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Faculty of Engineering, University of Technology, Sydney, P.O. Box 123 Broadway, NSW 2007, Australia
b
Department of Environmental Engineering, Pusan National University, Busan, 609-735, Korea
Tel. +82 (51) 510-2769; Fax +82 (51) 515-5347; email: cwkim@pusan.ac.kr
c
LIPE/INSA, 135 Avenue de Rangueil, 31078 Toulouse Cedex 04, France
d
NanoEntech, 7F Seogeon B/D, 1480 Gwanyang-dong, Dongan-gu, Anyang, Gyeonggi, Korea
Abstract
The conventional treatment for production of drinking water from surface water generally consists of coagulation,
flocculation, sedimentation and sand filtration. One of the main disadvantages of the conventional process combining
sedimentation and filtration is the rather long residence time. This is mostly due to the flocculation and sedimentation
phases (typically 2 h). The fiber filter recently developed has been very successful for the tertiary treatment of
biologically treated sewage effluents (more than 2 millions m3/d treated by this technology in Korea). In this paper,
a different application of this filter to drinking water production was tested. In this case, the fiber filter (with in-line
coagulation) was used as an alternative to the process of flocculation and sedimentation. Even though the first
design of the fiber filter showed good removal efficiency, the filter was modified in order to improve its performance
commensurate with the tightening of regulation on the water quality regulation. In this study, the filtration efficiency
of the newly designed filter was estimated using a range of filtration velocities from 60 to 100 m/h and a small
dosage of coagulant (13 mg/L) injected in-line. The polymeric coagulant (PAC: 11% as Al2O3) was used during
this experiment. The optimal operation conditions were determined based on the performance and filtration time.
Through these experiments, it was shown that the new fiber filter design was very efficient for particle removal at
a filtration velocity of 60 m/h (1500 m3/d) and 1 mg/L coagulant dosage, and these were considered as the optimal
operating conditions. Through the direct suspended solids (SS) measurement it was verified that backwash efficiencies
were also very good.
Keywords: Deep bed fiber filtration; Fiber filter; In-line coagulation; Surface water treatment; Alternative to the
process of flocculationsedimentation for water treatment
*Corresponding author.
Presented atInternational Workshop on Membranes and SolidLiquid Separation Processes, INSA-Toulouse, France
11 July 2007
0011-9164/08/$ See front matter 2008 Elsevier B.V. All rights reserved
doi:10.1016/j.desal.2007.11.051
324
1. Introduction
When producing drinking water from surface
water, coagulation, flocculation and sedimentation processes are generally applied [1]. This is
the case not only for removing most of the suspended solids which could clog the filter and
shorten the filtration period, but also for removing undesired organic and inorganic pollutants and
particles causing the color of potential sources of
organic-chlorinated compounds [2,3]. In place of
coagulation, flocculation and sedimentation, direct filtration (in-line coagulation ahead of a dual
media filter) has already been proposed [4,5].
However, due to rather small porosity of sand filters, this was limited to the treatment of raw water with low turbidity (dams, for instance).
The fiber filter has been developed recently,
and its efficacy for the tertiary treatment of wastewater has been proved during the last few years.
Several wastewater treatment plants (more than
2 million m3/d) in Korea are now equipped with
the fiber filter for obtaining treated water of high
quality (turbidity less than 2 NTU, COD less than
10 ppm) [6]. More recent results have shown that
this fiber filter could be used for drinking water
production [7]: not as an alternative to the sand
filter, but as an alternative to the coagulation, flocculation, and sedimentation process).
Even though the results obtained were quite
good, the design of the filter was modified in order to improve the performance for complying
with the stricter water quality regulation.
In this paper, a field-scale version of the modified filter was operated with an in-line injection
of a coagulant for the treatment of natural surface
water (Nak-dong River). Polymeric aluminum
chloride (PAC) (11% as Al2O3) was selected as
coagulant on the basis of a previous study [7].
The filtration efficiency was measured in a range
of filtration velocities, from 60 (1500 m3/d) to
100 m/h (2400 m3/d) and PAC dosages (from 1 to
3 mg/L). Through these experiments, it was expected that the optimal operation conditions would
be determined. A mass balance of SS could be
made thus allowing a direct estimation of the effectiveness of the backwashing process.
2. Materials and methods
2.1. Field-scale fiber filter plant
A field-scale fiber filter with an inside diameter of 650 mm and a height of 1500 mm was
installed as shown in Fig. 1.
Polyamide (nylon) fibers of 30 m were used
as filter media. The packing density of the fiber
was 80 kg/m3 and the porosity was 93%. The filter media was packed parallel to the vertical axis
of the fiber filter and the U-shaped bundles of fibers were fixed to a perforated plate at the bottom
of the filter. The filtration direction was partly
radial from the periphery of the filter in its lower
part to the axial perforated tube collecting the
treated water. Coagulants were directly injected
by a peristaltic pump to the feed pipe through a
static mixer. Coagulation began inside the inlet
pipe and the two phenomena of floc growth and
retention occurred inside the filter.
2.2. Materials
Nak-dong River water was used as influent
water without pre-treatment. The turbidity of the
water ranged from 6.5 to 11.5 NTU, and the chlorophyll-a (characteristics of algae) concentration
was between 11.5 and 41.2 g/L during the study
period. The pH was not controlled as it varied in
a proper range for coagulation with an average
value of 7.2.
PAC (11% as Al2O3) (poly aluminum chloride,
[Al2(OH)nCl6n]m) was selected as the coagulant
based on a previous study [7].
