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CONTENT
No.
Title
5.1
5.2
Food Additives
5.3
Medicine
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Page
Soap is a salt of a compound known as a fatty acid. A soap molecule consists of a long
hydrocarbon chain (composed of carbons and hydrogen) with a carboxylic acid group on one end
which is ionic bonded to a metal ion, usually a sodium or potassium. The hydrocarbon end is non
polar and is soluble in non polar substances (such as fats and oils), and the ionic end (the salt of a
carboxylic acid) is soluble in water.
Soaps can be made from animal fats and vegetable oils. The animal fats most commonly used
are fats from cows and goats. The vegetable oils often used are palm oil, olive oil and coconut
oil. Soaps are prepared by hydrolyzing fats or oils under alkaline condition. The reaction is
called saponification. This process involves boiling fats or oils with concentrated sodium
hydroxide solution or concentrated potassium hydroxide solution to produce glycerol and the
salts of fatty acids which are soaps.
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Sodium palmitate
1. The fats or oils are hydrolysed first to form glycerol and fatty acids. The soap produced
can be precipitated by adding common salt (sodium chloride) to the reaction mixture.
2. The sodium chloride added reduced the solubility of soap in water. As a result, precipitation of
soap occurs.
3. The properties of soap depend on :
a) The type of alkali used for saponification
b) The type of animal fats or vegetable oils used.
4. Soaps produced from sodium hydroxide are hard, whereas soaps produced from potassium
hydroxide are soft.
5. Animal fats (tallow) from cows and vegetable oils (such as palm oil or olive oil) ae used for
making soap.
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Detergent
1. Detergents are synthetic cleansing agents made from hydrocarbons obtained from petroleum
fractions. Thus, detergents are petrochemicals. Detergents are usually sodium salts of sulphuric
acid.
2. Detergents can be classified into three main types, depending on the charge on the detergent ion.
a) Anionic detergents where the head of the detergent particle contains a negatively charged
ion.
Negatively
Example: R O SO3-Na+ (Sodium alkyl sulphate)
charged ion
b) Cationic detergents where the head of the detergent particle contains a positively charged
ion.
Positively
Example: R N (CH3)3+BRcharged ion
Preparation of detergents
1. The detergent, sodium alkyl sulphate can be prepared from alcohols with chain lengths of 12 to
18 carbon atoms in two steps.
Steps 1: Reaction with concentrated sulphuric acid
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a) Step 1 : Alkylation
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c) Mechanical agitation during scrubbing helps to pull the grease free and also break the
grease into small droplets
d) The droplets do not coagulate and redeposit on the surface of the cloth due to the
repulsion between the negative charges on their surface.
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2) The cleansing action of soap or detergent depends on their chemical bonding and structures.
a) The ionic head (negatively charged) is soluble in water (hydrophilic) but insoluble in
oily layer.
b) The long hydrocarbon tail (neutral) is insoluble in water (hydrophobic) but soluble in
oily layer.
3) Oil cannot be washed away from clothing with water because oil (a covalent molecult0 is
insoluble in water.
4) Lifting greasy dirt from the surface cloth. When soap or detergent is added to the dirty surface of
a piece of cloth covered with a layer of oil or grease.
a) The negatively charged head (hydrophilic) of soap ions or detergent ions dissolves in
water.
b) The hydrocarbon tail (hydrophobic) of soap or detergent ions dissolves in the layer of
grease.
5) The water is agitated slightly; the grease begins to be lifted off the surface. This cause by the
forces of attraction between the water molecules and the negatively charged heads.
6) On further agitation during washing, the greasy dirt is lifted from the surface.
7) Emulsifying dirt in water
a) Soaps and detergents can act as emulsifying agents to emulsify oils and grease.
b) The process of emulsification breaks large drops of grease into smaller droplets that
floats in water. The greasy droplets repel on another because they carry the same charge.
As a result, the grease is suspended in the solution.
c) When the cloth is rinsed with the water, the droplet will be carried away.
d) The cleaning process become more efficient in the water containing the soap or detergent
solution is stirred
Property
Soap
Detergent
Cleaning power
Less powerfull
More powerfull
Ease of rinsing
Molecular structure
Formation of scum
pH
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Food Additives
Uses of food additives
Effects on health
Allergy: MSG
Carcinogenic: NaNO
Brain damage
Hyperactivity
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Example
Amylases, proteases,
cellulases
Sodium perborate
Optical whitener
Fluorescent dyes
Builder
Sodium tripolyphosphate
Suspension agent
carboxymethylcellulose
Filler
Silicones
Fragrance
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Function
To remove protein
stains such as blood
To convert stains into
colourless substances
To add brightness and
whiteness to white
fabrics
To enhance the
cleaning efficiency of
detergent by softening
the water
To prevent the dirt
particles removed from
redepositing onto
cleaned fabrics.
