Академический Документы
Профессиональный Документы
Культура Документы
of Concrete
Mixtures
1 4 t h
e d i t i o n
KEYWORDS: admixtures, aggregates, air-entrained concrete, batching, cement, cold weather, curing, durability, fibers,
finishing, high-performance concrete, hot weather, mixing, mixing water, mixture proportioning, placing, portland cement
concrete, properties, special concrete, standards, supplementary cementing materials, tests, and volume changes.
ABSTRACT: This book presents the properties of concrete as needed in concrete construction, including strength and
durability. All concrete ingredients (cementing materials, water, aggregates, admixtures, and fibers) are reviewed for their
optimal use in designing and proportioning concrete mixtures. Applicable ASTM, AASHTO, and ACI standards are
referred to extensively. The use of concrete from design to batching, mixing, transporting, placing, consolidating, finishing,
and curing is addressed. Special concretes, including high-performance concretes, are also reviewed.
REFERENCE: Kosmatka, Steven H.; Kerkhoff, Beatrix; and Panarese, William C.; Design and Control of Concrete Mixtures,
EB001, 14th edition, Portland Cement Association, Skokie, Illinois, USA, 2003.
Kosmatka, Steven H.
Design and control of concrete mixtures / by Steven H.
Kosmatka, Beatrix Kerkhoff, and William C. Panarese.
14th ed.
p. cm.
ISBN 0-89312-217-3 (pbk. : alk. paper)
1. Concrete. 2. ConcreteAdditives. 3. Portland cement.
I. Kerkhoff, Beatrix. II. Panarese, William C. III. Title.
TA439 .K665 2002
666'.893dc21
2001007603
PCA R&D Serial Number SN2561
Printed in the United States of America
EB001.14
ii
Table of Contents
Preface and Acknowledgements . . . . . . . . . . . . . . . . . . . . ix
Type MH. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33
Type LH . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33
Hydraulic Slag Cements . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33
Modified Portland Cements . . . . . . . . . . . . . . . . . . . . . . . . . 33
Special Cements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33
Masonry and Mortar Cements . . . . . . . . . . . . . . . . . . . . . 33
Plastic Cements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35
Finely-Ground Cements (Ultrafine Cements) . . . . . . . . . 35
Expansive Cements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36
Oil-Well Cements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36
Cements with Functional Additions . . . . . . . . . . . . . . . . 36
Water-Repellent Cements . . . . . . . . . . . . . . . . . . . . . . . . . 36
Regulated-Set Cements . . . . . . . . . . . . . . . . . . . . . . . . . . . 36
Geopolymer Cements . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37
Ettringite Cements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37
Rapid Hardening Cements . . . . . . . . . . . . . . . . . . . . . . . . 37
Calcium Aluminate Cements . . . . . . . . . . . . . . . . . . . . . . 37
Magnesium Phosphate Cements . . . . . . . . . . . . . . . . . . . 37
Sulfur Cements. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37
Selecting and Specifying Cements . . . . . . . . . . . . . . . . . . . . 37
Availability of Cements . . . . . . . . . . . . . . . . . . . . . . . . . . . 38
Drinking Water Applications . . . . . . . . . . . . . . . . . . . . . . 38
Canadian and European Cement
Specifications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38
Chemical Compounds and Hydration
of Portland Cement . . . . . . . . . . . . . . . . . . . . . . . . . . 39
Tricalcium Silicate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42
Dicalcium Silicate. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42
Tricalcium Aluminate . . . . . . . . . . . . . . . . . . . . . . . . . . 42
Tetracalcium Aluminoferrite . . . . . . . . . . . . . . . . . . . . . 42
Calcium Sulfate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42
Water (Evaporable and Nonevaporable) . . . . . . . . . . . . . 42
Physical Properties of Cement . . . . . . . . . . . . . . . . . . . . . . . 43
Particle Size and Fineness . . . . . . . . . . . . . . . . . . . . . . . . . 43
Soundness. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 44
Consistency . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 45
Setting Time . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 45
Early Stiffening (False Set and Flash Set). . . . . . . . . . . . . 46
Compressive Strength . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47
Heat of Hydration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47
Loss on Ignition . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49
Density and Relative Density
(Specific Gravity) . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49
Bulk Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 50
Thermal Analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 50
Thermogravimetric Analysis (TGA). . . . . . . . . . . . . . . . . 51
Differential Thermal Analysis (DTA) . . . . . . . . . . . . . . . . 51
Differential Scanning Calorimetry (DSC) . . . . . . . . . . . . 51
Virtual Cement Testing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 51
Transportation and Packaging . . . . . . . . . . . . . . . . . . . . . . . 52
Storage of Cement . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 52
Hot Cement . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53
References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53
Chapter 1
Fundamentals of Concrete . . . . . . . . . . . . . . . . . . . . . . . . . . 1
Freshly Mixed Concrete . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
Mixing. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
Workability. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
Bleeding and Settlement . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
Consolidation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
Hydration, Setting Time, and Hardening . . . . . . . . . . . . . 4
Hardened Concrete . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
Curing. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
Drying Rate of Concrete . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
Strength . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
Density . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
Permeability and Watertightness . . . . . . . . . . . . . . . . . . . . 9
Abrasion Resistance. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10
Volume Stability and Crack Control. . . . . . . . . . . . . . . . . 11
Joints . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
Durability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
Resistance to Freezing and Thawing . . . . . . . . . . . . . . . . 12
Alkali-Aggregate Reactivity . . . . . . . . . . . . . . . . . . . . . . . 13
Carbonation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14
Chloride Resistance and Steel Corrosion . . . . . . . . . . . . . 14
Chemical Resistance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
Sulfate Attack . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
Seawater Exposures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
