07-07-14 JR - Iplco Jee Adv Wta-9 (2013 p1) Final Q'paper

Narayana Sri Chaitanya IIT Academy
(Sri Sarvani Educational Society)
Common Central Office-Madhapur-Hyd

SEC: JR.COIPL
TIME: 3 HOURS
JEE-ADVANCED
WTA 9
DATE: 07-07-14
MAX MARKS: 180
JEE-ADVANCED-2013-P1-Model
IMPORTANT INSTRUCTIONS
PHYSICS:
Section
Sec I(Q.N : 1 10)
Sec II(Q.N : 11 15)
Sec III(Q.N : 16 20)
Question Type
Questions with Single Correct
Choice
Questions with Multiple Correct
Choice
Questions with Integer Answer
Type
+Ve
Mark
s
- Ve
Mark
s
No.of
Qs
Total
mark
s
10
20
-1
20
-1
20
20
60
Total
CHEMISTRY:
Section
Sec I(Q.N : 21 30)
Sec II(Q.N : 31
35)
Sec III(Q.N : 36
40)
Question Type
Choice
Choice
Type
+Ve
Mark
s
- Ve
Mark
s
No.of
Qs
Total
mark
s
10
20
-1
20
-1
20
20
60
No.of
Qs
Total
mark
s
Total
MATHEMATICS:
Section
Question Type
+Ve
Mark
s
- Ve
Mark
s

07/07/14_Jr.IPLCO_JEE-ADV(2013_P1)_WTA-9
Sec I(Q.N : 41 50)

Sec II(Q.N : 51
55)
Sec III(Q.N : 56
60)

Choice
Choice
Type
Total
10
20
-1
20
-1
20
20
60
Physics:
Friction: A solid surface relatively at rest on another solid surface, static friction as a force opposing the tendency of
relative motion on the other surface. Limiting friction, coefficient of static friction, Difference between fs,max/fs and
static friction as a self adjusting force, angle of friction. Direction of static friction, related Numerical problems,Friction
as the cause of motion (walking, vehicles etc). Minimum force required to move a block on a fixed horizontal surface on
another block with horizontal surface,A solid surface moving relatively on another solid surface. Kinetic friction
(Dynamic or sliding friction). Coefficient of kinetic friction. Direction of Kinetic friction,Cause of static friction, cause of
kinetic friction, methods to reduce friction, Advantages and disadvantages of friction, Dependence of friction on area of
contact, polishing a surface, A block on a fixed rough inclined plane, angle of repose,cases and acceleration down the
plane. Body projected up the inclined plane etc,Miscellaneous problems on Friction(60%) & constraint
equations,Problems in NLM without friction (Including spring problems)(40%)
Chemistry:
Ionic Equilibrium:Theories of acid & bases Arhenius, Bronsted-Lowry and Lewis theory, Ionic product of water and
pH scale, pH calculation involving strong and weak acids and bases, Levelling effect, Common ion effect (60 %) &
Chemical equilbirum: Reversible and Irreversible reactions, Homogenous and Heterogenous equilibria, characteristics of
equilibrium state, Law of mass action, equilibrium constant, characteristics of equilibrium constant, Kp, Kc relation ,
Equilibrium involving physical processes: solid - liquid; liquid - gas and solid - gas. General charecterstics of equilibrium
involving physical process, Lechatliers principle - factors effecting equilibrium concentration, pressure, temperature and
effect of catalyst, principle applied for synthesis of ammonia and sulphur trioxide and other typical reactions,
Thermodynamics of equilibrium constant. Significance of G and G in chemical equilibrium (40 %)
Mathematics:
Trigonometric equations, and inequations
Space for rough work

PHYSICS
Marks : 60
Max
SECTION I
Single Correct Answer Type
This section contains 10 multiple choice questions. Each question has four choices
(A), (B), (C) and (D) out of which ONLY ONE is correct.
1.
In the arrangement shown in figure, coefficient of friction between the two blocks is
1
. The force of friction acting between the two blocks is(Ground is horizontal and
2
smooth) (g=10ms-2)
A) 4 N
2.
B) 6 N
C) 8 N
D) 10 N
A log of weight W is pulled at a constant velocity and with a force F by means of a

rope of length L. The distance between the free end of the rope and the ground is h .
Neglecting the thickness of the log the coefficient of friction between the log and
ground is

A)
3.
F L2 h 2
WL Fh
B)
L2 h 2
WL Fh
C)
WL Fh
F L2 h 2
D)
WL Fh
L2 h 2
In the arrangement shown in vertical plane in fig, the block of mass m 2kg lies on the
wedge of mass M 8 kg .The initial acceleration of the wedge, if the surfaces are
smooth, is(acceleration due to gravity=g)
A)
4.
3 g 2
ms
23
B)
3 3 g 2
ms
23
C)
3 g 2
ms
23
D)
g
ms 2
23
A particle of mass m rests on a horizontal floor with which it has a coefficient of static
friction . For the block to just move
A) A minimum force Fmin
mg
1
has to be applied at an angle tan with the
1

2
horizontal
1
B) A minimum force Fmin mg has to be applied at an angle tan with the
horizontal .
C) A minimum force Fmin
mg
1 2
1
has to be applied at an angle tan with the
horizontal.

