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BY
LOHIT LEE PAIS
VIII SEM CIVIL,
S.J.C.E.,
MYSORE 570006.
ABSTRACT:
Due to sustained pressure of industrial and developmental activities, there is
appreciable disturbance in the ecological balance of nature and there is a rapid increase in
geo-environmental pollution. The concept of environmental geotechnics has emerged as an
answer to the need to understand and to characterize these multidisciplinary problems.
This paper highlights the scope of environmental geotechnics. It discusses, in particular,
the problems connected with Fly ash.
Fly ash is an industrial waste coming out of thermal power plants and the disposal
of it is a serious problem. The problem is very serious as fly ash is a very fine particle
having fineness of about 4000-8000 cm2/g and many a times, it even contains traces of
heavy metals. The present paper illustrates varied problems posed by fly ash to human
settlement as well as to the environment. It deals with the characterization of fly ash from
the point of view of geotechnical engineering, which is very much essential for the
planning of its safe disposal. It also discusses various remedial measures that are currently
being practiced all over the world to over come the geo-environmental problems posed by
fly ash and its disposal.
FLYASH
Fly ash is an industrial waste coming out of thermal power plants and the disposal
of it is a serious and continuously growing problem. So, one is compelled to find out easy
and low cost techniques to curb this problem. This is where the concept of sustainable
development has to be taken into account.
The current paper is aimed at presenting varied problems posed by fly ash to the
global environment and the engineering characterization of fly ash, which is needed for
effectively planning the safe disposal of fly ash. The paper also discusses different
remedial measures that are being practiced world wide to negotiate the geo-environmental
problem posed by fly ash and its disposal.
The rapid pace of industrialization has resulted in a large number of thermal power
plants, not only India, but also in other countries, to meet the domestic and industrial
energy requirements. Flyash is a waste product from these power stations and it is
estimated that about 100 million tones of flyash is produced as a by-product annually in
India only. Most of the ash generated from the power plants is disposed off in the vicinity
of the plants as a waste material covering vast area of valuable land. In India, the problem
of handling and disposal of coal ash is more complex due to high ash content (i.e., 30% to
50%) in coal.
The World Bank has cautioned India that by 2015, disposal of coal ash would
require 1000 square kilometers or one square meter of land per person, in its report on
environmental issues in the power sector. The coal ash thus stored affects the ecology of
the land, water and air in the region. Fly ash is reported to cause ailments like allergic
bronchitis, silicosis, and asthma. Besides, fly ash contaminates surface water and may also
have an effect on underground water, affects the aquatic life, is harmful for plants, and
corrodes exposed metallic structures in its vicinity. Studies by health authorities at
Santhaldih, in Purulia district of West Bengal, show that a large number of people in the
area are victims of lung infections and skin disease, caused by fly ash contamination of air
and water. The problem is a very serious one as fly ash is a very fine particle having
fineness of about 4000-8000 cm2 /g and many a times, it even contains traces of heavy
metals.
Even as dumping of fly ash from power plants becomes a burning issue among
environmental activists, the National Capital Power Station of the NTPC has come up with
an innovative technology for commercial utilization of this by-product. Known as the dry
ash technology, it is considered environment-friendly. Normally, fly ash mixed with water
was disposed of into a nearby natural water source without segregating the heavy toxic
metals like lead and arsenic. As a result, these harmful metals find their way into the
sources of groundwater. Under the dry ash technology, the fly ash is collected in huge
mounds with a filter bed provided at the bottom of the mound, while grass is planted on
the slopes of the fly ash mounds and polymer layering is also done to prevent the ash from
being flown by the wind. Some of the fly ash, which gets mixed with rainwater, is finally
collected in a specialized lagoon at the foot of the mound. The lagoon is designed to allow
the heavier metals to settle down at the bottom while the fly ash devoid of these toxic
metals is released into the nearby water source. The NTPC officials claim that under this
treatment, the use of water and land is reduced considerably. Moreover, the fly ash treated
by this method develops certain physical properties that make them more suitable for
commercial purposes.
Fly ash mission of the Department of Science and Technology has taken a major
initiative to tackle many problems of fly ash utilization and its safe storage to minimize the
adverse impact of fly ash on environment, keeping in mind future utilization of stored
material as well as storage sites.