Ettringite and Heat Induced
Delayed Expansion . . . . . . . . . . . . . . . . . . . . . . . . . . 17
Heat Induced Delayed Expansion . . . . . . . . . . . . . . . . 17
References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18
Chapter 2
Portland, Blended, and Other Hydraulic Cements . . . 21
The Beginning of an Industry. . . . . . . . . . . . . . . . . . . . . . . . 21
Manufacture of Portland Cement. . . . . . . . . . . . . . . . . . . . . 24
Types of Portland Cement. . . . . . . . . . . . . . . . . . . . . . . . . . . 27
Type I . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27
Type II . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27
Type III . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28
Type IV . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 29
Type V. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 29
Air-Entraining Portland Cements. . . . . . . . . . . . . . . . . . . 30
White Portland Cements . . . . . . . . . . . . . . . . . . . . . . . . . . 30
Blended Hydraulic Cements. . . . . . . . . . . . . . . . . . . . . . . . . 31
Type IS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31
Type IP and Type P . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31
Type I (PM). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31
Type S . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32
Type I (SM) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32
Hydraulic Cements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32
Type GU . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32
Type HE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32
Type MS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32
Type HS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33
iii
Contents, continued
Chapter 3
Fly Ash, Slag, Silica Fume, and
Natural Pozzolans . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 57
Chapter 5
Aggregates for Concrete . . . . . . . . . . . . . . . . . . . . . . . . . . . 79
Characteristics of Aggregates . . . . . . . . . . . . . . . . . . . . . . . . 80
Grading. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 80
Fine-Aggregate Grading . . . . . . . . . . . . . . . . . . . . . . . . . . 83
Fineness Modulus . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 84
Coarse-Aggregate Grading . . . . . . . . . . . . . . . . . . . . . . . . 84
Combined Aggregate Grading . . . . . . . . . . . . . . . . . . . . . 86
Gap-Graded Aggregates . . . . . . . . . . . . . . . . . . . . . . . . . . 86
Particle Shape and Surface Texture . . . . . . . . . . . . . . . . . 87
Bulk Density (Unit Weight) and Voids. . . . . . . . . . . . . . . 87
Relative Density (Specific Gravity) . . . . . . . . . . . . . . . . . 87
Density . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 88
Absorption and Surface Moisture . . . . . . . . . . . . . . . . . . 88
Bulking . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 88
Resistance to Freezing and Thawing . . . . . . . . . . . . . . . . 89
Wetting and Drying Properties. . . . . . . . . . . . . . . . . . . . . 90
Abrasion and Skid Resistance. . . . . . . . . . . . . . . . . . . . . . 90
Strength and Shrinkage . . . . . . . . . . . . . . . . . . . . . . . . . . . 91
Resistance to Acid and Other
Corrosive Substances. . . . . . . . . . . . . . . . . . . . . . . . . 91
Fire Resistance and Thermal Properties. . . . . . . . . . . . . . 92
Potentially Harmful Materials . . . . . . . . . . . . . . . . . . . . . . . 92
Alkali-Aggregate Reactivity . . . . . . . . . . . . . . . . . . . . . . . . . 93
Alkali-Silica Reaction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 93
Visual Symptoms of Expansive ASR . . . . . . . . . . . . . . 93
Mechanism of ASR. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 94
Factors Affecting ASR . . . . . . . . . . . . . . . . . . . . . . . . . . 94
Test Methods for Identifying ASR Distress . . . . . . . . . 94
Control of ASR in New Concrete . . . . . . . . . . . . . . . . . 94
Identification of Potentially
Reactive Aggregates. . . . . . . . . . . . . . . . . . . . . . . . . . 95
Materials and Methods to Control ASR . . . . . . . . . . . . 95
Alkali-Carbonate Reaction . . . . . . . . . . . . . . . . . . . . . . . . 95
Mechanism of ACR . . . . . . . . . . . . . . . . . . . . . . . . . . . . 95
Dedolomitization . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98
Test Methods for Identifying ACR Distress . . . . . . . . . 98
Materials and Methods to Control ACR . . . . . . . . . . . 98
Aggregate Beneficiation . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98
Handling and Storing Aggregates . . . . . . . . . . . . . . . . . . . . 98
Marine-Dredged Aggregate . . . . . . . . . . . . . . . . . . . . . . . . . 99
Recycled-Concrete Aggregate . . . . . . . . . . . . . . . . . . . . . . . . 99
References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 101
Fly Ash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 58
Slag . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 59
Silica Fume . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 60
Natural Pozzolans . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 60
Effects on Freshly Mixed Concrete. . . . . . . . . . . . . . . . . . . . 61
Water Requirements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 61
Workability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 62
Bleeding and Segregation . . . . . . . . . . . . . . . . . . . . . . . . . 62
Air Content. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 62
Heat of Hydration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63
Setting Time . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63
Finishability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64
Pumpability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64
Plastic Shrinkage Cracking . . . . . . . . . . . . . . . . . . . . . . . . 64
Curing. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64
Effects on Hardened Concrete . . . . . . . . . . . . . . . . . . . . . . . 64
Strength. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64
Impact and Abrasion Resistance. . . . . . . . . . . . . . . . . . . . 65
Freeze-Thaw Resistance . . . . . . . . . . . . . . . . . . . . . . . . . . 65
Deicer-Scaling Resistance . . . . . . . . . . . . . . . . . . . . . . . . . 66
Drying Shrinkage and Creep . . . . . . . . . . . . . . . . . . . . . . 67
Permeability and Absorption . . . . . . . . . . . . . . . . . . . . . . 68
Alkali-Aggregate Reactivity . . . . . . . . . . . . . . . . . . . . . . . 68
Sulfate Resistance. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 69
Corrosion of Embedded Steel . . . . . . . . . . . . . . . . . . . . . . 69
Carbonation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 69
Chemical Resistance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 69
Soundness. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 69
Concrete Color . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 69
Concrete Mix Proportions . . . . . . . . . . . . . . . . . . . . . . . . . . . 70
Availability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 70
Storage . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 70