1
D) A minimum force Fmin mg has to be applied at an angle tan with the
5.
horizontal.
The force along the incline required to just move a body up an inclined plane is double
the force along the incline required to just prevent it from sliding down. If is angle of
friction and is the angle which incline makes with the horizontal then,
A) tan tan
6.
B) tan 2 tan
C) tan 3 tan
D) tan 3 tan
A varying horizontal force F=at acts on a block of mass m kept on a smooth horizontal
surface. An identical block is kept on the first block. The coefficient of friction
between the block is . The time after which the relative sliding between the blocks
prevails is
A)
7.
2 g
a
B)
2 mg
a
C)
mg
a
D) 2 mga
Two block of masses 2 kg and 4 kg are connected by a light string and kept on
horizontal surface. A force of 16 N is acted on 4kg block horizontal as shown in
figure. Besides it is given that coefficient of friction between 4 kg and ground is 0.3
and between 2kg block and ground is 0.6. Then frictional force between 2 kg block
and ground is (Initial tension in string before F is applied is zero) (g=10ms-2)

A) 12 N
8.
B) 6 N
C) 4 N
D) zero
If the coefficient of friction between A and B is , the maximum acceleration of the

wedge A towards right for which B will remain at rest with respect to the wedge is
A) g
9.
B) g
C) g
D)
Two blocks A and B each of mass m are placed a smooth horizontal surface. Two
horizontal force F and 2F are applied on blocks A and B, respectively. As shown in
Fig. Block A does not slide on block B. Then the normal reaction acting between the
two blocks is (assume no friction between the blocks)

A) F
10.
B) F/2
C)
F
3
D) 3F
The system shown in Fig. is in equilibrium. Masses m1 and m2 are 2 kg and 8 kg,
respectively. Spring constants k1 and k2 are 50 N m 1 and 70 N m 1 , respectively. If the
compression in second spring is 0.5 m. What is the compression in first spring?
A) 1.3 m
B) -0.5 m
C) 0.5 m
D) 0.9 m
SECTION II
Multiple Correct Answer(s) Type
This section contains 5 multiple choice questions. Each question has four
choices (A), (B), (C) and (D) out of which ONE or MORE are correct.
11.
For the given situation shown in figure, choose the correct options (g=10ms-2)

12.
A) At t=1s, force of friction between 2 kg and 4 kg is 2N

B) At t=1s, force of friction between 2 kg and 4 kg is zero
C) At t=4s, force of friction between 4 kg and ground is 8 N
D) At t=15s, acceleration of 2kg is 1 ms-2
The two blocks A and B of equal mass are initially in contact when released from rest
on the inclined plane. The coefficients of friction between the inclined plane and A and
B are 1 and 2 respectively.
A) If 1 2 , the blocks will always remain in contact.

B) If 1 2 , the blocks will slide down with different accelerations.
1
1 2 , g sin .
2
12 g
D) If 1 2 , the blocks will have a common acceleration sin
1
2
C) If 1 2 , the blocks will have a common accelerations

13.
14.
Two blocks A and B of masses 5 kg and 2 kg, respectively, connected by a spring of

force constant=100 N m-1are placed on a fixed inclined plane of inclination 300as
shown in Fig. If the system is released from rest and observed for a small duration,
A) There will be no compression or elongation in the spring if all surfaces are smooth.
B) There will be elongation in the spring if A is rough and B is smooth.
C) There will be compression in the spring if A is rough and B is smooth.
D) There will be elongation in the spring if A is smooth and B is rough.
A man pulls a block of mass equal to himself with a light string. The coefficient of
friction between the man and the floor is greater than that between the block and the
floor
A) If the block does not move, then the man also does not move
B) The block can move even when the man is stationary
C) If both move then the acceleration of the block is greater than the acceleration of
man
D) If both move then the acceleration of man is greater than the acceleration of block

