01.

What is the formal charge on the O atom in H3O

ion?
a.1
b.2
c.3
d.4

(1)CH3COOH,
(2)CH3OH
(3)CH3CHO
(4)CH3CONH2
(5)CH3NH2
a.1 with 2
b.1 with 3
c.1 with 4
d.1 with 5

02.Arrange the following bonds from lowest to

highest polarity: C-F, C-C, and C-Cl.
a.C-Cl<C-C<C-C-F
b.C-F<C-Cl<C-C
c.C-C<C-Cl<C-F
d.They have the same polarity.

10.When benzene reacts with chlorine, a(n)

_________ reaction occurs whereas when
cyclohexene reacts with chlorine a(n) __________
reaction occurs.
a.oxidation, reduction
b.addition, oxidation
c.substitution, oxidation
d.substitution, addition

03.According to VSEPR model, what is your

prediction the arrangement of electron pairs for CH3-?
a.linear
b.tetrahedral
c.bent
d.trigonal
04.Which of the following react most readily with
Br2?
a.Straight chain alkanes
b.Branched alkanes
c.Alkenes
d.Aromatic Compounds
05.Oxidation of which of the following compounds
can lead to an aldehyde?
a.primary alcohol
b.secondary alcohol
c.tertiary alcohol
d.ether
06.Hydrolysis of an ester leads to two compounds.
Which of the following pairs compounds is form
from such hydrolysis?
a.An alcohol and an aldehyde
b.Two alcohols
c.An alcohol and a carboxylic acid
d.A ketone and a carboxylic acid
07.Which of the following is the best definition of the
chemical nature soap?
a.A soap is a very long molecule.
b.A soap is a long chain carboxylic acid.
c.A soap is an ester of glycerol and a long chain
carboxylic acid.
d.A soap is a salt of a long chain carboxylic acid.
08.The reaction of methane with chlorine to form
methyl chloride follows a free radical chain reaction
mechanism. The first step in this reaction mechanism
is
a.abstraction of a hydrogen from a methane molecule
by a chlorine molecule.
b.homolytic splitting of the chlorine molecule into
chlorine atoms.
c.photochemical splitting of one of the C-H bonds in
methane.
d.reaction of a hydrogen from methane with a
chlorine molecule to form HCl which then catalyzes
then catalyzes the reaction.
09.To form an amide, you would best advised to react
which of the following?

11.Which conditions will convert pentanoic acid to

pentanoyl chloride?
a.HCl
b.NaCl
c.SOCl2
d.LiAlH4 followed by HCl
12.Which compounds will yield benzoic acid when
hydrolysed?
I) Benzyl Ethanoate
II)Benzamide
III) Phenyl Ethanoate
IV)Methyl Benzoate
a.I,II
b.III,IV
c.I,III
d.II,IV
13.How many cycloalkanes of molecular formula
C6H12 do not show cis-trans isomerization?
a.2
b.3
c.4
d.5
14.Which reagents react with an alkene in a
Markovnikov orientation?
I)HBr II)H2O/H2SO4
III)Br2
IV)OsO4/ROOH
a.I,II
b.III,IV
c.II,IV
d.II,III,IV
15.Rank the following substituents with increasing
priority.
I) OH
II)-Cl
III)-CH3
IV)-H
a.I,III,II,IV
b.II,I,III,IV
c.III,I,II,IV
d.IV,III,I,II
16.Arrange the amines in order of increasing boiling
point (lowest first).

a.II,III,I,IV
b.III,I,IV,II
c.IV,II,III,I
d.IV,III,I,II

22.Which structures are aromatic?

17.Which is the classification of the following

amine?
a.II,III
b.III,IV
c.I,III
d.II,IV
a.10
b.20
c.30
d.40

23.Which is the electrophile in the nitration of

benzene?

18.Which is the name of the following compound?

24.Which is the major product of the following
reaction?

a.4-carboxy aniline
b.1-amino-4-carboxybenzene
c.benzylamide carboxylic acid
d.4-aminobenzoic acid
19.Arrange the amines in order of increasing boiling
point.
I)methylamine II)ethylamine
III)propylamine IV)cyclohexylamine
a.IV,III,II,I
b.I,II,III,IV
c.III,II,I,IV
d.II,I,IV,III
20.Arrange the amines in order of increasing
solubility in water.
I)ethylamine II)methylamine
III)propylamine IV)cyclohexylamine
a.II,I,III,IV
b.IV,II,III,I
c.IV,III,I,II
d.I,III,II,IV
21.Arrange the amines in order of increasing basicity
(weakest first).

a.IV,II,III,I
b.II,I.III.IV
c.I,II,III,IV
d.II,I,IV,III

25.Which is the IUPAC name for the following

structure?