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HANDLING
PROCEDURES
CONTENT :
INTRODUCTION
BASICS OF ADSORPTION
STORAGE INSTRUCTIONS
HANDLING INSTRUCTIONS
VESSEL LOADING INSTRUCTIONS
VESSEL UNLOADING INSTRUCTIONS
DISPOSAL OF CECA ADSORBENTS
INTRODUCTION
BASICS OF ADSORPTION
Introduction
STORAGE INSTRUCTIONS
HANDLING INSTRUCTIONS
The statements, technical information and recommendations contained herein are believed to be accurate as of the date hereof. Since
the conditions and methods of use of the product and of the information referred to herein are beyond our control, ARKEMA expressly
disclaims any and all liability as to any results obtained or arising from any use of the product or reliance on such information; NO
WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESS
OR IMPLIED, IS MADE CONCERNING THE GOODS DESCRIBED OR THE INFORMATION PROVIDED HEREIN. The information provided
herein relates only to the specific product designated and may not be applicable when such product is used in combination with other
materials or in any process. The user should thoroughly test any application before commercialization. Nothing contained herein
constitutes a license to practice under any patent and it should not be construed as an inducement to infringe any patent and the user
is advised to take appropriate steps to be sure that any proposed use of the product will not result in patent infringement. See MSDS for
Health & Safety Consideration
CECA
89, boulevard National
92257 La Garenne-Colombes Cedex - France
cecachemicals.com
1/ REQUESTED EQUIPMENT
1.1/ Area
Enough space is needed around the vessels to store
the drums or big bags. As a reminder, ground surface
for 1 pallet (4 drums or 1 big bag) is about 1m2.
Moreover, some space is necessary for the loading
process : filling the hopper, crane and forklift
manoeuvres, etc.
1.2/ Hopper and loading system
Except for the bottom ceramic balls (see 5.3/below),
the products are usually loaded via a hopper.
In the case of drums, it is recommended to first pour a
few drums in the hopper, and to lift the hopper with a
crane (the hopper must be equipped with lifting
hooks).
Loading 1/7
poured
products
Cone-bottom
shaped hopper
valve
rope
sleeve
Figure 1
lifted
big bag
rope
1.3/ Crane
sleeve
Figure 2
Attached to the bottom of the hopper, or to a coneshaped system fixed to the manhole (in particular
when big bags are lifted), a long sleeve prevents the
adsorbents from falling from too high. It is a flexible
cylinder-shape piece, which diameter is at least equal
to the diameter of the bottom opening of the hopper or
cone-shaped system.
The sleeve can be made from various flexible,
resistant materials, such as any cloth, plastic films,
flexible pipes, constructions conducts, etc. Its length
Loading 2/7
2/ UTILITIES
Note : a winch can also be used instead of a ladder.
1.8/ Rake
A rake (or a rake-type tool) is needed for bed
levelling operations.
1.9/ Rulers
3/ MANPOWER
Rulers are useful to measure the level of product in
the vessel from time to time, and therefore control
its homogeneity all around the vessel after a
levelling operation. Rulers have to be long enough.
If they cannot be easily provided, they can be
replaced by scaled ropes or by tape-measures.
Note : an alternate solution is to graduate the vessel
wall in several locations on its circumference and all
along its height while the vessel is empty (for
example using a chalk).
1.10/ Stainless yarn
Stainless yarn is used when wire mesh screens are
supplied in several pieces that have to be partially
overlapped and tied together (usually for large vessel
diameters).
Note : blind rivets can also be used.
1.11/ Spare screens
For each kind of wire mesh screen in the vessel, it is
necessary to have spares (and / or spare parts). This
is true essentially for change outs, in order to be able
to immediately replace former screens if damaged,
or at least to repair them.
1
2
2
2
Loading 3/7
Bottom of distributor
Baffle
plate
with 4
holes
600 mm
mini.
Top of products
Ceramic balls 1
Floating screen
20 mesh screen*
(+ 15 cm overlap)
Manhole /
dump port
Ceramic balls layers
10 mesh screen*
I-beam supports
20 mesh screen*
Optional and strongly recommended : Hold-down ring
all around the vessel circumference, to reliably maintain
the bottom screens and ensure a suitable tightness
Figure 3
Loading 4/7
Example of a platform
Figure 4
5/ LOADING OPERATION
Loading 5/7
Loading 6/7
The statements, technical information and recommendations contained herein are believed to be accurate as of the date hereof. Since
the conditions and methods of use of the product and of the information referred to herein are beyond our control, ARKEMA expressly
disclaims any and all liability as to any results obtained or arising from any use of the product or reliance on such information; NO
WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESS
OR IMPLIED, IS MADE CONCERNING THE GOODS DESCRIBED OR THE INFORMATION PROVIDED HEREIN. The information provided
herein relates only to the specific product designated and may not be applicable when such product is used in combination with other
materials or in any process. The user should thoroughly test any application before commercialization. Nothing contained herein
constitutes a license to practice under any patent and it should not be construed as an inducement to infringe any patent and the user is
advised to take appropriate steps to be sure that any proposed use of the product will not result in patent infringement.