References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 70
Chapter 4
Mixing Water for Concrete . . . . . . . . . . . . . . . . . . . . . . . . . . 73
Alkali Carbonate and Bicarbonate . . . . . . . . . . . . . . . . . . . . 74
Chloride . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 74
Sulfate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75
Other Common Salts . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75
Iron Salts. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75
Miscellaneous Inorganic Salts. . . . . . . . . . . . . . . . . . . . . . . . 75
Seawater . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75
Acid Waters . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 76
Alkaline Waters . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 76
Wash Water. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 76
Industrial Wastewater . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 76
Waters Carrying Sanitary Sewage . . . . . . . . . . . . . . . . . . . . 77
Organic Impurities. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 77
Sugar . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 77
Silt or Suspended Particles . . . . . . . . . . . . . . . . . . . . . . . . . . 77
Oils . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 77
Algae. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 77
Interaction with Admixtures. . . . . . . . . . . . . . . . . . . . . . . . . 77
References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 77
Chapter 6
Admixtures for Concrete . . . . . . . . . . . . . . . . . . . . . . . . . . 105
Air-Entraining Admixtures . . . . . . . . . . . . . . . . . . . . . . . . . 107
Water-Reducing Admixtures. . . . . . . . . . . . . . . . . . . . . . . . 107
Mid-Range Water Reducing Admixtures. . . . . . . . . . . . . . 109
High-Range Water Reducing Admixtures . . . . . . . . . . . . . 109
Plasticizers for Flowing Concrete . . . . . . . . . . . . . . . . . . . . 110
Retarding Admixtures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 113
Hydration-Control Admixtures . . . . . . . . . . . . . . . . . . . . . 113
Accelerating Admixtures. . . . . . . . . . . . . . . . . . . . . . . . . . . 113
Corrosion Inhibitors. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 114
Shrinkage-Reducing Admixtures . . . . . . . . . . . . . . . . . . . . 115
Chemical Admixtures to Reduce AlkaliAggregate Reactivity (ASR Inhibitors) . . . . . . . . . . 115
Coloring Admixtures (Pigments) . . . . . . . . . . . . . . . . . . . . 115
Dampproofing Admixtures . . . . . . . . . . . . . . . . . . . . . . . . . 116
Permeability-Reducing Admixtures . . . . . . . . . . . . . . . . . . 116
iv
Contents, continued
Water-Cementing Materials Ratio
and Strength Relationship . . . . . . . . . . . . . . . . . . . . 149
Strength. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 150
Water-Cementitious Material Ratio . . . . . . . . . . . . . . . . 151
Aggregates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 151
Air Content. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 152
Mild Exposure . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 153
Moderate Exposure . . . . . . . . . . . . . . . . . . . . . . . . . . . 153
Severe Exposure . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 153
Slump . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 153
Water Content . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 155
Cementing Materials Content and Type . . . . . . . . . . . . 156
Admixtures. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 157
Proportioning . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 157
Proportioning from Field Data . . . . . . . . . . . . . . . . . . . . 157
Proportioning by Trial Mixtures . . . . . . . . . . . . . . . . . . . 158
Measurements and Calculations. . . . . . . . . . . . . . . . . . . 159
Density (Unit Weight) and Yield. . . . . . . . . . . . . . . . . 159
Absolute Volume . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 159
Examples of Mixture Proportioning. . . . . . . . . . . . . . . . . . 160
Example 1. Absolute Volume Method
(Metric) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 160
Conditions and Specifications. . . . . . . . . . . . . . . . . . . 160
Strength. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 160
Water to Cement Ratio. . . . . . . . . . . . . . . . . . . . . . . . . 160
Air Content. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 160
Slump . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 160
Water Content . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 160
Cement Content . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 160
Coarse-Aggregate Content . . . . . . . . . . . . . . . . . . . . . 161
Admixture Content . . . . . . . . . . . . . . . . . . . . . . . . . . . 161
Fine-Aggregate Content . . . . . . . . . . . . . . . . . . . . . . . 161
Moisture . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 161
Trial Batch . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 161
Batch Adjustments . . . . . . . . . . . . . . . . . . . . . . . . . . . . 162
Example 2. Absolute Volume Method
(Inch-Pound Units) . . . . . . . . . . . . . . . . . . . . . . . . . 163
Conditions and Specifications. . . . . . . . . . . . . . . . . . . 163
Strength. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 163
Water to Cement Ratio. . . . . . . . . . . . . . . . . . . . . . . . . 163
Coarse-Aggregate Size. . . . . . . . . . . . . . . . . . . . . . . . . 163
Air Content. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 163
Slump . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 163
Water Content . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 163
Cement Content . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 163
Coarse-Aggregate Content . . . . . . . . . . . . . . . . . . . . . 163
Admixture Content . . . . . . . . . . . . . . . . . . . . . . . . . . . 163
Fine-Aggregate Content . . . . . . . . . . . . . . . . . . . . . . . 163
Moisture . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 164
Trial Batch . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 164
Batch Adjustments . . . . . . . . . . . . . . . . . . . . . . . . . . . . 165
Water Reducers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 166
Pozzolans and Slag . . . . . . . . . . . . . . . . . . . . . . . . . . . 166
Example 3. Laboratory Trial Mixture
Using the PCA Water-Cement
Ratio Method (Metric) . . . . . . . . . . . . . . . . . . . . . . . 166
Conditions and Specifications. . . . . . . . . . . . . . . . . . . 166
Durability Requirements . . . . . . . . . . . . . . . . . . . . . . . 166
Strength Requirements . . . . . . . . . . . . . . . . . . . . . . . . 166
Aggregate Size . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 166
Chapter 7
Fibers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 121
Advantages and Disadvantages
of Using Fibers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 121
Types and Properties of Fibers and
Their Effect on Concrete . . . . . . . . . . . . . . . . . . . . . 122
Steel Fibers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 122
