Calculation of Stress exponent (n) at different temperature and for different sample Sn-9wt%Zn -Xw

sample 0.00 Sb%

mass
700
800
900
1000
1200
1500

strain rate
stress Mpa ln (s Mpa)
T=50
ln (de/dt)
13.65 16.42925
15.6 16.56278
17.55 16.68056 0.000025 -10.59663
19.5 16.78593 0.000028 -10.48331
23.4 16.96825 0.00003 -10.41431
29.35 17.19139 0.000233 -8.363185

T=100
0.000032
0.000049
0.000096
0.000135

ln (de/dt)
-10.34977
-9.92369
-9.251162
-8.910236

T=130
0.000103
0.000227
0.000239
0.000429

ln (de/dt)
-9.180782
-8.390561
-8.339047
-7.754054

sample 0.45 Sb%

mass
700
800
900
1000
1200
1500

strain rate
stress Mpa ln (s Mpa)
T=50
T=100
T=130
13.65 16.42925
0.000028 -10.48331 0.000141 -8.866751
15.6 16.56278
0.00009 -9.315701 0.000219 -8.426439
17.55 16.68056 0.000007 -11.8696 0.000088 -9.338174 0.000304 -8.098483
19.5 16.78593 0.00001 -11.51293 0.000158 -8.752916 0.000534 -7.535115
23.4 16.96825 0.000033
-10.319
29.35 17.19139 0.000096 -9.251162

sample 0.85 Sb%

strain rate
mass
700
800
900
1000
1200
1500

stress Mpa ln (s Mpa)

13.65 16.42925
15.6 16.56278
17.55 16.68056
19.5 16.78593
23.4 16.96825
29.35 17.19139

T=50

T=100
T=130
0.000017 -10.9823 0.000097
-9.2408
0.000037 -10.20459 0.000139 -8.881037
0.000004 -12.42922 0.00011 -9.11503 0.000319 -8.050319
0.000007 -11.8696 0.000122 -9.01149 0.000546 -7.512892
0.000027 -10.51967
0.000086 -9.361163

sample 1.45 Sb%

strain rate
mass
700
800
900
1000
1200
1500

stress Mpa ln (s Mpa)

13.65 16.42925
15.6 16.56278
17.55 16.68056
19.5 16.78593
23.4 16.96825
29.35 17.19139

T=50

0.000003
0.000005
0.000014
0.000062

T=100
T=130
0.000017 -10.9823 0.000063 -9.672376
0.000034 -10.28915 0.000133 -8.925161
-12.7169 0.000052 -9.864267 0.000197 -8.532307
-12.20607 0.000086 -9.361163 0.000242 -8.326573
-11.17645
-9.688376

fferent sample Sn-9wt%Zn -Xwt.%Sb

0.45 Sb%

323K

Ln (de/dt)

-7

Linear (323

-8

373K
f(x) = 3.6176738159x - 68.338008678
Linear (373

-9

403K
f(x) = 4.4013825208x - 82.599866123
Linear (403
f (x) = 5.3039154298x - 100.40899139

-10
-11
-12
-13
16.3 16.4 16.5 16.6 16.7 16.8 16.9 17 17.1 17.2

tempreature K
stress exponent

tempreature
stress exponent

tempreature
stress exponent

tempreature
stress exponent

323
4.1972

0.00Sb%
373
403
4.2096
3.6599

Stress exponent (n)

Ln s

Stress exponent dependence on temperature for diffe

7
0.00 Sb
%

0.45 Sb%
373
403
4.4
3.61

323
5.3

323
6.14

0.85 Sb%
373
403
5.94
5.03

323
5.95

1.45 Sb%
373
403
4.46
3.77

3
300

320

340

360

380

Temperature (K)

400

42

0.85 Sb%

323K

403K
.4013825208x - 82.599866123
Linear (403K)

-8

Linear (373K)
f(x) = 5.0297149984x - 91.9881155144
403K

-9

Linear (403K)
f(x) = 5.9422791626x - 108.5571220344

.3039154298x - 100.4089913997

f(x) = 6.1391508391x - 114.8366665728

323K
Linear (323K)