See MSDS for Health & Safety Consideration
CECA
89, boulevard National
92257 La Garenne-Colombes Cedex - France
cecachemicals.com
Loading 7/7
1/ SAFETY
Unloading adsorbents from a process vessel requires
a good knowledge of the application and a thorough
understanding of the possible hazards. Most of the
time, toxic and/or explosive substances are present
in the vessel at the end of the process operation
(including after the last regeneration). This can be
the regeneration medium itself (fuel gas, etc.), heavy
hydrocarbon deposit (coke), or toxic adsorbed
molecules (H2S, etc.) in some applications, when the
last regeneration is not complete or not
homogeneous. In any case safety requires absolute
caution.
1.1/ Safety equipments and concerns
Safety / PPE (Personal Protective Equipment) outfits
and fittings have to be available and used according
to the plants safety rules. Contact CECA in case
you have any question or any doubt. Equipment
typically includes :
Helmet, gloves, security shoes, dust mask, harness,
goggles, clothes with long sleeves, Breathing
Apparatus systems, portable oxygen detector.
Before any entry in the vessel, the inside has to be
checked with an appropriate device to be lower than
20% of the Lower Explosive Limit (LEL).
Unloading 1/3
Unloading 2/3
2/ UNLOADING
All internals must be removed from the adsorbent
bed (temperature probes, sampling devices, etc.)
After having performed the operations described at
chapter 1.2/ and 1.3/, the vessel can be opened and
the unloading can start.
Gravity unloading :
If gravity unloading is chosen, the bottom side
manway (or the dump port) is carefully opened to let
the product flow. A special cone-shaped piece of
metal or wood is put below the manway to direct the
flow into the bin or big bags. The flow is controlled
by adjusting the manway opening. The product flow
is important at the beginning, and slowly decreases.
After some time, no more material goes out of the
vessel, and it is necessary to complete the unloading
manually, using rakes.
Pneumatic unloading :
If a pneumatic truck is chosen, the adsorbents must
be dry. A flexible pipe is put into the vessels and
sucks the products under vacuum. Most of the time
it is necessary that one person remains in the vessel
to direct the flexible pipe. Used adsorbents are then
sent to a bin or to empty big bags. The used material
is often broken and partially reduced to fines when
going through the suction system.
Grounding of the truck is required. This method is
the fastest and the easiest one.
The statements, technical information and recommendations contained herein are believed to be accurate as of the date hereof. Since
the conditions and methods of use of the product and of the information referred to herein are beyond our control, ARKEMA expressly
disclaims any and all liability as to any results obtained or arising from any use of the product or reliance on such information; NO
WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESS
OR IMPLIED, IS MADE CONCERNING THE GOODS DESCRIBED OR THE INFORMATION PROVIDED HEREIN. The information provided
herein relates only to the specific product designated and may not be applicable when such product is used in combination with other
materials or in any process. The user should thoroughly test any application before commercialization. Nothing contained herein
constitutes a license to practice under any patent and it should not be construed as an inducement to infringe any patent and the user
is advised to take appropriate steps to be sure that any proposed use of the product will not result in patent infringement. See MSDS for
Health & Safety Consideration
CECA
89, boulevard National
92257 La Garenne-Colombes Cedex - France
cecachemicals.com
Unloading 3/3
The statements, technical information and recommendations contained herein are believed to be accurate as of the date hereof. Since
the conditions and methods of use of the product and of the information referred to herein are beyond our control, ARKEMA expressly
disclaims any and all liability as to any results obtained or arising from any use of the product or reliance on such information; NO
WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESS
OR IMPLIED, IS MADE CONCERNING THE GOODS DESCRIBED OR THE INFORMATION PROVIDED HEREIN. The information provided
herein relates only to the specific product designated and may not be applicable when such product is used in combination with other
materials or in any process. The user should thoroughly test any application before commercialization. Nothing contained herein
constitutes a license to practice under any patent and it should not be construed as an inducement to infringe any patent and the user
is advised to take appropriate steps to be sure that any proposed use of the product will not result in patent infringement. See MSDS for
Health & Safety Consideration
CECA
89, boulevard National
92257 La Garenne-Colombes Cedex - France
cecachemicals.com
Disposal 1/1