Glass Fibers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 124
Synthetic Fibers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 125
Natural Fibers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 126
Unprocessed Natural Fibers . . . . . . . . . . . . . . . . . . . . 126
Wood Fibers (Processed Natural Fibers) . . . . . . . . . . 126
Multiple Fiber Systems . . . . . . . . . . . . . . . . . . . . . . . . . . . . 126
References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 127
Chapter 8
Air-Entrained Concrete . . . . . . . . . . . . . . . . . . . . . . . . . . . . 129
Properties of Air-Entrained Concrete. . . . . . . . . . . . . . . . . 129
Freeze-Thaw Resistance . . . . . . . . . . . . . . . . . . . . . . . . . 129
Deicer-Scaling Resistance . . . . . . . . . . . . . . . . . . . . . . . . 132
Air Drying . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 134
Treatment of Scaled Surfaces . . . . . . . . . . . . . . . . . . . 134
Sulfate Resistance. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 134
Resistance to Alkali-Silica Reactivity . . . . . . . . . . . . . . . 134
Strength. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 134
Workability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 136
Air-Entraining Materials . . . . . . . . . . . . . . . . . . . . . . . . . . . 136
Factors Affecting Air Content . . . . . . . . . . . . . . . . . . . . . . . 137
Cement . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 137
Coarse Aggregate. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 138
Fine Aggregate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 138
Mixing Water and Slump . . . . . . . . . . . . . . . . . . . . . . . . 138
Slump and Vibration . . . . . . . . . . . . . . . . . . . . . . . . . . . . 141
Concrete Temperature . . . . . . . . . . . . . . . . . . . . . . . . . . . 142
Supplementary Cementitious Materials . . . . . . . . . . . . 142
Admixtures and Coloring Agents . . . . . . . . . . . . . . . . . 142
Mixing Action. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143
Transporting and Handling . . . . . . . . . . . . . . . . . . . . . . 144
Finishing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 144
Tests for Air Content . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 144
Air-Void Analysis of Fresh Concrete . . . . . . . . . . . . . . . 145
Recommended Air Contents. . . . . . . . . . . . . . . . . . . . . . . . 145
References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 147
Chapter 9
Designing and Proportioning
Normal Concrete Mixtures . . . . . . . . . . . . . . . . . . . . . . . . . 149
Selecting Mix Characteristics . . . . . . . . . . . . . . . . . . . . . . . 149
v
Contents, continued
Special Placing Techniques . . . . . . . . . . . . . . . . . . . . . . . . . 194
Consolidating Concrete . . . . . . . . . . . . . . . . . . . . . . . . . . . . 194
Vibration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 195
Internal Vibration. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 195
External Vibration . . . . . . . . . . . . . . . . . . . . . . . . . . . . 197
Consequences of Improper Vibration. . . . . . . . . . . . . 198
Concrete Slabs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 198
Subgrade Preparation . . . . . . . . . . . . . . . . . . . . . . . . . . . 199
Subbase . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 199
Vapor Retarders and
Moisture-Problem Prevention . . . . . . . . . . . . . . . . . 199
Forms . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 200
Rain Protection. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 200
Placing and Spreading. . . . . . . . . . . . . . . . . . . . . . . . . . . 200
Screeding (Strikeoff) . . . . . . . . . . . . . . . . . . . . . . . . . . . . 200
Bullfloating or Darbying . . . . . . . . . . . . . . . . . . . . . . . . . 201
Edging and Jointing. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 202
Floating . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 202
Troweling . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 202
Brooming . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 203
Curing and Protection . . . . . . . . . . . . . . . . . . . . . . . . . . . 203
Placing on Hardened Concrete . . . . . . . . . . . . . . . . . . . . . . 204
Bonded Construction Joints in
Structural Concrete . . . . . . . . . . . . . . . . . . . . . . . . . 204
Preparing Hardened Concrete . . . . . . . . . . . . . . . . . . . . 204
Bonding New to Previously
Hardened Concrete . . . . . . . . . . . . . . . . . . . . . . . . . 205
Making Joints in Floors and Walls . . . . . . . . . . . . . . . . . . . 206
Isolation Joints . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 206
Contraction Joints . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 206
Construction Joints . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 208
Joint Layout for Floors . . . . . . . . . . . . . . . . . . . . . . . . . . . . 209
Filling Floor Joints . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 209
Unjointed Floors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 210
Removing Forms . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 210
Patching Cleaning, and Finishing. . . . . . . . . . . . . . . . . . . . 210
Holes, Defects, and Overlays . . . . . . . . . . . . . . . . . . . . . 210
Curing Patches . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 212
Cleaning Concrete Surfaces. . . . . . . . . . . . . . . . . . . . . . . 212
Finishing Formed Surfaces . . . . . . . . . . . . . . . . . . . . . . . 213
Special Surface Finishes. . . . . . . . . . . . . . . . . . . . . . . . . . . . 213
Patterns and Textures . . . . . . . . . . . . . . . . . . . . . . . . . . . 213
Exposed-Aggregate Concrete . . . . . . . . . . . . . . . . . . . . . 213
Colored Finishes. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 215
Stains, Paints, and Clear Coatings . . . . . . . . . . . . . . . . . 215
Precautions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 215
Protect Your Head and Eyes . . . . . . . . . . . . . . . . . . . . 215
Protect Your Back . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 216
Protect Your Skin . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 216
References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 216
Chapter 10
Batching, Mixing, Transporting, and
Handling Concrete . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 179
Batching . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 179
Mixing Concrete. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 180
Stationary Mixing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 180
Ready Mixed Concrete . . . . . . . . . . . . . . . . . . . . . . . . . . 180
Mobile Batcher Mixed Concrete
(Continuous Mixer) . . . . . . . . . . . . . . . . . . . . . . . . . 183
Remixing Concrete. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 183
Transporting and Handling Concrete . . . . . . . . . . . . . . . . 183
Delays . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 183
Early Stiffening and Drying Out. . . . . . . . . . . . . . . . . 183
