.
The work done by force of spring on block of mass m when the spring attains its natural
length is
kx02 / 3
a)
b) kx02 / 6
c) kx02 / 2
d) 3kx02 / 2
A frog sits at the end of a long board of length L. The board rests on a smooth
horizontal surface. The frog wants to jump to the opposite end of the board. What is the
minimum take off speed i.e. relative to the ground that allows the frog to do the trick.
Assume that frog and board have equal masses
a)
21.
b)
gL
3
c)
gL
2
d)
gL
4
A small block of mass m slides along a horizontal surface with a constant velocity v
meets a hill of mass 3m and height H (Hemispherical) which can move along the
horizontal plane. The block begins to slide up the hill. If the hill is initially at rest, what
value of v provides for the maximum subsequent velocity of the hill?
a)
22.
gL
1
8 gh
3
b)
4 gh
3
c)
4 gh
2
d)
2 gh
3
Find the maximum compression/elongation developed in the spring using the data given
in the form of a diagram
a)
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mv02
3k
b)
mv02
k
c)
mv02
6k
d)
mv02
2k
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23.
Two masses A and B are attached to an inextensible string of length L. It is present on a

smooth horizontal plane. B is given a velocity v ms 1 along the ground perpendicular to
AB. Find the tension in the string just after this instant.
a)
24.
b)
mv 2
3l
c)
2mv 2
3l
d)
3mv 2
4l
The linear density of a rod at a distance x from the lighter end is x 2 . The length of
the rod is L. The distance center of mass of the rod from the lighter end is
a)
25.
mv 2
2l
2L
2
b)
3L
4
c)
L
3
d)
L
2
From the square plate ABCD of side 2 m, OQCR square part of side 1 m is removed.
The center of mass of the remaining part is located at
a) 1/3
c) 1/
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2
2
m from O along OA
m from O along OA
b) 1/3
d) 1/
2
2
m from O along OC
m from O along OC
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26.
Three identical persons A, B and C are at the corners of an equilateral triangle of side
180m. At t = 0 they start moving with uniform speed of 40 ms-1 such that
A B C A . The speed of center of mass in the time interval 0 to 3 s
27.
a) Initially increases and then decreases to zero
b) remain as a positive constant
c) will be a harmonic function of time
d) remain zero
ABCD is a trapezium in which AB and CD are parallel, and of lengths a and b

respectively. The perpendicular distance between AB and CD is h. The distance of
center of mass from the side AB is
h( a b)
a) 3(a 2b)
28.
h(2a b)
b) 3(a 2b)
h(a 2b)
c) 3(a b)
h(2a b)
d) 3(a b)
A uniform arc of mass m and radius of curvature R is subtending an angle 2 at the

center. The distance of center of mass from the center of curvature is
a)
29.
2R
b)
R sin
c)
R sin
2
d) zero
On the horizontal surface of a table a chain of mass M and length L is placed so that
25% of the length is hanging from the edge. The work done to pull the hanging part on
to the table is
a)
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MgL
4
b)
MgL
16
c)
MgL
32
d)
MgL
12
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30.
A solid hemisphere of mass 20 kg and radius 2m is projected vertically up with it

curved surface facing the earth with a velocity 2 10 ms-1. At the highest point it turns up
down mysteriously about the flat surface due to action of some force at that point at that
instant for negligible time interval. Choose the correct from a, b and c
a) on reaching the ground velocity of center of mass 2 10 m s-1
b) on reaching the ground velocity of center of mass is 5 2 m s-1
c) Net work done by gravity is 400 J
a)a
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b) a, b
c) b, c
d) b
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CHEMISTRY
31.
The IUPAC name of the following compound is:
32.
a) n-propyl ethanoate
b) ethyl propanoate
c) pentanoic anhydride
d) n-propyl propanoate
Give the IUPAC name for the following structure:
33.
a) 2-methyl-3-ethylheptane
b) 3-ethyl-2-methylheptane
c) 5-isopropyloctane
d) 4-isopropyloctane
Which of the following name will be incorrect?
3, 6-Dimethyl cyclohexene
a)
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b)
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c)
d)
CH 3
CH 3CH 2CHCHCH 2CH 2CHCH 3
34.
35.
36.
The structure shown contains

a) 10 20, and 30 carbon atoms
c) 10 and 30 carbon atoms only
CH 2CH 3
CH 3CH 2
b) 10 and 20 carbon atoms only

