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11. A gas occupies a volume of 410 mL at 27 oC and 740 mm Hg pressure. Calculate the
volume the gas would occupy at STP.
= V2 = = = 363 mL
15. A 775 mL sample of NO2 gas is at STP. If the volume changes to 615 mL and temperature to
25 oC, what will be the new pressure?
P2 = = = 1.38 atm
19. A mixture contains H2 at 600. torr pressure, N2 at 200. torr pressure, and O2 at 300. torr
pressure. What is the total pressure of the gases in the system?
Ptot = P1 + P2 + P3 = 600. torr + 200. torr + 300. torr = 1100. torr
27. How many grams of NH3 are present in 725 mL of the gas at STP?
PV = nRT n = = = 0.0324 mol
0.0324 mol x = 0.552 g NH3.
35. Calculate the density of the following:
a) F2 gas at STP. d= x = 1.70 g/L
b) F2 gas at 27 oC and 1.00 atm. Calculate new volume:
V2 = = = 24.6 L
d= x = 1.54 g/L
43. In the lab, students generated and collected H2 gas according to the following equation:
Zn(s) + H2SO4(aq) H2(g) + ZnSO4(aq)
3.
Which of the substances listed below are reasonably soluble, and which are insoluble in
water?
a) KOH all potassium compounds are soluble; b) NiCl2 most chlorides are
soluble, c) ZnS most sulfides are insoluble, d) AgC 2H3O2 all acetates are
soluble, e) Na2CrO4 all sodium compounds are soluble.
a) 15.0 g KCl + 100.0 g H2O. (15.0 g KCl / 115 g solution) x 100 = 13.0 % KCl
b) 2.50 g Na3PO4 + 10.0 g H2O. (2.50 g / 12.5 g solution) x 100 = 20 % Na3PO4
c) 0.20 mol NH4C2H3O2 + 125 g H2O.
0.20 mol NH4C2H3O2 x = 15.4 g NH4C2H3O2
(15.4 g NH4C2H3O2/ 140.4 g solution) x 100 = 11.0 % NH4C2H3O2.
d) 1.50 mol NaOH in 33.0 mol H2O.
1.50 mol NaOH x = 60.0 g NaOH
33.0 mol H2O x = 595 g H2O.
(60.0 g NaOH / 655 g solution) x 100 = 9.16 % NaOH.
21. What will be the molarity of the resulting solutions made by mixing the following?
Assume that the volumes are additive.
a) 125 mL of 0.5 M H3PO4 with 775 mL of H2O. V1M1 = V2M2,
M2 = = = 0.0694 M.
b) 250 mL of 0.25 M Na2SO4 with 750 mL of H2O.
M2 = = = 0.0625 M.
c) 75 mL of 0.50 M HNO3 with 75 mL of 1.5 M HNO3.
0.075 mL x 0.50 mol/L = 0.0375 mol
0.075 mL x 1.5 mol/L = 0.1125 mol
total = 0.15 mol HNO3.
0.15 mol / 0.150 L = 1 mol/L = 1 M.
27. Use the equation to calculte the following:
3 Ca(NO3)2(aq) + 2 Na3PO4(aq) Ca3(PO4)2(s) + 6 NaNO3(aq)
molar mass 94.97 po4 Na3PO4: 163.9 Ca3(PO4)2: 310.2
a) the moles Ca3(PO4)2 produced from 2.7 mol Na3PO4.
2.7 mol Na3PO4 x = 1 4 mol Ca3(PO4)2
b) the moles NaNO3 produced from 0.75 mol Ca(NO3)2.
0.75 mol Ca(NO3)2 x = 2.25 mol NaNO3.
c) the moles Na3PO4 required to react with 1.45 L of 0.225 M Ca(NO3)2.
1.45 L x 0.225 mol Ca(NO3)2 / 1L = 0.326 mol Ca(NO3)2.
0.326 mol Ca(NO3)2. x = 0.218 mol Na3PO4.
33. What is the (a) molality, (b) freezing point and (c) boiling point of a solution
contaning 2.68g of naphthalene in 38.4 g benzene?
Molar mass: naphthalene: 128.2, benzene: 78.1
a)
x x = 0.544 m.
c)
tb = 0.544 m x 2.53 (oC kg bnz/mol npht) = 1.38 oC;
tb = 80.1 + 1.38 = 81.4 oC.
b)
tf = 0.544 m x 5.1 (oC kg bnz/mol npht) = 2.77 oC;
tf = 5.5 oC 2.77 oC = 2.7 oC.