Segregation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 184
Methods and Equipment for Transporting
and Handling Concrete . . . . . . . . . . . . . . . . . . . . . . 184
Choosing the Best Method . . . . . . . . . . . . . . . . . . . . . . . 188
Work At and Below Ground Level . . . . . . . . . . . . . . . . . 188
Work Above Ground Level . . . . . . . . . . . . . . . . . . . . . . . 188
References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 189
Chapter 12
Curing Concrete . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 219
Curing Methods and Materials. . . . . . . . . . . . . . . . . . . . . . 220
Ponding and Immersion . . . . . . . . . . . . . . . . . . . . . . . . . 221
Fogging and Sprinkling. . . . . . . . . . . . . . . . . . . . . . . . . . 221
Wet Coverings . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 221
Impervious Paper. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 222
Plastic Sheets . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 222
Membrane-Forming Curing Compounds . . . . . . . . . . . 223
Chapter 11
Placing and Finishing Concrete . . . . . . . . . . . . . . . . . . . 191
Preparation Before Placing . . . . . . . . . . . . . . . . . . . . . . . . . 191
Depositing the Concrete . . . . . . . . . . . . . . . . . . . . . . . . . . . 192
Placing Concrete Underwater. . . . . . . . . . . . . . . . . . . . . . . 193
vi
Contents, continued
Chapter 14
Cold-Weather Concreting . . . . . . . . . . . . . . . . . . . . . . . . . . 239
Chapter 16
Control Tests for Concrete . . . . . . . . . . . . . . . . . . . . . . . . 275
Chapter 13
Hot-Weather Concreting . . . . . . . . . . . . . . . . . . . . . . . . . . . 229
Chapter 15
Volume Changes of Concrete . . . . . . . . . . . . . . . . . . . . . . 257
Early Age Volume Changes . . . . . . . . . . . . . . . . . . . . . . . . 257
Chemical Shrinkage . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 257
Autogenous Shrinkage . . . . . . . . . . . . . . . . . . . . . . . . . . 258
Subsidence . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 259
Plastic Shrinkage . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 259
Swelling . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 259
Early Thermal Expansion . . . . . . . . . . . . . . . . . . . . . . . . 260
vii
Contents, continued
Volume and Length Change . . . . . . . . . . . . . . . . . . . . . . 290
Durability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 290
Frost Resistance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 290
Sulfate Resistance. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 290
Alkali-Silica Reactivity. . . . . . . . . . . . . . . . . . . . . . . . . 290
Alkali-Carbonate Reactivity . . . . . . . . . . . . . . . . . . . . 290
Corrosion Resistance . . . . . . . . . . . . . . . . . . . . . . . . . 290
Abrasion Resistance. . . . . . . . . . . . . . . . . . . . . . . . . . . 290
Moisture Testing. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 291
Carbonation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 291
pH Testing Methods . . . . . . . . . . . . . . . . . . . . . . . . . . . . 292
Permeability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 292
Nondestructive Test Methods . . . . . . . . . . . . . . . . . . . . . 292
Rebound Number Tests . . . . . . . . . . . . . . . . . . . . . . . . 292
Penetration Tests . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 293
Maturity Tests. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 293
Pullout Tests . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 293
Break-Off Tests . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 293
Dynamic or Vibration Tests. . . . . . . . . . . . . . . . . . . . . 294
Other Tests . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 294
References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 295
Chapter 17
High-Performance Concrete . . . . . . . . . . . . . . . . . . . . . . . 299
High-Early-Strength Concrete . . . . . . . . . . . . . . . . . . . . . . 300
High-Strength Concrete. . . . . . . . . . . . . . . . . . . . . . . . . . . . 303
Cement . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 305
Supplementary Cementing Materials . . . . . . . . . . . . . . 305
Aggregates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 305
Admixtures. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 306
Proportioning . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 306
Mixing. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 306
Placing, Consolidation, and Curing . . . . . . . . . . . . . . . . 307
Quality Control . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 308
High-Durability Concrete . . . . . . . . . . . . . . . . . . . . . . . . . . 308
Abrasion Resistance. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 308
Blast Resistance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 309
Permeability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 309
Diffusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 309
Carbonation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 309
Temperature Control . . . . . . . . . . . . . . . . . . . . . . . . . . . . 309
Freeze-Thaw Resistance . . . . . . . . . . . . . . . . . . . . . . . . . 310
Chemical Attack . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 310
Alkali-Silica Reactivity . . . . . . . . . . . . . . . . . . . . . . . . . . 310
Resistivity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 311
Self-Compacting Concrete. . . . . . . . . . . . . . . . . . . . . . . . . . 311
Reactive Powder Concrete . . . . . . . . . . . . . . . . . . . . . . . . . 312
References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 313
Chapter 18
Special Types of Concrete . . . . . . . . . . . . . . . . . . . . . . . . . 315
Structural Lightweight Concrete . . . . . . . . . . . . . . . . . . . . 315
Structural Lightweight Aggregates . . . . . . . . . . . . . . . . 316
Compressive Strength . . . . . . . . . . . . . . . . . . . . . . . . . . . 316
Entrained Air . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 317
viii
Specifications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 317
Mixing. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 317
Workability and Finishability . . . . . . . . . . . . . . . . . . . . . 317
Slump . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 317
Vibration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 317
Placing, Finishing, and Curing . . . . . . . . . . . . . . . . . . . . 317
Insulating and Moderate-Strength
Lightweight Concretes. . . . . . . . . . . . . . . . . . . . . . . 318
Group I . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 318
Group II . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 318
Group III . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 318
Mixture Proportions . . . . . . . . . . . . . . . . . . . . . . . . . . . . 318
Workability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 319
Mixing and Placing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 319
Thermal Resistance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 320
Strength. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 320