To add to tha bulk of the
detergents and enable it
to be poured easily
To control foaming in
detergent
To add fragrance to
both detergent and
fabrics
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B. Antioxidants: Vitamin and minerals is important additive they help to prevent fats from turning
rancid and also may protect against cancer, heart disease, and other diseases.
Beta carotene, Caramel, Carrot oil, Citrus red # 1, Dehydrated beets, FD&C
colors: Blue # 1, 2: Red # 3, 40; Yellow # 5, 6 - used in processed foods,
especially sweets and products marketed for children, soft drinks, baked goods,
frosting, jams, and margarine.
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Personal advices
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MEDICINE
A medicine is a substances used to prevent or cure disease or to reduce pain and
suffering due to illness. It can be classified into tradisional medicines and modern
medicines.
Traditional Medicine
Local name
Uses
Aloe vera
Lidah buaya
Betel
Sireh
Bitter gourd
Peria
Coconut
Kelapa
Garlic
Bawang putih
Ginger
Halia
Ginseng
Ginseng
Hibiscus
Bunga Raya
Turmeric
Kunyit
Cures pimples
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Functions
To treat Japanese encephalitis and hole in the
heart.
To threat lockjaw and convulsion.
To treat hepatitis B
Modern Medicine
Type of modern
medicine
Function
Examples
Analgesics-medicines
used to relieve pain
without causing
numbness of affecting
consciousness.
Aspirin, paracetamol
Antibiotics-used to kill
or slow down the
growth of bacteria.
Penicillin, streptomycin
Psychotherapeutic
medicines- used to
alter abnormal thinking,
feelings or behavior.
Stimulants,
antidepressants,
antipsychotic
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Drug abuse
Drug abuse, also called substance abuse or chemical abuse, is a disorder that is characterized by a
destructive pattern of using a substance that leads to significant problems or distress. It affects more
than 7% of people at some point in their lives. Teens are increasingly engaging in prescription drug
abuse, particularly narcotics (which are prescribed to relieve severe pain), and stimulant
medications, which treat conditions like attention deficit disorder.
Alcohol: Although legal, alcohol is a toxic substance, particularly to a developing fetus when a
mother consumes this drug during pregnancy.
Amphetamines: This group of drugs comes in many forms, from prescription medications
like methylphenidate (Ritalin, Concerta) anddextroamphetamine and amphetamine (Adderall) to
illegally manufactured drugs like methamphetamine ("meth"). Overdose of any of these
substances can result in seizure and death.
Anabolic steroids: A group of substances abused by bodybuilders and other athletes, this group
of drugs can lead to terrible psychological effects like aggression and paranoia, as well as
devastating long-term physical effects like infertility and organ failure.
Caffeine: While it is consumed by many, coffee, tea and soda drinkers, when consumed in
excess this substance can produce palpitations,insomnia, tremors and significant anxiety.
Cannabis: More commonly called marijuana, the scientific name for cannabis is
tetrahydrocannabinol (THC). In addition to the negative effects the drug itself can produce (for
example, infertility, paranoia, lack of motivation), the fact that it is commonly mixed ("cut") with
other substances so drug dealers can make more money selling the diluted substance or expose
the user to more addictive drugs exposes the marijuana user to the dangers associated with
those added substances. Examples of ingredients that marijuana is commonly cut with include
baby powder, oregano, embalming fluid, PCP, opiates, and cocaine.
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Cocaine: A drug that tends to stimulate the nervous system, cocaine can be snorted in powder
form, smoked when in the form of rocks (crack cocaine), or injected when made into a liquid.
Hallucinogens: Examples include LSD and mescaline, as well as so-called naturally occurring
hallucinogens like certain mushrooms, these drugs can be dangerous in their ability to alter the
perceptions of the user. For example, a person who is intoxicated with a hallucinogen may
perceive danger where there is none and to think that situations that are truly dangerous are not.
Those misperceptions can result in dangerous behaviors (like jumping out of a window because
the individual thinks they are riding on an elephant that can fly).
Inhalants: One of the most commonly abused group of substances due to its accessibility,
inhalants are usually contained in household cleaners, like ammonia, bleach, and other
substances that emit fumes. Brain damage, even to the point of death, can result from using an
inhalant just once or over the course of time, depending on the individual.
Nicotine: The addictive substance found in cigarettes, nicotine is actually one of the most habitforming substances that exists. In fact, nicotine addiction is often compared to the intense
addictiveness associated with opiates like heroin.
Opiates: This group is also called narcotics and includes drugs like heroine, codeine, Vicodin,
Percocet, and Percodan. This group of substances sharply decrease the functioning of the
nervous system. The lethality of opiates is often the result of the abuser having to use
increasingly higher amounts to achieve the same level of intoxication, ultimately to the point that
the dose needed to get high is the same as the dose that is lethal for that individual by halting the
person's breathing (respiratory arrest).
Phencyclidine: Commonly referred to as PCP, this drug can cause the user to feel extremely
paranoid, become quite aggressive and to have an unusual amount of physical strength. This can
make the individual quite dangerous to others.
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