CHARACTERIZATION OF FLY ASH
For effective planning and execution of any program of safe disposal of fly ash or
for the use of fly ash in various applications, it is very much essential to characterise the
fly ash both physically and chemically. In addition, engineering characterisation deserves
due merit.
Chemical composition
The chemical composition of ash depends largely on the geological factors related
to the coal deposits, the composition conditions, degree of pulverization and the removal
efficiency of pollution control devices. Table 1 presents the chemical composition of fly
ash.
PERCENTAGE
49-67
16-29
4-10
1-4
0.2-2
0.1-2
0.4-0.6
2300-5700
SPECIFIC GRAVITY
2.28-2.78
USA
2.03-2.49
India
1.84-2.67
India
1.58-2.39
UK
2.10-2.24
Poland
1.90-2.31
2.60-2.80
Pond ash
Soils
As it is evident from this table, most of the coal ashes have very low values of
specific gravities. Due to this ashes have tremendous advantages in geotechnical
engineering practice such as construction of embankments, retaining walls and abutments.
D50
(mm)
Fly ash
0.0027-0.02
0.036-0.2
Pond ash
0.014-0.038
MATERIAL
Bottom ash
0.08-0.7
0.1-0.2
0.46-6.4
UNIFORMITY
COEFFICIENT
13.3-10.0
COEFFICIENT OF
CURVATURE
7.1-5.3
1.20-0.95
5.8-9.1
0.83-1.03
2.16-0.73
Atterberg Limits
The Liquid limit of fly ash (obtained from cone penetration method.) is found to
range between 43% to 49% and it is non-plastic in nature. As per the Unified
Classification system, fly ash will fit into ML group, (Sridharan, 2000).
ENGINEERING PROPERTIES
The density of ash is an important parameter since it controls its strength,
compressibility and permeability characteristics. The degree of compaction of soil/ash is
measured conventionally in terms of dry density. The compacted unit weight depends upon
the amount and method of energy application, and material properties such as grain size,
gradation, particle shape, plasticity and moisture content at compaction. The choice of the
method of compaction depends on the type of material to be densified. Coal ash is nonplastic and uniformly graded indicating a need for vibratory densification; but the fineness
of the particles also suggests that high pressure may be necessary. Fly ash compaction
might thus be expected to be a hybrid experience with fine and coarse-grained soils.
Permeability characteristics
The properties of soil or ash which permits percolation or seepage of water under
a gradient is known as permeability and coefficient of permeability is defined as the
velocity of flow which will occur through the soil or ash under a unit hydraulic gradient.
This parameter is important in designing the liner to contain leachate migration, dyke to
prevent the loss of water as well as for the stability of slopes. The range of coefficient of
permeability values for pond ash and fly ash are given in Fig 1.
CONDITION OF
PLACEMENT.
CC
Conditioned compacted
0.19-
1.0-2.0
Hydraulically placed in
0.24
dense.
Lagoons.
0.24-
0.61
2.0-3.0
Dumps.
COMMENTS.
Strength characteristics
For any engineering application of fly ash, its strength characteristics are essential.
In a general sense, strength means shear strength only. In some special uses, as in highway
engineering where the pavement section and sub grade resist repetitive point loads with
very low deformation tolerances, the composite strength-stiffness for the sub grade needs
be determined. For this, one of the most common test is the California bearing ratio (CBR)
test.
Shear strength parameters
Both total strength parameters and effective strength parameters are required in
designs. For example, in the case of dyke design, total strength parameters are required for
stability analysis during construction period or for sudden draw-down conditions whereas
the effective strength parameters are required for designing the slope for steady seepage
case and for the long term stability. Strength properties of the fly ashes get affected by
variations in density, moisture content, particle size distribution and chemical
compositions. Since the fly ash is freely draining material, effective stress parameters are
easily realized. Typical results of shear strength parameters are shown in figures 2 and 3
(Sridharan et al 1998). The friction angle of 270 to 350 is obtained for these fly ashes under
saturated conditions. Thus a minimum value of friction angle of 25 0 can be expected for
fly ashes.