Resistance to Freezing and Thawing . . . . . . . . . . . . . . . 321
Drying Shrinkage. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 321
Expansion Joints. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 321
Autoclaved Cellular Concrete. . . . . . . . . . . . . . . . . . . . . . . 321
High-Density Concrete . . . . . . . . . . . . . . . . . . . . . . . . . . . . 321
High-Density Aggregates . . . . . . . . . . . . . . . . . . . . . . . . 322
Additions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 322
Properties of High-Density Concrete . . . . . . . . . . . . . . . 322
Proportioning, Mixing, and Placing . . . . . . . . . . . . . . . . 322
Mass Concrete . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 323
Preplaced Aggregate Concrete . . . . . . . . . . . . . . . . . . . . . . 325
No-Slump Concrete . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 325
Roller-Compacted Concrete . . . . . . . . . . . . . . . . . . . . . . . . 326
Water Control Structures . . . . . . . . . . . . . . . . . . . . . . . . . 326
Pavements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 326
Soil-Cement . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 327
Shotcrete . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 327
Shrinkage-Compensating Concrete . . . . . . . . . . . . . . . . . . 328
Pervious Concrete . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 328
White and Colored Concrete. . . . . . . . . . . . . . . . . . . . . . . . 329
White Concrete. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 329
Colored Concrete . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 329
Dry-Shake Method. . . . . . . . . . . . . . . . . . . . . . . . . . . . 329
Polymer-Portland Cement Concrete . . . . . . . . . . . . . . . . . 330
Ferrocement . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 330
References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 330
Appendix . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 335
Glossary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 335
ASTM Standards . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 341
AASHTO Standards. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 346
Metric Conversion Factors . . . . . . . . . . . . . . . . . . . . . . . . . 348
Cement and Concrete Resources . . . . . . . . . . . . . . . . . . . . 349
Index. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 351
CHAPTER 1
Fundamentals of Concrete
Concrete is basically a mixture of two components: aggregates and paste. The paste, comprised of portland cement
and water, binds the aggregates (usually sand and gravel
or crushed stone) into a rocklike mass as the paste hardens
because of the chemical reaction of the cement and water
(Fig. 1-1). Supplementary cementitious materials and
chemical admixtures may also be included in the paste.*
Aggregates are generally divided into two groups: fine
and coarse. Fine aggregates consist of natural or manufactured sand with particle sizes ranging up to 9.5 mm (38 in.);
coarse aggregates are particles retained on the 1.18 mm
(No. 16) sieve and ranging up to 150 mm (6 in.) in size. The
maximum size of coarse aggregate is typically 19 mm or
25 mm (34 in. or 1 in.). An intermediate-sized aggregate,
around 9.5 mm (38 in.), is sometimes added to improve the
overall aggregate gradation.
Cement
15%
Water
18%
Air
8%
Fine agg.
28%
Coarse agg.
31%
Mix 1
7% 14% 4%
24%
Airentrained
concrete
51%
Mix 2
15%
21%
3%
30%
31%
Mix 3
7%
16% 1%
25%
51%
Non-airentrained
concrete
Mix 4
Fig. 1-1. Concrete components: cement, water, fine aggregate and coarse aggregate, are combined to form concrete.
(55361)
* This text addresses the utilization of portland cement in the production of
concrete. The term portland cement pertains to a calcium silicate hydraulic
cement produced by heating materials containing calcium, silicon,
aluminum, and iron. The term cement used throughout the text pertains to
portland cement or blended hydraulic cement unless otherwise stated. The
term cementitious materials means portland or blended cement, used with
or without supplementary cementitious materials.
EB001
Fig. 1-3. Cross section of hardened concrete made with (left) rounded siliceous gravel and (right) crushed limestone. Cementand-water paste completely coats each aggregate particle and fills all spaces between particles. (1051, 1052)
Mixing
200
32
Casting temperature, F
52
72
92
Cement A
Cement B
100
50
10
20
30
Casting temperature, C
40
Slump, in.
Slump, mm
150
Workability
The ease of placing, consolidating, and finishing freshly
mixed concrete and the degree to which it resists segregation is called workability. Concrete should be workable but
the ingredients should not separate during transport and
handling (Fig. 1-5).
The degree of workability required for proper
placement of concrete is
controlled by the placement method, type of consolidation, and type of
concrete. Different types of
placements require different levels of workability.
Factors that influence
the workability of concrete
are: (1) the method and
duration of transportation;
(2) quantity and characteristics of cementitious materials; (3) concrete consistency (slump); (4) grading, Fig. 1-5. Workable concrete
shape, and surface texture should flow sluggishly into
place without segregation.
of fine and coarse aggre- (59292)
gates; (5) entrained air; (6)
water content; (7) concrete
and ambient air temperatures; and (8) admixtures. A uniform distribution of aggregate particles and the presence of
entrained air significantly help control segregation and
improve workability. Fig. 1-6 illustrates the effect of casting
temperature on the consistency, or slump, and potential
workability of concrete mixtures.
Properties related to workability include consistency,
segregation, mobility, pumpability, bleeding, and finishability. Consistency is considered a close indication of workability. Slump is used as a measure of the consistency or wetness
of concrete. A low-slump concrete has a stiff consistency. If
EB001
60
80
Compressive strength
100
10
15
20
25
30
Voids, %
Fig. 1-9. Effect of voids in concrete due to a lack of consolidation on modulus of elasticity, compressive strength, and
flexural strength.
4
ASTM C 403
(AASHTO T 22)
40
23C (73F)
Penetration resistance, MPa
30
Final Set
10C (50F)
20
4
3
2
10
Initial Set
0
6
8
Time, hr
10
12
1
0
14
Fig. 1-11. Initial and final set times for a concrete mixture at
different temperatures (Burg 1996).
HARDENED CONCRETE
Curing
Increase in strength with age continues provided (1) unhydrated cement is still present, (2) the concrete remains
moist or has a relative humidity above approximately 80%
(Powers 1948), (3) the concrete temperature remains favorable, and (4) sufficient space is available for hydration products to form. When the relative humidity within the concrete
drops to about 80%, or the temperature of the concrete drops
below freezing, hydration and strength gain virtually stop.
Fig. 1-12 illustrates the relationship between strength gain
and moist curing, while Fig. 1-13 illustrates the relationship
between strength gain and curing temperature.