2.3. Operating conditions
To determine the proper coagulant dosage, an
initial experiment was conducted at a filtration
velocity of 80 m/h, which has been previously
identified in the mid-range of velocity suited for
drinking water production [7]. The coagulant dos-
325
Backwashing Water
Valve-3
Filtrate Water
Valve-2
On- line
turbidity meter
In- line
injection
Coagulant
Static inline
mixer
Compressor
Raw water
Air
receive
tank
Air
Nak- dong
river
Valve-1
and 100 m/h (the maximum filtration velocity allowed by the influent pump) were used in this
experiment. Each filtration velocity was tested to
evaluate its effect on the effluent turbidity and
filtration run time until turbidity breakthrough.
2.4. Backwashing conditions
General filtration processes are divided into
filtration and backwashing processes. Backwash
process is used to recover the retention capacity
of the filter. Filter backwashing, based on the collapse-pulsing phenomenon studied by A. Amirtha-
326
Table 1
The values of the coagulants dosages during this study
Filtration velocity
Coagulants
PAC (mg/L)( 11% as Al2O3)
80 m/h
0
1
1.5
2
2.5
3
ventional coagulation, flocculation and sedimentation system. The second advantage is the smaller
dosage of coagulant compared to the actual dosage in the existing plants. For a turbidity of the
raw water of about 10 NTU, the present coagulant dosage (PAC: 11% as Al2O3) is in the range
1020 mg/L.
3.1. Determination of the optimal coagulant dosage
3.1.1. Filtration duration time and effluent
turbidity
Table 2
Backwashing conditions with air and water injection times
Total backwashing time: 5 min 43 s (343 s)
Numbers of backwashing stages:
14 times
Rinsing
Air
Water
Water
7s
15 s
35 s
Table 3
Filtration time till reaching the turbidity of 1 NTU in the
treated water
Coagulant dosage (mg/L)
1.5
100 80
2.5 3
60
50
50
327
filter due to the precipitation of aluminum hydroxide. This explains the decrease of filtration time.
A filtration time of 100 min corresponds to
about 130 times the hydraulic residence time
(HRT) in the filter. This value is similar to the
value observed in conventional sand filters for
which the residence time is about 10 min.
328
14
12
90
70
80
Removal efficiency(%)
SS(mg/L)
10
60
2
0
50
0
0.5
1.5
2.5
Coagulant dosage(mg/L)
IN
OUT
Efficiency
0.30
0.25
6
0.20
5
4
0.15
0.10
P re s s u re (k g f/c m 2 )
Backwashing period
T u rb id ity (N T U )
329
145 min.
0.05
set 1
0
0
160min.
60
120
set 2
180
240
300
0.00
360
Sampling time(min)
Influent
Effluent
Pressure
Table 4
Variation of productivity with filtration velocity
Filtration velocity
(m/h)
Productivity
(m3/h)
Productivity
(m3/m2d)
60
80
100
18.2
24.2
30.2
1320
1750
2200
330
Table 5
Calculation of the detached suspended solids after backwashing at each set for the continuous operation
Set 1
(First filtration)
Set 2
(Second filtration
after first backwash)
Set 3
(Third filtration after
second backwash)
160 min
412 g
47 g
365 g
180 min
444 g
56 g
388 g + 1 g= 389 g
175 min
440 g
60 g
380 g + 3 g = 383 g
364 g
1g
(0.3% of mass of
SS in filter)
386 g
3g
(0.7% of mass of
SS in filter)
381 g
2g
(0.5% of mass of SS in
filter)
0.35
T u rb id ity (N T U )
0.25
0.20
4
0.15
0.10
160 min
180 min
P re s s u re (k g f/c m )
0.30
175 min
0.05
0
0
110
220
330
440
0.00
550
Sampling time(min)
Influent
Effluent
Pressure
4. Conclusion
The following conclusions were drawn for a
better adaptation of the filter to the production of
331
95100.
[5] W. Doyen, R. Vandaele, B. Molenberghs, J. Cromphout, P. Bielen and B. Baee, Description of different effects of in-line coagulation upon semi-deadend ultrafiltration, Water Sci. Technol.: Water Supply, 3 (2002) 337344.
[6] R. Ben Aim, K.B. Han, H.J. Woo, P. Marteil, J.H.
Im, C.W. Kim and M.H. Hwang, An innovative deep
bed filter for the tertiary treatment of wastewater.
Proc. World Filtration Congress, New Orleans, USA,
2004.
[7] J.J. Lee, M.K. Jeong, J.H. Im, R. Ben Aim, S.H.
Lee, J.E. Oh, H.J. Woo and C.W. Kim, Enhancing
flexible fiber filter (3FM) performance using in-line
coagulation. Water Sci. Technol., 53(7) (2006) 59
66.
[8] A. Amirtharajah, N. McNelly, G. Page and J.
McLeod, Optimum backwash of dual media filters
and GAC filter-adsorbers with air scour. AWWA
Research Foundation, Denver, Colorado, USA,
1991, pp. 4974.
[9] A. Amirtharajah and D.P. Wetstein, Initial degradation of effluent quality during. J. AWWA, 72 (1980)
518524.
[10] J.J. Lee, J.H. Im, R. Ben Aim, K.B. Han, C.W. Kim
and H.J. Woo, Better understanding of the filtration
characteristics in 3FM (flexible fiber filter module).
Water Sci. Technol., 55 (2007) 7783.