d) 20 and 30 carbon atoms only
The IUPAC name of compound

a) 2-Amino-3-chloro-2-methylpent-2-enoic acid
b) 3-Amino-4- chloro-2-methylpent-2-enoic acid
c) 4-Amino-3-chloro-2-methylpent-2-enoic acid
d) All of the above
Which of the following compound is wrongly named?
a)
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;
C
H
H
O
H
32C
2lC
2-Chloro pentanoic acid
Page 13
;
C
H
C
H
H
3
3O
;
C
H
C
H
C
H
O
C
H
323
;
C
H
C
H
H
3
2O
32C
b)
c)
d)
37.
39.
2-Methyl hex-3-enoic acid
Hex-3-en-2-one
4-Methyl pentanal
; Number of functional groups in the above compound is

a) 7
38.
b) 6
c) 4
d) 5
What is correct IUPAC name of compound?
a) 4-cyclopropyl-4-propyl-1-hexene
b) 4-ethyl-4-cyclopropyl-1-heptene
c) 4-cyclopropyl-4-ethyl-1-heptene
c) Both b and c
The correct IUPAC name of the compound below is
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a) 3-ethyl-6-formylheptanoic acid
b) 3-ethyl-6-methyl-7-oxoheptanoic acid
c) 3-ethyl-6-methyl heptan-7-aloic acid
d) 5-ethyl-2-methyl-1-oxoheptanoic acid
COOH
COOH
40.
41.
IUPAC name of the following compound is
COOH
a) 6-ethyl-1, 4,8-octanetrioic acid
b) 2-ethyl-1, 4,6-hexanetricarboxylic acid
c) 3-ethyl-5-carboxy octanedioic acid
d) 4-carboxy-6-ethyloctanedioic acid
What is true about IUPAC naming of organic compound?

a) Two different compounds may have same IUPAC names
b) Naming is done according to source of occurrence of compounds.
c) Naming is done according to convention rules laid by IUPAC
d) Both a and c are correct
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42.
Which of the following compound cannot have the condensed formula C5H10O?
a) An aldehyde
43.
b) A ketone
c) An alkenol
d) A cyclic ketone
The correct IUPAC name of the following compound is
a) 1-ethyl-3-isopropyl-5-propylcyclohexane
b) 1-propyl-3-isopropyl-5-ethylcyclohexane
c) 3-ethyl-5-isopropylproylcyclohexane
d) 3-ethyl-5-propyl isopropylcyclohexane
44.
The correct IUPAC name of the following hydrocarbon is
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a) 4,5-diisopropyl-3-methylheptane
b) 3-methyl-4, 5-diisopropylheptane
c) 5-ethyl-4-isoproyl-3, 6-dimethylheptane
d)3-ethyl-4-isopropyl-2, 5-dimethylheptane
45.
The IUPAC name of the following compound is

OH
CN
Br
46.
(A) 4-Bromo-3-cyanophenol
(B) 2-Bromo-5-hydroxybenzonitrile
(C) 2-Cyano-4-hydroxybromobenzene(D) 6-Bromo-3-hydroxybenzonitrile
Which of the following names is IUPAC name for the given compound
a) 3-Formyl pentane-1,5-dial
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b) 1,2,3-Triformyl-propane
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c) 2-formylbutane-1,4-dial
47.
48.
d) Propane-1,2,3-tricarbaldehyde
The IUPAC name of the compound shown below is
a) 2-bromo-6-chlorocyclohex-1-ene
b) 6-bromo-2-chlorocyclohexene
c) 3-bromo-1-chlorocyclohexene
d) 1-bromo-3-chlorocyclohexene
The correct IUPAC name for

is
49.
a) 2-eethoxy-5-chloropentane
b) 1-chloro-4-ethoxy-4-methyl- butane
c) 1-chloro-4-ethoxy pentane
d) 5-chloro-2-ethoxy pentane
Which one of the underlined carbons is sp3 hybridized?

a) CH 3 CH CH 2
50.
b) CH 3 CH 2 NH 2
c) CH 3 CONH 2
d) CH 3CH 2 CN
In the reaction
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The hybridization state of marked carbon atom changes from

a) sp2 to sp
51.
b) sp3 to sp
c) sp3 to sp2
d) sp2 to sp3
Allyl isocyanide has

a) 9 sigma and 4 pi bonds
b) 8 sigma and 5 pi bonds
c) 8 sigma, 3 pi and 4non-bonded electrons

d) 9 sigma, 3 pi and 2non bonded electrons
52.
When a hybridization state of carbon atom changes from sp 3 to sp2 and finally to sp, the
angle between hybridized orbitals.
53.
a) is not affected
b) increases progressively
c) decreases gradually
d) decreases considerably
The decreasing order of bond dissociation energies of C-C, C-H and H-H bonds is
a) H-H> C-H > C-C
b) C-C >C-H>H-H
C) C-H > C-C > H-H
D) C-C >H-H>C-H
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54.
55.
56.
57.
The IUPAC name of C6H5COCl is