15.
Two masses of 10 kg and 20 kg are connected by a light spring as shown. A force of

200 N acts on a 20 kg mass as shown. At a certain instant the acceleration of 10 kg
mass is 12 ms 2 rightwards (All surfaces are smooth)
A) At that instant the 20 kg mass has an acceleration of 12 ms 2

B) At that instant the 20 kg mass has an acceleration of 4 ms 2
C) The stretching force in the spring is 120 N.
D) The collective system moves with a common acceleration of 30 ms 2 when the
extension in the connecting spring is the maximum.
SECTION III
Integer Answer Type
This section contains 5 questions. The answer to each question is single
digit integer, ranging from 0 to 9 (both inclusive).
16. Two blocks M and m are arranged as shown in the diagram. The coefficient of friction
1
3
between the between the blocks is m1 0.25 and between the ground and M is m2 . If
M 8 kg , then find the maximum value of m so that the system will remain at rest.
10

17.
The rear side of a truck is open and a box of 40 kg mass is placed 8 m away from the
open end as shown in figure. The coefficient of friction between the box and the
surface below it is 0.1 . On a straight road, the truck starts from rest and moves
with acceleration 2 ms 2 . Find the time when box falls off the truck. Take g 10 ms 2
18.
The block B has a mass of 10 kg. The coefficient of kinetic friction between block B
and the surface is 0.1. Neglect the mass of the smooth pulleys and cords. The
acceleration of the block A of mass 5 kg is
n
ms 2 . Find the approximate value of n (
100
g 10 ms 2 )
11

19.
For the pulley system shown in Fig. each of the cables at A and B is given a velocity
of 2ms 1 in the direction of the arrow. The upward velocity v of the load m. is
x 1
ms .
2
Find the value of x
20.
A block is lying on the horizontal frictionless surface. One end of a uniform rope is
fixed to the block which is pulled in the horizontal direction by applying a force F at
the other end. If the mass of the rope is half the mass of the block, the tension in the
middle of the rope will be
nF
. Find the value of n (Neglect sagging of rope under its
6
own weight)
12

CHEMISTRY
Marks : 60
Max
SECTION I
PCl3 g Cl2 g If total pressure at

21. PCl5 dissociates in a closed container as: PCl5 g

equilibrium of the reaction mixture is P and degree of dissociation of PCl5 is the

partial pressure of PCl3 will be:
A) P.
1
22.
B) P.
1
2
For the reaction, N 2 3H
C) P.
1
D) P.
1
2 NH 3 in a vessel equilibrium state is formed after the
addition of equal number of mole of N 2 and H 2 . Which of the following is correct?

A) H 2 N 2
23.
B) H 2 N 2
C) H 2 N 2
D) H 2 NH 3
For the following three reactions 1,2 and 3 equilibrium constants are given:
1) CO g H 2O g CO2 g H 2 g ; K1
2) CH 4 g H 2O g CO g 3H 2 g ; K 2
3) CH 4 g 2 H 2O g CO2 g 4H 2 g ; K 3
Which of the following relations is correct?
a) K1 K 2 K3
b) K 2 K 3 K1
c) K 3 K1 K 2
3
2
d) K 3 K 2 K1
13

24.
For the reaction,
PCl5 g

PCl3 g Cl2 g . The
forward reaction at constant
temperature is favored by:

A) Introducing an inert gas at constant volume
B) Introducing chlorine gas at constant volume
C) Introducing an inert gas at constant pressure
D) None of these
25.
Morphine C17 H19 NO3 , which is used medically to relieve pain is a base. What is its
conjugate acid?
A) C17 H18 NO3
26.
B) C17 H18 NO3
C) C17 H 20 NO3
D) C17 H 20 NO3
6
At 900 C , pure water has H 10 M , if 100 mL of 0.2 M HCl is added to 200 mL of 0.1 M
KOH at 900 C then pH of the resulting solution will be:

A) 5
27.
28.
B) 6
C) 7
D) None of these
For a polyprotic acid say H 3 PO4 , its three dissociation constants K1 , K 2 and K3 are in the
order:
A) K1 K 2 K 3
B) K1 K 2 K3
C) K1 K 2 K3
D) K1 K 2 K3
H 3 BO3 is a
A) Mono basic acid and weak lewis acid
B) Monobasic acid and weak bronsted acid
C) Monobasic acid and strong lewis acid
14

D) Tribasic acid and weak bronsted acid

29.
30.
0.01 M HA aq. is 2% ionized; OH of solution is (At 250C)