If concrete is resaturated after a drying period, hydration is resumed and strength will again increase. However,
it is best to moist-cure concrete continuously from the time
it is placed until it has attained the desired quality; once
concrete has dried out it is difficult to resaturate. Fig. 1-14
illustrates the long-term strength gain of concrete in an
outdoor exposure. Outdoor exposures often continue to
provide moisture through ground contact and rainfall.
Indoor concretes often dry out after curing and do not
continue to gain strength (Fig. 1-12).
5
EB001
100
60
30
20
2
10
91
365
50
8000
40
6000
5000
30
4000
20
3000
2000
23/10 (73/50)
10
23/23 (73/73)
1000
32/32 (90/90)
10
Age, days
20
6000
4000
20
7d
28d
3m
1y
Age at Test
3y 5y 10y 20y
2000
0
10000
60
7000
40
12000
w/c = 0.71
80
0 7 28
14000
w/c = 0.53
50
40
w/c = 0.40
0
30
100
90
75 mm (3 in.) depth
80
45 (13/4)
20 (3/4)
6 (1/4)
70
60
50
Shrinkage, millionths
800
600
400
200
Normal-density concrete
0
0.6
0.5
Mass loss, kg
0.4
0.3
0.2
Normal-density concrete
0.1
0
75
150
225
Time of drying, days
300
375
180
160
dry faster than voluminous concrete members with relatively small surface areas (such as bridge piers).
Many other properties of hardened concrete also are
affected by its moisture content; these include elasticity,
creep, insulating value, fire resistance, abrasion resistance,
electrical conductivity, frost resistance, scaling resistance,
and resistance to alkali-aggregate reactivity.
140
28 days
120
100
80
60
40
Concrete cylinders
20
0
1
Strength
10
100
Age, days
1000
10000
EB001
80
28-day strength
Moist cured cylinders
60
10000
8000
50
40
6000
30
4000
20
2000
10
0
0.25
70
0.35
0.45
0.55
0.65
Water-cement ratio
0.75
0
0.85
Density
Conventional concrete, normally used in pavements, buildings, and other structures, has a density (unit weight) in the
range of 2200 to 2400 kg/m3 (137 to 150 lb/ft 3). The density
of concrete varies, depending on the amount and density of
the aggregate, the amount of air that is entrapped or purposely entrained, and the water and cement contents,
which in turn are influenced by the maximum size of the
aggregate. Reducing the cement paste content (increasing
aggregate volume) increases density. Values of the density
of fresh concrete are given in Table 1-1. In the design of reinforced concrete structures, the combination of conventional concrete and reinforcing steel is commonly assumed
to weigh 2400 kg/m3 (150 lb/ft 3).
8
Maximum
size of
aggregate,
mm
Air
content,
percent
Water,
kg/m3
Cement,
kg/m3
2.55
2.60
2.65
2.70
2.75
19
37.5
75
6.0
4.5
3.5
168
145
121
336
291
242
2194
2259
2307
2227
2291
2355
2259
2339
2387
2291
2371
2435
2323
2403
2467
Maximum
size of
aggregate,
in.
Air
content,
percent
Water,
lb/yd 3
Cement,
lb/yd 3
2.55
2.60
2.65
2.70
2.75
4
112
3
6.0
4.5
3.5
283
245
204
566
490
408
137
141
144
139
143
147
141
146
149
143
148
152
145
150
154
EB001
Leakage, kg/(m 2 h), average for 48 hours
50
Non-air-entrained concrete
Hydraulic permeability, cm/sec x 10 -10
30
20
0.4
0.5
0.6
0.7
Water-cement ratio, by mass
2.5
Non-air-entrained concrete
Specimens: 25 x 150-mm (1 x 6-in.)
mortar disks
Pressure: 140 kPa (20 psi)
10.0
2.0
7.5
1.5
w/c ratio: 0.80
5.0
1.0
0.0
10
0
0.3
12.5
0.5
7
14
21
Period of moist curing and age at test, days
28
0.0
0.8
Fig. 1-19. Relationship between hydraulic (water) permeability, water-cement ratio, and initial curing on concrete
specimens (Whiting 1989).
Cumulative charge, coulombs
4000
Air content
2%
4%
6%
3000
2000
1000
ASTM C 1202
0
0.2
0.3
0.4
Water to cement ratio
0.5
Abrasion Resistance
Floors, pavements, and hydraulic structures are subjected
to abrasion; therefore, in these applications concrete must
have a high abrasion resistance. Test results indicate that
abrasion resistance is closely related to the compressive
strength of concrete. Strong concrete has more resistance to
10
10
10
4
Aggregate type
Limestone
Quartzite
Traprock
Chert
20
30
40
50
60
70
Time, minutes
100
Traprock surface
treatment
Metallic aggregate
surface treatment
80
60
40
20
0
0.25 0.50 0.75 1.00 1.25 1.50 1.75 2.00 2.25 2.50
Depth of abrasion, mm
Fig. 1-23. Effect of hard steel troweling and surface treatments on the abrasion resistance of concrete (ASTM C 779).
Base slab compressive strength was 40 MPa (6000 psi) at 28
days. All slabs were steel troweled (Brinkerhoff 1970).
11
EB001
of those ingredients, interactions between the ingredients,
and placing and curing practices determine the ultimate
durability and life of the concrete.
factors, such as: (1) the amount of aggregate used; (2) properties of the aggregate; (3) size and shape of the concrete
element; (4) relative humidity and temperature of the
ambient air; (5) method of curing; (6) degree of hydration;
and (7) time.
Two basic causes of cracks in concrete are: (1) stress
due to applied loads and (2) stress due to drying shrinkage
or temperature changes when concrete is restrained.
Drying shrinkage is an inherent, unavoidable property
of concrete; therefore, properly positioned reinforcing steel
is used to reduce crack widths, or joints are used to predetermine and control the location of cracks. Thermal stress
due to fluctuations in ambient temperature also can cause
cracking, particularly at an early age.
