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Department of Chemistry, Arignar Anna Government Arts College, Namakkal, TN, India.
2
Texas Materials Institute, University of Texas at Austin, Austin, TX 78712, USA.
3
Dept of Physics, B.S.Abdur Rahman University, Vandalur, Chennai, TN, India.
4
Department of Chemistry, Kumaraguru College of Technology, Coimbatore, TN, India.
5*
Department of Chemistry, Chikkanna Govt. Arts college, Tripur , TN, India.
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Fig. 1 : (a) The SEM image of PMWNTs; (b) JCMWNTS (b); (c) PPMWNTs and (d)CAC
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Fig 4 : Pseudo-first order plots for adsorption of Basic Brown dye onto PMWNTs, JCMWNTs, PPMWNTs and
CAC at 30C First order
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(1)
(2)
t
1
1
(t )
2
q t k 2q e
qe
h k 2 qe2
(5)
(6)
dq t
k 1( q e qt )
dt
(3)
log(q e qt )
log(qe ) k1
t
2.303
(4)
t 1
1
(t )
qt h qe
(7)
dqt
exp( q1 )
dt
(8)
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Fig .5 : Pseudo-second order plots for adsorption of Basic Brown dye onto PMWNTs, JCMWNTs, PPMWNTs and
CAC at 30C
qt
1
1
ln( ) ln t
(9)
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Fig .6 : Elovich plots for adsorption of Basic Brown dye onto PMWNTs, JCMWNTs, PPMWNTs and CAC at 30C
(10)
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Table 3. Kinetic parameters for the removal of Basic Brown dye by the chosen adsorbents PMWNTs, JCMWNTs,
PPMWNTs and CAC at different temperatures
Table 4. Isotherm parameters for the adsorption of Basic Brown dye on to the chosen adsorbents PMWNTs,
JCMWNTs, PPMWNTs and CAC at different temperatures
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Fig. 7 : Langmuir isotherms for adsorption of Basic Brown 4 dye onto PMWNTs, JCMWNTs, PPMWNTs and CAC
(11)
(12)
RL = 1 / (1+ bLC0)
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Fig 8. Freundlich isotherms for adsorption of Basic Brown dye onto PMWNTs, JCMWNTs, PPMWNTs
and CAC
C
K c Ae
Ce
G RT ln K c
log K c
S
H
2 . 303 R 2 . 303 RT
(13)
(14)
(15)
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Fig 9: Possible adsorption sites for binding of dyes on (a) MWNTs (b) Activated carbon
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t1 / 2 0 . 03
r02
Dp
(16)
Dit 2 n 2
6 1
2 exp
2
N 1 n
r2
t
F 1
= Dir2
(19)
6 1
exp n 2 t
2 N 1 n 2
(18)
(20)
r o
C
D f
C
(17)
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= Dir
2
o
(21)
(22)
(23)
REFERENCES
Basar, C.A., Applicabilityof the various adsorption models of three dyes adsorption onto activated carbon
prepared waste apricot, J. Hazard Mater., 135, 232241 (2006). http://dx.doi.org/10.1016/
j.jhazmat.2005.11.055
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