California Bearing Ratio
In highway engineering, where the pavement section and sub grade have to resist
repetitive loads with very low deformation tolerance, composites stiffness parameters are
employed for the sub grade. California Bearing Ratio is more commonly used to describe
the composites strength-stiffness parameters. CBR value for fly ash varies from 6.8 to
13.5% for soaked condition and from 10.8-15.4 % for unsoaked condition as reported in
literature (Sridharan et al 1996). The low CBR value can be attributed to the decreased
effective weight and loss of surface tension. Bottom ash show substantially higher CBR
values, the CBR value of pond ash is almost in the range for bottom ash. The addition of
materials like mooram improves the CBR value. The CBR value of pond ash has been
observed to increase from 22% to 45.3% upon addition of 33% of mooram.
From the above discussion of the characteristics and properties of fly ash, it is clear
that fly ash can be used in various geo-technical applications. Some of the typical geotechnical and other applications are indicated in subsequent paragraphs (Singh et al 1999;
Shroff, 1999; Tike et al,1999; Vimal Kumar et al, 1999).
Geo-technical applications
Some of the geo-technical application of fly ash is in the field of embankment
construction, fills, sub-base, pavement and stabilization.
Embankment
Use of flyash in embankment construction not only utilizes flyash for gainful
application but also provides the following advantages:
Does not deprive the nation of the agricultural produce that would be grown on
the top soil which otherwise would have been used for embankment construction.
Some typical examples of embankments constructed using fly ash are listed below:
Delhi metro is using fly ash for landfill and embankment construction.
Fills
Fly ash, while exhibiting high capacity under compacted condition, performs very
poorly under submerged condition. Because of this, fly ash has restricted application as a
fill material (Kaushik and Ramasamy, 1999). A typical application of fly ash in fills is as
follows;
DMRC (Delhi Metro Rail Corporation) has started using fly ash for construction of
railway embankments and land filling. The DMRC has adopted the technique for
filling up land in the Shastri Park area located on ShahdaraTis Hazari sector in
New Delhi, using 950 000 cubic metres of fly ash from the Indraprastha and
Rajghat power stations mixed with soil in a predetermined ratio.
Stabilization
Following are some examples of the field construction using soil stabilized with fly
ash:
Other applications
Because of pozzoloanic nature of fly ash, it is being widely used in the construction
of various cement concrete structure as a mineral admixture. These days, fly ash is also
being used as a raw material in cement manufacturing. Fly ash has been used in foreign
countries and also in India for producing bricks. It is interesting to note that fly ash has
been proved to be an effective pesticide (Narayanswamy,1999)
In a major breakthrough in process technology, fly ash has been converted into
zeolite, a raw material for the detergent industry. The new process was developed by
NEERI in Nagpur after five years of research. It is the least expensive method of
producing zeolite, an eco-friendly alternative to chemical additives in detergents. The
Institutes process involves fusing fly ash with caustic soda in an inert reactor heated to a
high temperature in a muffle furnace. Zeolite has traditionally been extracted from
aluminium plants, a by-product of the aluminium smelting process
CONCLUSIONS
Fly ash is a by-product obtained from thermal power stations. It affects the
ecosystem of the area drastically. It pollutes air as well as water and requires a vast land
area for its disposal, the value of which cannot be compensated by money specially in a
country like India, where land population ratio is much less as compared to other
countries. Hence any project, which aims at achieving sustainable development of the
country, should consider handling this problem effectively and efficiently. This calls for a
thorough understanding of physical, chemical and engineering characteristics of fly ash.
Even though many geotechnical and other applications using fly ash are quoted in
literature, before venturing into any such applications, the engineering characterization of
the fly ash to be used is necessarily to be carried out. The result of various research
programs undertaken by premier institutions in India and abroad with regard to the
characterisation of fly ash are favourable for its mass usage in the field.
ACKNOWLEDGEMENTS
Many information presented in this paper have been collected from the Internet and
newspapers. The author acknowledges these sources gratefully. The author wish to
express special gratefulness to Dr. K. Prakash, Assistant Professor, Department of Civil
Engineering, S.J.C.E., Mysore, for his guidance.
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