Concrete shrinkage cracks can occur because of
restraint. When drying shrinkage occurs and there is no
restraint, the concrete does not crack. Restraint comes
from several sources. Drying shrinkage is always greater
near the surface of concrete; the moist inner portions
restrain the concrete near the surface, which can cause
cracking. Other sources of restraint are reinforcing steel
embedded in concrete, the interconnected parts of a
concrete structure, and the friction of the subgrade on
which concrete is placed.
DURABILITY
The durability of concrete may be defined as the ability of
concrete to resist weathering action, chemical attack, and
abrasion while maintaining its desired engineering properties. Different concretes require different degrees of durability depending on the exposure environment and the
properties desired. The concrete ingredients, proportioning
Alkali-Aggregate Reactivity
6000
Alkali-aggregate reactivity is a type of concrete deterioration that occurs when the active mineral constituents of
some aggregates react with the alkali hydroxides in the
concrete. The reactivity is potentially harmful only when it
produces significant expansion. Alkali-aggregate reactivity
occurs in two formsalkali-silica reaction (ASR) and
alkali-carbonate reaction (ACR). Alkali-silica reaction is of
more concern than alkali-carbonate reaction because the
occurrence of aggregates containing reactive silica minerals
is more common.
Indications of the presence of alkali-aggregate reactivity may be a network of cracks, closed or spalling joints, or
displacement of different portions of a structure (Fig. 1-27).
Because deterioration due to alkali-aggregate reaction is a
slow process, the risk of catastrophic failure is low. Alkaliaggregate reaction can cause serviceability problems and
exacerbate other deterioration mechanisms, such as those
that occur in frost, deicer, or sulfate exposures.
Current practices to control alkali-silica reactivity
include the use of supplementary cementitious materials or
blended cements proven by testing to control the reaction.
Supplementary cementitious materials include fly ash,
ground granulated blast-furnace slag, silica fume, and
natural pozzolans (Fig. 1-28). Blended cements also contain
these materials to control alkali-silica reactivity. This practice allows the use of locally available aggregates and
cementitious materials. Reduction of the alkali content of
the concrete can also control the reaction.
Use of supplementary cementitious materials or
blended cements does not control alkali-carbonate reaction.
Fortunately this reaction is rare. If aggregate testing indicates that an aggregate is susceptible to alkali-carbonate
reactivity, the reaction can be controlled through the use of
selective quarrying, aggregate blending, reducing maximum aggregate size, or using special chemical compounds
that inhibit the reaction.
5000
4000
Air-entrained
concrete
3000
Non-air-entrained
concrete
2000
1000
0
4000
3000
2000
1000
0
0.3
0.4
0.5
0.6
0.7
0.8
Water-cement ratio, by mass
0.9
13
EB001
0.7
Type II cement, alkali = 1.00%
Class F fly ash
Rhyolitic reactive aggregate
ASTM C 227 mortar bars
0.6
0.5
0.4
0.3
0.2
Failure criterion
0.1
0
10
20
30
Fly ash dosage, percent
40
Carbonation
ACI 318 building code, provides reinforcing steel cover
requirements for different exposures.
Carbonation of concrete is a process by which carbon dioxide in the ambient air penetrates the concrete and reacts
with the hydroxides, such as calcium hydroxide, to form
carbonates (Verbeck 1958). In the reaction with calcium
hydroxide, calcium carbonate is formed. Carbonation and
rapid drying of fresh concrete may affect surface durability,
but this is prevented by proper curing. Carbonation of
hardened concrete does not harm the concrete matrix.
However, carbonation significantly lowers the alkalinity
(pH) of the concrete. High alkalinity is needed to protect
embedded steel from corrosion; consequently, concrete
should be resistant to carbonation to help prevent steel
corrosion.
The amount of carbonation is significantly increased in
concrete that has a high water to cement ratio, low cement
content, short curing period, low strength, and highly
permeable (porous) paste. The depth of carbonation in
good-quality, well-cured concrete is generally of little practical significance as long as embedded steel has adequate
concrete cover (Fig. 1-29). Finished surfaces tend to have
less carbonation than formed surfaces. Carbonation of
finished surfaces is often observed to a depth of 1 to 10 mm
(0.04 to 0.4 in.) and for formed surfaces, between 2 and 20
mm (0.1 and 0.9 in.) after several years of exposure,
depending on the concrete properties, ingredients, age, and
environmental exposure (Campbell, Sturm, and Kosmatka
1991). ACI 201.2R, Guide to Durable Concrete, has more
information on atmospheric and water carbonation and the
Chemical Resistance
Portland cement concrete is resistant to most natural environments; however, concrete is sometimes exposed to
substances that can attack and cause deterioration. Concrete
in chemical manufacturing and storage facilities is especially
prone to chemical attack. The effect of sulfates and chlorides
is discussed in this chapter. Acids attack concrete by dissolving cement paste and calcareous aggregates. In addition to
using concrete with a low permeability, surface treatments can
be used to keep aggressive substances from coming in contact
with concrete. Effects of Substances on Concrete and Guide to
Protective Treatments (Kerkhoff 2001) discusses the effects of
hundreds of chemicals on concrete and provides a list of
treatments to help control chemical attack.
Sulfate Attack
Excessive amounts of sulfates in soil or water can attack
and destroy a concrete that is not properly designed.
Sulfates (for example calcium sulfate, sodium sulfate, and
magnesium sulfate) can attack concrete by reacting with
hydrated compounds in the hardened cement paste. These
reactions can induce sufficient pressure to disrupt the
cement paste, resulting in disintegration of the concrete
(loss of paste cohesion and strength). Calcium sulfate
attacks calcium aluminate hydrate and forms ettringite.
Sodium sulfate reacts with calcium hydroxide and calcium
aluminate hydrate forming ettringite and gypsum.
Magnesium sulfate attacks in a manner similar to sodium
sulfate and forms ettringite, gypsum, and also brucite