-7

373K

373K
Ln (de/dt)

373K
.6176738159x - 68.3380086789
Linear (373K)

1.45 Sb%

Linear (323K)

-7

Linear (323K)

323K

Ln (de /dt)

45 Sb%

-8

Linear (373K)

-9

403K
f(x) = 3.7735410786x - 71.5600930407
Linear (403K)

-10

f(x) = 4.4593115245x - 84.214030372

f (x) = 5.9521426364x - 112.0770430055

-10
-11
-11

-12

-12

6 16.7 16.8 16.9 17 17.1 17.2 17.3

-13
16.3 16.4 16.5 16.6 16.7 16.8 16.9 17 17.1 17.2 17.3

-14
16.3 16.4 16.5 16.6 16.7 16.8 16.9 17 17.1 17.2 17.3

Ln s

Ln s

Ln s

onent dependence on temperature for different samples Sn-9wt.%Zn-Xwt.%Sb

0.00 Sb
%

340

360

380

Temperature (K)

400

420

-13

1.45 Sb%

323K

0.00 Sb%

Linear (323K)
373K

-7

Linear (373K)

-7.5

403K
= 3.7735410786x - 71.5600930407
Linear (403K)

-8
-8.5
Ln (de/dt)

= 4.4593115245x - 84.214030372
= 5.9521426364x - 112.0770430055

-9

323K
Linear (323K)
373K
Linear (373K)
403K
f(x) = 3.6599403228x - 69.2246649742
Linear (403K)
f(x) = 4.2095756033x - 81.1336865827
f(x) = 4.1972383785x - 79.344278446

-9.5
-10
-10.5

16.6 16.7 16.8 16.9 17 17.1 17.2 17.3

Ln s

-11
16.3 16.4 16.5 16.6 16.7 16.8 16.9 17 17.1 17.2 17.3
Ln s

-7

fig (6)
0.45 Sb
Linear
(0.45
f(x) Sb
= 3.6176738159x
5.0297149984x
91.9881155144
)
f(x)
=
-- 68.3380086789

Ln (de/dt)

-8

f(x) = 3.6599403228x - 69.2246649742

f(x) = 3.7735410786x - 71.5600930407

-9

-10
16.4 16.45 16.5 16.55 16.6 16.65 16.7 16.75 16.8 16.85
Ln s

3
300

45

activation energy (kJ/mol)

Stres s exponent (n)

0.00 Sb
%
0.45 Sb
%

17.55
MPa

40

35

30

25

20
320

340
360
380
Tem perature (K)

400

420

fig. (
):-Stress exponent dependence
on temperature for different samples
Sn-9Zn%-X Sb%

0.2

0.4

0.6 0.8
1
Sb content

1.2

1.4

1.6

fig.( ) relation between the Sb content

and its activation energy of their samples

0.00 Sb%
-5

-7

17.55 MPa

17.55
f(x) =-8 - 6.4993079574x + 8.6241665367
MPa
f(x) = - 6.1305255046x + 7.1072174772
-9

ln (de/dt)

ln (de/dt)

0.45 Sb%

Linear
(17.55
MPa)

-6
-7

f(x) = - 6.0257980369x + 8.1276761494

-8

-10

-9

-11

-10

-12
-13
2.4

f(x) = - 5.9815838056x + 7.1392975789

-11
-12

2.6

2.8
1000/T

3.2

2.4

2.6

2.8
1000/T

3.2

0.85 Sb%

1.45 Sb%
-7

-7

17.55 MPa

17.55 MPa
-8

f(x) = - 7.0582332321x + 9.96507965

-8
f(x) = - 6.3946990556x + 7.6385682607
f(x) = - 6.8265074198x + 8.4278802441

-9

ln (de/dt)

ln (de/dt)

f(x) = - 7.2554273666x + 10.1077210593

-9

-10
-10
-11
-11
-12
-12

-13

-14

-13
2.4

2.6

2.8
1000/T

3.2

2.4

2.6

2.8
1000/T

3.2