A) 2 x 10-4
B) 10-8
C) 5 x 10-11
D) 5 x 10-12
At equilibrium N 2O4 g 2 NO2 g the observed molecular weight of equilibrium
mixture is 80 g mol 1 at 350K. The percentage dissociation of N 2O4 (g) at 350 K is :
a) 10%
b) 15%
c) 20%
d) 18%
SECTION II
31.
A gas phase reaction, carried out in a vessel

C2 H 4( g ) H 2( g )
C2 H 6( g ) ;
H 136.8kJ mol 1 the equilibrium concentration of C2 H 4
can be increased by:
32.
A) increasing the temperature
B) Addition of inert gas at constant volume
C) Removing some H 2
D) adding some C2 H 6
2 mole each of A and B were taken in a container and the following reaction took
2C g 2 D g . When the system attained equilibrium:
place, 2 A g B g
A) A B
33.
B) A B
C) A B
D) D C
Which of the following are conjugate acid-base pairs?
A) HCO3 , CO32
B) C6 H 5 N H 3 , C6 H 5 NH 2
C) H 2C2O4 , HC2O4
D) OH , H
15

34.
35.
Which of the following statement(s) is/are correct about the water?

A) K i (ionization constant of water) < K w (ionic product of water)
B) pK i pK w
C) At 250 C , Ki 1.8 X 1014
D) Ionic product of water at 100 C is 1014
Which of the following expressions is/are true?
KW for a neutral solution

A) H OH
B) OH KW for an acidic solution
7
0
D) OH in water 10 M at 25 C
SECTION III
Integer Answer Type
36. One mole of ethyl alcohol was treated with one mole of acetic acid at 250 C . 2/3 of the
C) pH pOH 14 at all temperature
acid changes into ester at equilibrium. The equilibrium constant for the reaction is :
37.
38.
A mixture of N 2 and H 2 in the molar ratio 1:3 attains equilibrium when 50% of mixture
has reacted. If p is the total pressure of the mixture, the partial pressure of NH 3 formed
is P/y. The value of y is :
The total number of diprotic acids among the following is :
H 3 PO4 H 2 SO4 H 3 PO3 H 2CO3 H 2 S 2O7 H 3 BO3 H 3 PO2 H 2CrO4 H 2 SO3
39.
For the reaction, A( g ) B( g )

C( g ) D( g ) , the initial concentration of A and B are equal,
but the equilibrium concentration of C is twice that of equilibrium concentration of A.
The equilibrium constant is :
16

40.
pH of mixture of 200 ml of 0.2 M H 2 SO4 300 mL
of 0.2 M NaOH 200 mL of 0.1 M KOH
MATHEMATICS
Marks : 60
Max
SECTION I
41. The number of solutions of the equation cos 6 x tan 2 x cos 6 x.tan 2 x 1 in the interval
0, 2 is
A) 4
42.
B) 5
If
C) ,
2
, 2
2
D)
B) 1
C) 2
D) 4
1
sin , cos , tan are in G.P, then is equal to n z
6
A) 2n
45.

,
2
B)
3
3
If 0 x 2 , then the number of solutions of 3 sin x cos x 2 sin x cos x 8 is
A) 0
44.
D) 7
sin 3 cos3
cos
2 tan cot 1 if
sin cos
1 cot 2
A) 0,
2
43.
C) 6
B) 2n
C) n 1
D) n
Let 0, 4 satisfy the equation sin 2 sin 3 sin 4 6 . If sum of all the
values of is of the form k , then the value of k is
17

A) 6
46.
47.
49.
D) 2
3 tan 150 tan 150 , then ' ' is equal to n z
C) n
8
3
2
2
2
2
The solution of 4sin x tan x cos ec x cot x 6 0 is
A) n
B) n
C) n
4
6
3
B) n
D) n
D) n
12
If 2 cot 2 2 3 cot 4 cos ec 8 0 then
A) n , n z
50.
C) 4
The total number of solutions of sin 4 cos 4 x sin x cos x in 0, 2 is equal to

A) 2
B) 4
C) 6
D) 8
A) n
48.
B) 5
B) n , n z
C) 2n , n z
D) 2n , n z
The number of solutions of the equation sec x cos ecx 2 2 in 0, 2 is

A) 1
B) 2
C) 3
D) 4
SECTION II
51. A solution of the equation 1 tan 1 tan sec 2 2tan 0 . Where ' ' lies in the
2
, is given by
interval
2 2
A) 0
B)
C)
D)
6
18

52.
If cos p sin q ,
p q then the general values of ' ' are
2n 1
2n 1
A) 2 p q , n I B) 2 p q , n I
53.
7 5
,
6 6
55.
1
3
5 7
,
C)
6 6
4n 1
D) 2 p q , n I
1
2
A solution of the system of equations x y and cos2 x sin 2 y is given by