a) benzoyl chloride
b) benzene chloro ketone
c) benzene carbonyl chloride
d) chloro phynyl ketone
Consider the following compounds, all the carbon atoms are Sp 2 -hybridized in
1) chlroethene
2) benzene
3) buta-1, 3-diene 4) 1,3,5-hexatriene
a) 1,3,4 only
b) 1,2 only
c) 1,2,3,4
d) 3,4 only
How many sigma and pi bonds are there in tetracyano ethylene molecule?
a) 9 and 9
b) 9 and 7
c) 5 and 9
d) 5 and 7
The IUPAC name of the following compound
a) 3-dimethylamino-3-methyl pentane
b) 3-(N,N-trimethyl)-3-aminopentane
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c) 3-N,N-trimethyl pentanamine
d)3-(N,N-dimethyl)amino-3-methylpentane
58.
Match the following

Common names
IUPAC names
1. Dimethyl acetylene A. Propanone
2. Methyl acetic acid B, Trichloromethane
59.
3. Chloroform
C. Propanoic acid
4. Acetone
D. But-2-yne
a) 1-D, 2-C, 3-B, 4-A
b)1-A, 2-B, 3-C, 4-D
c) 1-C, 2-D, 3-A, 4-B
d) 1-B, 2-A, 3-D, 4-C
The name(s) of the following compound is/are

CH OH COOH
CH OH COOH
60.
a) tartaric acid
b) 2,3-dihydroxy butane-1,4 dioic acid
c) , ! dihydroxy succinic acid
d) all of the above
The IUPAC name of the compound
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CH 2 CH CH(CH 3 ) 2 is
a) 1,1-dimethyl-2-butene
b) 3-methyl-1-butene
c) 2-vinyl propane
d) none of these
MATHEMATICS
61.
62.
sgn x
x2
Let f : R R defined as f (x) = e e , where sgn x denotes signum function of x,

then f (x) is
a) Even and one-one
b) odd and one-one
c) neither even nor odd and one-one
d) neither even nor odd and not one-one
1
If 2f x xf 2f
x
1
x
2 sin x 4 cos 2 x cos , x R {0} then which of the
x
4
2
following statement is not true?

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a) f 2 f 1
2
1
b) f 2 f 1 0

c) f 2 f 1 f
2
1
d) f 1 f f 2 1
2
63.
f : R R defined as f x ln cos sin x then f is
64.
a) Both many to one and odd

b) Both many to one and even
c) one-one and odd
d) neither one-one nor even
If the function g : [ 1, 0] [1, 2] is defined as g (x) = 2 2x2 + x4, then g-1 (x) is
equal to
a)
65.
1 x 1
b)
1 x 1
c)
4
Let f : (1, 1) R defined as f x x x
less than or equal to x, then f (x) is

a)odd and one-one
c)many to one and even
1 x 1
1
1 x2
d)
1 x 1
where [ x ] denotes greatest integer
b) even and one-one

d) many to one and odd
x x 1 x 4 1 2 x 4 x 2 2
66.
Let f : R R defined as f x
67.
a) odd and one-one

b) even and one-one
c) many to one and even
d) many to one and neither even nor odd
Let f : R R defined as f (x) = x + 3x3 + 5x5 + ....... + 101x101then f (x) is
a) odd and one-one
b) odd and many to one
c) odd and into
d) neither even nor odd
68.
Let f(x) = x x 2
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x2 x 1
then f (x) is
x 1
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x 1
Statement-1 :The range of f (x) = x x 2 is the set of all real numbers.

xa
Statement-2 :The range of g (x) = x c x d is R if a (c, d), a, c, d R.(c<d)

a) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for
statement-1.
b) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct
explanation forstatement-1.
c) Statement-1 is false, statement-2 is true
d) Statement-1 is true, statement-2 is false.
69.
70.
x
f : R R is a function defined by f x e x e x then f is
e e
x
a) a bijection
b) an injection only
c) surjection only
d)neither injection nor surjection
Let f : R R be a continuous onto function satisfying f(x) + f( x) = 0, x R .

If f(3) = 2 and f(5) = 4 then the equation f(x) = 0 has
a) exactly three real roots
71.
c) atleast five real roots

d) atleast three real roots
The range of the function f x 4 x 2 x 2 1 is
a)
72.
b) exactly two real roots
3, 7
b)
3, 5
c)
2, 3
d)
3, 6
7
If g x 4cos 4 x 2cos 2 x 1 cos 4 x x 7 , then the value of g g 100 is equal to
2
a) 1
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b) 0
c) 1
d) 100
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73.
Let f : R R and g : R R be two one-one and onto functions such that they are mirror
images of each other about the line y=a. If h x f x g x then h x is
a) one-one and onto
b) one-one and into
c)many one and into
d) many one and onto
ax8 bx 6 cx 4 dx 2 15 x 1
x 0 .
x
74.
Suppose that f (x) is a function of the form f x
75.
If f (5) = 2 then the value of f ( 5) is equal to

a) 2
b) 28
c) 13
d) 13
f
A function has domain [ 1, 2] and range [0, 1]. The domain and range respectively
76.
of the function g defined by g (x) = 1 f (x + 1) is

a) [1, 1] ; [1, 0]
b) [2, 1]; [0, 1]
c) [0, 2] ; [1, 0]
d) [1, 3] ; [1, 0]
The function f is not defined for x = 0, but for all non zero real numbers x,
1

f (x) + 2 f = 3x. The equation f (x) = f ( x) is satisfied by

x
a) exactly one real number
c) no real numbers
77.
78.
f x
b) exactly two real numbers

d) all non zero real numbers
cos x
1 (where x is not an integral multiple of and [.] is Greatest Integer
x
2
Function) is
a) even function
b) odd function
c)neither even or odd
d) cannot be determined
x x
Let f : [ 1, ) (0, ) defined by f x e
then f (x), is
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79.
80.
81.
82.
83.
84.
85.
a) into and many to one

b) onto and many to one
c) one-one and onto
d) into and one-one
Let f : (1, ) [3, ) defined by f x 10 2 x x 2 , then f (x) is
a) one-one and onto
b) onto and many to one
c) many to one and into
d) one-one and into
Let f : [3, 4] [4, 6] defined by f x x 1 x 2 x 3 x 4 then f (x)
a) one-one & onto
b) one-one & into
c) neither one-one nor onto
d) onto and many to one
Let f : R+ {1,0, 1} defined by f (x) = sgn (x x 4 + x7 x8 1 ) where sgn denotes
signum function, then f(x) is
a) one-one and onto
b) into and many to one
c) onto and many to one
d) none of these
Let f : R R and satisfies f (x) + x f (x) = x + 1, then f (x) is
a) one-one and onto
d) none of these
Let f : [0, 4] [0, 9] defined by f x 6 x x 2 , then f (x) is
a) one-one and onto
d) none of these
Let f : [0, 3] [2, 8] defined by f ( x) 2 x 1 x 2 then f (x) is
a) many to one and onto
b) one-one and onto
c) Many to one and into
d) none of these
If the range of the function f (x) = 6 | x 1 | + |3x 2 | + 2x, is [a, ) then the value of
'a' is
a) 1
Jr.IPLCO
b) 2
c) 3
d) 4
Page 26

86.
The function f(x) =
x 1
can be written as the sum of an even function g (x) and an odd
x3 1
function h (x). The even function g (x), is

x 4 1
2( x 6 1)
87.
88.
x 4 1
x6 1
a)
b)
d)
Let f x x 2 x 3 x 4 and g(x) = f(x+1) then
a) g(x) is an even function
b) g(x) is an odd function
c) g(x) is neither even nor odd
d) g(x) is one-one
x,
0,
f x
if x is rational
if x is irrational
a) one-one and into

c) many one and onto
89.
x 4 1
2( x 6 1)
x 4 1
6
c) x 1
0,
x,
and g x
if x is rational
then f g is
if x is irrational
b) neither one-one nor onto

d) one-one and onto
1
2
If f x is an even function and satisfies the relation x . f x 2. f g x
x
where g x is an odd function, then the value of f 5 is

a) 0
90.
b)
35
55
c) 4
x2 2x c
is onto, if
x 2 4 x 3c
1
1
b) 0 c 4
c) c
2
2
d) 5
The real function f x

a) 0 c 2
Jr.IPLCO
d) 0 c 1
Page 27

PAPER SETTERS (NCO)

PHYSICS
Mr. SHANKAR
CHEMISTRY
Mr. G N REDDY
MATHEMATICS
Mr. K SRINIVAS
9440434981
9848268767
PAPER VERIFIED BY MDP-VEDAVYAS

SUBJECT
NAME OF THE FACULTY
PHYSICS
Mr. S S
CHEMISTRY
Mr. R K
8790253995
MATHS
Mr. SUBBARAO
9618553131
Jr.IPLCO
PHONE NUMBER
Page 28

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