A)
54.
4n 1
C) 2 p q , n I
2 1
,
3 3
B)
13 11
,
6 6
D)
If sin x cos x y 1/ y for x 0, , then

A) x
Let
, 0, 2 be
B) y 0
C) y 1
such
that
D) x
3
4
2 cos 1 sin sin 2 tan
tan 2 0 and 1 sin 3 , then can not satisfy

2
4
4
3

A) 0
B)
C)
2
2
3
3
2
D)
cot
2

cos 1,
2
3
2
2
SECTION III
Integer Answer Type
56.
The number of solutions of the equation tan x sec x 2 cos x lying in the interval 0, 2
57.
2
2
Number of roots of the equation sin x cos x tan x cot x
58.
x
x
Number of ordered pairs , x satisfying 2sin e e , 0, 3 is
59.
Number of roots of the equation cos7 x sin 4 x 1 in the interval 0, 2 is

19

60.
The number of solutions of sin x
x
is k for all x and total number of solutions of
10
3k

, is ' p ' . Then the value of
is
p
2
cos 2 x sin x for x
PAPER SETTER-DNMKL
SUBJECT
PHYSICS
CHEMISTRY
MATHS
NAME
SRI. RAGHVAN
SRI. POORAN CHANDAR
SRI. RAMESH GUPTHA
PH NO
9849781615
9581169045
9032820891
PAPER VERIFIED MDP-VEDAVYAS

SUBJECT
NAME OF THE FACULTY
PHONE NUMBER
PHYSICS
Mr. JANARDHAN
9490115871
CHEMISTRY
Mr. R K
8790253995
MATHS
Mr. A N S
9912342375
20

07-07-14 JR - Iplco Jee Adv Wta-9 (2013 p1) Final Q'paper

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Narayana Sri Chaitanya IIT Academy

(Sri Sarvani Educational Society)

Common Central Office-Madhapur-Hyd

Narayana Sri Chaitanya IIT Academy

Sec I(Q.N : 41 50)

Questions with Single Correct

Space for rough work

Narayana Sri Chaitanya IIT Academy

A log of weight W is pulled at a constant velocity and with a force F by means of a

Narayana Sri Chaitanya IIT Academy

Space for rough work

Narayana Sri Chaitanya IIT Academy

Space for rough work

Narayana Sri Chaitanya IIT Academy

If the coefficient of friction between A and B is , the maximum acceleration of the

Space for rough work

Narayana Sri Chaitanya IIT Academy

Space for rough work

Narayana Sri Chaitanya IIT Academy

A) At t=1s, force of friction between 2 kg and 4 kg is 2N

A) If 1 2 , the blocks will always remain in contact.

C) If 1 2 , the blocks will have a common accelerations

Space for rough work

Narayana Sri Chaitanya IIT Academy

Two blocks A and B of masses 5 kg and 2 kg, respectively, connected by a spring of

Space for rough work

Narayana Sri Chaitanya IIT Academy

Two masses of 10 kg and 20 kg are connected by a light spring as shown. A force of

A) At that instant the 20 kg mass has an acceleration of 12 ms 2

Space for rough work

Narayana Sri Chaitanya IIT Academy

Space for rough work

Narayana Sri Chaitanya IIT Academy

Find the value of x

Space for rough work

Narayana Sri Chaitanya IIT Academy

PCl3 g Cl2 g If total pressure at

equilibrium of the reaction mixture is P and degree of dissociation of PCl5 is the

2 NH 3 in a vessel equilibrium state is formed after the

addition of equal number of mole of N 2 and H 2 . Which of the following is correct?

Space for rough work

Narayana Sri Chaitanya IIT Academy

For the reaction,

PCl3 g Cl2 g . The

forward reaction at constant

temperature is favored by:

B) C17 H18 NO3

KOH at 900 C then pH of the resulting solution will be:

Narayana Sri Chaitanya IIT Academy

D) Tribasic acid and weak bronsted acid

0.01 M HA aq. is 2% ionized; OH of solution is (At 250C)

A gas phase reaction, carried out in a vessel

H 136.8kJ mol 1 the equilibrium concentration of C2 H 4

can be increased by:

A) increasing the temperature

B) Addition of inert gas at constant volume

Which of the following are conjugate acid-base pairs?

Narayana Sri Chaitanya IIT Academy

Which of the following statement(s) is/are correct about the water?

KW for a neutral solution

B) OH KW for an acidic solution

C) pH pOH 14 at all temperature

For the reaction, A( g ) B( g )